Aakash JEE Advanced Paper 2 Code 0 Solution PDF

DATE : 21/05/2017 CODE
0
Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005
Ph.: 011-47623456 Fax : 011-47623472
Time : 3 hrs.
Answers & Solutions Max. Marks: 183
for
JEE (Advanced)-2017
PAPER - 2 (Code - 0)
INSTRUCTIONS
QUESTION PAPER FORMAT AND MARKING SCHEME :
1. The question paper has three parts : Physics, Chemistry and Mathematics.
2. Each part has three sections as detailed in the following table :
Section Question Number of Category-wise Marks for Each Question Maximum

Type Questions Marks
Full Marks Partial Marks Zero Marks Negative of the
Marks Section
1 Single 7 +3 — 0 –1 21
Correct If only the bubble If none of the In all other
Option corresponding to bubbles is cases
the correct option darkened
is darkened
2 One or 7 +4 +1 0 –2 28
more If only the For darkening a bubble If none of the In all other
correct bubble(s) corresponding to each bubbles is cases
option(s) corresponding to correct option, provided darkened
all the correct NO incorrect option is
option(s) is(are) darkened
darkened
3 Compre- 4 +3 — 0 — 12
hension If only the bubble In all other
corresponding to cases
the correct answer
is darkened
1
JEE (ADVANCED)-2017 (PAPER-2) CODE-0
PHYSICS
SECTION - 1 (Maximum Marks : 21)

This section contains SEVEN questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If only the bubble corresponding to the correct option is darkened
Zero Marks : 0 If none of the bubbles is darkened
Negative Marks : –1 In all other cases
1. Consider regular polygons with number of sides n = 3, 4, 5.... as shown in the figure. The center of mass of all
the polygons is at height h from the ground. They roll on a horizontal surface about the leading vertex without
slipping and sliding as depicted. The maximum increase in height of the locus of the center of mass for each
polygon is . Then depends on n and h as
h h h
2⎛⎞ ⎛ 2 ⎞
(A)   h sin ⎜ ⎟ (B)   h sin ⎜ ⎟
⎝n⎠ ⎝ n ⎠
2⎛  ⎞ ⎛ 1 ⎞
(C)   h tan ⎜ ⎟ (D)   h ⎜  1⎟
⎝ 2n ⎠ 
⎜⎜ cos ⎛⎜ ⎞⎟ ⎟⎟
⎝ ⎝ n ⎠ ⎠
Answer (D)
/n
Sol. l
h

 
 
2 n

sin   cos
n
h
l
sin 
=l–h
⎡ 1 ⎤
= h⎢  1⎥
⎣ sin  ⎦
⎡ 1 ⎤
= h⎢ 1
 ⎥
⎢ cos ⎥
⎣ n ⎦
2
2. Consider an expanding sphere of instantaneous radius R whose total mass remains constant. The expansion is
such that the instantaneous density  remains uniform throughout the volume. The rate of fractional change in
⎛ 1 d ⎞
density ⎜ ⎟ is constant. The velocity v of any point on the surface of the expanding sphere is proportional
⎝  dt ⎠
to
1
(A) R (B)
R
(C) R3 (D) R2/3

Answer (A)
4
Sol. M  R 3
3
4 ⎡ 2 dR d ⎤
0  3R   R3
3 ⎢⎣ dt dt ⎥⎦
Dividing by 
dR 1 d
0  3R 2  R3 
dt  dt
dR
3R 2  R 3K
dt
dR
R
dt
⎛ hc ⎞
3. A photoelectric material having work-function 0 is illuminated with light of wavelength  ⎜   . The fastest
⎝ 0 ⎟⎠
photoelectron has a de-Broglie wavelength d. A change in wavelength of the incident light by  result in a change
d in d. Then the ratio d / is proportional to
(A) d2 /  2 (B) d / 
(C) 3d /  (D) 3d /  2
Answer (D)
h
Sol. d 
⎛ hc ⎞
⎜   ⎟ 2m
⎝  ⎠
⎛ hc ⎞ h
2m ⎜  ⎟ 
⎝  ⎠ d
2
⎛ hc ⎞ h
2m ⎜ f ⎟  2
⎝  ⎠ d
⎛ 1 ⎞ h2
2m hc ⎜ 2 d  ⎟   3
⎝ ⎠ d
d d 3
 k d2
d 
3

4. Three vectors P , Q and R are shown in the figure. Let S be any point on the vector R . The distance between

the points P and S is b R . The general relation among vectors P, Q and S is
b|R
Y P |
P R QP
S S
Q Q
O X

(A) S  1  b2  P  bQ (B) S   b  1 P  bQ

(C) S  1  b  P  bQ (D) S  1  b  P  b 2Q
Answer (C)

Sol. S = P  b | R | Rˆ

R
= P  b|R|
|R |

= P  bR

= P  b Q – P 

= (1 – b) P  bQ
5. A person measures the depth of a well by measuring the time interval between dropping a stone and receiving
the sound of impact with the bottom of the well. The error in his measurement of time is T = 0.01 seconds and
he measures the depth of the well to be L = 20 meters. Take the acceleration due to gravity g = 10 ms–2 and
the velocity of sound is 300 ms–1. Then the fractional error in the measurement, L/L, is closest to
(A) 1% (B) 5%
(C) 3% (D) 0.2%
Answer (A)
2L
Sol. t1 =
g
L
t2 =
V
L t2
 T = t1 + t2 t1
2L L
 T= 
g V
2 1 1
 T =  L  L
g 2 L V
⎛ 1 1 1 ⎞
 0.01 = ⎜   ⎟ L
⎝ 5 2  20 300 ⎠
⎛ 1 1 ⎞
 0.01 = ⎜  ⎟ L
⎝ 20 300 ⎠
4
(15  1)
 0.01 = L
300
0.01  300
 L =
16
L 3
  100 =  100 = 1%
L 16  20
6. A rocket is launched normal to the surface of the Earth, away from the Sun, along the line joining the Sun and
the Earth. The Sun is 3 × 105 times heavier than the Earth and is at a distance 2.5 × 104 times larger than the
radius of the Earth. The escape velocity from Earth's gravitational field is ve = 11.2 km s–1. The minimum initial
velocity (vs) required for the rocket to be able to leave the Sun-Earth system is closest to
(Ignore the rotation and revolution of the Earth and the presence of any other planet)
(A) vs = 72 km s–1 (B) vs = 22 km s–1
(C) vs = 42 km s–1 (D) vs = 62 km s–1
Answer (C)
4
m r = 2.5 × 10 R
Sol. vs E S
5
M1 = M M2 = 3 × 10 M
loss in KE = Gain in PE
 1 GM1m GM2m
mv s2  
2 R r
 1 2 GM G × 3 × 105M
vs  
2 R 2.5 × 104R
GM
 vs  2 × × 13
R
= 11.2 × 13  40.4 km/s

42 km/s
7. A symmetric star shaped conducting wire loop is carrying a steady state current I as shown in the figure. The
distance between the diametrically opposite vertices of the star is 4a. The magnitude of the magnetic field at the
center of the loop is
4a
 0I ⎡  0I ⎡
(A) 6 3 – 1⎤ (B) 6 3  1⎤
4a ⎣ ⎦ 4a ⎣ ⎦
 0I ⎡  0I ⎡
(C) 3 3 – 1⎤ (D) 3 2 – 3⎤
4a ⎣ ⎦ 4a ⎣ ⎦
5
Answer (A)
Sol. Considering one section out of symmetric star shaped conducting wire loop.
From geometry :
O (Center of loop)
°
30
°
2a
30
a
0°
30° 12
I
Magnetic field at the center of the loop due to all 12 identical sections is additive in nature.
 0I
 Bnet = 12 × cos30  cos120
4a
 0I
=  6  ⎣⎡ 3  1⎦⎤
4a

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options is(are) correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4 marks;
darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get –2 marks, as a wrong option is also
darkened.
8. A wheel of radius R and mass M is placed at the bottom of a fixed step of height R as shown in the figure. A
constant force is continuously applied on the surface of the wheel so that it just climbs the step without slipping.
Consider the torque  about an axis normal to the plane of the paper passing through the point Q. Which of the
following options is/are correct?
S
P Q
R
X
6
(A) If the force is applied normal to the circumference at point P then  is zero
(B) If the force is applied tangentially at point S then  0 but the wheel never climbs the step
(C) If the force is applied at point P tangentially then  decreases continuously as the wheel climbs
(D) If the force is applied normal to the circumference at point X then  is constant
Answer (A, D)
Sol. Correct options (A, D) [ Treating magnitude of force constant]
For option (A):
Applied force passes through point Q.
So, its torque is zero.
For option (D):
Torque due to applied force at x remains constant.
9. Two coherent monochromatic point sources S1 and S2 of wavelength  = 600 nm are placed symmetrically on
either side of the centre of the circle as shown. The sources are separated by a distance d = 1.8 mm. This
arrangement produces interference fringes visible as alternate bright and dark spots on the circumference of the
circle. The angular separation between two consecutive bright spots is . Which of the following options is/are
correct?
P1

P2
S1 S2
d
(A) The angular separation between two consecutive bright spots decreases as we move from P1 to P2 along the
first quadrant
(B) A dark spot will be formed at the point P2
(C) The total number of fringes produced between P1 and P2 in the first quadrant is close to 3000
(D) At P2 the order of the fringe will be maximum
Answer (C, D)
Sol. d = 1.8 × 10–3 m
= 18 × 10–4 m
P1
P
S1 S2 P2
d
7
and  = 6 × 10–7 m
Path difference at point P (as shown)
x = S1P – S2P = d sin , where  angle is measured from vertical line as shown.
For bright fringe d sin  = m ...(i)
Point P1 is the point of central maxima.
At point P2, path difference (x) = d
If P2 is the point of bright fringe, then
d
d  m ⇒ m   3000

On differentiating equation (i)
d cos  () = (m)  = constant for consecutive bright fringe

cos     as varies from 0 to
2
10. A point charge +Q is placed just outside an imaginary hemispherical surface of radius R as shown in the figure.
Which of the following statements is/are correct?
Q
Q ⎛ 1 ⎞
(A) The electric flux passing through the curved surface of the hemisphere is  ⎜ 1 ⎟
2 0 ⎝ 2⎠
(B) The component of the electric field normal to the flat surface is constant over the surface
Q
(C) Total flux through the curved and the flat surfaces is
0
(D) The circumference of the flat surface is an equipotential
Answer (A, D)
Sol. Net flux through curved surface and flat surface = 0
Q
45º
R
R
 Curved = – Plane
⎡ Q  ⎤
 ⎢ 1  cos  ⎥
2
⎣ 0 ⎦
⎡ Q ⎛ 1 ⎞⎤
 ⎢ ⎜ 1 ⎟⎥
⎣ 2 0 ⎝ 2⎠⎦
The circumference points are equidistant from Q
 All points will be at the same potential.
 Option (A) and (D) are correct.
8
11. A rigid uniform bar AB of length L is slipping from its vertical position on a frictionless floor (as shown in the figure).
At some instant of time, the angle made by the bar with the vertical is . Which of the following statements about
its motion is/are correct?

L
O
(A) Instantaneous torque about the point in contact with the floor is proportional to sin
(B) The trajectory of the point A is a parabola
(C) The midpoint of the bar will fall vertically downward
(D) When the bar makes an angle  with the vertical, the displacement of its midpoint from the initial position is
proportional to (1 – cos)
Answer (A, C, D)
l
Sol. Torque about O, at any instant is mg. sin  .
2
 Option (A)
l
 2
mg
O
As no external force acts along x-axis, therefore centre of mass will fall vertically downward.
 Option (C)
P (x,y)
 l
2 l
l 2
cos
2 
O
Displacement of centre of mass along y-axis
l
 1  cos 
2
 Option (D)
l
x   sin , y  l cos 
2
2
⎛ 2x ⎞ y2
 ⎜ ⎟  2  1
⎝ l ⎠ l
 Trajectory is not parabola
9
12. A source of constant voltage V is connected to a resistance R and two ideal inductors L1 and L2 through a switch
S as shown. There is no mutual inductance between the two inductors. The switch S is initially open. At t = 0,
the switch is closed and current begins to flow. Which of the following options is/are correct?
S
R
+ V L1 L2
–
V L2
(A) After a long time, the current through L1 will be R L  L
1 2
V L1
(B) After a long time, the current through L2 will be R L  L
1 2
(C) The ratio of the currents through L1 and L2 is fixed at all times (t > 0)
V
(D) At t = 0, the current through the resistance R is
R
Answer (A, B, C)
V
Sol. Final current through battery =
R
V ⎛ L2 ⎞
 Current through L1 = R ⎜ L  L ⎟
⎝ 1 2⎠
V ⎛ L1 ⎞
Current through L2 = R ⎜ L  L ⎟
⎝ 1 2⎠
At t = 0 current through source = zero
– tR
⎛ L1L2 ⎞
At any time i = V  ⎛ 0 – V ⎞ ⎜⎝ L1  L2 ⎟⎠
e
R ⎜⎝ R ⎟⎠
L2
 Current through L1 = i L  L  i1
1 2
iL1
Current through L2 = L  L  i 2
1 2
i1 L2

i 2 L1
10
3R
13. A uniform magnetic field B exists in the region between x = 0 and x  (region 2 in the figure) pointing normally
2
into the plane of the paper. A particle with charge +Q and momentum p directed along x-axis enters region 2 from
region 1 at point P1 (y = –R). Which of the following option(s) is/are correct?
y
Region 1 Region 2 Region 3
× × ×
× × B ×
× × ×
× × ×
O × × ×
× × × P2 x
+Q P1 × × ×
(y = –R) × × ×
× × ×
3R/2
(A) When the particle re-enters region 1 through the longest possible path in region 2, the magnitude of the change
in its linear momentum between point P1 and the farthest point from y-axis is p / 2
8 p
(B) For B  , the particle will enter region 3 through the point P2 on x-axis
13 QR
2 p
(C) For B  , the particle will re-enter region 1
3 QR
(D) For a fixed B, particles of same charge Q and same velocity v, the distance between the point P1 and the
point of re-entry into region 1 is inversely proportional to the mass of the particle
Answer (B, C)
Sol. The particle will follow circular trajectory inside the magnetic field region. The magnetic field cannot change the
magnitude of velocity and momentum.
3R
For longest possible path, the radius of circular motion can be .
2
O P2
P1
At farthest point from y-axis, the momentum is directed upwards.

  p  2p
11
The radius and hence separation between p1 and re-entry point is proportional to m, if Q, v, B are same.
The particle will return to region only if it completes the half circle.
3R
r
2
mV 3R

B 2
p 3R

QB 2
2p
B
3QR
8p p 13R
If B  ;r  
13QR QB 8
 r
O P2
r-r cos R

P1
It passes through point P2 if r – r cos = R
R
3
12
sin   2 
r 13
13R ⎛ 5 ⎞
1– R
8 ⎝ 13 ⎟⎠
⎜
R=R
14. The instantaneous voltages at three terminals marked X, Y and Z are given by
Vx  V0 sin t ,
⎛ 2 ⎞
VY  V0 sin ⎜ t 
3 ⎟⎠
and
⎝
⎛ 4 ⎞
VZ  V0 sin ⎜ t 
⎝ 3 ⎟⎠
An ideal voltmeter is configured to read rms value of the potential difference between its terminals. It is connected
between points X and Y and then between Y and Z. The reading(s) of the voltmeter will be
1 3
(A) VYZ  V0 (B) VXY  V0
rms rms
2 2
(C) Independent of the choice of the two terminals rms

(D) VXY  V0
12
Answer (B, C)
⎛ 2 ⎞
Sol. VXY = V0 sin t – V0 sin ⎜ t 
⎝ 3 ⎟⎠
V0
V0
60°
3 V0
V0
rms 3V0
VXY 
2
⎛ 2 ⎞ ⎛ 4 ⎞
VYZ = V0 sin ⎜ t  ⎟  V0 sin ⎜ t  3 ⎟
⎝ 3 ⎠ ⎝ ⎠
3 V0
V0 V0
60°
V0
rms 3V0
VYZ 
2
 B, C

This section contains TWO Paragraphs.
Based on each paragraph, there are TWO questions.
For each question, darken the bubble(s) corresponding to the correct option in the ORS.
Zero Marks : 0 In all other cases
PARAGRAPH 1
Consider a simple RC circuit as shown in Figure 1.
Process 1: In the circuit the switch S is closed at t = 0 and the capacitor is fully charged to voltage V0 (i.e.,
charging continues for time T >> RC). In the process some dissipation (ED) occurs across the resistance R. The
amount of energy finally stored in the fully charged capacitor is EC.
V0
Process 2: In a different process the voltage is first set to and maintained for a charging time T >> RC. Then
3
2V0
the voltage is raised to without discharging the capacitor and again maintained for a time T >> RC. The
3
process is repeated one more time by raising the voltage to V0 and the capacitor is charged to the same final
voltage V0 as in Process 1.
13
These two processes are depicted in Figure 2.
v
Process 1
S V0
R 2V0/3
Process 2
C T >> RC
V + V0/3
–
T 2T t
Figure 1
Figure 2
15. In Process 1, the energy stored in the capacitor EC and heat dissipated across resistance ED are related by :
(A) EC = ED In 2 (B) EC = ED
1
(C) EC = 2ED (D) EC = ED
2
Answer (B)
Sol. Final charge on capacitor = CV
Wb = CV2
1
Ec = CV 2
2
ED = Wb – Ec
1
= CV2 – CV 2
2
1
= CV 2
2
EC  ED
16. In Process 2, total energy dissipated across the resistance ED is :

1⎛ 1 ⎞ ⎛1 2⎞
(A) ED  CV02 ⎟ (B) ED  3 ⎜ CV0 ⎟
3 ⎜⎝ 2 ⎠ ⎝2 ⎠
1
(C) ED  3CV02 (D) ED  CV02
2
Answer (A)
Sol. ED = Wb – V
CV0 ⎡V0 2V0 ⎤ 1

= ⎢   V0 ⎥ – CV02
3 ⎣3 3 ⎦ 2
CV0 ⎡V0  2V0  3V0 ⎤ 1 2
=
3 ⎢⎣ 3 ⎥ – 2 CV0
⎦
CV0 1
= 2V0  – CV02
3 2
⎛ 2 1⎞ 2
= ⎜ – ⎟ CV0
⎝ 3 2 ⎠
CV02
=
6
14
PARAGRAPH 2
One twirls a circular ring (of mass M and radius R) near the tip of one's finger as shown in Figure 1. In the process
the finger never loses contact with the inner rim of the ring. The finger traces out the surface of a cone, shown
by the dotted line. The radius of the path traced out by the point where the ring and the finger is in contact is r.
The finger rotates with an angular velocity 0. The rotating ring rolls without slipping on the outside of a smaller
circle described by the point where the ring and the finger is in contact (Figure 2). The coefficient of friction between
the ring and the finger is  and the acceleration due to gravity is g.
R
r
R
Figure 1 Figure 2
17. The total kinetic energy of the ring is
1
M 02  R  r 
2
(A) M 02  R  r 
2
(B)
2
3
M 02  R  r 
2
(C) M 02 R 2 (D)
2
Answer (C)
1 1
Sol. k  Mv c2  Ic 2
2 2
VC = 0(R – r)
1 1
 M 02 (R  r )2  MR 2 02
2 2
1 r ⎞ 1
2 0
⎛
 M 02R 2 ⎜ 1  ⎟  M 02R 2 R– r
2 ⎝ R ⎠ 2
r << R
r
0
R
1 1
k M 02R 2  M 02R 2
2 2
 M02R 2
18. The minimum value of 0 below which the ring will drop down is
g 3g
(A) 2  R  r  (B) 2  R  r 
g 2g
(C)  R  r  (D)  R  r 
15
Answer (C)
Sol. N
Mg
N = M2 (R – r)
f = Mg
f  N
Mg  M2 (R – r)
g
0 
 R  r 
END OF PHYSICS
16
CHEMISTRY

19. The order of basicity among the following compounds is

NH NH2
H3C NH2 N NH HN N
H2N NH
I II III IV
(A) IV > I > II > III (B) IV > II > III > I
(C) I > IV > III > II (D) II > I > IV > III
Answer (A)
NH2
Sol. H N NH
2
IV
Resonance with two NH2 groups increases electron density on 'N' of NH
NH
Lesser increase of electron density on = NH due to
only one resonance with one –NH2
CH3 NH2
sp2
N
–
N This LPe is not available as it is involve in aromatic Sextet.
H 'N' is bonded to sp2 C on both sides.
III
N This LPe– is not involve in aromaticity. So more available

H
Also, 'N' is bonded to sp3 C on one side.
II
 IV > I > II > III
17
20. The major product of the following reaction is
OH
i) NaNO2, HCl, 0°C

ii) aq.NaOH
NH2
– + OH
O Na
(A) (B)
N=N
N2Cl
OH
N=N OH
(C) (D)
Cl
Answer (B)
–
OH OH O
Sol. NaNO2 + HCl aq.NaOH

0°C
+
NH2 N+  NCl– NN
OH O
N=N N=N H
21. Which of the following combination will produce H2 gas?
(A) Au metal and NaCN(aq) in the presence of air (B) Zn metal and NaOH(aq)
(C) Fe Metal and conc. HNO3 (D) Cu metal and conc. HNO3
Answer (B)
Sol. Zn + 2NaOH  Na2ZnO2 + H2
Iron become passive with conc. HNO3.
Copper liberate NO2 with HNO3
22. The standard state Gibbs free energies of formation of C(graphite) and C(diamond) at T = 298 K are
fG°[C(graphite)] = 0 kJ mol–1
fG°[C(diamond)] = 2.9 kJ mol–1
The standard state means that the pressure should be 1 bar, and substance should be pure at a given temperature.
The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by 2 × 10–6 m3 mol–1. If
C(graphite) is converted to C(diamond) isothermally at T = 298 K, the pressure at which C(graphite) is in equilibrium
with C(diamond), is
[Useful information : 1 J = 1 kg m2s–2; 1 Pa = 1 kg m–1 s–2; 1 bar = 105 Pa]
(A) 14501 bar (B) 29001 bar
(C) 1450 bar (D) 58001 bar
18
Answer (A)
Sol. Gº = V·P
 2900  2  10 –6 P
2900  106
 P  Pa
2
PF–1 = 14500 bar

 PF = 14501bar
23. The order of the oxidation state of the phosphorus atom in H3PO2, H3PO4, H3PO3 and H4P2O6 is
(A) H3PO4 > H4P2O6 > H3PO3 > H3PO2 (B) H3PO2 > H3PO3 > H4P2O6 > H3PO4
(C) H3PO4 > H3PO2 > H3PO3 > H4P2O6 (D) H3PO3 > H3PO2 > H3PO4 > H4P2O6
Answer (A)
Sol. Oxidation state
H3PO4 P=+5
H4P2O6 P=+4
H3PO3 P=+3
H3PO2 P=+1
H3PO4 > H4P2O6 > H3PO3 > H3PO2
24. For the following cell,
Zn(s) | ZnSO4(aq) || CuSO4(aq) | Cu(s)
when the concentration of Zn2+ is 10 times the concentration of Cu2+, the expression for G (in J mol–1) is
[F is Faraday constant; R is gas constant; T is temperature; E°(cell) = 1.1 V]
(A) 2.303RT – 2.2F (B) 1.1F
(C) –2.2F (D) 2.303RT + 1.1F
Answer (A)
Sol. Zn | ZnSO4 || CuSO4 | Cu

(aq) (aq)
G =G° + RT In Q
G = G° + 2.303 RT log Q

⎛ [Zn2 ] 10 ⎞
⎜⎜ Q   ⎟
⎝ [Cu2 ] 1 ⎟⎠
G°= – nF E°Cell
= – 2F  1.1
= – 2.2 F
10
G = – 2.2 F + 2.303 RT log
1
G  2.303 RT – 2.2 F
19
25. Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water changes the freezing
point of the solution. Use the freezing point depression constant of water as 2 K kg mol–1. The figures shown below
represent plots of vapour pressure (V.P.) versus temperature (T). [molecular weight of ethanol is 46 g mol–1]
Among the following, the option representing change in the freezing point is
1
Wate ter
r Wa
Ice 1 nol
V.P./bar
V.P./bar
tha
(A) (B) Ice +E
ter
Wa
Water + Et
h anol
270 273 271 273
T/K T/K
1
ter Wate
Wa r
1 nol Ice
V.P./bar
V.P./bar
tha
(C) Ice +E (D)
ter
Wa
Water + Et
h anol
270 273 271 273
T/K T/K
Answer (C)
⎡ W  1000 ⎤
Sol. Tf = iK f ⎢ 2 ⎥
⎣ M2  W1 ⎦
⎡ 34.5  1000 ⎤
= 1 2 ⎢
⎣ 46  500 ⎥⎦
=3K
273 (K) – Tf = 3 (K)
 Tf = 270 K
Also, with decrease in temperature, V.P. decreases.
 Graph (C) is correct.

option is darkened
darkened.
20
26. In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The correct option(s) among
the following is(are)
(A) The activation energy of the reaction is unaffected by the value of the steric factor
(B) Since P = 4.5, the reaction will not proceed unless an effective catalyst is used
(C) The value of frequency factor predicted by Arrhenius equation is higher than that determined experimentally
(D) Experimentally determined value of frequency factor is higher than that predicted by Arrhenius equation
Answer (A, D)
A exp erimental
Sol. Steric factor 
A calculated
Steric factor = 4.5
It means Aexperimental > Acalculated
[This seems that reaction occurs more quickly than particles collide, thus concept of steric factor was introduced]
27. For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its
equilibrium constant K in terms of change in entropy is described by
(A) With increase in temperature, the value of K for exothermic reaction decreases because favourable change
in entropy of the surroundings decreases
(B) With increase in temperature, the value of K for exothermic reaction decreases because the entropy change
of the system is positive
(C) With increase in temperature, the value of K for endothermic reaction increases because the entropy change
of the system is negative
(D) With increase in temperature, the value of K for endothermic reaction increases because unfavourable change
in entropy of the surroundings decreases
Answer (A, B, D)
Sol. Whether reaction is endothermic or exothermic in forward direction increase in temperature cause intake of heat
from surrounding to system in endothermic direction due to which entropy change in system is positive and S
of surrounding is negative.
28. The correct statement(s) about surface properties is(are)
(A) Adsorption is accompanied by decrease in enthalpy and decrease in entropy of the system
(B) Cloud is an emulsion type of colloid in which liquid is dispersed phase and gas is dispersion medium
(C) The critical temperatures of ethane and nitrogen are 563 K and 126 K, respectively. The adsorption of ethane
will be more than that of nitrogen on same amount of activated charcoal at a given temperature
(D) Brownian motion of colloidal particles does not depend on the size of the particles but depends on viscosity
of the solution
Answer (A, C)
Sol. Adsorption is an exothermic process and is accompanied by decrease is entropy,
H  0, S  0
sys sys
More is critical temperature (Tc), more are intermolecular forces of attraction.

 More is extent of adsorption.
29. Among the following, the correct statement(s) is(are)
(A) AlCl3 has the three-centre two-electron bonds in its dimeric structure
(B) BH3 has the three-centre two-electron bonds in its dimeric structure
(C) Al(CH3)3 has the three-centre two-electron bonds in its dimeric structure
(D) The Lewis acidity of BCl3 is greater than that of AlCl3
21
Answer (B, C, D)
H e– H e
– H
Sol. B – B It has two 3c-2e bonds.
e– e
H H H
Cl Cl Cl
2AlCl3  Al Al No 3c-2e bond
Cl Cl Cl
CH3 CH3 CH3

Al Al Has two 3c-2e bonds.
CH3 CH3 CH3
Also BCl3 is stronger lewis acid than AlCl3.

30. For the following compounds, the correct statement(s) with respect to nucleophilic substitution reaction is(are)
CH3 CH3
Br Br H3C – C – Br Br
CH3
I II III IV
(A) I and III follow SN1 mechanism
(B) Compound IV undergoes inversion of configuration
(C) The order of reactivity for I, III and IV is : IV > I > III
(D) I and II follow SN2 mechanism
Answer (A, B, D)
Sol. When medium is highly polar and protic I & III will follow SN1.
Hence, (A) is correct.
Option (B) is correct as
Nu–
Br Nu
SN2
Inversion in case of SN2.

(D) I & II will follow SN2 when medium is polar aprotic and nucleophile is strong in high concentration.
(C) is incorrect for both SN1 and SN2 conditions.
31. The option(s) with only amphoteric oxides is(are)
(A) ZnO, AI2O3, PbO, PbO2
(B) Cr2O3, CrO, SnO, PbO
(C) Cr2O3, BeO, SnO, SnO2
(D) NO, B2O3, PbO, SnO2
Answer (A, C)
Sol. ZnO, Al2O3, PbO, PbO2, Cr2O3, BeO, SnO and SnO2 are amphoteric oxides.
NO is neutral oxide
CrO is basic oxide
B2O3 is acidic oxide
22
32. Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is C8H8O.
Q undergoes Cannizzaro reaction but not haloform reaction, whereas S undergoes haloform reaction but not
Cannizzaro reaction
i) O3/CH2CI2
(i) P Q
ii) Zn/H2O (C8H8O)
i) O3/CH2CI2
(ii) R S
ii) Zn/H2O (C8H8O)
The option(s) with suitable combination of P and R, respectively, is(are)
H3C
CH3 CH3
CH3
(A) and
CH3 CH3
(B) H3C and

CH3
CH3 H3C
CH3
(C) and
H3C CH3
(D) H3C and H 3C

CH3
Answer (B, C)
O O
(i) O3/CH2Cl2
Sol. CH3 CH3 C–H+H–C–H
(ii) Zn/H2O
Undergoes
Cannizzaro's
reaction
CH2 O O
O3/CH2Cl2
C C + H–C–H
Zn/H2O
CH3 CH3
Undergoes
Haloform reaction
O O
O3/CH2Cl2
CH3 C – H + CH3 – C – H
Zn/H2O
CH3 CH3 Undergoes

Cannizzaro's reaction
CH3
CH3 O CH3 CH3
O3/CH2Cl2
C +
Zn/H2O
CH3 O
CH3
CH3 Undergoes
Haloform reaction
23

PARAGRAPH 1
Upon heating KCIO3 in the presence of catalytic amount of MnO2, a gas W is formed. Excess amount of W reacts
with white phosphorus to give X. The reaction of X with pure HNO3 gives Y and Z.
33. W and X are, respectively
(A) O3 and P4O6 (B) O2 and P4O6
(C) O2 and P4O10 (D) O3 and P4O10
Answer (C)
34. Y and Z are, respectively
(A) N2O5 and HPO3 (B) N2O3 and H3PO4
(C) N2O4 and HPO3 (D) N2O4 and H3PO3
Answer (A)
Solutions of Q.No (33) & (34)
[MnO ]
Sol. 2KClO3 
2
 2KCl  3O2
(W )
5O2  P4  P4O10
(X)
P4O10  4HNO3  2N2O5  4HPO3

(X) (Z)
PARAGRAPH 2
The reaction of compound P with CH3MgBr (excess) in (C2H5)2O followed by addition of H2O gives Q. The
compound Q on treatment with H2SO4 at 0ºC gives R. The reaction of R with CH3COCl in the presence of
anhydrous AlCl3 in CH2Cl2 followed by treatment with H2O produces compound S. [Et in compound P is ethyl
group]
(H3 C)3C
CO2Et
Q R S
P
35. The reactions, Q to R and R to S, are
(A) Dehydration and Friedel-Crafts acylation
(B) Friedel-Crafts alkylation, dehydration and Friedel-Crafts acylation
(C) Friedel-Crafts alkylation and Friedel-Crafts acylation
(D) Aromatic sulfonation and Friedel-Crafts acylation
24
Answer (B)
36. The product S is
HO3S
O CH3 H3COC
(H3C)3C
(H3C)3C H3C CH3
(A) (B)
COCH3
H3C
CH3
(H3C)3C COCH3
(H3 C)3C CH3
(C) (D)
COCH3
Answer (C)
Solutions of Q. 35 and 36
– +
O OMgBr
C(CH3)3 C – OEt CH3MgBr (excess)/(C2H5)2O C(CH3)3 CH3–C–CH3
(P)
H2O
H H
O O–H
C(CH3)3 C(CH3)2 H2SO4/ C(CH3)3 CH3–C–CH3
0°C
(Q)
–H2O (dehydration)
CH3
CH3
C(CH3)3 C(CH3)2 C(CH3)3
(alkylation)
(R)
O
CH3–C–Cl/AlCl3
(Acylation)
CH3
CH3
C(CH3)3
COCH3
(S)
END OF CHEMISTRY
25
MATHEMATICS
37. Let S = {1, 2, 3, ..., 9}. For k = 1, 2, ..., 5, let Nk be the number of subsets of S, each containing five elements
out of which exactly k are odd. Then N1 + N2 + N3 + N4 + N5 =
(A) 125
(B) 210
(C) 252
(D) 126
Answer (D)
Sol. Required number of subsets
= 5C1 × 4C4 + 5C2 × 4C3 + 5C3 × 4C2 + 5C4 × 4C1 + 5C5 × 4C0
= 5 + 40 + 60 + 20 + 1
= 126
Alternate method
Coefficient of x5 in (1 + x)5(1 + x)4
= 9C5
= 126
38. The equation of the plane passing through the point (1, 1, 1) and perpendicular to the planes 2x + y – 2z = 5
and 3x – 6y – 2z = 7, is
(A) –14x + 2y + 15z = 3
(B) 14x – 2y + 15z = 27
(C) 14x + 2y – 15z = 1
(D) 14x + 2y + 15z = 31
Answer (D)
Sol. Required equation of plane is
x 1 y 1 z 1
2 1 2  0
3 6 2
 –14(x – 1) – 2(y – 1) + (–15)(y – 1) = 0
 14 x  2y  15 y  31
26
39. Let O be the origin and let PQR be an arbitrary triangle. The point S is such that

OP  OQ  OR  OS  OR  OP  OQ  OS  OQ  OR  OP  OS
Then the triangle PQR has S as its
(A) Incentre
(B) Circumcentre
(C) Orthocenter
(D) Centroid
Answer (C)

Sol. OP  OQ  OR  OS  OR  OP  OQ  OS  OQ  OR  OP  OS
P

OP  OQ  OR  OS  OR  OP  OQ  OS
S
 OP  (OQ  OR )  OS  (OR  OQ )  0

 RQ  (OP  OS )  0 Q R

 RQ  SP  0

 RQ  SP

and similarly from OR  OP  OQ  OS  OQ  OR  OP  OS

SR  PQ
 S is the orthocentre.
40. How many 3 × 3 matrices M with entries from {0, 1, 2} are there, for which the sum of the diagonal entries of
MT M is 5?
(A) 162
(B) 135
(C) 126
(D) 198
Answer (D)
⎡ a1 b1 c1 ⎤ ⎡a1 a2 a3 ⎤
⎢
Sol. Let M  ⎢a2 b2 c2 ⎥⎥ , M T  ⎢⎢b1 b2 b3 ⎥⎥
⎢⎣a3 b3 c3 ⎥⎦ ⎢⎣c1 c2 c3 ⎥⎦
3
Sum of diagonal entries = ∑a
i 1
2
i  bi2  ci2   5
 Possible cases are (one 2, one 1 and seven zeros) or (five 1's and four 0's)
9! 9!
   72  126  198
7! 5!4!
27
41. Three randomly chosen non-negative integers x, y and z are found to satisfy the equation x + y + z = 10. Then
the probability that z is even, is
6
(A)
11
36
(B)
55
1
(C)
2
5
(D)
11
Answer (A)
Sol. x + y + z = 10
12  11
n(s) = 10+3–1C = 12C =  66
3–1 2
2
Let z = 2n, where n = 0, 1, 2, 3, 4, 5
x + y + 2n = 10
x + y = 10 – 2n
5
Total such solution  ∑ (11  2n )  36
n 0
36 6
P(E) = 
66 11
1 1
42. If f : »  » is a twice differentiable function such that f (x) > 0 for all x » , and f ⎛⎜ ⎞⎟  , f (1)  1 , then
⎝ 2⎠ 2
1
(A)  f (1)  1
2
1
(B) 0  f (1) 
2
(C) f (1)  0
(D) f (1)  1
Answer (D)
1 1
Sol. f ( x )  0 , f ⎛⎜ ⎞⎟  and f(1) = 1
⎝2⎠ 2
B
f ( x ) is always increasing 1
1 A
f (1)  f ⎛⎜ ⎞⎟ 1/2
f (1)  ⎝2⎠
1
1 1/2 1
2
f (1)  1
Slope of tangent at B > Slope of chord AB.
28
 
1
43. If y = y(x) satisfies the differential equation 8 x  9  x  dy  4 9 x dx , x  0 and y  0  7 , then
y(256) =
(A) 80
(B) 9
(C) 16
(D) 3
Answer (D)
dx
Sol. As, dy 
8 x 9 x  4 9 x
Integrating,
y  4 9 x c
at x = 0, y  7  c = 0
so, y  4  9  x
at x = 256, y = 3

option is darkened
darkened.
44. If the line x =  divides the area of region R   x, y   »2 : x 3  y  x,0  x  1 into two equal parts, then
1
(A) 0   
2
(B) 2 4  4 2  1  0
(C)  4  4 2  1  0
1
(D)   1
2
29
Answer (B, D)
 1
3 3 y
Sol. ∫ ( x  x ) dx  ∫ ( x  x ) dx
0  y = x3
y=x
 1
x2 x4 2
x x
4
 
 4 0 2 4 
2 x 4 ⎛ 1 1 ⎞ ⎛ 2  4 ⎞
   ⎜  ⎟⎜  ⎟
2 4 ⎝2 4⎠ ⎝ 2 4 ⎠ x
O (0, 0) (1, 0)
4 1 x=
  2   0
2 4
 2 4  42  1  0
Let f ( )  2 4  42  1
1 1
f (0)  1  0 , f ⎛⎜ ⎞⎟   0
⎝2⎠ 8
f (1)  1  0
⎛1 ⎞
 ⎜ , 1⎟
⎝2 ⎠
cos(2 x ) cos(2 x ) sin(2 x )

45. If f ( x )   cos x cos x  sin x , then
sin x sin x cos x
(A) f(x) attains its maximum at x = 0

(B) f(x) attains its minimum at x = 0
(C) f (x) = 0 at more than three points in (–, )
(D) f (x) = 0 at exactly three points in (–, )
Answer (A, C)
Sol. C1  C1  C2
0 cos 2 x sin2 x
f ( x )  2cos x cos x  sin x
0 sin x cos x
 f ( x )  2cos x (cos 2 x cos x  sin x sin 2 x )
 f ( x )  2cos x cos3 x ; (f(0) = 2 maximum at x = 0)
 f ( x )  cos 4 x  cos 2 x
30
f ( x )  2sin2 x (4cos 2 x  1)
1
 sin 2 x  0 or cos 2 x  
4
2x  0, ,  
  1
x  0, ,  and cos 2 x   gives 4 solutions in (–, )
2 2 4
 Total number of solutions = 7
98 k 1
46. If I  ∑ k 1 ∫ kk 1 dx, then
x( x  1)
49
(A) I 
50
49
(B) I 
50
(C) I < loge99

(D) I > loge99
Answer (A, C)
98
⎛ k 1 dx ⎞
Sol. I = ∑ (k  1) ⎜⎝ ∫
k 1 x( x  1) ⎟⎠
k
k 1
98
⎧ ⎛ x ⎞⎫ 98
⎧ ⎛ k  1⎞ ⎛ k ⎞⎫
 ∑
k 1
(k  1) ⎨log ⎜ ⎟⎬
⎩ ⎝ 1  x ⎠ ⎭k
 ∑ (k  1) ⎨log ⎜
k 1 ⎩ ⎝ k  2
⎟⎠  log ⎜⎝ ⎟⎬
k  1⎠ ⎭
98
⎧ ⎛ k  1⎞ ⎛ k ⎞⎫
 ∑ ⎩⎨(k  1)log ⎜⎝ k  2 ⎟⎠  k log ⎜⎝ k  1⎟⎠ ⎭⎬  log(k  1)  log k 
k 1
⎧ ⎛ 99 ⎞ ⎛ 1⎞ ⎫
 ⎨99log ⎜
⎝ ⎟⎠  log ⎜⎝ ⎟⎠ ⎬   log99  log1
⎩ 100 2 ⎭
⎛ 99 ⎞
 99log ⎜ ⎟  log2  loge (99)
⎝ 100 ⎠
1  x(1  1  x ) ⎛ 1 ⎞
47. Let f ( x )  cos ⎜ for x  1. Then
1 x ⎝ 1  x ⎟⎠
(A) limx 1 f ( x )  0
(B) limx 1 f ( x )  0
(C) limx 1 f ( x ) does not exist
(D) limx 1 f ( x ) does not exist
31
Answer (B, C)
1  x (1  | 1  x |) ⎛ 1 ⎞
Sol. f ( x )  cos ⎜ ⎟
| 1 x | ⎝ 1 x ⎠
1  x (1  x  1) ⎛ 1 ⎞
lim cos ⎜ ⎟
x 1  ( x  1) ⎝ 1 x ⎠
1 x2 ⎛ 1 ⎞
lim cos ⎜ ⎟
 ( x  1)
x 1 ⎝ 1 x ⎠
⎛ 1 ⎞
lim – (1  x )cos ⎜ ⎟ = a number lying between –2 and 2
x 1 ⎝ 1 x ⎠
Hence, limit does not exist.
1  x (1  (1  x )) ⎛ 1 ⎞
lim cos ⎜ ⎟
x 1  (1  x ) ⎝ 1 x ⎠
1  x (2  x ) ⎛ 1 ⎞
lim cos ⎜ ⎟
x 1 (1  x ) ⎝ 1 x ⎠
⎛ 1 ⎞
lim(1  x )cos ⎜ ⎟0
x 1 ⎝ 1 x ⎠
48. If f : »  » is a differentiable function such that f(x) > 2f(x) for all x  », and f(0) = 1, then
(A) f(x) is increasing in (0, )
(B) f(x) < e2x in (0, )
(C) f(x) > e2x in (0, )
(D) f(x) is decreasing in (0, )
Answer (A, C)
Sol. f ( x )  2f ( x )  0
e 2 x  f ( x )  2e 2 x  f ( x )  0
d
dx
 e 2 x f ( x )  0  e2x  f ( x ) is increasing function.
e 2 x  f ( x )  1 for all x  (0,  )
f ( x )  e2 x
∵ f ( x )  2f ( x )  e2 x  0
 f(x) is increasing
f ( x )  f (0) f (x)  1
Also as, f ( x )   f ( x ) 
x 0 x
i.e., f ( x )  e2 x  x  (0, 1)
 e2 x  x  (1, )
32
sin(2 x )
49. If g ( x )  ∫ sin1(t )dt, then
sin x
⎛ ⎞
(A) g  ⎜  ⎟  2
⎝ 2⎠
⎛ ⎞
(B) g  ⎜  ⎟  2
⎝ 2⎠
⎛ ⎞
(C) g  ⎜⎝ ⎟⎠  2
2
⎛ ⎞
(D) g  ⎜ ⎟  2
⎝ 2⎠
Answer (No options is correct)
Sol. g ( x )   sin1  sin 2 x   2cos 2 x   sin1  sin x   cos x
 ⎛⎞ ⎛ ⎞
g⎜ ⎟  0 , g⎜  ⎟  0
⎝2⎠ ⎝ 2⎠
None of the given options is correct.
50. Let  and  be non-zero real numbers such that 2(cos – cos) + cos cos = 1. Then which of the following
is/are true?
⎛ ⎞ ⎛ ⎞
(A) tan ⎜ ⎟  3 tan ⎜ ⎟  0
⎝ 2⎠ ⎝ 2⎠
⎛ ⎞ ⎛ ⎞
(B) 3 tan ⎜ ⎟  tan ⎜ ⎟  0
⎝ 2⎠ ⎝ 2⎠
⎛ ⎞ ⎛ ⎞
(C) tan ⎜ ⎟  3 tan ⎜ ⎟  0
⎝ 2⎠ ⎝ 2⎠
⎛ ⎞ ⎛ ⎞
(D) 3 tan ⎜ ⎟  tan ⎜ ⎟  0
⎝ 2⎠ ⎝ 2⎠
Answer (A, C)
Sol. As 2(cos – cos) = 1 – coscos
2cos   1
⇒ cos  
2  cos 
Using componendo and dividendo
1  cos  ⎛ 1  cos  ⎞
⇒  3⎜ ⎟
1  cos  ⎝ 1  cos  ⎠
 
⇒ tan2  3 tan2  0
2 2
 
So, tan  3 tan  0
2 2
Or
 
tan  3 tan  0
2 2
33

PARAGRAPH-1

Let O be the origin, and OX , OY , OZ be three unit vectors in the directions of the sides QR, RP, PQ ,
respectively, of a triangle PQR.

51. | OX  OY | 
(A) sin (P + R)
(B) sin 2R
(C) sin (P + Q)
(D) sin (Q + R)
Answer (C)

QR  RP
Sol. OX  OY 
pq
pq sin R

pq
 sin(P  Q )
52. If the triangle PQR varies, then the minimum value of cos(P  Q )  cos(Q  R )  cos(R  P ) is
3
(A) 
2
3
(B)
2
5
(C)
3
5
(D) 
3
Answer (A)
Sol. cos(P + Q) + cos(Q + R) + cos(R + P) = –(cosP + cosQ + cosR)
3
Maximum value of cosP + cosQ + cosR =
2
3
Hence minimum of –(cosP + cosQ + cosR) = 
2
34
PARAGRAPH-2
Let p, q be integers and let ,  be the roots of the equation, x2 – x – 1 = 0, where  . For n = 0, 1, 2, ... ,
let an = pn + qn.
FACT : If a and b are rational numbers and a  b 5  0 , then a = 0 = b.
53. If a4 = 28, then p + 2q =

(A) 12
(B) 21
(C) 14
(D) 7
Answer (A)
Sol. a4 = 28
4 4
⎛ ⎞ ⎛ ⎞
p ⎜ 1  5 ⎟  q ⎜ 1  5 ⎟  28
⎝ 2 ⎠ ⎝ 2 ⎠
 56( p  q )  24 5( p  q )  28  16
 p=q=4
54. a12 =
(A) a11  2a10
(B) a11  a10
(C) a11  a10
(D) 2a11  a10
Answer (B)
Sol. 2 –  – 1 = 0  12 = 11 + 10 ...(i)
and 12 = 11 + 10 ...(ii)
Multiplying (i) by p and (ii) by q and adding, a12 = a11 + a10
END OF MATHEMATICS
35

Aakash JEE Advanced Paper 2 Code 0 Solution PDF

Enviado por

Dados do documento

Descrição original:

Título original

Direitos autorais

Formatos disponíveis

Compartilhar este documento

Compartilhar ou incorporar documento

Opções de compartilhamento

Você considera este documento útil?

Este conteúdo é inapropriado?

Direitos autorais:

Formatos disponíveis

Aakash JEE Advanced Paper 2 Code 0 Solution PDF

Enviado por

Direitos autorais:

Formatos disponíveis

DATE : 21/05/2017 CODE

2. Each part has three sections as detailed in the following table :

Section Question Number of Category-wise Marks for Each Question Maximum

SECTION - 1 (Maximum Marks : 21)

Zero Marks : 0 If none of the bubbles is darkened

Negative Marks : –1 In all other cases

(C) R3 (D) R2/3

(A) d2 /  2 (B) d / 

(C) 3d /  (D) 3d /  2

= 11.2 × 13  40.4 km/s

SECTION - 2 (Maximum Marks : 28)

This section contains SEVEN questions.

Zero Marks : 0 If none of the bubbles is darkened

Negative Marks : –2 In all other cases

 Trajectory is not parabola

At t = 0 current through source = zero

At farthest point from y-axis, the momentum is directed upwards.

It passes through point P2 if r – r cos = R

(C) Independent of the choice of the two terminals rms

SECTION - 3 (Maximum Marks : 12)

16. In Process 2, total energy dissipated across the resistance ED is :

CV0 ⎡V0 2V0 ⎤ 1

17. The total kinetic energy of the ring is

SECTION - 1 (Maximum Marks : 21)

Zero Marks : 0 If none of the bubbles is darkened

Negative Marks : –1 In all other cases

19. The order of basicity among the following compounds is

Resonance with two NH2 groups increases electron density on 'N' of NH

N This LPe– is not involve in aromaticity. So more available

 IV > I > II > III

i) NaNO2, HCl, 0°C

Sol. NaNO2 + HCl aq.NaOH

PF–1 = 14500 bar

Sol. Zn | ZnSO4 || CuSO4 | Cu

G = G° + 2.303 RT log Q

SECTION - 2 (Maximum Marks : 28)

This section contains SEVEN questions.

Zero Marks : 0 If none of the bubbles is darkened

Negative Marks : –2 In all other cases

More is critical temperature (Tc), more are intermolecular forces of attraction.

CH3 CH3 CH3

Also BCl3 is stronger lewis acid than AlCl3.

Inversion in case of SN2.

(B) H3C and

(D) H3C and H 3C

CH3 CH3 Undergoes

SECTION - 3 (Maximum Marks : 12)

Zero Marks : 0 In all other cases

P4O10  4HNO3  2N2O5  4HPO3

 –14(x – 1) – 2(y – 1) + (–15)(y – 1) = 0

Then the triangle PQR has S as its

SECTION - 2 (Maximum Marks : 28)

cos(2 x ) cos(2 x ) sin(2 x )

(A) f(x) attains its maximum at x = 0

 f ( x )  2cos x (cos 2 x cos x  sin x sin 2 x )

 f ( x )  2cos x cos3 x ; (f(0) = 2 maximum at x = 0)

 Total number of solutions = 7

(C) I < loge99

(A) limx 1 f ( x )  0

(B) limx 1 f ( x )  0

(C) limx 1 f ( x ) does not exist

(D) limx 1 f ( x ) does not exist