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JANUARY 2018
years
129
The technical service magazine for the rubber industry Volume 257, No. 4
@rubberworld
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Contents Vol. 257, No. 4 January 2018
FEATURES
JANUARY 201
8
22 Prediction of rolling
years
129
The technical
25 Characterization of
made of eq ounds
ual Mooney,
equal composition
polymers
Characterizing
rubber
Instrumentat
by Alina K. Latshaw and Thomas Rauschmann, ion/Testing
Labs Director
ies
TA Instruments Waters. Advanced rheological
.comorld
measurements are correlated to polymer chain
www.rubberw
architecture. ACS Events
, page 74
31
@rubberworl
Rheology of EPDMs
d
A ,
of a C-Therm TCi ther-
CQUISITIONS mal conductivity analyz-
er. The modular system
SBR
EXPANSIONS
9HIGH QUALITY
allows ARDL to expand
on its wide range of capa-
bilities for testing, analysis and material characterization. The
device can assist customers in studying materials' thermal
conductivity and effusivity to ASTM D7984 for research and
development and quality control.
Wacker Chemical (www.wacker.com), Adrian, MI, part of
the global chemical group Wacker Chemie AG, is planning a
number of concurrent expansion projects to support regional
growth and demand for silicones and HDK pyrogenic silica.
9IN STOCK
Triple digit million dollar investments in North America align
with Wacker's overall expansion strategy to add capacity in
Europe and Asia.
Continental (www.contitech.us), Fairlawn, OH,
announced a $9.3 million expansion of the rubber mixing
9GREAT SERVICE
operations at its industrial hose plant in Norfolk, NE, to
accommodate its North American manufacturing facilities by
providing rubber for industrial hoses and whitewall tires for
passenger cars.
High Duty &
Wabash MPI and Carver (www.wabashmpi.com/www.
carverpress.com), Wabash, IN, announced the completion of
a recent expansion at their Wabash, IN, facility in response to
Dumping Fees
continued growth. This 5,000 square foot expansion includes
new warehouse and service areas which allow for reorganiza-
tion of the companies' current space for new offices, increased Call us today and see how
manufacturing capacities and improved efficiency for Wabash
and Carver's hydraulic and pneumatic presses. HB Chemical can save you money.
Orion Engineered Carbons (www.orioncarbons.com),
Luxembourg, a global supplier of specialty and high-perfor-
mance carbon black, has completed construction of a carbon
black production line at its plant in Yeosu, South Korea, to
produce specialty products.
Tahoma Rubber and Plastics (www.tahomarubberplas-
tics.com), Barberton, OH, added a 170 mm gear pump strainer
to its Abbeville, SC, plant to provide new capabilities to meet
customer demand. The strainer allows for the removal of cured
particles or contamination from rubber compounds. The plant
has also installed the capacity to produce sheeted fiber-filled
rubber compounds.
Smithers Rapra (www.smithersrapra.com), Akron, OH,
HB
CHEMICAL
1665 Enterprise Pkwy, Twinsburg, OH 44087
has invested in expanded tire testing capabilities at its tire and Ph: (800) 991-2436 F: (330) 920-0971
wheel testing laboratory in Suzhou, China. The testing equip- www.hbchemical.com
ment gives the Suzhou lab a 35% boost in capacity.
TESTING INSTRUMENTS
9HIGH QUALITY
Good Design awards
from the Chicago Athenaeum Museum of Architecture
and Design in cooperation with the European Center for
Architecture, Art, Design and Urban Studies for their design
excellence. The winning tires were selected from several thou-
sand entries spanning more than 55 countries.
9IN STOCK
Sumitomo Rubber North America (www.srigroup.co.jp),
Kobe, Japan, announced that MicroStrategy has awarded it
the 2017 Ventana Research Leadership Award in the digital
technology category. Using MicroStrategy Mobile, SRNA is
responsible for the sales and distribution for Falken, Dunlop
Motorcycle and Ohtsu branded tires throughout North America
and the Caribbean markets.
The Association for Rubber Products Manufacturers
(www.arpminc.org), Indianapolis, IN, released its revised
Application Guide for Radial Lip Type Shaft Seals (OS-4). The
ARPM OS-4 is a guide for the selection of radial lip seals.
9GREAT SERVICE
The U.S. Tire Manufacturers Association (www.ustires.
org), Washington, D.C., hails the vote of the Ohio Senate to
pass motorist safety legislation that prohibits the installation of
unsafe used tires as an important consumer production measure.
HB Chemical has the SBR you
need, in stock, duty-free, and
Quality registrations
without the high anti-dumping
The Material Research Center of CoreTech System Ltd.
(Moldex3D) (www.moldex3d.com), Taiwan, has successfully fees you are currently paying.
passed ISO/IEC 17025 certification. Its materials characterization
abilities on shear viscosity, heat capacity and dynamic viscosity are
approved in compliance with international standards.
Mokon (www.mokon.com), Buffalo, NY, a designer and man-
ufacturer of advanced heating and cooling equipment for industrial
markets, has successfully transitioned from ISO 9001:2008 to the
HB
ISO 9001:2015 quality standard.
PolyOne (www.polyone.com), Cleveland, OH, a global pro-
vider of specialized polymer materials, services and solutions, has
been certified to the American Chemistry Council's Responsible
Care Management System.
Vortex Global Limited (www.vortexglobal.com), Darlington,
U.K., has been certified to the ISO 9001:2015 standard.
CHEMICAL
For all the latest 1665 Enterprise Pkwy, Twinsburg, OH 44087
Ph: (800) 991-2436 F: (330) 920-0971
business briefs
click here: www.hbchemical.com
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The Rubber Economist
Rubber industry exhibits cyclical behavior
Is there regularity or predictability of variables influencing the ment. In the past, a complete rubber consumption cycle was
rubber industry? One sometimes hears comments such as “win- about five years. However, the China effect during the 2000s,
tering is due, therefore the natural rubber (NR) supply should
be declining and the price firming up,” or “it is approaching
summer holidays in North America and Europe, thus rubber Highlights
demand should be falling and the prices are likely to be weaken- s The growth estimate for world rubber consumption this year
ing.” What we would like to know is: “Do rubber demand, sup- has been revised downward, but should still show a faster
rate than last year.
ply and prices move in a predictable behavior, or do they move
s The slower global growth rate is due to a lower forecast for
randomly, independent from just one or a few variables?” If we PRVWUHJLRQVLQFOXGLQJWKH$VLD3DFL¿F
look at the monthly growth rate of world rubber consumption s7KHPRUHSHVVLPLVWLFRXWORRNLVGXHWRDVORZHUUXEEHUR൵WDNH
from January 1971 to December 2017, as shown in figure 1, for all four of the largest rubber consuming countries: China,
we can see the growth rate does move in a cyclical manner, and USA, India and Japan.
the speed and length of the upturns and downturns are generally s7KHGRZQZDUGUHYLVLRQIRUWKHJOREDOUXEEHUR൵WDNHZDV
quite similar. mainly a revision of a slower growth for NR.
s Despite the revision, consumption of NR is expected to be
Four elements of a time series more rapid than SR, bringing the percentage of global SR
consumption down by 2019.
A time series is usually composed of four elements, including a
s World NR production for this year is now expected to increase
seasonal component, an irregular component, a long-term secu- HYHQIDVWHUWKDQSUHYLRXVO\HVWLPDWHGGHVSLWHDORZHU¿JXUH
lar trend and a long-term cyclical movement. We will come to for the output in the major producing countries.
discussing in detail the seasonal factors in the rubber industry s There is a detailed analysis: “Do rubber demand, supply and
next, but to give you an example, one of the macro-economic prices move in a predictable behavior, or do they move very
variables is the seasonal fluctuation of housing starts in the much more randomly, independent from just one or a few
USA, which usually peaks around April-June and reaches a variables?”
low around December-February. An irregular movement for the s World SR output in 2017 is now expected to show an increase
even slower than last year, as all regions are expected to show
rubber consumption was the financial crisis in 2008 and 2009,
DQHJDWLYHJURZWKUDWHZLWKWKHH[FHSWLRQRI$VLD3DFL¿FDQG
which caused the growth rate to fall sharply in 2008 and 2009, Latin America.
and an equally sharp increase in 2010 (figure 1). Many economic s The picture on rubber stocks has changed from the last report,
variables and those related to the rubber industry, such as rubber DV15LVH[SHFWHGWRVKRZDVPDOOVXUSOXVUDWKHUWKDQGH¿FLW
consumption, have long-term influencing trends, from the rising The reason is that the increase in demand for NR has not been
level of the population to GNP. as rapid as anticipated, and supply from smaller producers has
LQFUHDVLQJO\EHFRPHPRUHVLJQL¿FDQW
Cyclical movements s Global NR stocks are now expected to increase and surpass
If one takes away the seasonal factor, the irregular movement the record level reached in 2014.
s65GH¿FLWZLOOFRQWLQXHIRUWKHQH[WWKUHH\HDUVEULQJLQJ
and the long-term trends from a time series, such as the rubber
global SR stocks down to the lowest level since 2001.
consumption growth rate, we will be left with a cyclical move- s Despite record levels expected for global stocks, the NR stock
to consumption ratio may not show a sharp rise.
s There may be a sharper decline in SR stocks in both absolute
Figure 1 - growth rate of world rubber and relative terms to consumption.
consumption, January ’71 - December ’17 s NR prices have fallen quite sharply in recent months, e.g., the
average prices in November of STR20 fell to the lowest level
20 since September 2002.
15 s7KHUHKDVEHHQDORWRIQHZVDQGHYHQWVD൵HFWLQJUXEEHUSULFHV
10 but the gradual increase in the stock/consumption ratio was
OLNHO\WREHWKHPRVWLPSRUWDQWIDFWRULQÀXHQFLQJWKHZHDN
Percent
5 rubber prices.
0 s If the stocks/consumption ratio may increase only marginally,
-5 the short term price outlook is not going to change much and
rubber prices may just remain at a relatively low level.
-10 s There has also been a similar movement to NR of SR prices in
-15 North America, Europe and Asia. For both NR and SR, the
Jan. '71 Jan. '81 Jan. '91 Jan. '01 Jan. '11 latex was holding up better than the dried counterpart.
2008 2009
6,000 2010 2011 1.2 Consumption
2012 2013
2014 2015 Production
5,000 2016 2017 1.1
$ per ton
4,000 1.0
3,000 0.9
2,000 0.8
1,000 0.7
0 Jan. Feb. Mar. Apr. May Jun. Jul. Aug. Sep. Oct. Nov. Dec.
Ja
M
Ap .
M
Ju
Ju
Au
Se .
O
No
Fe
De
ct
ar
ay
n.
n.
l.
g
r.
p.
b.
v.
c.
or if the winter is mild. It is sometimes necessary to distinguish
.
Conclusion
In conclusion, there is a degree of regularity or predictability in
rubber production and consumption, but not so much for rubber
prices.
Butyl rubber ionomer-thermoplastic Assigned: Wright Asphalt Products black-rich rubber tread zone to the car-
graft copolymers and methods for Key statement: This invention encom- bon black-rich tread base layer by an
production thereof passes rubber modified asphalt cement extension of a lateral tread zone or by
U.S. patent: 9,815,929 compositions, as well as systems, an intermediate carbon black-rich rub-
Issued: November 14, 2017 apparatuses, methods for preparing, as ber bridge.
Inventors: Conrad Siegers and Richard well as methods for using rubber-mod-
Steevensz ified asphalt cement compositions.
Assigned: Lanxess 3 2 6
7A 7 7 7B
Key statement: The present invention Tire with rubber tread of intermedi- 5A 5B
is directed to the functionalization of al and lateral zones with path of 6A 6B
butyl rubber ionomer and optionally least electrical resistance 8A 8B
4
the grafting of polyamide to halobutyl U.S. patent: 9,809,058 9 9
rubber ionomers. Specifically, dis- Issued: November 7, 2017
closed are methods and products Inventors: Roberto Cerrato Meza, Jun-
resulting therefrom for creating func- ling Zhao and Austin Gale Young
tionalized ionomers and grafting poly- Assigned: Goodyear Tire & Rubber
amide to halobutyl ionomers via reac- Key statement: The invention relates
tive extrusion. The process comprises to a tire having a rubber tread of a cir-
reacting a halobutyl polymer with at cumferentially zoned tread. The tread
least one nitrogen and/or phosphorous zones are comprised of three circum-
based nucleophile to provide a halobu- ferential load bearing zones, with each
tyl ionomer comprising conjugated zone containing a portion of the run- Combined tire
diene units; grafting of an amine-reac- ning surface of the tread, comprised of U.S. patent: 9,815,331
tive dienophile to said ionomer to form a silica-rich intermedial rubber zone Issued: November 14, 2017
a functionalized ionomer; and option- positioned between and extending Inventor: Garyg Gong
ally blending the resulting functional- beneath two carbon black-rich lateral Assigned: Xiamen Lenco
ized ionomer with polyamide. tread zones. The tread configuration Key statement: Disclosed is a com-
contains an underlying carbon black- bined tire, including a tire casing and a
System and method for high rich base rubber layer. The intermedial core. The tire casing is an annular
throughput preparation of rubber- and stratified lateral zones are com- member having a core groove around
modified asphalt cement prised of rubber compositions having the periphery; the core is an annular
U.S. patent: 9,803,085 differentiated rebound physical proper- member nested within the core groove
Issued: October 31, 2017 ties. A path of least electrical resis- of the tire casing in an interference fit,
Inventor: Theodore P. Flanigan tance extends from a lateral carbon and forms a gap with the inner wall of
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0.19
sistance factor values are calculated using equation C:
0.17
0.15 Percent variation = [(Predicted value – measured
0.13 value)/measured value] x 100 (C)
0.11
We have also calculated the correlation coefficient be-
0.09
y = 0.0046x + 0.3483 tween rebound resilience and RRF with a dynamic mechani-
0.07 R2 = 0.98 cal analyzer. The coefficient of correlation value is found to
0.05 be 99%.
35.0 40.0 45.0 50.0 55.0 60.0 65.0
Linear regression used for prediction of rolling resistance fac-
Rebound measured by rebound resilience tester tor and its coefficient of regression are mentioned in figure 1.
106 1.4
A EPDM 1 B
EPDM 2 1.2
Viscosity, K *(Pa.s)
1.0
105
Tan delta
0.8
0.6
104
0.4
0.2
103 0.0
0.01 0.1 1 0.01 0.1 1 10
Shear rate (1/s) Shear rate (1/s)
have a Mooney viscosity of 65 MU. Conversely, larger differ- predicting the flow behavior of these materials in processes
ences in behavior are observed at low shear rates, which are where a low shear rate is experienced, such as during start-up of
equivalent to longer time scales. EPDM 1 shows a lower tan the manufacturing processing, and especially as a material re-
delta value around 0.85 at the lowest tested shear rate, while laxes and flows within a mold.
EPDM 2 is approximately 1.25. A smaller tangent delta value A strain sweep was then used to investigate the presence and
indicates a larger amount of elasticity within the material, which degree of long chain branching between the two samples, shown
can correlate to a higher molecular weight or the presence of in figure 2. Both samples show similar behavior at small strains,
branching. Significant differences in the complex viscosity and with the elastic modulus, G’, around 80 kPa at low strains. The
tangent delta are observed at low frequencies which correlate to elastic modulus is related to the elastic component in the mate-
long time scales, indicating that the polymer architectures, such rial and correlates with the degree of structure within a material.
as molecular weight or degrees of branching, are different. Prob- A high modulus value corresponds to a strong microstructure,
ing within the low frequency region yields information associ- such as high molecular weight, a more rigid polymer chain
ated with molecular weight, which the Mooney test fails to chemistry, or interactions between the polymer and additives. At
measure. The low frequency response is particularly useful for strains less than approximately 2° of arc, the modulus for both
samples is independent of strain. This is expected and is identi-
fied as the linear viscoelastic regime. At strains higher than the
Figure 2 - data from a strain sweep are critical strain of 2° of arc, both moduli decrease, showing a de-
plotted as the elastic modulus (G’) and pendence on strain. This region is known as the non-linear re-
tangent delta as a function of strain; gime and can provide insight into the branching nature of the
significant differences between EPDM 1 material. Significant differences between the two polymers are
and EPDM 2 are observed at high strains, observed as deviations in tangent delta at high strain amplitudes.
in the non-linear regime Testing at strains within the non-linear regime show greater sen-
sitivity to differences in polymer architecture.
100 10
Shear modulus, G’ (kPa)
EPDM 1
9
Upon closer observation of the Lissajous plot at 90° of arc or
EPDM 2 1,255% strain, which is constructed by plotting the transient
8
stress versus shear rate, as shown in figure 3, the difference in
Tan delta
7
6 sample response is apparent. It is known that a Lissajous plot
10 5 showing secondary loops is indicative of a linear polymer archi-
4 tecture, while the absence of secondary loops is characteristic of
3 a branched polymer architecture (ref. 4). The data show EPDM
2 1 to be a branched polymer compared to EPDM 2, which is a
1 linear polymer. Further quantitative analysis can be performed by
1 0 calculating a long chain branching (LCB) index number based
0.1 1 10 100
on the stress versus shear rate response (refs. 5 and 6). A negative
Strain (° of arc)
LCB index is indicative of a linear polymer, while branched
S’ (dNm)
8
100,000
Shear stress (Pa)
6
50,000
4
0
-10 -8 -6 -4 -2 0 2 4 6 8 10 2 Sample 1
-50,000 Sample 2
0
-100,000 0 2 4 6 8 10 12 14 16 18 20
EPDM 1 EPDM 2
-150,000 Time (minutes)
LCB 1.21 -1.25
-200,000
index
manufacturing process, cured more slowly than sample 2, which
-250,000
showed no processing issues. In addition, both curves show a
Shear rate (1/s) similar minimum torque around 1 dNm. The results from the
MDR tests were unable to distinguish the differences between
polymers are indicated by a positive value. In this case, EPDM 1 the materials, and were not showing the information needed to
has an LCB index of 1.21, while EPDM 2 has an LCB index of identify the root cause of the processing issues.
-1.25, confirming that EPDM 1 is a branched architecture, while Frequency sweep tests on the RPA were performed to charac-
EPDM 2 is linear. The branched nature of EPDM 1 is also veri- terize both samples and correlate differences in viscoelasticity
fied by a higher viscosity and lower tangent delta at low frequen- with their processing behavior. The complex viscosity is shown
cies, shown in the frequency sweep in figure 1, both of which are as a function of angular frequency in figure 5. Both samples
indicative of a material with more elasticity. In addition, EPDM
1 demonstrated a greater degree of shear thinning compared to
EPDM 2. Long chain branching can improve additive incorpora- Figure 5 - data from a frequency sweep
tion and a material’s ability to shear thin, which aids with pro- show the complex viscosity as a function of
cessing. The processing issues experienced when switching from angular frequency for samples 1 and 2;
EPDM 1 to EPDM 2 can be traced back to the lack of long chain the frequency spectra show similar
branching in EPDM 2. Testing on the RPA was used to help behavior in processability between both
troubleshoot and discover the root cause of the processing chal- samples, especially in the high shear rate
lenges after switching EPDM suppliers. Few other analytical range which correlates with flow behavior
techniques are available to practically characterize these impor- in an extrusion process
tant polymer properties.
0.6
0.5 0.3% to over 1,000% strain. The storage modulus (G’) and the
0.4 tangent delta for both samples are shown as a function of strain
percent in figure 7. Deviations in behavior are seen as the applied
0.3
strain increases in the non-linear regime. The storage modulus for
0.2 Sample 1 sample 1 remains higher than for sample 2, indicating a stronger
0.1 Sample 2 elastic structure within the material. As previously discussed, this
0 equates to a stronger microstructure, usually as a result of higher
1 10 100
molecular weight, polymer rigidity and additive interactions. This
Angular frequency (rad/s)
is also corroborated by the tangent delta signal, with sample 1
showing a lower tangent
delta, which corresponds to a
Figure 7 - data from a strain sweep are plotted as the elastic modulus larger degree of elasticity.
(G’) and tangent delta as a function of strain; significant differences The data at 90° of arc, or
between the rubber compound samples are observed at high strains; in strain percent of 1,255%, can
the non-linear regime, the Lissajous plot shown for both samples at be recast by plotting the tran-
90° of arc (inset) indicates differences in long chain branching and sient shear stress against the
energy dissipated during the applied oscillation shear rate in the Lissajous
plot. The long chain branch-
6 ing index can be calculated
Sample 1 from the Lissajous plot. Both
Sample 2 Lissajous plots show a lack
Sample 1 Sample 2 of secondary loops, indicat-
5
LCB index 2.73 0.18 ing the presences of long
chain branching. This is con-
Shear modulus, G’ (kPa)
150,000
of 2.73 and 0.18 for samples
100,000
Stress, V (Pa)
LCB index
Tan delta
3.0
4
2.0
2
1.0
0.0 0
BR 1 BR 2 BR 1 BR 2
The presence of long chain branching contributes to the elas- sample 1 shows a larger amount of energy dissipated at high
tic character of the material. Usually, the presence of long chain shear which is akin to the shear rates experienced within the ex-
branching improves processability; however, process engineers truder. The larger amount of energy dissipation could cause local
saw challenges and scorching problems with sample 1, despite temperature increase within the sample as it is sheared within the
the higher degree of long chain branching. The work dissipated extruder.
during oscillation and shear can be calculated from the Lissajous Despite the MDR cure curve showing sample 1 would cure
plot by measuring the area within the ellipse when plotting tran- more slowly, local temperature elevations within the sample as a
sient stress against strain. This work is associated with viscous result of energy dissipation from the induced shear in the ex-
heating; this heat must be removed from the material or it will truder could result in scorching of sample 1 during the extrusion
result in local temperature rise. Analysis at 90° of arc, or strain process. The RPA was able to quantify differences between the
percent of 1,255%, shows the work dissipated to be 177 J and two rubber compounds and help process engineers optimize their
169 J for samples 1 and 2, respectively. Compared to sample 2, processing conditions by decreasing the extruder speed, and then
re-evaluating the compound formulation.
Figure 9 - the percent change in BR 1 and Stability differences in BR from different suppliers
BR 2 due to the simulated mixing step is For some polymers, such as BR, SBR and NBR, it is important
shown; the tangent delta and LCB index in to understand the amount of aging experienced when subjected
BR 1 are unaffected, with a percent change to shear and temperature, such as in a mixing process. In this
less than 3% and 15%, while the case, the RPA can be used to stress the polymer under high shear
viscoelastic properties for BR 2 are highly and temperature, mimicking the mixing procedure while evalu-
affected, with changes on the order of 50% ating the changing of the structure of the polymer by measuring
and 100% the viscoelastic properties. With a proper testing method, the
RPA can be used to characterize a material before the mixing
120
Difference before/after aging (%)
8 25
7.5
7 LE HE
6.5 bMWD' 20
4.5
4
3.5 10
3
2.5
2 5
1.5
1
0.5 0
0 30 60 90 120 150 180 210 240 0 20 40 60
Time (seconds) Time (seconds)
115 0.75
110 0.7
105 0.65
95 0.55
90
85 0.5
80 0.45
75 0.4
70 0.35
65 0.3
60 0.25
55 0.2
50
45 0.15
40 0.1
35 0.05
0 30 60 90 120 150 180 210 240 0
0 30 60 90 120 150 180 210 240
Time (seconds) Time (seconds)
8 25
7.5
7
6.5 P1 20
4.5
4
3.5 10
3
2.5
2 5
1.5
1
0.5 0
0 30 60 90 120 150 180 210 240 0 20 40 60
Time (seconds) Time (seconds)
115 0.75
110 0.7
105 0.65
95 0.55
90 0.5
85 0.45
80 0.4
75 0.35
70 0.3
65 0.25
60 0.2
55 0.15
50 0.1
45 0.05
40 0
35
0 30 60 90 120 150 180 210 240 0 30 60 90 120 150 180 210 240
Time (seconds) Time (seconds)
particular, the power uptake exhibited a fast CB incorporation figure, the power uptake profiles exhibit either one peak, like that
peak that gradually decayed until reaching about 3 kW. However, at a CB/oil ratio of 1, or two at a ratio of 1.5. The single peak at
in the case of the high CATR polymer (P1), the power uptake the low CB/oil ratio was attributed to the initial sluggish filler/oil
exhibited two distinct peaks correlated with CB incorporation incorporation peak. As the CB/oil ratio increased, the incorpora-
and dispersion. Note the filler incorporation peak at about 15 tion became faster and the incorporation peak gradually moved
seconds coincidentally matches the melting temperature of P1. to shorter times due to the absence of the lubricating effect. The
We suspect incorporation and dispersion of carbon could only be second filler dispersion peak started developing at a CB/oil ratio
achieved when the EPDM reached the melting temperature and of 1.4, to fully appear at a ratio of 1.5. As observed, the presence
softened. However, as described later, the formulation has a clear of large amounts of oil has a detrimental impact on the CB incor-
impact on the position of this peak. The graph also shows that the poration, which translates into late incorporation peaks and a
low CATR polymer exhibited a faster temperature rise, as well as dramatic reduction in the temperature rise. Note that the tem-
a more effective use of the mixer volume, with the ram position perature rise profile clearly shows two temperature ramps: 1) a
coming down to zero much faster. Note that despite the fact the fast ramp at the beginning of the mixing cycle clearly associated
final temperature is the same for both polymers, the figure shows with CB incorporation and dispersion, and 2) a slower ramp
that the energy required for the high CATR polymer is greater comparable within the evaluated window of CB/oil ratios associ-
and that it translates into a higher temperature rise for mixing ated with having a homogeneous compound.
cycles beyond four minutes. As mentioned, to understand the effect of architecture in the
Figure 5 shows the effect of varying the CB/oil from 1 to 1.5 mixing profile of semicrystalline polymers, we need to consider
at a constant overall phr of 426. Maintaining a constant overall the effect of CATR as an additional variable compared to the
phr was a key parameter in this set of experiments in an attempt amorphous set. Furthermore, we recognized that any trends
to maintain a constant polymer basis where CB increased at the made are formulation dependent and may vary for different phr
expense of oil. A CB/oil ratio of 1 offers an oil rich environment, formulations. In an attempt to make a fair comparison, we se-
while a ratio of 1.5 refers to a high filler loading. As shown in the lected a series of polymers within a tight C2 window between
8
7 distinct events during this process and categorized their perfor-
6 mance. Based on this table, the nMWD' polymers exhibited a
5
4 fast temperature rise throughout the mixing cycle; the ram came
3 down the fastest to a closed position, and the power draw had a
2 fast stabilization at about 3 kW. In the case of the nMWD'/LE
1
0 architecture, the polymer also exhibited strong intensity of the
-1 CB incorporation peak comparable to the bMWD' polymers.
Note that the differences in architecture played a more prominent
0
20
40
60
80
100
120
140
160
180
200
220
240
differentiating role in the case of mixing semicrystalline poly-
Time (seconds) mers. Compared to the amorphous polymers, the bMWD'/HE
architecture characterized in both the amorphous and semicrys-
105 talline polymers exhibited a slow decay in the power draw and
100 took more time for the ram to fully close.
95
90
Batch temperature (°C)
85 Summary
80 To understand the effect of polymer architecture on the mixing
75
70 process of EPDM, this article selected a series of representative
65 EPDM polymers and categorized them into four distinct MWD'/
60
55 n CB LCB combinations. LCB information was captured by its effect
50
RQHODVWLFLW\XVLQJWKH¨įRUGLIIHUHQFHLQWKHSKDVHDQJOHDW
45 and 100 Rad/s, but observations can be equally extended to other
40 rheological indicators of viscosity or shear thinning. The selected
polymers covered both amorphous and semicrystalline composi-
tions at 70 MV, and 5% ENB. Mixing cycle information in-
0
20
40
60
80
100
120
140
160
180
200
220
240
8 25
7.5 LE HE
7
6.5 bMWD' 20
4.5
4
3.5 10
3
2.5
2 5
1.5
1
0.5 0
0 30 60 90 120 150 180 210 240 0 20 40 60
Time (seconds) Time (seconds)
115 0.75
110 0.7
105 0.65
95 0.55
90
85 0.5
80 0.45
75 0.4
70 0.35
65 0.3
60 0.25
55 0.2
50
45 0.15
40 0.1
35 0.05
0 30 60 90 120 150 180 210 240 0
0 30 60 90 120 150 180 210 240
Time (seconds) Time (seconds)
tion. Mixing cycle information was categorized into five attri- cosity-molecular weight relationships,” Fall 186th Technical
butes associated with distinct events during the process and re- Meeting of the Rubber Division, ACS, Cleveland, OH, 2015.
lated back to polymer architecture. 2. J. Noordermeer, “Ethylene-propylene elastomers,” Encyclo-
pedia of Polymer Science and Technology, 4th ed.; John Wiley &
References Sons, Inc., Vol. 6, pp. 178-196.
1. J.C. Tuberquia, C. Li Pi Shan, T. Clayfield, L. Nguyen, T. 3. H.C. Booij, “Long-chain branching and viscoelasticity of
Kashyap and K. Blackwell, “Long chain branching in EPDM ethylene-propylene-diene elastomers,” Kautschuk Gummi
polymers: An open door to a complete spectrum of Mooney vis- Kunststoffe 1991, 44 (2), pp. 128-130.
This report details the results of accelerated heat aging studies undertaken on re-mixed
samples of those materials studied for the natural aging study and on the 20 new com-
SRXQGVFKRVHQWRUHSUHVHQWSRO\PHUVQRWDYDLODEOHLQDQGWRUHÀHFWFKDQJHVLQ
FRPSRXQGLQJSUDFWLFH,QDGGLWLRQWRWKRVHSURSHUWLHVVWXGLHGIRUWKHDUWL¿FLDOZHDWKHULQJ
exposures, compression set and dynamic properties were also measured.
Experimental details
Figure 1 - examples of various extents of Polymers used in this study were natural rubber (NR; SMR CV
chip and cut damage to the treads of: TBR/ 60) and high cis butadiene rubber (BR; Buna CB 24 from Ar-
heavy truck tires (a) and (b); OTR/ lanxeo). The reinforcing filler was an N339 grade of carbon black
construction vehicle tire (c); and mud- (CB). All other ingredients were rubber grade chemicals. The
terrain light truck tire (d) rubber formulations are given in table 1.
Rubber compounds were prepared in two mixing stages. For
the first stage, all ingredients except CBS accelerator and sulfur
were mixed for five minutes in an internal mixer (SYD-2L from
Everplast, Taiwan) at 50 rpm with a chamber wall temperature of
(a) 80°C. The CBS and sulfur curatives were added in the second
mixing stage on a two-roll mill at a temperature of 60°C.
(c) Curing properties were determined by a moving die rheometer
(MDR 3000 Basic, MonTech, Germany) according to ASTM
6204 at 160°C. Rubber specimens with an outer diameter of 55
mm and thickness of 13 mm (see geometry shown in figure 2)
were cured in a heated press (LaBEcon 300, Fontijne Presses,
Netherlands) at 160°C according to the curing time t90 + 1 minute
(b) (d) per 1 mm of the thickness (13 minutes total added for specimen
thickness of 13 mm).
Laboratory chip and cut testing was performed on the rubber
specimens using an instrumented chip and cut analyzer (ref. 5)
Figure 2 - photograph of instrumented chip (ICCATM) manufactured by Coesfeld GmbH, Germany (figure
and cut analyzer (ICCA) showing expanded 2), and distributed in the Americas by Endurica LLC, USA. The
view of impacting device and sample (left)
and diagram of rubber sample geometry
with 55 mm outer diameter and 13 mm Table 1 - rubber formulations
thickness (right)
NR/BR 50CB NR/BR 65CB
NR 75 75
BR 25 25
CB (N339) 50 65
55
Zinc oxide 3 3
Ø
Ø Stearic acid 1 1
26
IPPD(a) 1.5 1.5
CBS(b) 2.5 2.5
Sulfur 1.7 1.7
(a) N-isopropyl-N’-phenyl-p-phenylenediamine
(b) N-cyclohexyl-2-benzothiazole sulfonamide
Ff Normal force
Normal force, fn
Fn Z
Friction force
Force
ai
1 2 3 4 Time of sliding, ts
Time
16.55
0.
8 test results for a variety of agricultural tires, truck and bus radial
R2
Ra 0.8
Ra (TBR) tires, and light truck tires. The details cannot be shared due
8 to confidentiality considerations with major tire manufacturers.
0.
Ra The cut and chip behavior as a function of number of impact
Parameter P (N/cycles)
12
1,000 1,000
10
Number of impact cycles, n
2,500 2,500 8
5,000 5,000 6
10,000 4
2
15,000
0
20,000
0 10,000 20,000 30,000 40,000
30,000
Cycles, n
40,000
treads in service.
Abrasion of rubber involves both mechanical fracture and
cycles was compared for two blend compounds: NR/BR 50CB thermal-oxidative effects (aging/degradation) (ref. 6). Consider-
and NR/BR 65CB (see formulations in table 1). The results are ing the latter, impact-induced localized temperature increases of
presented in figures 6 and 7. The slope of the P versus n data the rubber during ICCA testing are of interest, and a study was
shows very distinct values for the two materials. A greater slope conducted to investigate this using a high speed, thermal imaging
is associated with less CC resistance. Inspection of the rubber camera. These preliminary results were shown during the presen-
specimen surfaces and the flat response of P with increasing num- tation of this paper at the 192nd Meeting of the Rubber Division,
ber of cycles for the NR/BR 65CB compound both show that no ACS, in October 2017.
significant chipping of rubber was evident for this material which In addition to cyclic impact, the ICCA can also be used in full
was reinforced with a significantly higher amount of carbon black contact mode as a friction and wear measurement device. This is
compared to the NR/BR 50CB compound, which showed clear an area of ongoing research with this flexible instrument.
CC damage.
The development of cutting patterns on the rubber surfaces, References
and the related chipping away of material that follows, show dis- 1. J. Beatty and B. Miksch, “A laboratory cutting and chipping
tinct characteristics that depend on normal load (not shown here), tester for evaluation of off-the-road and heavy duty tire treads,”
number of impact cycles, and especially the rubber formulation Rubber Chem. Technol. 55, 1,531 (1982).
(figure 6). Along with the P values, such differences in visual 2. C. Nah, B.W. Jo and S. Kaang, “Cut and chip resistance of
damage responses from cyclic impact reveal that the ICCA can NR-BR blend compounds,” J. Appl. Polym. Sci. 68, 1,537 (1998).
effectively distinguish the CC behavior of different rubber com- 3. M. Scherbakov and M.R. Gurvich, “A method of wear charac-
pounds. terization under cut, chip and chunk conditions,” J. Elastom.
Plast. 35, 73 (2003).
Conclusion 4. J.-H. Ma, Y.-X. Wang, L.-Q. Zhang and Y.-P. Wu, “Improvement
The instrumented chip and cut analyzer is a new test device for of cutting and chipping resistance of carbon black-filled styrene
the rubber laboratory that controls and records multiple applied butadiene rubber by addition of nanodispersed clay,” J. Appl.
loads and displacements during cyclic impact to mimic and quan- Polym. Sci. 125, 3,484 (2012).
tify the cut and chip damage experienced by tire tread compounds ((XFKOHU+0LFKDHO0*HKGH2.UDWLQD56WRþHN5
on rough terrain. The surface roughness characteristics of the Kipscholl and J.-M. Bunzel, “Wear of technical rubber materials
rubber specimens, created from the repetitive impacting process, under cyclic impact loading conditions,” Kautsch. Gummi
produce fluctuations in the friction force that are quantified using Kunstst. 69, 22 (2016).
the P parameter, thus allowing evaluation of the CC tendency of 6. A.N. Gent and C.T.R. Pulford, “Mechanisms of rubber abra-
rubber compounds in the laboratory to predict CC behavior of tire sion,” J. Appl. Polym. Sci. 28, 943 (1983).
Dynamic/thermomechanical
Creep and stress relaxation
are broken down into spectrophoto-
Fluid resistance
Heat build-up
Permeability
and microscopy. Each of these subdi-
Hardness
Adhesion
Abrasion
visions is further broken down into the
Fatigue
Tensile
Set
R.D. Abbott Company, Inc. s s s s s s s s s s s s
Akron Rubber Development Lab, Inc. s s s s s s s
Alloy Extrusion Co. s s
Alttran s s s s s s s s s
Aspen Research Corp. s s s s s s s s
Atlas Material Testing Technology LLC
DSET Laboratories
EAG Labortories s s s s s s s s s
Eastern Laboratories, Inc. s s s s s s s s
Elastomer Research Testing B.V. s s s s s s s s s s s
Element Los Angeles s s
Element Materials Technology s s s s s s s s
Endurica, LLC s s s s s s
Experimental Services, Inc. s s s s s s s s s s
Green Globe Laboratories
Hauser GmbH s s s s s s s
Intertek Automotive Research s s s s s s s
In USA, Inc.
MEI-Charlton, Inc. s s s s s s s s s s s
MonTech
Differential scanning
Dissipation constant
Mass spectrometry
Thermogravimetric
Dielectric strength
Ozone resistance
Dielectric factor
Extrudability
calorimetry
absorption
Brittleness
Cure rate
Electron
Infrared
Optical
Liquid
Gas
s s
s s s s s s s s s s s s s s s s s s s s
s s
s s s s s
s s s s s s s s s s s s s s s s s s
s s s
s s
s
s
s s s s s s s s
s s
s
s
s s s s s s
s s s s s
s
s s s s s s s
s s s s s s s s s s s
s s s s s s
s s s
s s s
Dynamic/thermomechanical
Creep and stress relaxation
are broken down into spectrophoto-
Fluid resistance
Heat build-up
Permeability
and microscopy. Each of these subdi-
Hardness
Adhesion
Abrasion
visions is further broken down into the
Fatigue
Tensile
Set
NSL Analytical Services s s s s s s s s s s s
O-Ring Prüflabor Richter GmbH s s s s s s s s s
Bill Peltzman and Assoc., Inc.
UL Verification Services s s s s s s s s
VTEC Laboratories Inc. s s s s s s s s s s s s s s s
Western Technologies Inc. s s s s s
Differential scanning
Dissipation constant
Mass spectrometry
Thermogravimetric
Dielectric strength
Ozone resistance
Dielectric factor
Extrudability
calorimetry
absorption
Brittleness
Cure rate
Electron
Infrared
Optical
Liquid
Gas
s s s s s s s s s s
s s s s s s s s s s
s s s s s s s s s s s
s s
s
s
s s s s
s s s s
s
s s
s s s s s s s s s s s s
s s s s s s s s s s s s s s s s s
s s s
s s s s s s s
s s s s s s s s s s
s s s s s s s s s s s s s s s s
ensable Understanding
Thermoplastic
Elastomers
Mixing of Rubber
Compounds
Author: Limper, A. Copy-
ce Tools
d.com/bookstore
Author: Holden, G.
Copyright: 2000 ISBN:
9781569902899
Softcover: 110 pages
right: 2012
ISBN: 9781569904589
Hardcover: 239 pages
!PPLIED 4EST 3YSTEMS )NC
,EVERETT ! !NDERSON #O
!METEK 53 'AUGE $IV
VULCANIZATES HAS BEEN BROKEN DOWN INTO
STRESSSTRAIN TESTS TIME
DEPENDENT TESTS
!UTOMATION 0RODUCTS
!CU
'AGE 3YSTEMS
!LPHA 4ECHNOLOGIES
DESTRUCTIVE TESTS DURABILITY AND ELECTRICAL
!SYLUM 2ESEARCH
PROPERTIES )NSTRUMENTS AND TEST EQUIPMENT
#7 "RABENDER
"ETA ,ASER-IKE
"# !MES #O
!3-
(ASBACH
FOR THE CHEMICAL ANALYSIS OF RAW MATERIALS
"ASLER 6ISION
!CROLAB ,TD
VULCANIZED AND UNVULCANIZED RUBBER INCLUDE
2$ !BBOTT
!DMET )NC
SPECTROSCOPY CHROMATOGRAPHY THERMAL
ANALYSIS AND MICROSCOPY
0ERMEABILITY s s
$URABILITY
)NSTRUMENTATIONEQUIPMENT FOR THE TESTING OF RUBBER VULCANIZATES
&LUID RESISTANCE s s
(EAT RESISTANCE STATIC s s s
(EAT BUILD
UP s s s s
$ESTRUCTIVE
&ATIGUE s s s s
TESTS
!BRASION s s s
#RACK AND CUT GROWTH s s s
$YNAMICTHERMOMECHANICAL s s s
4IME
DEPENDENT
2EBOUND AND RESILIENCE s s
TESTS
#REEP AND STRESS RELAXATION s s s s
Set s s s
!DHESION s s s s s
3TRESSSTRAIN
(ARDNESS s s s s
TESTS
4EAR s s s s s
4ENSILE s s s s s
s s s
-ICROSCOPES
$IMENSIONS s s s s s s
0HYSICAL TESTING OF RUBBER
2AW MATERIALS VULCANIZED AND s s s s s
UNVULCANIZED RUBBER TESTING
0ROCESSABILITY TESTING s s s s s s
$ISSIPATION FACTOR s
%LECTRICAL
PROPERTIES
$IELECTRIC STRENGTH s
$IELECTRIC CONSTANT s
"RITTLENESS s s
$URABILITY
7EATHERING RESISTANCE s
/ZONE RESISTANCE s
s
CDS Analytical, Inc.
s
s
s
s
Cober, Inc.
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
Corporate Consulting Services
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
Dek-Tron Scientific Instruments
s
Despatch Industries
s
s
s
s
s
s
s
Dewes Gumbs Die and Presses
s
s
s
s
Dillon
s
s
Eagle Polymer Equipment
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
Ektron Tek Co.
s
s
s
s
s
s
s
s
s
s
s
Elastocon AB
s
s
Electronic Development Labs
s
s
s Electro Standards Laboratories
s
Emerson Apparatus
s
s
Endurica, LLC
s
s
Exova
s
FISA North America
s
Forte Technology
s
s
s
s
s
s
s
s
s
s
s
Goettfert
s
s
s
s
s
s
GreCon
s
s
Hamamatsu Corporation
s
Harris Instruments
s
s
s
s
Hoto Instruments
s
s
s
s
s
s
Hydramotion
Imada, Inc.
s
s
s
s
Imass, Inc.
65
The following grid lists the types of instru-
mentation and test equipment offered by
Leica Microsystems
Instron Corporation
destructive tests; durability and electrical
LMI Technologies
properties. Instruments and test equipment
Maag Automatik
J.M. Machinery
Mast/Keystone
for the chemical analysis of raw materials,
Malcam, Ltd.
Kokusai, Inc.
KLA-Tencor
Meeco, Inc.
vulcanized and unvulcanized rubber include
spectroscopy; chromatography; thermal
Indusco
Impakt
analysis; and microscopy.
Permeability s s
Durability
Instrumentation/equipment for the testing of rubber vulcanizates
Fluid resistance s
Heat resistance (static)
s s
Heat build-up s s
Destructive
Fatigue s s
tests
Abrasion s s
Dynamic/thermomechanical s s s s s
Time-dependent
Set s s s s s
Adhesion s s s
Stress/strain
Hardness s s s
tests
Tear s s s s s
Tensile s s s s s s
Microscopes s s
Dimensions s s s s s
Physical testing of rubber
Processability testing s s s s s s s s
Dissipation factor s
properties
Electrical
Dielectric strength s s
Dielectric constant s s
Brittleness s
Durability
Weathering resistance s
Ozone resistance s s
s
s
s
s
Micromeritics Instrument Corporation
s
s
Micro-Vu
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
MonTech USA
s
s
s
s
MTI Instruments
s
MTS Systems
s
s
s
NDC Infrared Engineering
s
s
s
s
s
s
s
s
s
s
s
s
s
Netzsch Instruments North America
s
Newage Testing Instruments
s
s
s
s
s
Nikon, Inc.
s
OAI (Optical Associates Inc.)
s
s
s
s
s
ODC Tooling and Molds
s
s
OHMIC Instruments
s
Olympus-NDT
s
s
Ontario Die International
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
Oxford Instruments
s
Pacific Transducer
s
Perkin Elmer Instruments
s
s
s
s
PLV Systems
s
s
s
s
s
s
s
s
s
s
PPD Group
s
s
Precision Quincy Ovens
Prescott Instruments
s
s
Princo Instruments
67
PTC Instruments/PTC Metrology
Schenck Corporation
Rex Guage Co., Inc.
TA Instruments, Inc.
Qualitest USA, LLC
destructive tests; durability and electrical
Q-Lab Corporation
Starrett Bytewise
properties. Instruments and test equipment
Taber Industries
Scanco USA
vulcanized and unvulcanized rubber include
spectroscopy; chromatography; thermal
analysis; and microscopy.
Permeability s s s s
Durability
Instrumentation/equipment for the testing of rubber vulcanizates
Fluid resistance s s s
Heat resistance (static) s s
Heat build-up s s s
Destructive
Fatigue s s s s
tests
Abrasion s s s s
Crack and cut growth s s
Dynamic/thermomechanical s s s
Time-dependent
Hardness s s s s s s s
tests
Tear s
Tensile s s
Microscopes s s s
Dimensions s s s s s
Physical testing of rubber
Processability testing s s s
Dissipation factor s
properties
Electrical
Dielectric strength s
Dielectric constant s
Brittleness s s s
Durability
Weathering resistance s s
Ozone resistance s
s
s
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Testing Machines, Inc.
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Testo, Inc.
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Thermo Scientific
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Thermotron Industries
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s Thwing-Albert Instruments Co.
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Tinius Olsen Testing Machine Co.
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TSI Incorporated
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U-Can
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United Calibration Corporation
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United Testing Systems, Inc.
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Vindum Engineering, Inc.
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Wabash MPI
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Wallace Instruments
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Webber Manufacturing Co.
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Williamson
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Willrich Precision
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Winters Instruments
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Rubber Division, ACS 2018 Courses
Elastomer Training Center in Akron, OH
Advanced Rubber Technology – February 13-15
Natural Polymers, Renewable Resources – February 27-March 1
Introduction to Compounding, Testing and Mixing of Elastomers –
rubber.org classroom March 6 & 7, tours March 8
Silicone Basics – March 8
Intro to Rubber Technology for
Training and education are essential to Non-Technologists – March 20
Molding of Rubber – March 21
maintaining a qualified workforce and for a
Introduction to Rubber Bonding – March 22
student to be competitive when searching Intermediate to Advanced Compounding and
Testing of Rubber – classroom April 10-12,
for a job in the industry. Procedures and best tours April 13
practices are continuously changing within Understanding Raw Materials, the Building Blocks
of Rubber Compounding – April 23
our industry and to stay ahead or on top of Compounding for Performance – April 24 & 25
trends, Rubber Division, ACS provides you an Solving Problems in Rubber Compounding
and Processing – April 26
opportunity to invest in your company and its Dynamic Rubber Design – May 1 & 2
future and increase the knowledge base of An Introduction to Continuous Vulcanization – May 7
An Introduction to Flexible Cellular Rubber – May 8 & 9
your employees by offering training courses
Chemistry & Technology of Polyurethane Elastomers – May 10
throughout the year. Failure Analysis of Rubber & Plastics by Physical and Chemical
Analysis – May 11
Essentials of Rubber Technology – May 14
Silicone Rubber Chemistry and Technology – May 14
Visit rubber.org/upcoming-training for Compound Mixing and Consistency – May 15
more information about these courses, Establishing a Rubber Molding Process – May 15
including full descriptions, pricing, Applied Rubber Technology – May 16 & 17
CEUs and more.
Educational Symposium during our International
Elastomer Conference in Louisville, KY
Introduction to Rubber Technology for Non-Technologists –
October 9
Essentials of Rubber Technology – October 9
Silicone Rubber Chemistry and Technology – October 9
Introduction to Bonding – October 10
Compound Mixing and Consistency – October 10
Establishing a Rubber Molding Process – October 10
Silicone Basics – October 11
Internal Mixers and Mixing Parameters – October 11
Meetings
Rubber Division offers training rubber industry, including those work-
ing in engineering, sales, administration,
Training and educational opportunities neers and managers, including a new human resources or any other non-techni-
are offered by the Rubber Division of the generation, to polymer science from a cal area, looking for a very basic, easy to
American Chemical Society throughout bio-based approach. understand introduction to the jargon of
the year. Upcoming training opportuni- s Introduction to Compounding, the rubber trade.
ties, to be held at the Elastomer Training Testing and Mixing of Elastomers (March s Molding of Rubber (March 21): This
Center in Akron, OH, will include the 6-8): This seminar will present an over- course is an introduction to one of the
following: view of compounding elastomers. Topics main processes in the industry, the form-
s Advanced Rubber Technology will include elastomers, fillers, oils/plasti- ing and vulcanization of rubber products
(February 13-15): This course will pro- cizers and curing agents. Also discussed by use of molds. After an introduction
vide professionals with an in-depth under- will be the mixing and testing of elas- to basic rubber technology, participants
standing of rubber products. In addition to tomer compounds and how to select an will explore the major variations of the
learning the science, practical topics such elastomer for a given application. molding process, which are compression,
as production-scale synthesis, character- s Silicone Basics (March 8): This transfer and injection molding.
ization, processing and curing will be cov- course will cover silicone characteristics s Introduction to Rubber Bonding
ered, along with biomedical applications and benefits, different types, how it is (March 22): This course is designed for
of rubber. made, curing, silica powders, additives, those whose operations include or will
s Natural Polymers, Renewable HCR processing and LSR differences. include the bonding of rubber compounds
Resources (February 27 - March 1): This s Introduction to Rubber Technology to solid substrates (metals, plastics, etc.)
course with a textbook strives to intro- for Non-Technologists (March 20): This wanting to learn about the chemistry,
duce, educate and inspire scientists, engi- course is geared towards those new to the mechanics and overall methods for
HB
CHEMICAL
P
Twinsburg, OH 44087
Ph: (800) 991-2436 F: (330) 920-0971
www.hbchemical.com
“MORE THAN A
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Lianda Corporation is a leading importer and distributor of specialty polymers
and chemicals for the rubber and plastics industries. For over 23 years, we have
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