Energy Balance on W1

T1= 500ᴏC
Hot Steam In

T1= 25ᴏC T2= 400ᴏC

Natural Gas In Natural Gas Out

T1= 110ᴏC
Hot Steam Out

T1 = 25ᴏC = 298 K

T2 = 400ᴏC = 673 K

QNaturalGas  QCH 4  QC2 H 6  QC3 H8  QCO2  QN 2

T2
Qi  ni 
T1
C P dT

C P, gas  A  BT  CT 2  DT 3

The following values of cp are referred in the book of Cengel in Appendix 1 Table A-2:

Component A B C D Temperature Range (K)

CH4 19.89 5.024×10-2 1.269×10-5 -11.01×10-9 273 - 1500
C2H6 6.900 17.27×10-2 -6.406×10-5 7.285×10-9 273 - 1500
C3H8 -4.04 30.48×10-2 -15.72×10-5 31.74×10-9 273 - 1500
H2O(g) 32.24 0.1923×10-2 1.055×10-5 -3.595×10-9 273 - 1800
 H2 29.11 -0.1916×10-2 0.4003×10-5 -0.8704×10-9 273 - 1800
CO 28.16 0.1675×10-2 0.5372×10-5 -2.222×10-9 273 - 1800
CO2 22.26 5.981×10-2 -3.501×10-5 7.469×10-9 273 - 1800
N2 28.90 -0.1571×10-2 0.8081×10-5 -2.873×10-9 273 - 1800

For CH4:

 19.89  5.024  10 
673
2
QCH 4  560 .9353 T  1.269  10 5 T 2  11.01  10 9 T 3 dT
298

QCH 4  9670563 .082 kJ hr

For C2H6:

 6.900  17.27  10 
673
2
QC2 H 6  18.8947 T  6.406  10 5 T 2  7.285  10 9 T 3 dT
298

QC2 H 6  537461 .3984 kJ hr

For C3H8:

  4.04  30.48  10 
673
2
QC3 H 8  1.1809 T  15.72  10 5 T 2  31.74  10 9 T 3 dT
298

QC3 H 8  48366 .07037 kJ hr

For CO2:

 22.26  5.981  10 
673
2
QCO2  8.8569 T  3.501  10 5 T 2  7.469  10 9 T 3 dT
298

QCO2  144868 .3775 kJ hr

For N2:

 28.90  0.1571  10 
673
2
Q N 2  0.5905 T  0.8081  10 5 T 2  2.873  10 9 T 3 dT
298

Q N 2  6589 .7447 kJ hr

Calculating for QNatural Gas:


Q Natural Gas   QCH 4  QC2 H 6  QC3 H 8  QCO2  Q N 2 
Q Natural Gas  9670563 .082  537461 .3984  48366 .07037  144868 .3775  6589 .7447 
Q Natural Gas  10407848 .67 kJ hr
The Cp of H2O at 500ᴏC = 2.1365 kJ / kg K

Q  mC p T
 10407848 .082  mCW 2.1365 383  773 
mCW  12490 .892 kg hr