Chemistry ​ vineetloomba.

com
Class XII ​P​REPARED BY​:

DPP
E​R​. V​INEET ​L​OOMBA ​(B.T​ECH​. IIT R​OORKEE​)
TARGET : JEE Main/Adv
Solid State
LEVEL – I
1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. ​Which (A) Lium cell (A) A (A) (C) Metallic cells (A) Which

(A) The (A) The would (A) In (A) In (A) (C) Solid (A) Name ​ v​ match a tetragonal

0.48 ionic ? 1 cubic orthorhombic 3.06 rbody 282 N/2 tetrahedral face fraction closed

i​
edge ​c in
​ CO+ ​ the be of of 2.0 r​2 pm
​ metal gold ​a box
​ centered × the the centered is
 n​
​ crystals, units
geometry = : crystal length 10g packed a an of of exhibits 11​

e​
following crystallizes (B) example the gold has ​ class of geometry 6.023 array

e​
given void a ? sodium : ​ Atomic possible body (B) (B) (B) (B) (B) (B) for
 t​
expressions of available of × can in covalent 0.52 2 rN 383 which the 10​ c​N the +

l​
​ ​chloride spheres, mass (B) rcrystal ​
centered be 23 pm ​a type
​ face = used all in

o​
octahedral ​a ​2​of is the primitive of centered (C) ​(C) type
​ to cubic true gold unit the
 o​
unit ​ four build 1.53 ​r​c number
​ in : is + cell cell unit types (C) (B) (D) (C) (C) (C) (B)

m​
(D) (C) r197. case ​ cubic ​a ×
​ the cubic = are is 10cell. 0.68 metallic 4 3 101

monocliniunit of 0.72

o​
molecular 4 167 are crystal, approximate Clcell (D) of –​ ​ : pm is lithium 181 : cubic
 m​
diamond ​ pm, number atoms the :

per unit
of unit
size of Na​+
(A) hexagonal (B) tetragonal (C) monoclinic (D) orthorhombic
12. ​The cubic unit cell of aluminium (molar mass 27.0 g/mol) has an edge length of 405
pm. Its density is
2.70 g/cc. The type of unit cell is : (A) primitive (B) face centered (C) body centered (D)
end centered
2
13. ​Co-ordination ratio changes to lower number e.g. 8 : 8 to 6 :6 on :
(A) applying pressure (B) increasing temperature (C) a and b (D) change in catalyst
14. ​M+​​ X​– ​has FCC structure with octahedral void. Anion has radius 300 pm. The ideal
radius of cation is :
(A) 0.414 × 300 (B) 0732 × 300(C) 0.155 ×300(D) 0.225 × 300
15. ​An element exists as hexagonal close packed structure as well as cubic closed
packed structure. In
which case the element would have higher density ? (A) ccp (B) hcp (C) same in both
(B) unpredictable
16. ​What is the coordination number of atoms in BCC, HCP and CCP and simple
lattices.
(A) 8, 12, 12, 6(B) 6, 12, 12, 8(C) 12, 6, 8, 12(D) 12, 12, 8, 6
17. 18. 19. 20. 1. 2. 3. 4. P ​ repared By: ​MATHEMATICS E ​ r. Vineet Loomba (IIT Roorkee)
–​
A and compound B​ ions is the AB​2 crystal.
​ possesses the CaF​2 type
​ crystal (A) 8, 4 (B)
4, 8 (C) 12, 6 In the closest packing of atoms the size of the tetrahedral (A) smaller than
octahedral void (B) (C) equal to octahedral void (D) The molar volume of KCl and NaCl
are 37.46 ml crystals is : (A) 1.296 (B) 1.116 (C) NaCl shows schottky defects, AgCl
frenkel defects. (A) motion of ions and not motion of electrons (C) lower co-ordination
number of KCl A metal (A) A (i) (ii) What (A) In voids (A) If what (A) ​ v​ solid metal ‘a’

i​
a 2 AAB ; crystalline is ​2​is and is ​2 ​B in ​ fcc between Atoms Atoms the the ​a ​the has

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the ​ 50% edge distance formula a unit cubic A B (B) of ​ solid, occupy are A

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length cell the Aand ​3​unit arranged of of Band ​ tetrahedral anion ​2 (B)
​ (B) (B) B the
 t​
closest of all cell has structure 4; AB ​a ​the ​2​ the compound B bcc with the in are

l​ o​
approach unit octahedral c.c.p. following voids. arranged ​ cell cell of (C) (C)

edge metal array

o​
? of ​ What between ​LEVEL AABvoids
​ an ​2​arrangements in B408 ​2 is
​ ​2 (C)
​ ​(C)
m​
atomic CCP is :

structure. Write the co-ordination number of A​2+

b​
1.341 and ​– greater
​ both ​II Their
​ (B) (D) 27.94 (A) ​ motion higher than electrical

a​
and void ml. (D) ​ octahedral (B) The co-ordination 6, is of : 12
 .​ c​ o​
electrons ​ conductivity (D) ratio ​ 0.950 of void ​ unit and number is cell not

m​
due edges motion of to AgCl :

of the two
of ions
pm. Its density is 10.6 g/cc. Number of atoms of the
4; fcc (D) 1; ccp
of atoms
and half the tetrahedral voids.
(D) AB​4 lattice
​ and cations A occupy 50% of the octahedral the formula of the solid?
(D) A​2​B​3 crystal
​ having face centered cubic lattice, then the two atoms in the crystal ?

​ ​The ionic radii of Mg​ and O​ ions are 66 pm and 140 pm respectively.
2 ​a​(D) 1​ ​2()a2 5. 2+ ​ 2– ​

What type of interstitial void

Mg​ is likely to occupy ? What is the probable co-ordination number of Mg​2+ ​ion ? (A)
2+ ​

tetrahedral , 6 (B) octahedral , 6 (C) tetrahedral , 4 (D) octahedral , 8

6. ​Centre, face planes, diagonal planes, edge centre axis, face centre axis, diagonal
axis of symmetry of a
3 ​cubic cell are respectively (A) 1, 3, 6, 6, 3, 4 (B) 3 6, 6, 1, 3, 4 (C) 3, 6, 6, 3, 4, 1 (D) 1,
3, 6,4, 6, 3
7. ​In Cations a compound Y are equally XY​2​O​4​, distributed oxide ions are arranged in
CCP and cations X are present in octahedral voids. between octahedral and tetrahedral
voids. The fraction of the octa- hedral voids occupied is : (A) 1/2 (B) 1/4 (C) 1/8 (D) 1/6
8. ​A solid has a structure in which W atoms are located at the corners of the cubic
lattice, O atoms at the centre of the edges and Na atom at the centre of the cube. The
formula of the compound is : (A) NaWO​2 ​(B) Na​2​WO​3 ​(C) NaWO​3 ​(D) NaWO​4 ​9. ​The
number of unit cells in 58.5 g of NaCl is approximately –
(A) 6 × 10​20 ​(B) 1.5 × 10​23 ​(C) 6 × 10​23 ​(D) 0.5 × 10​24
10. ​A mineral is composed of Ca , Ti and oxygen . With Ca​+2 ​at cube corners , Ti ions in
the centre and
1. 2. 3. 4. 5. 6. 7. 8. 9. 10. P ​ repared By: ​MATHEMATICS E ​ r. Vineet Loomba (IIT Roorkee)
oxide ions in the face centre of the unit cell . The formula of the mineral Ti are : (A) (C)
Ca Ca TiTi​3 2 ​OO​4 3 ​; + 2 ; + 2 (B) (D) Ca Ca Ti Ti OO​3 2 ​; + 4 ; + 2

Which (A) Which (A) Which (A) Which (A) The ?​(A) TiO(A)
​ Which (A) Which (A) The (A)

(C) In ​v​ an ​CaF​CaFNHNHHgS ​2​MnOhexagonal cadmium the the fluorite (rutile)

i​
hcp NaCl ​ 44​type of of of of of ​2 2 Cl
​ I same same ​2 and
​ the the the the the

n​
structure, shows of structure ccp iodide following following following following
 e​ e​
following packing coordination crystals (B) ​ structure NH6 : all ​4​ shows 3 F

fraction (B) (B) (B) (B) (B) (B) (B) contain crystals crystals crystals structures
coordination. crystals the

t​ l​
MgO SrClBeFAlFe ZnS ice triclinic for ​ number 8 ​2 2 a
​ : ​ one have have have 4

o​
given show coordination. ​ have Bravais 8 6 4 (C) (C) Which element 4 : : :
o​
layered 8 6 4 : SiC KCl ​LEVEL ​2 coordination coordination coordination lattice

m​
coordination of (C) (C) (C) (C) (C) (C) (B) ​ would Which the lattices BaFMnO

MnO SiOgraphite ​– ​rhombohedral the ? ​III

b​
following ​2 2 (D)
​ (D) (D) same be of ​ ??

?
 a​ .​
? SnONaCl all the expected ? density the (D) ​2 ​ following solids PbOabove ​ to

co​ m ​
(D) (D) (D) (D) (D) have ​2 ​ and the ​ oxidation state monoclinic

NH​4​Br
ZnS
solids have fluorite-like lattices
ThO​2
a rutile-like structure ?
diamond
have
of
(A) octahedral sites are occupied (B) tetrahedral sites are unoccupied (C) octahedral as
well as the tetrahedral sites are occupied (D) octahedral as well as the tetrahedral sites
are unoccupied
4 ​11. ​Which of the following statements are correct for the rock-salt structure ?
(A) the tetrahedral sites are smaller than the octahedral sites (B) the octahedral sites
are occupied by cations and the tetrahedral sites are empty (C) the radius ratio is 0.732
(D) the radius ratio is 0.999
12. ​Which of the following compounds represent a normal 2 : 3 spinel structure ?

(A) Mg​II​Al​2​III​O​4 (B)

​ Co​II​(Co​III​)​2​O​4 (C)
​ Zn(TiZn)O​4​(D) Ni(CO)​4 13.
​ ​Which of the following
statements are correct ?
(A) the coordination number of each type of ion in a CsCl crystal is eight (B) a metal that
crystallizes in a bcc structure has a coordination number of twelve (C) a unit cell of an
ionic crystal shares some of its ions with other unit cells (D) the length of the unit cell is
NaCl is 552 pm (given that r​Na​+ ​= 95 pm and r​Cl​- ​= 181 pm)
​ repared By: ​MATHEMATICS E
1. 2. 3. P ​ r. Vineet Loomba (IIT Roorkee)
LEVEL – IV
Match the following columns Column I Column Structure No. of atoms/unit ​(a)
SCC (i) 2 (b) Body centred cubic (ii) 4 (c) Face centred cubic (iii) 5 (d) End centred (e)
Edge centred (A) (B) (C) (D) ​Match the following Column Location ​(a) corner (b)
edge centre (c) body centre (d) face centred (A) (a) - (i) , (b) (C) ​Match ​(a) (b) (c) (A)

i​ n​
v​ (a) ​ - ​the Column Structure ​SCC BCC FCC (a) (iii) ​ - ​following ​(i) , (b)

e​
- (a) (a) (a) (a) ​I ​- ​ I ​(z) - - - - ​of ​(ii) - (iv) , cubic cubic (i) , (b) (iv) , (b) (iv) , (b) (iii) ,
 e​
(b) ​columns atom ​, ​columns ​, ​ (c) (c) - (i) (ii) (iii) (b) (iv) (v) - (ii) , (c) - (iii) , (d) -

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(iv) ​in ​(iii) ​ - - - ​cube ​(ii) (i) (iii) , ​ (d) , , , (c) (c) ​ (c) - (iv) - - (ii) - (iv) (ii)

o​ m​
, , , (d) (d) (d) ​Column Contribution ​(i) (ii) (iii) (iv) (B) - ​ - (i) - - (ii) , (d) -

(i) (D) ​Column II Location of atoms ​corners as well as Only at corners Corners as well
 b​
as - (ii) - (x) , (c) (i) (i) , , , , (e) (e) (e) (e) 1 6 - ​ - - (ii) - ​II

1/2 1 1/8 1/4 (a) - (iv) (a) - (iii) face centre body centre - (iii) - (y) (ii)

a​
(iv) (ii) , , ​II ​ cell

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to the unit cell
(b) - (i) , (c) - (ii) , (d) - (i) (b) - (ii) , (c) - (iv) , (d) - (i)
Column III Coordination number ​(x) 8
(y) 12 (z) 6
(B) (a) - (ii) - (x) , (b) - (i) - (y) , (c) - (iii) - (z) (C) (a) - (iii) - (z) , (b) - (i) - (x) , (c) - (ii) - (y)
(D) (a) - (ii) - (z) , (b) - (iii) - (x) , (c) - (i) - (y)
4. Match the following columns
5 ​Column I Column II Column III Location of ions No. of occupied voids Void ​(a)
Cs​+ ​in CsCl structure (i) All (p) Octahedral (b) Na​+ ​in NaCl structure (ii) Alternate (q)
​
Tetrahedral (c) Zn​++ in ZnS structure (iii) One fourth (r) Triangular (d) (e) F ̄ Nain + ​in
CaFNa​2 2​structure O structure
(iv) One third (s) Cuboidal
(A) (a) - (i) - (s) , (b) - (i) - (q) , (c) - (ii) - (q) , (d) - (i) - (q) , (e) - (i) - (q) (B) (a) - (ii) - (s) ,
(b) - (i) - (r) , (c) - (ii) - (q) , (d) - (iii) - (q) , (e) - (i) - (q) (C) (a) - (i) - (s) , (b) - (iii) - (r) , (c)
- (ii) - (r) , (d) - (i) - (q) , (e) - (i) - (s) (D) (a) - (ii) - (r) , (b) - (i) - (s) , (c) - (iii) - (q) , (d) - (i)
- (q) , (e) - (ii) - (q)
5. Match the following column
Column I Column II 6. 7. Structure Packing efficiency ​(a) atoms (b) atoms (c) atoms
(d) atoms (A) (a) - (iii) , (C) (a) - (iii) , ​Match the following Column Structure (a) ​Spinel

(b) Antifluorite ​(c) Wurtzite (d) Fluorite (e)

​ Corundum ​(A) (a) - (ii) (B)
​ (a) - (ii) (C) (a) - (iii)
(D) (a) - (v) ​Match the following Column Structure (a) ​(b) (c) (d) (e) (A) (B) (C)

i​ n​
v​ Density dielectric equal Anion Cation (a) (a) (a) ​ - - - (ii) (i) (iii) are

present at corners as well as on edge centre are present at corners as well as on face
centre are present at corners as well as on body centre are present only at corners (b) -

(i) , (c) - (iv) , (d) - (iii) (B) (a) - (ii) , (b) - (iv) , (c) - (ii) , (d) - (i) (D) (a) - (v) , no. structure ​,

e​
, , , of ​structure I​ ​ I ​(b) (b)
​ (b) ​structure (b)
​ constant of crystal ​- -​ - structure cations
 e​ t​
- ​(i) (v)
​ (iv) (iv) ​column column ​ , ,​ , , ​(c) decreases
​ (c) (c) increases (c) ​ & ​- -​

l​ o​ o​
(iv) -​ - (iv) anions (i) ​ (v) ​, ,​ , ​ , ​(d) (d)
​ (d) (d) are ​- -​ - ​(iii) -​ (iii) (iii) ​ (i)

m​
missing ​, ,​ , , ​(e) (e)
​ (e) (e) ​ - -​ - - ​(v) (ii)
​ (ii)
 b​ a​ .​
(ii) from ​ the (b) (b) ​Column Examples ​(ii) ​(iii) (iv) ​ - - (v) (iv) , , ​ (c) (iv) (i)

c​ o​
​ ​II ​
ZnFe​BaClZnS (c) - - (iv) ​2 (i)
​ ​2​O, ​4 (i)
​ (ii) (iii) K, ​ 2​(d) (d) O ​2 (v)
​ Fe​2​O​3

Column II Crystal defect ​(i) Schottky (ii) Frenkel lattice (iii) F-centres vacancies having
unpaired electrons
is missing from its site and occupies void , (b) - (i) , (c) - (iv) , (d) - (iii) , (e) - (v) , (b) - (ii)
, (c) - (i) , (d) - (iii) , (e) - (ii)
, (b) - (iv) , (c) - (v) , (d) - (i) , (e) - (ii)

m​
p/6 ​ p/6 p/12

3 ​p/8
- (iii) - (iii)
defect defect
(D) (a) - (v) , (b) - (iv) , (c) - (i) , (d) - (iii) , (e) - (ii)
Prepared By: ​MATHEMATICS ​Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 6
LEVEL I
1. ​A ​2. ​B ​3. ​C ​4. ​C ​5. ​B ​6. ​A ​7. ​C ​8. ​D ​9. ​B ​10. ​D ​11. ​D ​12. ​B ​13. ​B ​14. ​A ​15. ​C ​16. ​A ​17. ​A ​18.
A ​19. ​B ​20. ​A
LEVEL II
1. ​C ​2. ​C ​3. ​B ​4. ​D ​5. ​B ​6. ​A ​7. ​A ​8. ​C ​9. ​B ​10. ​B
LEVEL III
1. ​ABC ​2. ​ABD ​3. ​AB ​4. ​AC ​5. ​AB ​6. ​AD ​7. ​AC ​8. ​BC ​9. ​AC ​10. ​AB ​11. ​AC ​12. ​AB ​13. ​AC
LEVEL IV
1. ​B ​2. ​C ​3. ​D ​4. ​A ​5. ​C ​6. ​A ​7. ​B
ANSWER KEY

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Prepared By: ​MATHEMATICS ​Er. Vineet Loomba (IIT Roorkee)