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CHEMISTRY – HSSC 1
ALL CHAPTERS MCQS AND SHORT QUESTIONS
3) Formula that gives us information about the simplest ratio of atoms in compound
(a) structural formula (b) molecular formula
(c) empirical formula (d) molar ratio
14) The order of the rate of diffusion of gases NH3, SO2, Cl2 and CO2 is
(a)NH3 > SO2 > Cl2 > CO2 (b) NH3 > CO2 > SO2 > Cl2
(c) Cl2> SO2 > CO2 > NH3 (d) None of these
15) If absolute T of a gas is doubled and the pressure is reduced to one half the volume of gas
(a) remain unchanged (b) increases four times
(c) reduce to half (d) be double
16) At high temperature isotherm moves away from both the axis because of increase in,
(a) pressure (b) volume
(c) no. of moles (d) all above
18) Equal volumes of H2 and He are inserted in the same vessel. The P exerted are in the ratio:
(a) 1:1 (b) 2:1
(c) 1:2 (d) all above
19) If absolute temperature is doubled and the pressure is increased 4 times. The volume is
(a) half (b) double
(c) four times (d) remains the changed
22) Concept of distribution of velocities among the gas molecules was developed by
(a)Claudius (b)Maxwell
(c)Boltzman (d)Vanderwaal
23) A real gas obeying Vander Waal’s equation will resemble ideal gas if:
(a) both ‘a’ and ‘b’ are large (b) both ‘a’ and ‘b’ are small
(c) ‘a’ is small and ‘b’ is large (d) ‘a’ is large and ‘b’ is small
24) Deep sea divers breath mixture of nitrogen and oxygen in a ratio of:
(a)96% N2 and 4% O2 (b)4% and N2 and 96% O2
(c)80% N2 and 20% O2 (d) 20% N2 and 80% O2
27) The unit of the rate constant is the same as that of the rate of reaction in
(a)first order reaction (b) second order reaction
(c)zero order reaction (d) third order reaction
29) The rate of reaction between two specific time intervals is called
(a)instantaneous rate (b) average rate
(c)specific rate (d) ordinary rate
30) The sum of exponents of the conc. terms in the rate equation is called
(a)rate of reaction (b) order of reaction
(c)specific rate constant (d) average rate
31) The average rate and instantaneous rate of a reaction are equal
(a)at the start (b) at the end
(c)in the middle (d) when 2 rate have time interval = zero
34) When a reaction occurs in many steps then the slowest step is the
(a)main step (b) enthalpy determining step
(c)mechanism determining step (d) rate determining step
37) Electrolysis is the process in which a chemical reaction takes place at the expense of
(a) chemical energy (b) electrical energy
(c) heat energy (d) none of these
47) A substance which in molten state or in solution form allows electric current to pass is
(a) electrolyte (b) insulator
(c) conduction (d) none of these
49) Sodium metal is obtained by the electrolysis of fused NaCl in a cell is called
(a) Nelson’s cell (b) Down’s cell
(c) Daniell cell (d) Voltaic cell
50) The change in heat energy of a chemical reaction at constant temperature and pressure is
(a)enthalpy change (b) bond energy
(c)heat of sublimation (d) internal energy change
53) The freezing mixture used in ice cream machine consists of ice and
(a)NaCl (b) CaCl2
(c)KNO3 (d) both a & c
61) The order of the rate of diffusion of gases NH3, SO2, Cl2 and CO2 is ______
a) NH3 > SO2 > Cl2 > CO2 b) NH3 > CO2 > SO2 > Cl2
c) CO2 > NH3 > SO2 > Cl2 d) SO2 > NH3 > CO2 > Cl2
63) Which of the following molecule has zero dipole moment ________
a) NH3 b) H2O c) ChCl3 d) BF3
64) Which of the following has unpaired electrons in antibonding molecular orbital____
a) N2-2 b) O2+2 c) B2 d) F2
a) b) c) d)
73) Equal masses of methane and oxygen are mixed in an empty container at 25 oC, the fraction of
total pressure exerted by O2 is________
a) 8/9 b) 1/3 c) 1/9 d) 3/1
77) Salts which absorbs moisture from the atmosphere are called _________
a) Hydroscopic salt b) Celtic salt c) Kosher salt d) Hygroscopic salt
80) At normal boiling point of substance, the vapour pressure of the substance __________
a) Equal to 760cm of Hg b) Different for different substances
c) Equal to 760torr d) Does not have a definite value
81) If the maximum area of orbitals is shared during overlapping, it means _______
a) Maximum energy loss b) Minimum energy loss
c) Energy stays constant d) Maximum gain of energy
82) If the temperature and pressure of 2dm3 of CO2 are doubled, then volume of CO2 would
become
a) 8 dm3 b) 6 dm3 c) 4 dm3 d) 2 dm3
83) If 10g of a gas at 1atm pressure is cooled from 2730C to 0 0C at constant volume, it’s pressure
would become ______
a) 2atm b) 1atm c) ½ atm d) 273atm
Why σ2Px is not equal to π2Py, π2Pz according to molecular orbitals energy level although
they all are degenerate orbitals?
A puff of smoke weighs 0.1 gram. How many atoms are present (Assume smoke is pure
Carbon)?
Why e/m value of cathode rays is same for all gases?
Justify that the distance gap between different orbitals increases from lower to higher
orbitals?
A photon of wave number 102.70 X 105m-1 jumps from higher orbital to n = 1. Find the number
of orbit from where the electron falls?
Find the percentage composition of Nitrogen in NH2CONH2?
Why SiF4 does not show Dipole moment?
Why lone pair acquires more space as compared to bond pair?
The bond length of HBr is 1.4 x 10-10m and it’s observed dipole moment is 0.79D. Find the
percentage ionic character of the bond? (Unite positive charge 1.6022x10-19 C)
Where is the maximum probability of finding the electrons in σ and π bond?
Find the value of Ideal gas constant when units are cm3 torr mol-1 K-1?
Why water vapors do not behave ideally at 273K?
Why water boils at 120 0C in pressure cooker?
Draw a graph showing the effect of temperature on vapor pressure of Ethanol, Water, Diethyl
ether and Ethylene glycol?
Give any three uses of liquid crystals?
What type of intermolecular forces will dominate in the following liquids, NH3, C8H18 and
CH3COCH3 ?
What is Anisotropy and Allotropy?
How to get Sodium Chloride from Saline solution?
KCl (solid) and KCl (Liquid) which one of them can conduct electricity and which can not, give
your reason?
A very well known gas is enclosed in container having volume of 500 cm3 at STP, it’s mass
comes out to be 0.72g. What is the molar mass of this gas?
How many covalent bonds are present in 9g of water?
Differentiate between limiting and non limiting reactant?
How many molecules of water are there in 12 g of ice?
Define the theoretical and actual yield?
What is conversion factor?
What is the relationship between mass and volume of gas at STP?
Why actual yield is lesser than theoretical yield?
How mass of electon can be calculated from e/m ratio and charge?
How does Mosley’s Law help in the production of X-rays?
Which quantum number is also called sub shell quantum number?
What is the difference between Orbit and Orbital?
Why is 4s orbital lower in energy than 3d orbital?
What is (n+l) rule?
Differentiate between Frequency and wavelength?
State some defects of Bohr’s model?
Differentiate between Molecular Solids and metallic solids?
What is Bond Order?
Differentiate between Paramagnetism and Diamagnetism?
What is Hybridization?
Give some drawbacks of Valence Bond Theory
For What purpose Calorimeter is used?
State the Hess’s law of constant heat of summation?
What is Born-Haber cycle? What is it advantage?
Explain the term Enthalpy?
Prove that change in Enthalpy is equal to heat of reaction?
What is meant by standard enthalpy of atomization and also give example?
How many covalent bonds are present in 34 grams of ammonia(NH3) ?
[At.masses N=14,H=1]
Using Bohr’s equation calculate the distance travelled by an electron of a
Hydrogen atom when it jumps from 1st to 2nd orbit.
Write three properties of canal rays.
Describe the shape of following molecules by using VSEPR concept;
a. PH3 b. H2S
Explain sigma bond and Pi bond giving one example in each case.
What is plasma? Give its four properties.
What is vapour pressure of a liquid? Discuss the effect of temperature and
intermolecular forces on the vapour pressure.
Give two definitions of Lattice Energy with an example in each case.
Calculate pH of a Buffer solution containing 0.1 M acetic acid (CH3COOH) and 1.0
M sodium acetate (CH3COONa). The pKa for acetic acid is 4.76.
Use the concept of Hydrolysis to explain why aqueous solutions of some salts
are acidic, basic or neutral,
Define the following:
a. Average rate of reaction
b. Instantaneous rate of reaction
c. Order of reaction
The reaction given below is first order in H2 and half order in Br2 :
H2ig) + Br2(g) -> 2HBr(g)
Write rate equation (rate law) of the reaction and deduce overall order of
reaction.
Calculate the mass percent of a solution containing 10 grams of sugar and
100 grams of water.
Using Raoult’s law prove that the Relative Lowering of vapour pressure is equal
to the mole fraction of the non-volatile, non-electrolyte solute.
What is lionization energy? Why is the 1st I.E < 2nd I.E and so on?
Why does the I.E increase along the period?
Why do the boiling points of noble gases increase down the group?
Freshly cut surface of the metal is shiny. Why?
What is order of reaction? Give an example of zero order reaction?
Define Molar heat of Vaporization and Molar heat of Sublimation
Explain why heat of sublimation of a substance is greater than heat of vaporization.
State and explain Hess’s law using a general reaction.
Balance the following Redox equation by using oxidation number method:
NaCI02 + Cl2NaO + CI02