Escolar Documentos
Profissional Documentos
Cultura Documentos
INSTRUCTIONS:
1. Detach one (1) answer sheet from the bottom of your Examinee ID/Answer Sheet Set.
2. Write the subject title "CHEMICAL ENGINEERING PRINCIPLES” on the box provided.
3. Shade Set Box "A" on your answer sheet if your test booklet is Set A; Set Box "B" if your
test booklet is Set B.
In order to extract acetic acid from dilute aqueous solution with isopropyl ether,
the two immiscible phases are passed countercurrently through a packed column 3 m in
Chemical Engineering Principles – Set A Page 3 of 14
length and 75 mm in diameter. It is found that, if 0.5 kg/m^2s of the pure ether is
used to extract 0.25 kg/m^2s of 4.0 per cent acid by mass, then the ether phase leaves
the column with a concentration of 1.0 per cent acid by mass. (Hint: Heightunit =
L’R/KRa) The equilibrium relationship is given by: (kg acid/kg isopropyl ether) = 0.3
(kg acid/kg water)
600 ml/s of water at 320 K is pumped in a 40 mm inside diameter pipe through a total
length of 150 m in a horizontal direction and up through a vertical height of 10m.
In the pipe there is a control valve which may be taken as equivalent to 200 pipe
diameters and there are other fittings equivalent to 60 pipe diameters. Also, in the
line there is a heat exchanger across which there is a loss in head of 1.5 m of water.
If the main pipe has a roughness of 0.0002 m and the overall pump efficiency is 60%,
24. How much is the head loss due to the valve and fittings?
a. 1.1 J/kg
b. 1.1 x 10^3 J/kg
c. 9.1 x 10^6 J/kg
d. 9.1 x 10^7 J/kg
25. What is the total dynamic head?
a. 2.3 x 10^7 J/kg
b. 2.2 x 10^6 J/kg
c. 130 J/kg
d. None of the choices
26. What is the power requirement of the pump?
a. 128 W
b. 1.3 x10^2 J/kg
c. 1.3 x10^3 kW
d. 1.3 x10^2 kW
27. 10 metric tons (10 Mg) of a solution containing 0.3 kg Na2CO3/kg solution is
cooled slowly to 293 K to form crystals of Na2CO3.10H2O. What is the yield of
crystals if the solubility of Na2CO3 at 293 K is 21.5 kg/100 kg water and during
cooling 3 percent of the original solution is lost by evaporation?
a. 3288 kg
b. 9338 kg
c. 4669 kg
d. 6536 kg
28. Allows the engineer to explore the kinetics of a photophysical intermolecular
deactivation process.
a. Equilibrium constant
b. Pre-exponential factor
c. Stern-Volmer relationship
d. Damkohler number
29. This phenomenon occurs in a fluid flow system when the local static pressure
drops below the vapor pressure of the liquid at the existing temperature, resulting
to damage to pumps and control valves from the formation of “bubbles” or voids.
a. Cavitation
b. Choked flow
c. Flashing
d. Water hammering
30. The stoichiometric air-fuel ratio of pure lauric acid methyl ester (MW = 200.32)
is:
a. 10
b. 14.5
c. 8.4
d. 11.7
MN/m2 and the pressure of this gas is raised to 2.6 MN/m2 by a pump at the upstream
end of the pipe. The conditions of flow are isothermal and the temperature of the gas
is 293 K. Viscosity of hydrogen = 0.009 mN-s/m^2 at 293 K.
Tests on a small scale tank 0.3 m diameter (Rushton impeller, diameter 0.1 m) have
shown that a blending process between two miscible liquids (aqueous solutions,
properties approximately the same as water, i.e. viscosity 1 mN s/m2, density 1000
kg/m3) is satisfactorily completed after 1 minute using an impeller speed of 250
rev/min. It is decided to scale up the process to a tank of 2.5 m diameter using the
criterion of constant tip-speed.
c. transition plate
d. bubble plate
39. In the extraction of acetic acid from an aqueous solution with benzene a
packed column of height 1.4 m and cross-sectional area 0.0045 m2, the
concentrations measured at the inlet and the outlet of the column are:
acid concentration in the inlet water phase, CW2 = 0.69 kmol/m3.
acid concentration in the outlet water phase, CW1 = 0.684 kmol/m3.
flowrate of benzene phase = 5.6 × 10^−6 m3/s = 1.24 × 10^−3 m3/m2s.
inlet benzene phase concentration, CB1 = 0.0040 kmol/m3.
outlet benzene phase concentration, CB2 = 0.0115 kmol/m3.
Determine the overall transfer coefficient in kmol/m^3
a. 3.33 x 10^-5
b. 7.66 × 10^−4
c. 13.54 x 10^-4
d. 7.99 x 10^-4
40. A liquid with no appreciable elevation of boiling-point is concentrated in a
triple-effect evaporator. If the temperature of the steam to the first effect is
395 K and vacuum is applied to the third effect so that the boiling-point is 325
K, what are the approximate boiling-points in the three effects (T1, T2, and
T3)? The overall transfer coefficients may be taken as 3.1, 2.3, and 1.1 kW/m2 K
in the three effects respectively.
a. 381.5 K, 325 K, 363.2 K
b. 325 K, 363.2 K, 381.5 K
c. 363.2 K, 381.5 K, 325 K
d. 381. 5K, 363.2 K, 325 K
41. 0.126 kg/s of a solid product containing 4 percent water is produced in a dryer
from a wet feed containing 42 percent water on a wet basis. Ambient air at 294 K
and of 40 percent relative humidity is heated to 366 K in a preheater before
entering the dryer from which it leaves at 60 percent relative humidity. Assuming
that the dryer operates 224 adiabatically, what must be the flowrate (m^3/s) of
air to the preheater?
a. 3.76
b. 0.84
c. 0.12
d. 3.16
42. A device for increasing the velocity of a fluid in steady flow is a
a. nozzle
b. vent
c. orifice
d. venture
43. Which one among the following materials has the best insulating property?
a. window glass
b. wood
c. air
d. dry concrete
A pump draws a solution having a relative density of 1.84 from a tank through a 3
inch/75 mm SCH 40 steel pipe. Pump efficiency is 60%. Suction line velocity is at 3
ft/s (0.914 m/s). The pump discharges through a 2-in (50 mm) SCH 40 pipe to an
overhead tank 50 ft (15.2 m) above the feed tank. Friction losses in the entire piping
system are 10 ft-lbf/lbm (29.9 J/kg).
c. 120.3
d. 330.2
45. What pressure must the pump develop in kN/m^2?
a. 330
b. 660
c. 1320
d. 2437
46. What is the power of the pump?
a. 2.34 hp
b. 3.25 hp
c. 3.30 hp
d. 3.20 hp
A venturi meter is to be installed in a 100-mm line to measure the flow of water. The
maximum flow rate is expected to be 75 mm^3/h at 15°C. The manometer used to measure
the differential pressure is to be filled with mercury, and water is to fill the
leads above the surfaces of the mercury. The water temperature will be 15°C throughout.
If the maximum manometer reading is to be 1.25 m and the venturi coefficient is 0.98…
47. What throat diameter, to the nearest millimeter, should be specified for the
venturi?
a. 36 mm
b. 32 mm
c. 39 mm
d. 29 mm
48. What will be the power to operate the meter at full load if the pressure recovery
is 90 percent of the differential pressure?
a. 3.209 kW
b. 2.888 kW
c. 0.321 kW
d. 0.289 kW
49. A filtration operation in which the pressure drop is held constant and the flow
rate is allowed to fall with time.
a. constant rate filtration
b. bconstant pressure filtration
c. constant rate filtration followed by constant pressure filtration
d. centrifugal filtration
50. Also known as Oslo Crystallizer
a. Classified-Suspension Crystallizer
b. Mixed-Suspension, Classified-Product Removal Crystallizer
c. Forced-Circulation Evaporator-Crystallizer
d. Reaction Crystallizer
51. Determine the molar volume (in m3/kmol) of n-butane at 510K and 25bar by using
the ideal gas equation.
a. 1.691
b. 169.61
c. 0.1691
d. 16.961
52. Determine the molar volume (in m3/kmol) of n-butane at 510K and 25bar by using
the generalized compressibility factor equation. Use Zo=0.865, ω=0.2, and Zi
=0.038.
a. 14.807
b. 1.4807
c. 0.14807
d. None of the choices
Chemical Engineering Principles – Set A Page 8 of 14
A solution of HNO3 in water has a specific gravity of 1.10 at 25°C. The concentration
of the HNO3 is 15 g/L of solution.
A limestone analyses (weight %): CaCO3: 92.89%, MgCO3: 5.41%, Inerts: 1.70%
By heating the limestone you recover oxides known as lime.
60. How many pounds of CaO can be made from 1 short ton of this limestone?
a. 534 lb
Chemical Engineering Principles – Set A Page 9 of 14
b. 1033 lb
c. 1039 lb
d. 1041 lb
61. How many pounds of CO2 can be recovered per pound of limestone?
a. 0.437 lb CO2/lb limestone
b. 0.563 lb CO2/lb limestone
c. 1.234 lb CO2/lb limestone
d. None of the choices
62. How many pounds of limestone are needed to make 1 ton of lime?
a. 2330 lb
b. 5444 lb
c. 3350 lb
d. 3550 lb
63. Weeping in distillation or absorption column
a. increases tray efficiency
b. provides larger surface for mass transfer
c. results due to low gas velocity
d. is due to bubble cups
c. log Ca vs time
d. Ca vs time
69. A fluid flows through 2 CSTR in series. Each reactor has a capacity of 400,000
L and the fluid enters at 100 L per hr. The fluid undergoes a first order decay
with a half life of 24 hours. Find the approximate conversion of the fluid.
a. 66.8
b. 74.7
c. 85.3
d. 99.1
70. Cavitation occurs in a centrifugal pump when
a. the discharge pressure becomes too high
b. the discharge valve is closed
c. the suction pressure is too high
d. suction is lost
71. An ultracentrifuge is used to separate high-molecular weight fractions in
polymeric or biological systems. What is the gradient for mass transfer in the
separation using this mass transfer device?
a. temperature
b. pressure
c. concentration
d. electric field
72. Which is a part of a spray drying system?
a. Plenum
b. Atomizer
c. Knife
d. Steam heater
A slurry containing 100 kg of whiting per m3 of water is filtered in a plate and frame
press, which takes 900 s to dismantle, clean, and reassemble. The density of the
whiting is 3000 kg/m3. The resistance of the filter medium may be neglected and the
viscosity of water is 1 mN·s/m2. In an experiment, a pressure difference of 165 kN/m 2
produced a flow of water of 0.02 cm3/s through a centimeter cube of filter cake.
73. If the cake is incompressible and has a voidage of 0.4, what is the optimum
thickness of cake for a filtration pressure (−ΔP) of 1000 kN/m2?
a. 40 mm
b. 50 mm
c. 60 mm
d. 70 mm
74. If the cake is washed at 500 kN/m2 and the total volume of wash water
employed is 25 percent of that of the filtrate, what is the optimum thickness of
the cake?
a. 40 mm
b. 50 mm
c. 60 mm
d. 70 mm
N2 + 3 H2 -----> 2 NH3
Chemical Engineering Principles – Set A Page 11 of 14
In a given plant, 4202 lb of nitrogen and 1046 lb of hydrogen are fed to the
synthesis reactor per hour. Production of pure ammonia from this reactor is 3060 lb
per hour.
A room, under normal atmospheric conditions, has a dry bulb and wet bulb temperatures
of 150 deg F and 90 deg F, respectively. Using the Grosvenor chart, answer the
following:
Chemical Engineering Principles – Set A Page 12 of 14
A contact sulfuric acid plant produces 98.0 % sulfuric acid, by absorbing SO3 into a
97.3% sulfuric acid solution. A gas containing 8.00 % SO3 (remainder inerts) enters
the SO3 absorption tower at the rate of 28 lb mol per hour. 98.5 % of the SO3 is
absorbed in this tower. 97.3 % sulfuric acid is introduced into the top of the tower
and 95.9 % sulfuric acid from another part of the process is used as make - up acid.
c. 6070
d. 6670
92. Calculate in tons/day the amount of 98 % H2SO4 solution produced:
a. 2120
b. 2040
c. 2240
d. 2420
93. TiCl4 can be formed by reacting titanium dioxide (TiO2) with hydrochloric acid.
TiO2 is available as an ore containing 78 % TiO2 and 22 % inerts. The HCl is
available as 45 wt% solution (the balance is water). The per pass conversion of
TiO2 is 75 %. The HCl is fed into the reactor in 20 % excess based on the reaction.
Pure unreacted TiO2 is recycled back from a separator to mix with the TiO2 feed.
What kg of 45 wt % HCl solution is fed? (MW: TiO2 79.9; HCl 36.47; TiCl4 189.7)
a. 0.54 kg
b. 2.50 kg
c. 2.05 kg
d. 0.26 kg
94. The heat absorbed by an object inside a closed car which is exposed under the
intense heat of the sun can be considered as heat transfer by
a. conduction
b. convection
c. radiation
d. oxidation
95. Steam enters an adiabatic turbine at 10 MPa and 500 degC at a rate of 3 kg/s
and leaves at 0.1 MPa. If the power output of the turbine is 2 MW, determine the
turbine efficiency.
a. 0.2348
b. 0.3216
c. 0.6784
d. 0.7652
96. A 30 MW geothermal electric power plant uses hot steam from the earth at 157
deg C to heat and vaporize isobutane, which turns a turbine that is connected to
a generator. The isobutane is subsequently cooled to 27 degC using fans and
condensed back to a liquid. The overall efficiency of the plant is 40% of the
ideal (Carnot) efficiency. How many joules of heat must be released to the
atmosphere per second?
a. 2.5 x10^8
b. 2.2 x10^8
c. 3 x10^7
d. 5.2 x10^8
97. What unit operation originated in the mining of Trona (Na2CO3•NaHCO3•2H2O)
ore (Trona process)?
a. Fractional Distillation
b. Crystallization
c. Evaporation
d. Leaching
98. A feed of pure A equivalent to a concentration CAo = 1 M is treated in two
reactors of 2-L volume each and reacts with a rate of rA = 0.05 CA2 (in M/s).
Find the liquid feed rate in L/min that will give a final outlet concentration
of CA = 0.10 M if two MFRs in series are used.
a. 0.44
b. 1.8
c. 0.25
Chemical Engineering Principles – Set A Page 14 of 14
d. 4.2
99. For binary unicomponent diffusion, the concentration profile of the diffusing
component along the diffusion path is:
a. Linear
b. Quadratic
c. Exponential
d. Logarithmic
100. In a gas absorption operation, when the operating line crosses the
equilibrium curve
a. the NTU is zero
b. the liquid flow rate is maximum
c. the gas flow rate is maximum
d. the number of stages is infinite
Set A*
SUBMIT THIS TEST BOOKLET TOGETHER WITH THE ANSWER SHEET TO YOUR ROOM
WATCHERS. BRINGING THE TEST BOOKLET OUT OF THE ROOM WILL BE A GROUND FOR
CANCELLATION OF YOUR EXAMINATION
**END**
Answer Key for Day 2 Reviewer – Version 3.0 Ultimate:
USE AT YOUR OWN RISK
PREPARED ON: NOVEMBER 2016
1. C 34. D 68. B
2. A 35. B 69. D
3. C 36. B 70. C
4. C 37. D 71. _
5. D 38. D 72. B
6. A? 39. B 73. D
7. B? 40. D 74. C
8. C 41. D 75. A
9. D 42. A 76. A
10. B 43. B 77. C
11. C 44. [see MSH 5th/6th Ed Example 4.6] 78. C
12. B 45. [see MSH 5th/6th Ed Example 4.6] 79. A
13. A 46. [see MSH 5th/6th Ed Example 4.6] 80. D
14. A 47. [see MSH 5th/6th Ed Example 8.4] 81. _
48. [see MSH 5th/6th Ed Example 8.4]
15. C 82. A
49. B
16. D 83. B?
50. A
17. B 84. _
51. A [see SvNA Example 3.10]
18. A 85. _
52. D [see SvNA Example 3.10]
19. B 86. _
53. B
20. A 87. _
54. B
21. A 88. C?
55. D
22. D 89. C
56. D
23. C 90. C [see SUP* Example 3.6B]
57. A
24. A 91. B
58. B
25. D 92. C
59. B
26. A 93. A
60. D
27. D 94. C
61. A
28. C 95. C
62. _?
29. A 96. A/B [disputed]
63. C
30. D 97. C?
64. _?
31. A 98. A?
65. _?
32. B 99. D
66. A
33. B 100. D
67. D
Notes:
MSH = McCabe, Smith and Harriot (Unit Operations of Chemical Engineering
SvNA = Smith, van Ness, Abbot (Thermodynamics)
SUP = Supplementary Problems in Basic Principles and Calculations in Chemical Engineering