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CPage#it) [Solution Slot - 1 (Chemistry) ACIDITY & BASICITY ERCISE - 1 HINT & SOLUTON Qi @ (@)H-F (b) H- cl (© H-Br ()H-1 LL 4 v ‘ F cr Bro r In aroup we see the size factor more the size, more stable the anion, more the acidity. d>c>b >a (acidic strength) i NH, {0 i -F ii) (a) * b) cy a) HN OM @~h, ©, "Sue (d) r- In period we see the E.N, factor more the electron negativity, more stable the anion, more the acidity. E.N. order = F > “OH > “NH, > “CH, Acidity order =d>c>b>a gs (ili) (a) CH, - CH, - O- H (0) CH CH-O-H (e) CHy-F-O-H y cH cH, +1@H)- cH, --0 .@ More stable -~CH-O — r CH ~ CH - 0 @- bo cH, @& 2(+D) effect — Three + I group less stable (acidic strength)a > b > c (iv) (a) F = CH, ~ CH, - 0-H =F - CH, - CH, -o° (b) NO, = CH, - CH,-OQ-H = NO, ~ CH, - CH, - (©) Br-CH,-CH,-O-H > Br-CH,-CH,- (d) NHy- CH, -CH,-O-H > NH; - CH, ~ CH, - o NH, > -NO, > - F > -Br acidic strength = d>b>a>c Q.2() (a) CH - COOH _-H*, CH, =c- =I order = ° (b) CH, - CH, - OH +1€H)- CH, 0 (©) CgHgOH _=H* , Che - (Phenoxide ion) Solution Slot - 1 (Chemistry) o _ oo (d) C,HsS0, —> [-Lorder - ¢- R > Ph] I 3 (More the resonating structures, more the stability) d>a>c>b Og COOH (b) ae wo oy SoH — i Ur... J yo ‘ io | ye sp sp ° (more-t) Stability =C >b>a acidity =c>b>a CH, - COOH I cOoH CH, - COOH 4 Goon oh HY ee we] 00H “He - - cH,-¢-0 Gili) (@) coo" (b) 7000 (c) a I cH, | oO coo_ “coo. CH, - § -o Q3 (a) C-cH,-€-0-H =H, c)-cH,- b- 0 (one 1 group) (b) Cl-GH,-C-O-H aH, c= en, - €-0 (0-1 909) a a FR | I ( oF e- 0-H Cl-¢-€- 0" (Three -1 groups) a (most stable) Ans. c>b>a (Pase#3s__) tl CH, ~ CH, = CH= C-0-H [Solution Slot - 1 (Chemistry) i Gi) (a) ait CHy-CHy- CH= C-0- F F (0) CHy-H- CH, -G-O-H HY, CH. CH CH, G07 F F ° q (0) GHy- CH CHy-C-0-H att, CH, CH CH, G- 0- F F ° In this type of case are see "pNP" rule. pistancé | Power Number Acidic strength = a > b>c i 1 - (ii) (2) No,-cH,-€-0-H 9 HY, NO, - CH, -C- oF . i (vb) F-CH,-C-0-H _cHt, F-cH,-C-o (c) Ph-CH,-C-O-H Ht, ph-cH,-C-o . 1 (d) CH;- CH, - C- OH Ht, CcH,-CH,-C-o Acidic Strength : a>b>c>d Qa) (a) (b) 6H (©) :0H oO NO, a cH, (strongel acid) L t o o No, a cH, “I “1 41 (most stable conjugate base) Acidic strength = a > b >c