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2019_Apr_Jee-Main Question Paper_Key & Solutions
2019_Jee-Main Question Paper_Key & Solutions
PHYSICS
1. A damped harmonic oscillator has a frequency of 5 oscillations per second. The
amplitude drops to half its value for every 10 oscillations. The time it will take to
1
dropto of the original amplitude is close to:
1000
1) 50 s 2) 100 s 3) 20 s 4) 10 s
Ans: 3
1
Sol: T  sec
5
t1/2  2sec
A
for approx. time = 20 sec
210
2. A cell of internal resistance r drives current through an external resistance R. The
power delivered by the cell to the external resistance will be maximum when:
1) R = 1000 r 2) R = r 3) R = 2r 4) R = 0.001 r
Ans: 2
Sol: Power maximum when R=r.
3. A uniform rectangular thin sheet ABCD of mass M has length a and breadth b, as
shown in the figure. If the shaded portion HBGO is cut–off, the coordinates of the
centre of mass of the remaining portion will be
 2a 2b   5a 5b   3a 3b   5a 5b 
1)  ,  2)  ,  3)  ,  4)  , 
 3 3   12 12   4 4   3 3 
Ans: 2
  
Sol: m1 r1  m2 r2  M rcm  
M  3a  3b   3M  a  b 
 i  j   r  M  i  j 
4 4 4  4 2 2 2 
3M   a 3a    b 3b  
r     i     j
4 2  2 16   2 16 
5a  5b 
 i j
16 16
Sri Chaitanya IIT Academy

# 304, Kasetty Hegihts, Ayappa Society, Madhapur, Hyderabad – 500081
 www. srichaitanya.net,  iconcohyd@srichaitanyacollege.net
 5a  5b 
r2  i  j
12 12
4. In a line of sight radio communication, a distance of about 50 km is kept between
the transmitting and receiving antennas. If the height of the receiving antenna is 70
m, then the minimum height of the transmitting antenna should be:
(Radius of the Earth = 6.4 10 m )
6
1) 51 m 2) 20 m 3) 40 m 4) 32 m
Ans: 4
Sol: 2 RhT  2 RhR  50km
 hT  25m
5. In a simple pendulum experiment for determination of acceleration due to gravity
(g), time taken for 20 oscillations is measured by using a watch of 1 second least
count. The mean value of time taken comes out to be 30 s. The length of pendulum is
measured by using a meter scale of least count 1 mm and the value obtained is
55.0 cm. The percentage error in the determination of g is close to:
1) 6.8% 2) 0.2% 3) 3.5% 4) 0.7%
Ans: 1
dg dT dl
Sol: 2 
g T l
dg 1 101
 2 
g 30 55
200 10
%   6.66  0.18  6.8%
30 55
6. A parallel plate capacitor has 1 F capacitance. One of its two plates is given 2C
charge and the other plate, 4C charge. The potential difference developed across
the capacitor is:
1) 1 V 2) 5 V 3) 3 V 4) 2 V
Ans: 1
Q 1
Sol: V    1V
C 1
7. Two magnetic dipoles X and Y are placed at a separation d, with their axes
perpendicular to each ot.her. The dipole moment 0f Y is twice that of X. A particle

of charge q is passing through their mid–point P, at angle  = 45° with the

horizontal line, as shown in figure. What would be the magnitude of force on the
particleat that instant ? (d is much larger than the dimensions of the dipole)
   2M
1) 0 2)  0   q
 4   d 3
 
 2 
   2M   M
3) 2  0   q 4)  0   q
 4   d 3  4   d 3
   
 2   2 
Ans: 1
20 M
Sol: B1 
4  d / 2
3
20 M
B2 
4 d / 2
3
   

Force = q V  B  0    V || B 
8. A solid sphere and solid cylinder of identical radii approach an incline with the
same linear velocity (see figure). Both roll without slipping all throughout. The two
h
climb maximum heights hsph and hcyl on the incline. The ratio sph is given by:
hcyl
4 2 14
1) 1 2) 3) 4)
5 5 15
Ans: 4
2
Sol: Toal K.E. =  I cm  M R  2
1 2 V
2 R
12 
K .E.sph    1 mV 2
2  5 
11 
K .E.cy    1 mV 2
2  2 
hsph K .E.sph 7 / 5 14
  
hcy K .E.cy 3 / 2 15
9. A nucleus A, with a finite de–broglie wavelength A , undergoes spontaneous fission
into two nuclei B and C of equal mass. B flies in the same direction as that of A,
while C flies in the opposite direction with a velocity equal to half of that of B. The
de–Broglie wavelengths B and C of B and C are respectively :
A A
1) 2A , A 2) A ,2 A 3) A , 4) , A
2 2
Ans: 4
   h h h 
Sol: PA  PB  PC     2  A  3  A
 A 2 22 2
10. The temperature, at which the root mean square velocity of hydrogen molecules
equals their escape velocity from the earth, is closest to:
[Boltzmann Constant kB =1.38 X 10–23 J/K
Avogadro Number NA = 6.02 X 1026 /kg
Radius of Earth : 6.4 X 106 m
Gravitational acceleration on Earth = 10 ms–2]
1) 650 K 2) 104 K 3) 3 X 105 K 4) 800 K
Ans: 2
(But according to given data in the question no answer, avogadro number is given
wrong )
3RT
Sol:  2 gR
M
25
3 T
3  2 10  6.4 106  T  104 K
3
2 10

11. A circuit connected to an ac source of emf e  e0 sin 100t  with t in seconds, gives a

phase difference of between the emf e and current i. Which of the following
4
circuits will exhibit this ?
1) RC circuit with R=1 k  and C=10  F
2) RL circuit with R=1 k  and L=10 mH
3) RC circuit with R= 1 k  . and C = 1  F
4) RL circuit with R=1 k  and L=1mH
Ans: 1
1
Sol: R
C
1
RC   103

12. Young’s moduli of two wires A and B are in the ratio 7:4. Wire A is 2m long and has
radius R. Wire B is 1.5 m long and has radius 2 mm. If the two wires stretch by the
same length for a given load, then the value of R is close to :
1) 1.7 mm 2) 1.3 mm 3) 1.5 mm 4) 1.9 mm
Ans: 1
e
Sol: F  YA
l
F
 cons tan t
e
YA
 cons tan t
l
Y1 A1 l1
 
Y2 A2 l2
7 R2 22 4 4 4
 2   R2   R  1.7 mm
4 2 3 73

13. A body of mass m1 moving with an unknown velocity of v1 i , undergoes a collinear

collision with a body of mass m2 moving with a velocity v2 i . After collision, m1 and
 
m2 move with velocities of v3 i and v4 i , respectively. If m2=0.5 m1 and v3 =0.5 v1 ,
then v1 is:
v2 v2
1) v4  2) v4  v2 3) v4  4) v4  v2
2 4
Ans: 4
   
Sol: m1 v1  m2 v2  m1 v3  m2 v4 2m2  m1 and Let m2  m
2mv1  mv2  2m0.5v1   mv4  v1  v4  v2
14. A particle starts from origin O from rest and moves with a uniform acceleration
along the positive x– axis. Identify all figures that correctly represent the motion
qualitatively. (a = acceleration,  = velocity, x = displacement, t = time)
A) B) C) D)
1) ABC 2) ABD 3) BC 4) A
Ans: 2
Sol: a=constant
V = at
1
S  at 2
2
15. A positive point charge is released from rest at a distance ro from a positive line
charge with uniform density. The speed (  ) of the point charge, as a function of
instantaneous distance r from line charge, is proportional to :
 r  r r
2) v    3) v  ln  
   r / r0
1) v  ln 4) v  e
 r   r   r 
0 0 0
Ans: 1
r  
 
r
Sol: E  V   E.d r   dr
2 0 r r r
2   0 r
0 0
  r  1 2  r 
V  ln    2 V  mu  u  V  u  ln  
 
2 0  r0  2  r 
0
 
16. The electric field in a region is given by E   Ax  B  i , where E is in NC–1 and x is
in metres. The values of constants are A=20 SI unit and B=10 SI unit. If the
potential at x=1 isV1 and that at x= –5 is V2, then V1 –V2is:

1) 320 V 2) –520 V 3) 180 V 4) –48 V

Ans: 3
 
Sol: V   E.dxi
1
V1 V2    Ax  B dx
5
5
Ax
2 
  Bx 
2 
1
 
 105  50  10  10  200  20  180V
2
17. The ratio of mass densities of nuclei of 40 Ca and 16 O is close to:

1) 0.1 2) 1 3) 2 4) 5
Ans: 2
Sol: Radius of the nucleus is given by R  R0 A So, Density constant
1/3
       

 
18. Let A1  3, A2  5 and A1  A2  5 . The value of 2 A1  3 A2 . 3 A1  2 A2 is: 
1) –106.5 2) –112.5 3) –99.5 4) –118.5
Ans: 4
     
   
Sol: A1  A2 . A1  A2  25  9  25  2 A1. A2  25 
  9
A1. A2 
2
  9
 6 A12  6 A22  5 A1. A2  6 9  6  25  5
2
= – 69 + (–22.5) = – 118.5
19. Two very long, straight, and insulated wires are kept at 90° angle from each other in
xy–plane as shown in the figure.
These wires carry currents of equal magnitude I, whose directions are shown in the
figure. The net magnetic field at point P will be:

1)
2 d  
0 I  
x y 2) zero 3) 
2d  
0 I  
x y 4)
0 I 
d
z
Ans: 2
  I     I  
Sol:
 2d   
B1   0  K  B2   0  K  B p  0
 2d   
20. A common emitter amplifier circuit, built using an npn transistor, is shown in the
figure. Its dc current gain is 250, RC  1 k and VCC = 10V. What is the minimum
base current for VCE to reach saturation?
1) 7  A 2) 40  A 3) 10  A 4) 100  A
Ans: 2
10 10mA
Sol: O  Vcc  I c RL  I c  3
 10mA  I B   40 A
10 250
21. If Surface tension (S), Moment of Inertia (I) and Planck's constant (h), were to be
taken as the fundamental units, the dimensional formula for Linear momentum
would be:
1) S 3/2 I 1/2 h 0 2) S 1/2 I 1/2 h1 3) S 1/2 I 3/2 h1 4) S 1/2 I 1/2 h 0
Ans: 4
PS I h
a b c
Sol:
1 1
  MT  ML  ML T 
a b c
1 2 1
MLT 2 2
 P  S I h0
2 2
22. An electric dipole is formed by two equal and opposite charges q with separation d.
The charges have same mass m. It is kept in a uniform electric field E. If it is slightly
rotated from its equilibrium orientation, then its angular frequency  is :
2qE qE qE qE
1) 2) 2 3) 4)
md md md 2 md
Ans: 1
  
Sol: T  P  E
  d 2 
2m    qd  E sin    
2qEd 2qE
 
  2  
2
md md
23. A rocket has to be launched from earth in such a way that it never returns. If E is
the minimum energy delivered by the rocket launcher, what should be the mjnimum
energy that the launcher should have if the same rocket is to be launched from the
surface of the moon ? Assume that the density of the earth and the moon are equal
and that the earth's volume is 64 times the volume of the moon.
E E E E
1) 2) 3) 4)
16 32 64 4
Ans: 1
4 
G   R 3  m
GMm 3 
Sol: E  E  E  R2
R R
E2  R2 
2
 1 
2
 E
    E2    E 
E  R   4  16
1 1
24. A convex lens (of focal length 20 cm) and a concave mirror, having their principal
axes along the same lines, are kept 80 cm apart from each other. The concave
mirror is to the right of the convex lens. When an object is kept at a distance of 30
cm to the left of the convex lens, its image remains at the same position even if the
concave mirror is removed. The maximum distance of the object for which this
concave mirror, by itself would produce a virtual image would be
1) 10 cm 2) 20 cm 3) 30 cm 4) 25 cm
Ans: 1
1 1 1 1 1 1
Sol:       V  60cm
V 30 20 V 20 30
Focal length of concave mirror is 10cm
25. In the circuit shown, a four–wire potentiometer is made of a 400 cm long wire,
which extends between A and B. The resistance per unit length of the potentiometer
wire is r= 0.01  /cm If an ideal voltmeter is connected as shown with jockey J at 50
cm from end A, the expected reading of the voltmeter will be:

1) 0.50 V 2) 0.75 V 3) 0.20 V 4) 0.25 V

Ans: 4
Sol: Total resistance of potentiometer wire is 4 
4
Total potential drop across wire is 3V  2V
6
For 50cm voltmeter reading
50 1
 2   0.25V
400 4
26. A rectangular solid box of length 0.3 m is held horizontally, with one of its sides on
the edge of a platform of height 5 m. When released, it slips off the table in a very
short time  =0.01 s, remaining essentially horizontal. The angle by which it would
rotate when it hits the ground will be (in radians) close to
1) 0.02 2) 0.3 3) 0.28 4) 0.5

Ans: 4
l ml 2 3g 310
Sol: mg       50rad / sec 2
2 3 2l 2  0.31
  50 0.01  0.5rad / sec
2h 2 5
t   1sec
g 10
  t  0.5rad

27. Calculate the limit of resolution of a telescope objective having a diameter of 200cm,
if it has to detect Light of wavelmgth 500 nm coming from a star.
9 9
1) 152.510 radian 2) 457.510 radian
9 9
3) 305 10 radian 4) 610 10 radian
Ans: 3
1.22 1.22  500109
Sol:    2
 305109 rad
D 200 10
28. In the figure shown, what is the current (in Ampere) drawn from the battery? You
are given:
R1  15 , R2  10, R3  20, R4  5, R5  25, R6  30 , E  15V
1) 7/18 2) 20/3 3) 9/32 4) 13/24

Ans: 3
160
Sol: Reff =
3
15 3 9
Current I   A
160 32
29. The magnetic field of an electromagnetic wave is given by:

 
  Wb
B  1.6 106 cos 2 107 z  6 1015 t  2 i  j 2
m
The associated electric field will be:

 
  V
1) E  4.8 102 cos2 107 z  6 1015 t  i  2 j
m

 
  V
2) E  4.8102 cos 2 107 z  6 1015 t  2 j i
m

 
  V
3) E  4.8 102 cos2 107 z  6 1015 t  2 i  j
m

 
  V
4) E  4.8 102 cos2 107 z  6 1015 t   i  2 j
m
Ans: 4
1.6 106
Sol: E0  B0C   3108
5
4.8 102
 V/m
5

 
  V
E  4.8 102 cos2 107 z  6 1015 t   i  2 j
m
30. The given diagram shows four processes i.e., isochoric, isobaric, isothermal and
adiabatic. The correct assignment of the processes, in the same order is given by:
1) dabc 2) adbc 3) dacb 4) adcb

Ans: 1
PV  constant
n
Sol:
If n = 0, isobaric
n = 1 isothermal
n   adiabatic
n   isochoric

CHEMISTRY
31. The maximum prescribed concentration of copper in drinkmg water is :
1) 0.5 ppm 2) 3 ppm 3) 0.05 ppm 4) 5 ppm
Ans: 2
Sol: Fact. NCERT Pg No.408.
32. The major product obtained in the following reaction is
NH2
(i)CHCl3/NaOH
CH3 (ii)Pd/C/H2
CN O
NHCH3
NHCH3
CH3
1) 2) CH3
OH CN O
H2N
NHCHCl2 NHCH3
3) CH3 4) CH3
CN OH CN OH
Ans: 1
NH2 NC NHCH3
(i)CHCl3/NaOH (ii)Pd/C/H2
CH3 CH3 CH3
CN O CN O OH
Sol: H2N
33. Fructose and glucose can be distinguished by :

1) Barfoed’s test 2) Benedict's test
3) Seliwanoff’s test 4) Fehling’s test
Ans: 3
Sol: Barfoed's test: Positive for Fructose and glucose.
Seliwanoff’s test: Positive for Fructose and negative for glucose.
Benedict’s test: Positive for Fructose and glucose.
Fehling’s test: Positive for Fructose and glucose.
34. The structure of Nylon–6 is:
O O
1) (CH2)6 C NH 2) C (CH2)6 NH
n n

O O
3) C (CH2)5 NH 4) (CH2)4 C NH
n n
Ans: 3
O
Nylon-6: C (CH2)5 NH
Sol: n
35. The covalent alkaline earth metal halide (X = Cl, Br, I) is :
1) MgX2 2) BeX2 3) CaX2 4) SrX2
Ans: 2
Sol: Beryllium halides are covalent due to more polarizing power of small Be2+ ion with
more charge density.
36. 0.27 g of a long chain fatty acid was dissolved in 100 cm3 of hexane. 10 mL of this
solution was added dropwise to the surface of water in a round watch glass. Hexane
evaporates and a monolayer is formed. The distance from edge to centre of the
watch glass is 10 cm. What is the height of the monolayer ?
3
[Density of fatty acid = 0.9 g cm ;   3 ]
1) 106 m 2) 102 m 3) 104 m 4) 108 m
Ans: 1
m
Sol: d 
v
0.027 in 10 ml
0.9 
310  h
2
0.027
Height of the layer   104 cm  106 m .
0.9  3100
37. For the following reactions, equilibrium constans are given:
S  s   O2  g   SO2  g ; K1  10
52
2S  s   3O2  g   2SO3  g ; K 2  10129

The equilibrium constant for the reaction,
2SO2  g   O2  g   2SO3  g 
1) 10181 2) 1077 3) 10154 4) 1025
Ans: 4
S  s   O2  g   SO2  g ; K1  10
52
Sol:
2S  s   3O2  g   2SO3  g ; K 2  10129
K2
Keq for 2SO2  g   O2  g   2SO3  g  is given by the relation K eq  2
 1025 .
K1
38. The correct statement about ICl5 and ICl4 is:

1) ICl5 is trigonal bipyramidal and ICl4 is tetrahedral

2) ICl5 is square pyramidal and ICl4 is tetrahedral
3) both are isostructural

4) ICl5 is square pyramidal and ICl4 is square planar.
Ans: 4
Sol: ICl5 have 4 B.P and 1 L.P. It is square pyramidal. ICl4 have 4 B.P. and 2 L.P. The
two L.P occupy opposite corners of octahedral. So it square planar.
39. The major product of the following reaction is:
CH3
O
H3C (1)t-BuOK
Cl (2)Conc.H2SO4/Δ
O CH3
H3C
1) 2) O
H3C CH3 CH3
CH3 O
O
3) H3C 4)
CH3
H3C CH3
Ans: 3
Sol:
CH3 CH3
O O
H3C (1)t-BuOK H C
3
Cl
H2C
(2)Conc.H2SO4/Δ
CH3
O
H3C

40. The compound that inhibits the growth of tumors is:

1) trans   Pt Cl 2  NH 3 2  2) trans   Pd Cl 2  NH 3 2 
3) cis   Pd Cl 2  NH 3 2  4) cis   Pt Cl 2  NH 3 2 
Ans: 4
Sol: cis–platini is used as anti–tumer agent.
41. For a reaction scheme A  k1
 B 
k2
 C , if the rate of formation of B is set to be
zero then the concentration of B is given by:
k 
1) k1  k2  A 2) k1  k2  A 3)  1  A 4) k1k2  A
 k 
2
Ans: 3
d B K
Sol:  0  K1  A  K 2  B    B   1  A
dt K2
42. Among the following molecules/ ions,
2 2 2
C2 , N 2 , O2 , O2
Which one is diamagnetic and has the shortest bond length?
2 2 2
1) O2 2) C2 3) N 2 4) O2
Ans: 2
2 2
Sol: Bond order C2– = 3; N 2 =2; O2 =1 and O2 = 2.
2
C2 is diamagnetic since all electrons are paired and have shortest bond length due
to triple bond.
43. The major product of the following reaction is:
CH3
(1)Cl2/hν
(2)H2O,Δ
Cl
CH2OH CHCl2 CHO COOH
1) Cl 2) Cl 3) Cl 4) Cl
Ans: 3

CH3 CHO
(1)Cl2/hν
(2)H2O,Δ
Sol: Cl Cl
44. Calculate the standard cell potential (in V) of the cell in which following reaction
takes place :
Fe aq   Ag aq  Fe aq   Ag s 
2  3
Given that
E Ag  / Ag  xV
0
EFe2 / Fe  yV
0
EFe3 / Fe  zV
0
1) x  y 2) x  z 3) x  2 y  3 z 4) x  y  z
Ans: 3
Fe aq   Ag aq  Fe aq   Ag s 
2  3
Sol:
E o  EFe
o
2
/ Fe
3  E
o

Ag / Ag
Fe 
 Fe2  Fe3

 yV

 zv
3 z  2 y  EFe
o
2
/ Fe
3
3  2 y  3 z
o
EFe 2
/ Fe
E o  x  2 y  3z
45. The major product in the following reaction is:
NH2
N
N Base
+ CH3I
N N
H
NH2 NH2
NH2 NHCH3
N N
+ N N
N N
NCH3 N
N +
N N N
N N H N N
1) H 2)H3C 3) CH3 4) H

Ans: 3
NH2 NH2
N N
N N
Base
+ CH3I
N N N +
H N
H
Sol: CH3
46. The major product obtained in the following reaction is:
CH3 O
NaOH
OHC CH3
Δ
CH3
1) 2) H3C
OHC
H3C CH2
O
CH3
3) 4) H3C
OHC
H3C CH3
O
Ans: 3
Sol: Intramolecular aldol condensation
CH3
CH3 O
NaOH
OHC CH3
Δ
H3C
O
47. Which one of the following alkenes when treated with HCl yields majority an anti
Maxkovnikov product?
1) CH 3O  CH  CH 2 2) Cl  CH  CH 2
3) F3C  CH  CH 2 4) H 2 N  CH  CH 2
Ans: 3
Sol:

Cl
HCl
H3CO CH CH2 H3CO CH CH3 Markonikov's product
HCl
F3C CH CH2 F3C CH2 CH2 Anti markonikov's product
Cl
Cl
HCl
Cl CH CH2 Cl CH CH3 Markonikov's product
Cl
HCl
H2N CH CH2 H2N CH CH3 Markonikov's product
48. The calculated spin–only magnetic moments (BM) of the anionic and cationic
species of [Fe(H2O)6]2 and [Fe(CN)6], respectively, are :
1) 4.9 and 0 2) 2.84 and 5.92 3) 0 and 5.92 4) 0 and 4.9
Ans: 1
Sol: The compound containing [Fe(H2O)6]2 cation and [Fe(CN)6] anion must be
[Fe(H2O)6]2 [Fe(CN)6]. It contains 2[Fe(H2O)6]2+ cation and [Fe(CN)6]4– anion in
which Iron is present as Fe2+ ion. In [Fe(H2O)6]2+ since H2O is weak ligand there will
be 4 unpaired electrons with 4.9 BM while in [Fe(CN)6]4– all the electrons are paired
as the CN– is strong ligand with zero unpaired electrons and zero magnetic moment.
49. The IUPAC symbol for the element with atomic number 119 would be:
1) uun 2) uue 3) unh 4) une
Ans: 2
Sol: For 1 the abreviation is U (from unium) and for 9 is e (from enneium). So the
IUPAC symbol is uue.
50. The percentage composition of carbon by mole in methane is :
1) 20% 2) 25% 3) 75% 4) 80%
Ans: 1
1
Sol: % of C by mole = 100  20%
5
51. The Mond process is used for the:
1) extraction of Zn 2) purification of Ni
3) purification of Zr and Ti 4) extraction of Mo
Ans: 2
Sol: Nickel is purified by Mond’s process using the formation of unstable volatile
compound. Ni(CO)4.
52. The statement that is INCORRECT about the interstitial compounds is :

1) they are chemically reactive 2) they have metallic conductivity
3) they have high melting points 4) they are very hard
Ans: 1
Sol: They are relatively non reactive
53. Polysubstitution is a major drawback in
1) Friedel Craf t’ s alkylation 2) Reimer Tiemann reaction
3) FriedelCraft's acylation 4) Acetylation of aniline
Ans: 1
Sol: Polyalkylation – Products of Friedel–Crafts are even more reactive than starting
material. Alkyl groups produced in Friedel–Crafts Alkylation are electron–donating
substituents meaning that the products are more susceptible to electrophilic attack
than reactant.
54. For the solution of the gases w, x, y and z in water at 298 K, the Henrys law
constants
(KH) are 0.5, 2, 35 and 40 kbar, respectively. The correct plot for the given data is :
1) 2)
3) 4)
Ans: 2
Sol: KH for w, x, y, z are 0.5, 2, 35 & 40.
P  KH X
P  K H 1  X water 
P  K H  K H X water  y  c  mx
KH values increases in the order z > y > x > w.

55. Consider the bcc unit cells of the solids 1 and 2 with the position of atoms as shown
below. The radius of atom B is twice that of atom A. The unit cell edge length is 50%
more in solid 2 than in 1. What is the approximate packing efficiency in solid 2?
1) 75% 2) 65% 3) 45% 4) 90%

Ans: 4
Sol: 3a  2r  4r  6r
a  2 3r
4 3 4
r    2r 
3
3 3 4 9r 3
Packing fraction =   0.90
a3 3  8  3 3r
3
i.e. 90% is the packed in the solid B

56. 5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till
its temperature becomes 200 K. If CV = 28 J K–1 mol–1, calcuIate  U and  PV for
this process. ( R  8.0 JK 1 mol1 )
1) U  14 kJ ;  pV   18 kJ 2) U  14 J ;  pV   0.8 J
3) U  14 kJ ;  pV   4 kJ 4) U  2.8 kJ ;  pV   0.8 kJ
Ans: 3
Sol: U  28  5 100  14kJ
 pV   p2v2  p1v1  nR T2  T1 
 5  8.314 100  4 kJ
57. The ion that has sp3d2 hybridization for the central atom, is:
   
1)  ICl4  2)  ICl2  3)  IF6  4)  BrF2 
Ans: 1

Sol: ICl4 have 4 B.P. and 2 L.P (steric number 6). So central atom is involved in sp3d2
hybridization.

58. If p is the momentum of the fastest electron ejected from a metal surface after the
irradiation of light having wavelength  , then for 1.5 p momentum of the
photoelectron, the wavelength of the light should be:
(Assume kinetic energy of ejected photoelectron to be very high in comparison to
work function) :
2 4 3 1
1)  2)  3)  4) 
3 9 4 2
Ans: 2
Sol: W0 is too small in comparision to K.E.
P2
KE 
2m
hc P 2

 2m
2
hc 2 P
 1.5
N 2m
N 1

 1.5
2
4
N  
9
59. Which of the following compounds will show the maximum ‘enol’ content ?
1) CH 3COCH 2COOC2 H 5 2) CH 3COCH 2CONH 2
3) CH 3COCH 2COCH 3 4) CH3COCH3
Ans: 3
Sol:
CH3COCH2COOC2H5 % enol = 0.00025
CH3COCH2CONH2 % enol = <7.5

CH3COCH2COCH3 % enol = 72
CH3COCH3 % enol = 0.00025
60. The strength of 11.2 volume solution of H2O2 is:
[Given that molar mass of H=1 g mol–1 and O=16 g mol–1]
1) 1.7% 2) 34% 3) 13.6% 4) 3.4%
Ans: 4
Sol: 1M = 2N = 3.4% w/v = 11.2 vol.

MATHEMATICS
61. The tangent and the normal lines at the point  
3,1 to the circle x 2  y 2  4 and the
x–axis form a triangle. The area of this triangle (in square units) is:
2 1 1 4
1) 2) 3) 4)
3 3 3 3
Ans: 1
1 4 1 2
Sol:   .2. . 
2 3 2 3
         
62. Let a  3 i  2 j x k and b  i  j  k , for some real x. Then a  b  r is possible if :
3 3 3 3 3 3
1) 0  r  2) r 3 3) 3 r 5 4) r  5
2 2 2 2 2 2
Ans: 4
r  2  x   3  x  25  2 x 2  2 x  38
2 2
Sol:
5 3

2
63. If three distinct numbers a, b, c are in G.P. and the equations ax2 + 2bx +c =0 and
dx  2ex  f  0 have a common root, then which one of the following statements
2
is correct ?
d e f
1) , , are in A.P. 2) d, e, f are in G.P.
a b c
d e f
3) d, e,f are in A.P. 4) , , are in G.P.
a b c
Ans: 1
b  ac  D1  4b  4ac  0  ax  2bx  c  0 has equal roots each is  .
2 2 2
Sol:
2b 2 c
 2   ,   and  is a root of dx 2  2ex  f  0
a a
c  b  d 2bc f d 2e f
 d    2e    f  0    0   0
 a   a  a ac c a b c
20
1
64. The sum  k k is equal to
k 1 2
11 3 21 11
1) 1  20 2) 2  17 3) 2  20 4) 2  19
2 2 2 2
Ans: 4

1 2 3 20
Sol: S  2  3  ....  20
2 2 2 2
S 1 3 19 20
 2  3  ....  20  21
2 2 2 2 2
1   1  
20
1    
S 1 1 1 1 20 2   2   20 11
   2  3  ....  20  21   21  1  20
2 2 2 2 2 2 1 2 2
1
2
65. If the system of linear equations
x – 2y + kz =1
2x + y + z = 2
3x – y – kz =3
has a solution (x, y, z), z  0, then (x, y) lies on the straight line whose equation is:
1) 4x–3y–1=0 2) 3x–4y–4=0 3)3x–4y–1=0 4) 4x – 3y – 4 = 0
Ans: 4
Sol: From the given eqs, (1) + (3)  4x – 3y – 4 = 0
66. The tangent to the parabola y2=4x at the point where it intersects the circle x2 + y2
=5 in the first quadrant, passes through the point :
 1 4 3 7  1 1 1 3
1)  ,  2)  ,  3)  ,  4)  , 
 3 3   4 4   4 2   4 4 
Ans: 2
y  4 x, x  y  5  x  4 x  5  0
2 2 2 2
Sol:
x  1 x  5  y  2 y  0
Eq of tangent is 2y = 2(x+1)  x – y + 1 = 0
dx
 
1/3
67. If   x f  x  1  x 6
 C where C is a constant of integration, then
x 1  x 
2/3
3 6
the function f(x) is equal to :

1 1 3 1
1)  2 2)  3 3) 4) 
2x 6x x2 2x3
Ans: 4
1
 3
1  16 
dx dx 1  x 
Sol:  x 3 1  x 6 
2/3

1 
2/3

6 1
c
x  6  1
7
x  3

68. Suppose that the points (h, k), (1, 2) and (–3, 4) lie on the line L1. If a line L2 passing
k
through the points (h, k) and (4, 3) is perpendicular to L1, then equals:
h
1 1
1)  2) 3 3) 0 4)
7 3
Ans: 4
h  4 k  3 5
Sol: eq of L1 is x + 2y = 5     1
1 2 5
1 1 1 
 
69. Let the numbers 2, b, c be in an A.P. and A   2 b c  . If det(A)  [2,16],then c
 4 b2 c2 
 
lies in the interval:
2) 2  2 ,4 4) 3,2  2 
3/4 3/4
1) [4,6] 3) [2,3)
 
Ans: 1
A  2 b  2  2b  2  c 
3
Sol:
1 b  2  2  3  b  4
70. The minimum number of times one has to toss a fair coin so that the probability of
observing at least one head is at least 90% is:
1) 2 2) 4 3) 5 4) 3
Ans: 2
1 1
Sol: 1  n  0.9  n  0.1
2 2
71. Two vertical poles of heights, 20 m and 80 m stand apart on a horizontal plane. The
height (in meters) of the point of intersection of the Lines joining the top of each
pole to the foot of the other, from this horizontal plane is :
1) 12 2) 18 3) 15 4) 16
Ans: 4
h 80 h 20 hx hx
Sol:  ,     x  h  16
x y x y x 20 80

x
72. Let f  x   g t  dt , where g is a non–zero even function. If f(x+5)=g(x), then
0
x
 f t  dt equals:
0
5 x5 x5 5
1)  g t dt 2) 2  g t  dt 3)  g t dt 4) 5  g t  dt
x5 5 5 x5
Ans: 1
Sol: g x  f '  x & g  x  g  x  f  x  5  f 5  x and also f(x) is odd.
x 5 x x 5 5
Put t  5  y  f x dt   f  y  5 dy   g  y dy   g t dt
0 5 5 x 5
73. Let f : R  R be a diiferentiable function Satisfying f '3  f '2  0 . Then

1
1  f 3  x   f 3  x
lim  is equal to
x0 1  f  2  x   f  2 
 
1) 1 2) e 3) e–1 4) e2
Ans: 1
1
1  f 3 x f 3 f 2 x f 2 
 1  f 3  x  f 3  x lim 
Sol: L  lim      e x  1 f 2 x f 2 
x  0
x0 1  f 2  x  f 2 
    
lim

 e x0 f '  3 f  x    f '  2  x   e 0  1 
 x   x , 1  x  1

74. Let f : 1,3  R be defined as f  x    x  x , 1 x  2

 x   x , 2 x3
where [t] denotes the greatest integer less than or equal to t. Then, f is discontinuous
at:
1) only three points 2) only one point
3) only two points 4) four or more points
Ans: 1




  x  1, 1  x  0
Sol: 
f x    x , 0 x 1  f x  is d isco n tin u o u s a t 0 ,1 ,3 .

 2 x, 1 x  2

 x  2, 2 x3

 6, x3

75. Let S     x, y  : y 2  x,0  x   and A  is area of the region S  . If for a
,0    4, A  : A4  2 : 5 , then  equals:
1 1 1 1
 4 3  4 3  2 3  2 3
1) 2  2) 4  3) 2  4) 4 
 25   25   5   5 
Ans: 2

4 A 2 16
Sol: A    2 xdx       3/2 
0
3 A  4 5 5
76. The number of integral values of m for which the equation
1  m  x
2 2
 21  3m x  1  8m  0 has no real root is:
1) 1 2) 2
3) infinitely many 4) 3
Ans: 3
2
Sol: D  0  8m 3  8m 2  2m  0  2m  2m  1  0  m  0
77. If the eccmtricity of the standard hyperbola passing through the point (4, 6) is 2,
then the equation of the tangent to the hyperbola at (4, 6) is :
1) 3x–2y=0 2) 2x–3y+10=0 3) 2x–y–2=0 4) x–2y+8=0
Ans: 3
x2 y2
Sol: Eq. of hyperbola is 2  2  1, it passes through (4,6)  a2=4.
a 3a
Eq. of tangent is 2x–y=2.
 
 i  1 , then 1  iz  z 5  iz 8  is equal to:
3 i 9
78. If z 
2 2
3) 1  2i 
9
1) 0 2) –1 4) 1
Ans: 2
 9
Sol:
 6

Z  cos    1  iz  z 5  iz 8   1
79. The height of a right circular cylinder of maximum volume inscribed in a sphere of
radius 3 is :
2
1) 3 2) 3 3) 2 3 4) 6
3
Ans: 3
 h2 
Sol: V   
9  4  h

 
dv  3h 2  d 2v
  9 
   0  h  2 3 & 2  0 for h =2 3
dh  4  dh
80. The number of four–digit numbers strictly greater than 4321 that can be formed
using the digits 0, 1, 2, 3, 4, 5 (repetition of digits is allowed) is :
1) 360 2) 288 3) 310 4) 306
Ans: 3
Sol:
Total no. = 310.
Let f  x  a a  0 be written as f(x) =f1(x) +f2(x), where f1(x) is an even function
x
81.
and f2(x) is an odd function. Then f1(x + y) +f1(x – y) equals:
1) 2 f1  x f1  y  2) 2 f1  x  y  f1  x  y 
3) 2 f1  x  y  f 2  x  y  4) 2 f1  x  f 2  y 
Ans: 1
Sol: ax  ax ax  ax ax y ax y
f 1  x  , f 2  x   f1  x  y  f1  x  y   a  ay 
 a ay 
2 2 2 2
 a x  ax   a y  a y 
 2
 2   2   2 f1  x  f1  y 
82. The vector equation of the plane through the line of intersection of the planes
x+y+ z= 1 and 2x+3y+4z=5 which is perpendicular to the plane x – y+ z =0 is :
     
 
1) r. i k  2  0  
2) r. i k  2  0
 
3) r i  k   2  0 4) r  i  k   2  0
   
Ans: 1
x 1 y 1 z 1
Sol: Line of intersection of the planes x+y+z=1, 2x+3y+4z=5 is  
1 2 1

x 1 y 1 z 1
Eq. of required plane is 1 2 1 0 xz20
1 1 1
 r i  k   2  0
83. Which one of the following statements is not a tautology ?
1)  p  q  ~ p   q 2)  p  q  p
3)  p  q    p  ~ q  4) p   p  q 
Ans: 3
Sol: 1) p  p  q  ~ p   p  q   T
2) ~  p  q   p   ~ p  ~ q   p  T
~  p  q   p  ~ q    ~ p  ~ q    p  ~ q
3)
  ~ p  p  ~ q  T
4) p  ~ p  T
2y
84. Given that the slope of the tangent to a curve y  y  x at any point (x,y) is . If
x2
the curve passes through the centre of the circle x2 + y2 – 2x – 2y = 0, then its
equation is :
1) x loge y  2 x 1 2) x log e y  2 x 1
3) x log e y  2 x 1 4) x log e y   x 1
2
Ans: 1
dy 2 y 2
Sol:  2  log y   c , it possess through (1,1)
dx x x
2
 log y  2   x log y  2 x  2
x
85. If a point R(4, y, z) lies on the line segment joining the points P 2,3,4 and
Q(8, 0, 10), then the distance of R from the origin is:
1) 2 14 2) 6 3) 2 21 4) 53
Ans: 1
2 y 3 z  4
Sol: Here, P, Q, R are collinear   
6 3 6
 y  3  1  y  2, z  4  2  z  6  OR  2 14

86. In an ellipse, with centre at the origin, if the difference of the lengths of major axis
 
and minor axis is 10 and one of the foci is at 0,5 3 , then the length of its latus
rectum is:
1) 8 2) 10 3) 6 4) 5
Ans: 4
Sol: Here, given ellipse is vertical ellipse & b – a = 5, b2 – a2 = 75
 b  a  15  b  10, a  5  LLR  5
 1 6
 1 12 
87. If the fourth term in the binomial expansion of  1log10 x  x  is equal to
 x 
200,and x >1, then the value of x is:
1) 100 2) 10 3) 103 4) 104
Ans: 2
3/2 1
6
Sol: T4  C3 x  log10
10 x
 4
. x  200  x  10
88. If the lengths of the sides of a triangle are in A.P. and the greatest angle is double
the smallest, then a ratio of lengths of the sides of this triangle is:
1) 5:9:13 2) 3:4:5 3) 4:5:6 4) 5:6:7
Ans: 3
Sol: 2b  a  c; A   ;, C  2 , B    3  a  b  c 
 3  3
 2 sin 3  sin   sin 2  2 cos    cos  /2  cos  
 2 4

 a : b : c  sin  : sin 3 : sin 2  1: 3  4 sin 2  : 2 cos  
5 6
 1: :  4 : 5 : 6
4 4
If f 1  1, f '1  3, then the derivative of f  f  f  x   f  x of x=1 is
2
89.
1) 12 2) 9 3) 15 4) 33
Ans: 4
Sol: f 1  1, f ' 1  3
Let
2 dy
y  f f f  x  f  x 
     f ' f f  x . f ' f  x . f 'x  2 f 'x. f x
   
dx
dy

dx
at x=1 = f '1. f '1. f '1  2 f '1. f 1  27  6  33
90. A student scores the following marks in five tests : 45, 54, 41, 57, 43. His score is not
known for the sixth test. If the mean score is 48 in the six tests, then the standard
deviation of the marks in six tests is :
10 10 100 100
1) 2) 3) 4)
3 3 3 3
Ans: 1
Sol: Let marks in the 6th test is x
41  43  45  54  57  x
 48   x  48
6
1 100 10
2
6

  2   48  412  432  452  54 2  57 2  482   2  
3
 
3
Prepared by
Sri Chaitanya Faculty


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