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Precipitation in the Solar

System
Gordon McIntosh, University of Minnesota–Morris, Morris, MN

A
s an astronomy instructor, I am always look- Venus Express spacecraft is currently in orbit about Ve-
ing for commonly observed Earthly experi- nus. One of the objectives of this mission is to study
ences to help my students and me under- the possible water and sulfuric acid cycles of Venus.6
stand and appreciate similar occurrences elsewhere There may also be a form of snow on Venus. Theo-
in the solar system. Recently I wrote a short TPT ries indicate that lead sulfide and/or bismuth sulfide
article on frost.1 This paper is on the related phe- snow may form in the atmosphere of Venus.7 The
nomena of precipitation. Precipitation, so common metals lead and bismuth are blasted into the atmo-
on most of the Earth’s surface as rain, snow, and sphere through volcanic eruptions and interact chemi-
other forms of water, also occurs on other bodies in cally with sulfur compounds. At high elevations,
the solar system. However, the precipitating chemical cooler than the lower surface of the planet, the sulfides
on the other bodies is rarely water, may never reach would condense out of the atmosphere and coat the
the solid surface of the body, and may even occur on mountain tops. This hypothesis is supported by radar
bodies that do not have a well-defined solid surface. studies that indicate high dielectric constant materials
For reference, the Earth has a global average of such as PbS, Bi2S3 or other heavy metal compounds
24.5 mm of precipitable water in the atmosphere.2 at higher elevations on the planet. The material could
Precipitable water is the integrated total mass of water fall as snow or be deposited as frost.1
per unit area in the atmosphere from the surface of The surface and atmosphere of Mars have been
the Earth to the top of the atmosphere. The result of studied extensively by the Mars Global Surveyor for
this calculation gives the quantity of water in units of the past 10 years. This spacecraft has discovered that
kg m-2. However, since liquid water has a well-known the south pole of Mars accumulates approximately 1.5
density, the precipitable water is usually expressed in to 2.0 m of CO2 snow, and the polar cap expands by
terms of the equivalent depth of the water. approximately a factor of 10 over the Martian winter.8
The planet Venus was studied by the Mariner 10 Due to topographical differences, the north polar
spacecraft in 1974 and by Pioneer Venus in 1978. region only accumulates 1.0 m of CO2 snow during
These studies resulted in the discovery of a precipi- its winter, and the area of the north polar cap only in-
table mass of dilute sulfuric acid with an equivalent creases slightly. As with Earth’s snow cover, Mars’ CO2
depth of 0.1 to 0.2 mm.3 Research suggests that coverage expands and contracts with its seasons. Up
although the liquid drops would evaporate before to a third of the atmospheric CO2 may be involved in
reaching the surface of the planet, precipitation is “not the annual exchange of gases and solids at the Martian
unlikely” in the atmosphere of Venus.4 Other models polar caps. It seems likely that a CO2 “snow” con-
suggest that the largest particles could generate mist denses out of the atmosphere into crystals that fall to
and drizzle if they consist of liquid spheres.5 The the surface of the planet.

502 DOI: 10.1119/1.2798364 The Physics Teacher ◆ Vol. 45, November 2007
Fig. 3. Water geyser above the surface
of Enceladus. A black and white and a
color enhanced image, also on this month‘s
cover. (Courtesy NASA/JPL/Space Science
Fig. 2. A drainage system on the Institute.)
surface of Titan thought to carry
methane to the pool in the lower
part of the image. (Courtesy NASA/
JPL/ESA/University of Arizona.)

Fig. 1. A lava field on Io. The older


surface (upper right) is thought
colorful surface of this world (see Fig. 1). The SO2
to be streaked with SO2 snow. “falls to the ground as frozen particles or crystals, like
(Courtesy NASA/JPL-Caltech.) snowflakes.”14
The gas giant planet Saturn is hypothesized to have
The CO2 snow crystals would not be the beautiful a region in its atmosphere where helium condenses
six-pointed dendritic snow crystals that fall to Earth as from the gas to the liquid state and falls to a lower
water snow. The CO2 crystals would be octahedrons9 level of the planet. This condensation occurs at certain
or a cubeoctahedron.10 It is likely that various condi- pressures and temperatures at which the helium is
tions under which the CO2 snow forms will affect the immiscible in the liquid metallic hydrogen that domi-
crystal structure, just as Earthly snow can have a vari- nates the planetary material in these regions. This
ety of structures depending on the physical conditions phase separation leads to droplets of helium that drop
during formation. as rain through the liquid metallic hydrogen until
A direct buildup of CO2 frost on the surface is also they reach a warmer region where they again dissolve
probable.1 The frost and snow then sublimates during in the hydrogen. The effect would be to reduce the
the subsequent spring and summer, and the cycle is helium in the upper region, enrich the helium in the
repeated during the Martian year. lower region, and convert gravitational potential en-
Water rain may have played a part in the surface ergy to thermal energy. This energy conversion warms
history of Mars. Large-scale features shown in intro- the planet and may play an important role in the ther-
ductory astronomy texts 11 are usually used to support mal development of extra-solar giant planets as well as
the hypothesis of flowing water on the surface. Recent Saturn. The heat generated in this process is thought
observations indicate that water may still flow on the to be partially responsible for the fact that Saturn radi-
surface,12 but no current water precipitation has been ates away more energy than it receives from the Sun.
suggested. Present results indicate only 20 microns of Thermal studies of Saturn indicate that this helium
precipitable water in the Martian atmosphere.13 rain may have been forming and falling for three bil-
The sulfur volcanoes of Io, a satellite of Jupiter, lion years!15 The conditions on Jupiter, although simi-
blast large quantities of the material into the space lar, are not thought to reach the necessary temperature
around the body. The sulfur reacts with other chemi- and pressure for the helium-liquid metallic hydrogen
cals including oxygen to form SO2. This compound phase separation to occur.
condenses to a crystalline structure in the atmosphere Titan, the largest satellite of Saturn, has recently
of the body and then falls to the surface of Io. This been observed in great detail by the Cassini and Huy-
sulfur compound and others form the well-known gens spacecrafts. One of the discoveries when the Huy-

The Physics Teacher ◆ Vol. 45, November 2007 503


Table I. Materials that are suggested or observed to precipi- thin atmosphere may go through a cycle of conden-
tate on various solar system bodies.
sation and sublimation.22 This cycle of nitrogen
Solar System Precipitation References between the atmosphere and surface of the body oc-
Body curs because of Pluto’s large obliquity, or tilt of the
Venus H2SO4, PbS, Bi2S3 3, 4, 5, 7
rotation axis. The large obliquity causes a temperature
difference between the poles. The sunlit pole is warm
Mars CO2, (H2O in past) 8
enough (50-60 K) for nitrogen to sublime, and the
Io SO2 14
dark pole is cold enough (25-40 K) for nitrogen to
Saturn He 15
condense out of the atmosphere as snow or onto the
Titan CH4 16 surface as frost. Other trans-Neptunian objects such as
Enceladus H 2O 18 Xena and Sedna may have nitrogen atmospheres that
Triton N2 20,21 experience a similar cycle of condensation and subli-
Pluto N2 22 mation.23
The precipitation described above and listed in
gens spacecraft descended to the surface of Titan was Table I has a number of effects on the physical proper-
the existence of a drainage network (Fig. 2).16 This ties of these solar system bodies. Snow of various types
network is thought to carry methane precipitation to increases the albedo of the body, which will affect the
large pools or seas. Methane is a small constituent of surface temperature. The seasonal temperature varia-
the mainly nitrogen atmosphere. As a result of this tions of Mars are buffered by latent heat of condensa-
precipitation, hydrocarbon lakes are thought to exist tion and sublimation of CO2. The present tempera-
on the surface of Titan.17 If these lakes are shown to ture of Saturn has been increased by the condensation
exist, Titan will be only the second body in the solar and precipitation of helium in the planet. And the
system after Earth to possess such surface bodies of physical surface of a body is altered by precipitating
liquids. materials collecting and flowing on the surface. Exam-
Images of Enceladus, another satellite of Saturn, ples are the gullies carved on Titan by flowing methane
show a spray of liquid or fine icy particles that ema- and on Mars by flowing water.
nate from vents at the surface of the body (Fig. 3).
These vents are observed in the south polar region of Acknowledgment
the body, distinguished by its “tiger stripe” appear- Thanks to a very knowledgeable reviewer for a num-
ance.18 The icy particles fall back to the surface. This ber of useful comments.
fresh snow cover may explain the bright regions be-
tween the darker stripes. The energy source for these References
hydrothermal geysers is not yet known. Tidal heating 1. G. McIntosh, “Frost in the solar system,” Phys. Teach.
or radioactive decays may provide the energy neces- 44, 226–227 (April 2006).
sary to liquefy and pressurize the subsurface water.19 2. David Randel et al., “A new global water vapor dataset,”
Triton, the largest satellite of Neptune, also has Bull. Am. Meteorol. Soc. 77 (June 1996); http://www1.
geyser-like plumes that expel gas and liquids into cira.colostate.edu/climate/NVAP/bulletin.htm.
the atmosphere of the body.20 It is thought that dark 3. R. Knollenberg and D. Hunten, “Clouds of Venus: Par-
subsurface particles containing carbon compounds ticle size distribution measurements,” Sci. 203, 792–795
(Feb.1979).
absorb sunlight, raising the temperature and vapor-
izing the surrounding nitrogen. The high pressure gas 4. J.B.Cimino and C. Elachi, “Precipitation on Venus:
Properties and possibilities of detection,” J. Atmos. Sci.
then vents through cracks in the surface and carries
36, 1168–1177 (July 1979).
the dark particles aloft. The return of this material to
5. R. Knollenberg, L. Travis, M. Tomasko, P. Smith, B.
the surface may account for the dark streaks of mate-
Ragent, L. Esposito, D. McCleese, J. Martonchik, and
rial observed on the surface of this body. A seasonal R. Beer, “The clouds of Venus: A synthesis report,” J.
“snowfall” of N2 ice may also occur on Triton.21 Geophys. Res. 85, 8059–8081 (1980).
It is even speculated that the nitrogen in Pluto’s 6. European Space Agency, Venus Express; http://www.esa.

504 The Physics Teacher ◆ Vol. 45, November 2007


int/SPECIALS/Venus_Express/SEML26808BE_0. 17. NASA Jet Propulsion Laboratory, “Planetary photo-
html. journal”; http://photojournal.jpl.nasa.gov/catalog/
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10. The Exploratorium, “Journey to Mars”; http://www. covery and basic characterization,” Sci. 250, 410 (Oct.
exploratorium.edu/mars/snowflakes.html. 1990).
11. For example, A. Fraknoi, D. Morrison, and S. Wolff, 21. J. Pollack, J. Schwartz, and K. Rages, “Scatterers in Tri-
Voyages to the Planets, 3rd ed. (Thompson Brooks/Cole, ton’s atmosphere: Implications for the seasonal volatile
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gest water still flows in brief spurts on Mars”; http:// Pluto,” Icarus 120, 247 (April 1996).
mpfwww.jpl.nasa.gov/mgs/newsroom/20061206b. 23. C. Hansen and D. Paige, “Seasonal behavior of nitro-
html. gen atmospheres on trans-Neptunian objects,” Ameri-
13. Bruce Jakosky and Michael Mellon, “Water on Mars,” can Astronomical Society, DPS Meeting #38, Presenta-
Phys. Today 57, 71 (April 2004); http://www.physics tion #44.09 (2006).
today.org/vol-57/iss-4/p71.html. PACS code: 95.00.00
14. P. Geissler, “Volcanic activity on Io during the Galileo
era,” Annu. Rev. Earth Pl. Sci. 31 (1), 175 (2003). Gordon McIntosh is a professor of physics at the
15. J. Fortney and W. Hubbard, “Effects of helium phase University of Minnesota, Morris. He enjoys teaching a
variety of physics and astronomy courses and carrying out
separation on the evolution of extrasolar giant planets,” research in radio astronomy.
Astrophys. J. 608, 1039 (June 2004).
Division of Science and Mathematics, University
16. M. Tomasko et al., “Rain, winds, and haze during the of Minnesota, Morris, Morris, MN 56267;
Huygens Probe’s descent to Titan’s surface,” Nature mcintogc@morris.umn.edu
438, 765 (Dec. 2005).

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