Question Report PDF

Paper Code
(0999DJA110318004) )0999DJA110318004)
DISTANCE LEARNING PROGRAMME
(Academic Session : 2018 - 2019)
LEADER TEST SERIES / JOINT PACKAGE COURSE

TARGET : JEE (Main + Advanced) 2019
Test Type : UNIT TEST TEST # 04 Test Pattern : JEE-Advanced
TEST DATE : 19 - 08 - 2018
Time : 3 Hours Maximum Marks : 252
READ THE INSTRUCTIONS CAREFULLY / Ïi;k bu funsZ'kksa dks /;ku ls i<+sa
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR / fujh{kd ds vuqn s'kks a ds fcuk eqg js a u rksM+ s
GENERAL / lkekU; %
1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so.
;g eksgjcU/k iqfLrdk vkidk iz'ui= gSA bldh eqgj rc rd u rksM+s tc rd bldk funsZ'k u fn;k tk;sA
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
iz'uksa dk mÙkj nsus ds fy, vyx ls nh x;h vkWfIVdy fjLikal 'khV (vks- vkj- ,l-) (ORS) dk mi;ksx djsaA
3. Blank spaces are provided within this booklet for rough work.
dPps dk;Z ds fy, bl iqfLrdk esa [kkyh LFkku fn;s x;s gSaA
4. Write your name, form number and sign in the space provided on the back cover of this booklet.
bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke o QkWeZ uEcj fyf[k, ,oa gLrk{kj cukb;sA
5. After breaking the seal of the booklet, verify that the booklet contains 46 pages and that all the
23 questions in each subject and along with the options are legible. If not, contact the invigilator for
replacement of the booklet.
bl iqfLrdk dh eqgj rksM+us ds ckn Ïi;k tk¡p ysa fd blesa 46 i`"B gSa vkSj izR;sd fo"k; ds lHkh 23 iz'u vkSj muds mÙkj fodYi Bhd
ls i<+s tk ldrs gSaA ;fn ugha] rks iz'ui= dks cnyus ds fy, fujh{kd ls lEidZ djsaA
6. You are allowed to take away the Question Paper at the end of the examination.
ijh{kkFkhZ iz'ui= dks ijh{kk dh lekIrh ij ys tk ldrs gSaA
OPTICAL RESPONSE SHEET / vkW fIVdy fjLika l 'khV (vks - vkj-,l-) %
7. The ORS will be collected by the invigilator at the end of the examination.
vks- vkj- ,l- dks ijh{kk ds lekiu ij fujh{kd ds }kjk ,d= dj fy;k tk,xkA
8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
vks- vkj- ,l- esa gsj&Qsj@foÏfr u djsaA vks - vkj-,l- dk dPps dke ds fy, iz ;ks x u djs a A
9. Write your name, form number and sign with pen in the space provided for this purpose on the ORS.
Do not write any of these details anywhere else on the ORS. Darken the appropriate bubble
under each digit of your form number.
viuk uke vkSj QkWeZ uEcj vks-vkj-,l- esa fn, x, [kkuksa esa dye ls fy[ksa vkSj vius gLrk{kj djsaA buesa ls dksbZ Hkh fooj.k
vks - vkj-,l- es a dgha vkSj u fy[ks a A QkWeZ uEcj ds gj vad ds uhps vuq:i cqycqys dks dkyk djsaA
DARKENING THE BUBBLES ON THE ORS / vks- vkj-,l- ij cqy cqy ksa dks dkyk djus dh fof/k %
10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
vks-vkj-,l- ds cqycqyksa dks dkys ckW y ikW b UV dye ls dkyk djsaA
11. Darken the bubble COMPLETELY. / cqycqys dks iw. k± :i ls dkyk djsaA
12. The correct way of darkening a bubble is as : / cqycqys dks dkyk djus dk mi;qDr rjhdk gS :
13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
vks-vkj-,l- e'khu tk¡P; gSA lqfuf'pr djsa dh cqycqys lgh fof/k ls dkys fd, x;sa gSaA
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
"un-darken" a darkened bubble.
cqycqys dks rHkh dkyk djsa tc vki mÙkj ds ckjs esa fuf'pr gksA dkys fd, gq, cqycqys dks feVkus vFkok lkQ djus dk dksbZ rjhdk ugha gSA
15. Take g = 10 m/s2 unless otherwise stated. / g = 10 m/s2 iz;qDr djsa] tc rd fd vU; dksbZ eku ugha fn;k x;k gksA
QUESTION PAPER FORMAT AND MARKING SCHEME / iz ' ui= dk iz k :i vkSj va d u ;ks tuk %
16. The question paper has three parts : Physics, Chemistry and Mathematics.
bl iz'ui= esa rhu Hkkx gSa % HkkSfrd foKku] jlk;u foKku ,oa xf.krA
17. Each part has three sections as detailed in table page 45.
izR;sd Hkkx esa rhu [k.M gSa ftudk fooj.k i`"B 45 ij rkfydk esa fn;k x;k gSA
Please see the page 45 of this booklet for rest of the instructions/ Ïi;k 'ks " k funs Z ' kksa ds fy, bl iq f Lrdk ds i` " B 45 dks i<+ sa A
Target : JEE (Main + Advanced) 2019/19-08-2018
SYLLABUS :
PHYSICS : Work, Energy & Power, Magnetic effect of current, Magnetism
CHEMISTRY : Chemical Bonding, Solid state, Chemical kinetics
MATHEMATICS : Point and Straight Line, Indefinite integration
SOME USEFUL CONSTANTS

Atomic No. : H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140
· Boltzmann constant k = 1.38 × 10–23 JK–1

1
· Coulomb's law constant = 9 ×10 9
4 pe0
· Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
· Speed of light in vacuum c = 3 × 108 ms–1
· Stefan–Boltzmann constant s = 5.67 × 10–8 Wm–2–K–4
· Wien's displacement law constant b = 2.89 × 10–3 m–K
· Permeability of vacuum µ0 = 4p × 10–7 NA–2
1
· Permittivity of vacuum Î0 =
m0 c2
· Planck constant h = 6.63 × 10–34 J–s
Space for Rough Work / dPps dk;Z ds fy, LFkku
Note : In case of any correction in the test paper, please mail to dlpcorrections@allen.ac.in within 2 days along with Paper Code
& Your Form No.
(uks V % ;fn bl iz'u i= esa dksbZ Correction gks rks Ïi;k Paper Code ,oa vkids Form No. ,oa iw.kZ Test Details ds lkFk 2 fnu ds vUnj
dlpcorrections@allen.ac.in ij mail djsaA)
LTS-2/46 0999DJA110318004
Leader Test Series/Joint Package Course/19-08-2018
HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
Hkkx-1 : HkkSfrd foKku
SECTION–I(i) : (Maximum Marks : 18)
[k.M –I(i) : (vf/kdre vad : 18)
This section contains SIX questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
For each question, darken the bubble corresponding to the correct option in the ORS.
For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
bl [k.M esa N% iz'u gaS
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gSaA ftuesa ds o y ,d gh lgh gSaA
izR;sd iz'u ds fy, vks-vkj-,l ij lgh mÙkj fodYi ds vuq:i cqycqys dks dkyk djsaA
izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuq l kj fn;s tk,a xs %
iw.kZ vad : +3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k gAS
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gAS
½.k vad : –1 vU; lHkh ifjfLFkfr;ksa esaA
1. A particle of mass m is moving in a circle having radius R and its centripetal acceleration is
given by aC = KRt where R is radius of circle, t is time and K is any constant. Find power (watt)
delivered by total force acting on particle.
æO;eku m okyk ,d d.k f=T;k R okys o`Ùk esa xfr'khy gS rFkk bldk vfHkdsUæh; Roj.k aC = KRt }kjk fn;k tkrk gS tgk¡
R o`Ùk dh f=T;k] t le; rFkk K dksbZ fu;rkad gA
S d.k ij dk;Zjr dqy cy }kjk nh x;h 'kfDr (okWV) gksxh%&
mKR2 mKR1/ 2 5m 3 3 / 2
(A) (B) (C) mR3 K 3 / 2 (D) RK
2 2 4
2. A pendulum of length l = 1m is released from q0 = 60°. The rate of change of speed of the bob at
q = 30° is (g = 10 m/s2) :-
yEckbZ l = 1m okys ,d ljy yksyd dks q0 = 60° ij fojkekoLFkk ls NksM+k tkrk gAS q = 30° ij xksyd dh pky esa
ifjorZu dh nj gS (g = 10 m/s2) :-
60°
(A) 5 3 m / s2 (B) 2.5 m/s2 (C) 10 m/s2 (D) 5 m/s2

0999DJA110318004 LTS-3/46
r
3. A force F has components Fx = axy – by2, Fy = –axy + bx2 where a = 2 N/m2 and b = 2 N/m2
(figure). Calculate the work done by the force on an object of mass 4kg if it is moved on a closed
path from (x, y) values of (0, 1) to (4, 1) to (4, 3) to (0, 3) and back to (0, 1) (all coordinates in
meters). The path between the points is always the shortest straight one and all the distances
are given in meters :-
r
,d cy F ds ?kVd Fx = axy – by2, Fy = –axy + bx2 gS tgk¡ a = 2 N/m2 o b = 2 N/m2 g]S fp= ns[ksaA bl cy }kjk
4kg æO;eku ds fi.M ij fd;s x;s dk;Z dh x.kuk dhft;s ;fn fi.M dks ,d can iFk ij (x, y) ds eku (0, 1) ls (4, 1)
ls (4, 3) ls (0, 3) rd ys tkdj iqu% (0, 1) rd ys tk;k tk;sA lHkh funsZ'kkad ehVj esa gSA fcUnqvksa ds e/; iFk lnSo y?kqÙke
ljy js[kh; gksrk gS rFkk lHkh nwfj;k¡ ehVj esa nh x;h gS%&
Arrows represent the
y
force at different points
3
1
0 4 x
2 31
(A) 64 J (B) 0 J (C) 72 J (D) 18 J
4. An electron is revolving around a proton in a circular orbit of diameter 1Å. If it produces a
magnetic field of 14 wb/m2 at the proton, then its angular velocity will be about :-
,d bysDVªkWu izkVs ksu ds pkjksa vksj 1Å O;kl okyh o`Ùkkdkj d{kk esa pDdj yxk jgk gAS ;fn ;g izksVksu ij 14 wb/m2 dk
pqEcdh; {ks= mRiUu djrk gS rks bldk dks.kh; osx yxHkx gksxk%&
(A) 4.375 × 1016 rad/s (B) 2.25 × 1014 rad/s (C) 4 × 1015 rad/s (D) 8.75 × 1016 rad/s
LTS-4/46 0999DJA110318004
5. As shown in the figure, three sided frame is pivoted at P and Q and hangs vertically. Its sides
are of same length and have a linear density of 3 kg/m. A current of 10 3 amp is sent through
the frame, which is in a uniform magnetic field of 2T directed upwards as shown. Angle through
which the frame will be deflected in equilibrium is :-
fp=kuqlkj rhu Hkqtkvksa okyk ,d Ýse P rFkk Q ij dhydhr gS ,oa Å/okZ/kj yVdk gqvk gSA bldh Hkqtk,sa leku yEckbZ
rFkk 3 kg/m jfS [kd ?kuRo okyh gSaA bl Ýse esa 10 3 amp dh /kkjk izokfgr dh tkrh gS tks fp=kuqlkj Åij dh fn'kk
esa dk;Zjr 2T ds le:i pqEcdh; {ks= esa gAS Ýse lkE;koLFkk esa fdl dks.k ij fo{ksfir gksxk %&
I P Q
q B
(A) 30° (B) 45° (C) 60° (D) 90°

6 A 50 kg block is being lifted at a constant speed by a machine from ground to a building 4 m
high. The machine being used has a constant power of 250 W. What is the time (in sec) taken for
the lift?
,d 50 kg ds CykWd dks ,d e'khu }kjk /kjkry ls fu;r pky ls mBkdj 4 m Å¡ph ,d bekjr ds Åij j[kuk gAS ;g e'khu
250 W dh fu;r 'kfä dk mi;ksx djrh gA S CykWd dk mBkus esa yxk le; (lsd.M esa) gksxk %&
(A) 6 (B) 10 (C) 8 (D) 15
0999DJA110318004 LTS-5/46
SECTION–I(ii) : (Maximum Marks : 16)
[k.M –I(ii) : (vf/kdre vad : 16)
This section contains FOUR questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 In all other cases.
bl [k.M esa pkj iz'u gaS
izR;sd iz'u ds pkj mÙkj fodYi (A), (B), (C) vkjS (D) gaS ftuesa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
izR;sd iz'u ds fy, vks-vkj-,l- ij lkjs lgh mÙkj (mÙkjksa) ds vuq:i cqycqys (cqycqyksa) dks dkyk djsaA
iw.kZ vad : +4 ;fn flQZ lkjs lgh fodYi (fodYiksa) ds vuq:i cqycqys (cqycqyksa) dks dkyk fd;k gAS
'kwU; vad : 0 vU; lHkh ifjfLFkfr;ksa esaA
7. A conservative force is acting along x-axis, such that the variation of force with x is as shown in
the figure. Potential energy at x = 0 is U = 0, at x = a is U = 20J, at x = b is U = –10J and at
x = c is U = –20J.
(A) The minimum kinetic energy at x = 0 required to reach x = b is 20J
(B) The minimum kinetic energy at x = 0 required to reach x = c is 20J
(C) If the particle is released from rest at x = 0, it will reach x = c with kinetic energy of 20J
(D) If the particle is given kinetic energy of 30J at x = c towards x = 0, it will reach x = 0 with
kinetic energy of 10J
F
a b c x
,d laj{kh cy x-v{k ds vuqfn'k bl izdkj yx jgk gS fd x ds lkFk cy esa ifjorZu fp=kuqlkj gksrk gSA x = 0 ij fLFkfrt
ÅtkZ U = 0, x = a ij U = 20J, x = b ij U = –10J o x = c ij U = –20J gAS
(A) x = b rd igq¡pus ds fy;s x = 0 ij U;wure vko';d xfrt ÅtkZ 20J gAS
(B) x = c rd igq¡pus ds fy;s x = 0 ij U;wure vko';d xfrt ÅtkZ 20J gAS
(C) ;fn d.k dks x = 0 ij fojkekoLFkk ls NksM+k tk;s rks ;g x = c ij 20J xfrt ÅtkZ ds lkFk igq¡psxkA
(D) ;fn d.k dks x = c ij x = 0 dh vksj 30 J xfrt ÅtkZ nh tk;s rks ;g x = 0 ij 10J xfrt ÅtkZ ds lkFk igq¡px s kA
LTS-6/46 0999DJA110318004
8. A block is attached to a spring of spring constant k initially in natural length. A constant force F
starts acting on a block as shown in figure. (All surfaces are frictionless)
1 2 F2
(A) Potential energy function for this combination of forces can be U(x) = kx - Fx -
2 2k
1 2 F
(B) Potential energy function for this combination of forces can be U(x) = kx - Fx -
2 2k
F
(C) x = is the position of stable equilibrium
k
2F
(D) x = 0 and x = are the position of unstable equilibrium
k
k
F
m
x
x=0
,d CykWd izkjEHk esa ewy yEckbZ esa fLFkr k fLizax fu;rkad okyh fLizax ls tqM+k gAS CykWd ij ,d fu;r cy F fp=kuqlkj
yxuk izkjEHk gksrk gSA (lHkh lrgssa ?k"kZ.k jfgr gAS )
1 2 F2
(A) cyksa ds bl la;kstu ds fy;s fLFkfrt ÅtkZ Qyu U(x) = kx - Fx - gks ldrk gSA
2 2k
1 2 F
(B) cykas ds bl la;kstu ds fy;s fLFkfrt ÅtkZ Qyu U(x) = kx - Fx - gks ldrk gSA
2 2k
F
(C) x = LFkk;h lkE;koLFkk dh fLFkfr gAS
k
2F
(D) x = 0 o x = vLFkk;h lkE;koLFkk dh fLFkfr;k¡ gSA
k
0999DJA110318004 LTS-7/46
9. Two equal masses are raised at constant velocity by ropes that run over pulleys as shown. Mass
B is raised twice as fast as mass A. The magnitudes of the forces are FA and FB, while the power
Supplied is respectively PA and PB. Which of the following statements is correct?
nks leku æO;eku fp=kuqlkj f?kjfu;ksa ij ls xqtjrh jfLl;ksa }kjk fu;r osx ls mBk;s tkrs gAS æO;eku B dks æO;eku A dh
rqyuk esa nqxquh rsth ls mBk;k tkrk gAS cyksa ds ifjek.k FA o FB gS tcfd nh x;h 'kfDr Øe'k % PA o PB gSA
lgh dFku@dFkuksa dks pqfu;s%&
B
A
(A) FB = FA (B) PB = PA (C)PB = 2PA. (D) FB = 2FA

LTS-8/46 0999DJA110318004
10. A ball is hanging vertically by a light inextensible string of length L from fixed point O.The ball
of mass m is given a speed u at the lowest position such that it completes a vertical circle with
centre at O as shown. Let AB be a diameter of circular path of ball making an angle 60° with
vertical as shown, then
(A) The difference in kinetic energy of ball at positions A and B is mgL.
(B) The difference in value of tension in a string at positions A and B will be 3 mg.
r r r r r
(C) If the accelerations of ball at positions A and B will be a A and a B , then the value of |a A + a B|
will be 7g .
(D) The difference in centripetal force at the positions A and B will be 2 mg.
60°
A
u
m
,d xsan fLFkj fcUnq O ls yEckbZ L dh gYdh vforkU; jLlh }kjk Å/okZ/kj yVdh gqbZ gSA fuEure fLFkfr ij æO;eku m dh
xsan dks pky u bl izdkj nh tkrh gS fd ;g O dsUæ okyk Å/okZ/kj o`Ùk fp=kuqlkj iw.kZ djrh gSA ekuk AB xsan ds o`Ùkkdkj
iFk dk O;kl gS tks Å/okZ/kj ls 60° dks.k cukrk g%S &
(A) fLFkfr;ksa A rFkk B ij xsan dh xfrt ÅtkZ esa varj mgL gAS
(B) fLFkfr;ksa A rFkk B ij jLlh esa ruko ds eku esa varj 3 mg gksxkA
r r r
(C) ;fn fLFkfr;ksa A rFkk B ij xsan ds Roj.k aA rFkk aB gks rks |ar A + ar B| dk eku 7g gksxkA
(D) fLFkfr;ksa A rFkk B ij vfHkdsUæh; cy esa varj 2mg gksxkA
0999DJA110318004 LTS-9/46
SECTION–I(iii) : (Maximum Marks : 12)
[k.M –I(iii) : (vf/kdre vad : 12)
This section contains TWO paragraphs.
Based on each paragraph, there are TWO questions.
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options is
correct.
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases
bl [k.M esa nks vuqPNsn gSa
izR;sd vuqPNsn ij nks iz'u fn, x;sa gaSA
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gSa ftuesa ds o y ,d lgh gSaA
izR;sd iz'u ds fy, vks-vkj-,l- ij lgh mÙkj fodYi ds vuq:i cqycqys dks dkyk djsaA
Paragraph for Questions 11 and 12
iz' u 11 ,oa 12 ds fy;s vuq P Ns n
A person wants to roll a solid non-conducting spherical ball of mass m and radius r on a surface
whose coefficient of static friction is µ. He placed the ball on the surface wrapped with n turns of
closely packed conducting coils of negligible mass at the diameter. By some arrangement he is
able to pass a current i through the coils in the anticlockwise direction as seen from +y-axis.
r
A constant horizontal magnetic field B is present throughout the space as shown in the figure.
(Assume µ is large enough to help rolling motion)
,d O;fDr m æO;eku rFkk r f=T;k okyh ,d Bksl vpkyd xksykdkj xsan dks LFkfS rd ?k"kZ.k xq.kkad µ okyh ,d lrg ij
yq<+dkuk pkgrk gSA og xsan dks ,d i`"B ij j[krk gS rFkk xsan ij ux.; æO;eku okyh lehiLFk ca/kh gq;h pkyd dq.Mfy;ksa
ds n ?ksjs O;kl ij fyiVs gq;s gAS fdlh O;oLFkk }kjk og bu dq.Mfy;ksa esa +y v{k ls ns[kus ij okekorhZ fn'kk esa i /kkjk
izokfgr dj ldrk gAS ;gk¡ ij ,d fu;r {kfS rt pqEcdh; {ks= Br fo|eku gAS µ dk eku bruk i;kZIr gS fd ykVS uh xfr gks ldsA
y
i B
11. If current i is passed through the coils the maximum torque in the coil is :-
;fn dq.Mfy;ksa esa i /kkjk izokfgr gks rks dq.Myh ij vf/kdre cyk?kw.kZ gksxk%&
(A) –pnir2B k̂ (B) pnir2B ĵ (C) -pnir 2 Bjˆ (D) pnir 2 Bkˆ
12. The angular velocity of the ball when it has rotated through an angle q is (q < 180°) is :-
tc xsan dks.k q (q < 180°) ij ?kw.kZu dj pqdh gks rc xsan dk dks.kh; osx gksxk%&
10 pniB 5 pniB 5 pniB 5 pniB
(A) sin q (B) sin q (C) cos q (D) sin q
7 m 14 m 14 m 7 m
LTS-10/46 0999DJA110318004
2
A particle of mass m moves in one dimension. Its potential energy is given by U (x) = – U 0e - x / a2 ,
where U0 and a are positive constants.
2
æO;eku m okyk ,d d.k ,d foeh; xfr dj jgk gAS bldh fLFkfrt ÅtkZ U (x) = – U 0e - x / a2 g]S tgk¡ U0 rFkk a
èkukRed vpj gAS
13. An energy diagram showing the potential energy U (x), the kinetic energy K (x), and the total
energy E < 0 for a motion which is bound between turning points x = ± a is :-
fcUnq x = ± a ds e/; ifjc¼ xfr ds fy, fLFkfrt ÅtkZ U (x), xfrt ÅtkZ K (x) rFkk dqy ÅtkZ E < 0 dks n'kkZus okyk
ÅtkZ vkjs[k gksxk %&
U(x)
U(x)
x
E
(A) E (B)
KE KE
x
U(x) U(x)
x
KE x
(C) (D) KE
E
E
14. The speed of the particle at origin, x = 0 such that the when the particle reaches the positions
x = ±a, it will reverse its motion is
d.k dh ewyfcUnq] x = 0 ij pky D;k gksuh pkfg;s rkfd tc d.k fLFkfr;ksa x = ±a ij igq¡prk gS rks bldh xfr foijhr gks
tk;s\
2U0 æ 1ö 2U 0 U0 æ 1ö 2U 0
(A)
m ç1 - e ÷ (B) (1 - e ) (C)
m ç1 - e ÷ (D)
è ø m è ø m
0999DJA110318004 LTS-11/46
SECTION–I(iv) : (Maximum Marks : 6)
[k.M –I(iv) : (vf/kdre vad : 6)
This section contains TWO questions.
Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D)
out of which ONLY ONE is correct
bl [k.M esa nks iz'u gaS
izR;sd iz'u esa lqey
s u lwph gAS lwfp;ksa ds fy, dksM ds fodYi (A), (B), (C) vkSj (D) gaS ftuesa ls dso y ,d lgh gAS
15. There exists uniform magnetic field 10Tiˆ in space. A particle of mass m = 10 kg and charge
q = pC is projected from origin with velocity (2iˆ + 3jˆ + 4k)
ˆ m/s. The position of particle is observed
at t = 0.5 sec, 1 sec and 2 sec respectively. Following table coordinates of the particles at given
moments
lef"V esa le:i pqEcdh; {ks= 10Tiˆ fo|eku gAS æO;eku m = 10 kg rFkk vkos'k q = pC okys ,d d.k dks ewyfcUnq
ls (2iˆ + 3jˆ + 4k)
ˆ m/s osx ls iz{ksfir fd;k tkrk gSA t = 0.5 sec, 1 sec rFkk 2 sec ij d.k dh fLFkfr;k¡ izsf"kr dh tkrh
gAS fuEu rkfydk esa bu {k.kksa ij d.k ds funsZ'kkad fn, x;s gaSA
x-coordinate y-coordinate z-coordinate
x-funs Z ' kka d y-funs Z ' kka d z-funs Z ' kka d
t = 0.5 sec x1 y1 z1
t = 1 sec x2 y2 z2
t = 2 sec x3 y3 z3
List-I/lw p h -I List-II/lw p h -II
(P) x1 (1) 0
(Q) x2 (2) 1
(R) y3 (3) 2
(S) z3 (4) 3
(A) P ® 3; Q ® 2; R ® 1; S ® 1 (B) P ® 2; Q ® 3; R ® 1; S ® 1
(C) P ® 1; Q ® 3; R ® 2; S ® 4 (D) P ® 1; Q ® 2; R ® 3; S ® 4
LTS-12/46 0999DJA110318004
16. A lift of mass m kg has to be taken through a height h from state of rest to state of rest.
This process is done in shortest possible time with the help of cables which can bear a tension
0 £ T £ 3 mg. In list-I are given statements regarding variation of a given quantity with respect
to time and in list II are given some graphs showing variation of these quantities with time.
Match the List-I with List-II.
æO;eku m kg okyh ,d fy¶V dks fojkekoLFkk ls h Å¡pkbZ ij fojkekoLFkk rd ys tkuk gSA bl izfØ;k dks U;wure laHko
le; esa mu dscy dh lgk;rk ls lEiUu djuk gS tks 0 £ T £ 3 mg ruko dks lgu dj ldrh gAS lwph-I esa le; ds lkis{k
nh xbZ jkf'k esa ifjorZu ds lanHkZ esa dqN dFku fn;s x;s gS rFkk lwph-II esa le; ds lkFk bu jkf'k;ksa esa ifjorZu dks n'kkZus okys
vkjs[k iznf'kZr gSA lwph feyku dhft;sA
List–I/lw p h –I List–II/lw p h –II
(P) Variation of velocity of lift with time (1)
fy¶V ds osx esa le; ds lkFk ifjorZu
(Q) Variation of power delivered by tension (2)

in cable with time.
dscy esa mRiUu ruko }kjk nh x;h 'kfDr esa le;
ds lkFk ifjorZu
(R) Variation of power delivered by gravity (3)
with time
xq:Ro }kjk iznku 'kfDr esa le; ds lkFk ifjorZu
(S) Variation of acceleration of lift with time (4)
fy¶V ds Roj.k esa le; ds lkFk ifjorZu

(A) P ® 3; Q ® 2; R ® 1; S ® 4 (B) P ® 3; Q ® 2; R ® 4; S ® 1
(C) P ® 2; Q ® 3; R ® 4; S ® 1 (D) P ® 2; Q ® 3; R ® 1; S ® 4
0999DJA110318004 LTS-13/46
SECTION-II : Numerical Value Type (Up to second decimal place)
No question will be asked in section II
[k.M–II : la[;kRed eku izdkj (n'keyo ds nks LFkku rd)
[k.M II es a dks b Z iz ' u ugha gS A
SECTION–III : (Maximum Marks : 24)
[k.M –III : (vf/kdre vad : 24)
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
For each question, darken the bubble corresponding to the correct integer in the ORS.
izR;sd iz'u dk mÙkj 0 ls 9 rd (nksuksa 'kkfey) ds chp dk ,d ,dy vadh; iw.kk±d gAS
izR;sd iz'u esa] vks-vkj-,l- ij lgh iw.kk±d ds vuq:i cqycqys dks dkyk djsaA
iw.kZ vad : +4 ;fn flQZ lgh mÙkj ds vuq:i cqycqys dks dkyk fd;k gAS
1. ˆ = B uˆ above the earth surface where
Suppose a hypothetical magnetic field exists in space B 0 r
û r is a unit vector directed radially outward from origin. Origin is on surface of earth. A light
charged particle has to perform uniform circular motion in the combined uniform (vertical)
gravitational field of earth and magnetic field with speed v and radius r. Height of the plane of
nv2
motion from earth surface will be h = . Find n.
g
ekuk lef"V esa i`Foh dh lrg ds Åij ,d dkYifud pqEcdh; {ks= Bˆ = B0 uˆ r fo|eku g]S tgk¡ û r ewyfcUnq ls f=T;h;
ckgj dh vksj funsZf'kr ,d bdkbZ lfn'k gSA ewyfcUnq i`Foh dh lrg ij gSA ,d gYdk vkosf'kr d.k i`Foh ds le:i
Å/okZ/kj xq:Rokd"kZ.k {ks= rFkk pqEcdh; {ks= ds la;qä izHkko esa v pky rFkk r f=T;k okyh le:i o`Ùkkdkj xfr djrk gSA
nv2
;fn xfr ds ry dh i`Foh dh lrg ls Å¡pkbZ h= gks rks n Kkr dhft;sA
g
LTS-14/46 0999DJA110318004
2. A neutral atom of atomic mass number 100 which is stationary at the origin in gravity free space
emits an a-particle (A) in z-direction. The product ion is P. A uniform magnetic field exists in the
x-direction. Disregard the electro magnetic interaction between A and P. If the angle of rotation
12np
of A after which A and P will meet for the first time is radians, what is the value of n ?
25
ijek.kq Øekad 100 okyk mnklhu ijek.kq tks ewyfcUnq ij xq:Roghu {ks= esa fLFkj voLFkk esa gS] z-fn'kk esa a-d.k (A)
mRlftZr djrk gSA mRikn vk;u P gSA ;gk¡ x-fn'kk esa ,dleku pqEcdh; {ks= fo|eku gSA A o P ds e/; fo|qr pqEcdh;
12np
vUr%fØ;k dks ux.; ekfu,A ;fn A ds ?kw.kZu dks.k dk eku jsfM;u g]S ftlds i'pkr~ A o P izFke ckj feysxas rks
25
n dk eku Kkr dhft;sA
3. Figure shows a square loop 10 cm on each side in the x-y plane with its centre at the origin.
An infinite wire is at z = 12 cm above y-axis. What is torque on loop due to magnetic force?
If torque is expressed as 12x ×10–6 N-m, fill value of x.
fp= esa x-y ry esa fLFkr 10 cm Hkqtk okyk ,d oxkZdkj ywi n'kkZ;k x;k g]S ftldk dsUnz ewyfcUnq ij gSA y-v{k ds Åij
z = 12 cm ij ,d vuUr yEck rkj fLFkr gAS pqEcdh; cy ds dkj.k ywi ij fdruk cyk?kw.kZ yxsxk\ ;fn bls
12x × 10–6 N-m esa iznf'kZr fd;k tk;s rks x dk eku Kkr dhft;sA
z
i1 = 65A 12 cm
D
y
A
C
10 cm i2 = 78A
B x
0999DJA110318004 LTS-15/46
4. Figure shows circular region of radius R = 3 m in which upper half has uniform magnetic field
r r
B = 0.2 ( -kˆ ) T and lower half has uniform magnetic field B = 0.2kT
ˆ . A very thin parallel beam of
point charges each having mass m = 2 gm, speed v = 0.3 m/sec and charge q = +1 mC are
projected along the diameter as shown in figure. A screen is placed perpendicular to initial
velocity of charges as shown. If the distance between the points on screen where charges will
strikes after being deflected by the magnetic field is 4X meters, then calculate X.
fp= esa R = 3 m f=T;k okyk ,d o`Ùkkdkj Hkkx n'kkZ;k x;k g]S ftlds Åijh v/kZHkkx esa Br = 0.2 ( -kˆ ) T dk le:i
r
ˆ dk le:i pqEcdh; {ks= fo|eku gSA fcUnq vkos'kksa ls cuh ,d cgqr
pqEcdh; {ks= rFkk fupys v/kZHkkx esa B = 0.2kT
iryh lekUrj iaqt dks O;kl ds vuqfn'k fp=kuqlkj iz{ksfir fd;k tkrk gSA bu fcUnq vkos'kksa esa ls izR;sd dk æO;eku
m = 2 gm, pky v = 0.3 m/sec o vkos'k q = +1 mC gSA vkos'kksa ds izkjfEHkd osx ds yEcor~ ,d insZ dks fp=kuqlkj
j[kk tkrk gAS ;fn insZ ij mu fcUnqvksa ds e/; nwjh 4X ehVj gks tgk¡ vkos'k pqEcdh; {ks= ls fopfyr gksus ds ckn Vdjkrs
gaS rks X dk eku Kkr dhft;sA
Screen
R
R
LTS-16/46 0999DJA110318004
5. In the rigid wire frame ABCDEF, shown in figure, a current I 0 = 4A flows through the wire from
F to A and radii of curves AB, CD and EF are a, b and c respectively with centres at O. If this
loop is immersed in a uniform magnetic field of magnitude 1.3 T and directed along the line
joining (2, 3, 4) to (–7, 2, 0) and allowed to rotate about the x-axis only, then find the value of
torque t (N-m) exerted on the loop by the axis. (Given : a = 3m, b = 1m, c = 2m).
fp= esa iznf'kZr n`<+ rkj Ýse ABCDEF esa /kkjk I0 = 4A rkj esa F ls A fljs dh vksj cgrh gAS oØksa AB, CD rFkk EF
dh f=T;k;sa Øe'k% a, b o c gS rFkk bu lHkh oØksa dk dsUæ O ij gAS ;fn bl ywi dks ifjek.k 1.3 T okys le:i pqEcdh;
{ks= esa Mqcks;k tkrk gS rFkk ;g {ks= fcUnqvksa (2, 3, 4) ls (–7, 2, 0) dks tksM+us okyh js[kk ds vuqfn'k bafxr gS rFkk bl ywi
dks dsoy x-v{k ds ifjr% ?kw.kZu djk;k tkrk gS rks v{k }kjk ywi ij vkjksfir cyk?kw.kZ t (N-m) dk eku Kkr dhft,s
(fn;k gS % a = 3m, b = 1m, c = 2m). z
F y
O A
D
E
x
7
6. A string is wrapped over a fixed horizontal cylinder of radius m and its other end is connected
66
to a point mass, which hangs in air such that 1.2 m length of string is free. Find minimum
velocity (in m/s) given to mass perpendicular to length of cylinder, so that string never gets slack
before wrapping over cylinder completely once. (Take g = 9.8 m/s2)
7
,d jLlh m f=T;k okys fLFkj {kSfrt csyu ds Åij fyiVh gq;h gS rFkk blds nwljs fljs ls ,d fcUnq æO;eku tqM+k gS tks
66
ok;q esa bl izdkj yVdrk gS fd jLlh dk 1.2 m yEck Hkkx Lora= jgrk gSA æO;eku dks csyu dh yEckbZ ds yEcor~ fdruk
U;wure osx (m/s esa) fn;k tkuk pkfg;s rkfd jLlh csyu ds pkjksa vksj ,d ckj iw.kZr;k fyiVus ls igys dHkh <hyh uk gks\
(g = 9.8 m/s2 ysa)
side view
1.2m
1.2m
v
0999DJA110318004 LTS-17/46
SECTION–IV : (Maximum Marks : 8)
[k.M –IV : (vf/kdre vad : 8)
This section contains ONE questions.
Question contains two columns, Column-I and Column-II.
Column-I has four entries (A), (B), (C) and (D)
Column-II has five entries (P), (Q), (R), (S) and (T)
Match the entries in Column-I with the entries in column-II.
One or more entries in Column-I may match with one or more entries in Column-II.
The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
For each entry in column-I, darken the bubbles of all the matching entries. For example,
if entry (A) in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles
in the ORS. Similarly, for entries (B), (C) and (D).
For question, marks will be awarded in one of the following categories :
For each entry in Column-I
Full Marks : +2 If only the bubble(s) corresponding to all the correct match(es) is (are)
darkened
bl [k.M esa ,d iz'u gaS
iz'u esa nks dkWye gSa ] dkWye -I rFkk dkWye -II
dkWye-I esa pkj izfo"V;k¡ (A), (B), (C) rFkk (D) g Sa
dkWye-II esa ik¡p izfof"V;k¡ (P), (Q), (R), (S) rFkk (T) g Sa
dkWye-I dh izfof"V;ksa dk dkWye -II dh izfof"V;ksa ls lqefs yr djsa
dkW ye-I dh ,d ;k ,d ls vf/kd izfof"V;k¡] dkW ye-II dh ,d ;k ,d ls vf/kd izfof"V;ksa ls lqefs yr gks ldrh gaS
vks-vkj-,l- esas uhps n'kkZ;h x;h tlS h 4 × 5 vkO;wg nh x;h gS :
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
dkW y e -I dh izR;sd izfof"V ds fy, lHkh lqefs yr izfof"V;ksa ds cqycqyksa dks dkyk djsaA mnkgj.k Lo:i ] ;fn
dkWye-I dh izfof"V (A) izfof"V;ksa (Q), (R) rFkk (T) ls lqesfyr gks ] rks bu rhuksa cqycqyksa dks vks-vkj-,l- esa dkyk
djsaA blh izdkj izfof"V;ksa (B), (C) rFkk (D) ds fy;s Hkh djsa
vadu ;kstuk :
dkWye-I dh izR;sd izfof"V ds fy,
iw.kZ vad : +2 ;fn flQZ lHkh fodYi (fodYiksa) ds vuq:i cqycqys (cqycqyksa) dks dkyk fd;k tk;
'kwU; vad : 0 vU; lHkh voLFkkvksa esa
LTS-18/46 0999DJA110318004
cx
1. A particle of mass 'm' moves under a conservative force with potential energy U(x) =
x + a2 2
where c & a are positive constants. (Assume in each case particle is located at stable equilibrium)
Column-I Column-II
c
(A) Position of unstable equilibrium is (P) Less than
ma
c
(B) For the particle to be confined in the (Q) Just more than
ma
region the velocity of particle at
x = –a must be
2c
(C) For particle to reach x = +¥, (R) Just more than
ma
velocity of particle at x = –a must be (S) x = –a
(D) For the particle to reach x = –¥,
velocity of particle at x = –a must be (T) x = +a
cx
'm' nzO;eku dk ,d d.k U(x) = fLFkfrt ÅtkZ ds lkFk ,d laj{kh cy ds v/khu xfr djrk gS tgk¡ c o a
x + a2
2
/kukRed fu;rkad gAS (ekuk çR;sd çdj.k esa d.k LFkk;h lkE;koLFkk ij fLFkr gAS )
dkW ye-I dkW ye-II
c
(A) vLFkk;h lkE;koLFkk dh fLFkfr gksxh (P) ls de
ma
c
(B) d.k dks {k=S esa ifjc¼ cuk;s (Q) ls vf/kd
ma
j[kus ds fy;s d.k dk x = –a ij osx gksxk
2c
(C) d.k ds x = +¥ rd igq¡pus ds fy;s (R) ls vf/kd
ma
d.k dk x = –a ij osx gksxk
(D) d.k ds x = –¥ rd igqapus ds fy;s] (S) x = –a
d.k dk x = –a ij osx gksxk (T) x = +a
0999DJA110318004 LTS-19/46
PART-2 : CHEMISTRY
Hkkx-2 : jlk;u foKku
correct.
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gSaA ftuesa ds o y ,d gh lgh gSaA
1. Radius of cation and anion are 2.5 Å & 2.6Å respectively. If a cubic crystal system is prepared
by combination of above cation and anion then edge length of unit cell is (Take 3 = 1.7 )
/kuk;u rFkk ½.kk;u dh f=T;k Øe'k% 2.5 Å rFkk 2.6Å gS ;fn ,d ?kuh; fØLVy ra= dks mijksDr /kuk;u rFkk ½.kk;u
ds la;kstu }kjk cuk;k x;k g]S rks bdkbZ ly
S ds fdukjs dh yEckbZ gS (fn;k gS 3 = 1.7 )
(A) 2.7Å (B) 2Å (C) 3Å (D) 6Å
2. A cubic unit cell contains manganese ions at the corners and fluoride ions at the centres of each
edge. The coordination number of maganese ion is-
,d ?kuh; bdkbZ dksf"Bdk esa eaxS uht vk;u dksuksa ij rFkk ¶yksjkbM vk;u izR;sd fdukjs ds dsUnz ij fLFkr gSA eaxS uht
vk;u dh leUo; la[;k D;k gksxh\
(A) 8 (B) 2 (C) 4 (D) 6
LTS-20/46 0999DJA110318004
3. The decomposition of a gaseous substance (A) to yield gaseous products (B), (C) follows first
order kinetics. If initially only (A) is present and l0 minutes after the start of the reaction
the pressure of (A) is 200 mm Hg and that of total pressure is 300 mm Hg, then the rate constant
for A ® B + C is
,d xl
S h; inkFkZ (A) ds fo?kVu ls izkIr xl
S h; mRikn (B) rFkk (C) dh vfHkfØ;k izFke dksfV cyxfrdh dk vuqlj.k
djrh gSA ;fn izkjEHk es a dsoy (A) mifLFkr gS rFkk vfHkfØ;k izkjaHk gksus ds l0 feuV ds ckn (A) dk nkc
200 mm Hg rFkk lEiw.kZ feJ.k dk nkc 300 mm Hg gS rks vfHkfØ;k] A ® B + C ds fy, nj fu;arkd gS &
(A) (1/600) ln 1.25 sec–1 (B) (2.303/10) log 1.5 min–1
2.303
(C) (1/10) ln 1.25 sec–1 (D) log 1.5 sec
–1
600
4. Consider following 1st order reaction, where [C] is equal to [D] at all times after the start of
reaction. Time at which concentration of all three are equal
fuEu izFke dksfV vfHkfØ;k ij fopkj dhft,] tgk¡ vfHkfØ;k ds izkjEHk ds i'pkr~ lHkh le;ksa ij [C], [D] ds cjkcj
gksrk gAS og le; crkb;s ftl ij lHkh rhuksa inkFkksZ dh lkUærk leku gksrh gS
K1 C
A K2
D
1 1 1 1
(A) t = ln 3 (B) t = ln 3 (C) t= ln 2 (D) t = ln 2
2K1 K1 3K1 2K1
0999DJA110318004 LTS-21/46
5. In which of the following species presence of double bond does NOT affect idealised bond angle :-
(I) POCl3 (II) XeO3F2 (III) XeO2F4 (IV) XeO4
(A) II , III, IV (B) I , II only (C) III , IV only (D) I , II , III
fuEu esa ls dkuS lh Lih'kht esa] f}&cU/k dh mifLFkfr vkn'kZ (idealised) cU/k dks.k dks izHkkfor ugha djrh gS :-
(I) POCl3 (II) XeO3F2 (III) XeO2F4 (IV) XeO4
(A) II , III, IV (B) dsoy I , II (C) dsoy III , IV (D) I , II , III
6. Which of the following statement is INCORRECT ?
(A) In SiH3NCO, nitrogen is sp2 hybridised
(B) Colour of halogens is due to HOMO-LUMO electronic transition
(C) Boiling point of H2O is greater than H2S
(D) Maximum number of atom in plane in I2Cl6 is 8
fuEu esa ls dkuS lk dFku xyr g\ S
(A) SiH3NCO esa, ukbVªkt s u sp2 ladfjr gS
(B) gy
S kstuksa ds jax dk dkj.k HOMO-LUMO bysDVªkfu; laØe.k gS
(C) H2S dh rqyuk esa H2O dk DoFkukad vf/kd gksrk gS
(D) I2Cl6 esa ,d ry esa mifLFkr ijek.kqvksa dh vf/kdre la[;k 8 gS
LTS-22/46 0999DJA110318004
darkened.
izR;sd iz'u ds fy, vks-vkj-,l- ij lkjs lgh mÙkj (mÙkjksa) ds vuq:i cqycqys (cqycqyksa) dks dkyk djsaA
7. A layered sequence for fcc is as shown below
1 2 6 10 11 z
5 9 7 14
x
4 3 8 13 12 y
if a face diagonal passes through the centre of atom 4 & the centre(s) of which other atom(s),
it passes
(A) 9, 10 (B) 5, 11 (C) 5, 2 (D) 8, 12
fcc ds fy, ijrksa ds Øe fuEu izdkj iznf'kZr gS
1 2 6 10 11 z
5 9 7 14
x
4 3 8 13 12 y
;fn ,d Qyd fod.kZ ijek.kq 4 ds dsUnz ls xqtjrk gS] rks vU; ijek.kqvksa ftuds dsUnzkas ls ;g xqtjsxk og gS
(A) 9, 10 (B) 5, 11 (C) 5, 2 (D) 8, 12
2/3
8. For a given reaction, rate = k[A] [B] . Correct option(s) is/are :-
(A) Units of k = mol–5/3 L5/3 sec–1
(B) If [B]0 is large compare to [A]0 then reaction obey first order kinetics
(C) on diluting the solution 8 times rate will become 32 times the initial rate
(D) the reaction is a complex reaction
0999DJA110318004 LTS-23/46
,d vfHkfØ;k ds fy,, nj = k[A] [B]2/3. lgh fodYi g@S gaS :-

(A) k dh bdkbZ = mol–5/3 L5/3 sec–1
(B) ;fn [A]0 dh rqyuk esa [B]0 cgqr vf/kd gS rks vfHkfØ;k izFke dksfV cyxfrdh dk vuqlj.k djrh gSA
(C) foy;u dks 8 xquk ruq djus ij nj] izkjfEHkd nj ls 32 xquk gks tkrh gSA
(D) ;g vfHkfØ;k ,d tfVy vfHkfØ;k gAS
9. Which among the following molecule(s) have peroxy linkage :-
fuEu essa ls dkuS ls v.kqvksa esa ijkWDlh cU/ku mifLFkr gaS :-
(A) CrO5 (B) H4P2O8 (C) H2S2O8 (D) HClO4
10. In which of the following given process, product is/are paramagnetic species?
fuEu esa ls dkuS ls çØe eas mRikn vuqpqEcdh; Lih'kht g@S ga?S
(A) NO ¾¾® NOÅ (B) O2 ¾¾® O2!
(C) NO ¾¾® NO! (D) O3 ¾¾® O3!

LTS-24/46 0999DJA110318004
correct.
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gSa ftuesa ds o y ,d lgh gSaA
iz' u
11 ,oa 12 ds fy;s vuq P Ns n
Kinetics of acidic hydrolysis of ester is pseudo I order reaction
+
CH3COOCH3(aq.) + H 2O (l) ¾¾¾
[H ]
® CH3COOH(aq.) + CH3OH(aq.)
excess
Rate law is given by : r = K[H+] [H2O] [CH3COOCH3] ; K = 1.8 × 10–3 M–2 sec–1
where H+ ion concentration is given by acid catalyst . In an experiment 1M CH3COOCH3 is
hydrolysed using 0.1M HCl as catalyst.
,LVj ds vEyh; ty vi?kVu dh xfrdh] Nn~e izFke dksfV vfHkfØ;k gksrh gS
+
CH3COOCH3(aq.) + H 2O (l) ¾¾¾
[H ]
® CH3COOH(aq.) + CH3OH(aq.)
excess
nj fu;e fuEu izdkj fn;k tk ldrk gS : r = K[H+] [H2O] [CH3COOCH3] ; K = 1.8 × 10–3 M–2 sec–1
tgk¡ H+ vk;u lkUnzrk dks vEy mRizsjd }kjk fn;k tkrk gS ,d iz;ksx esa 1M CH3COOCH3 dk ty vi?kVu
0.1M HCl dks mRizjs d ds :i esa mi;ksx djds gksrk gAS
11. Calculate the time at which ester concentration reduce to 0.25M [ln2 = 0.7]
(Given density of pure H2O = 1gm/ml)
og le; Kkr dhft;s ftl ij ,LVj dh lkUnzrk 0.25M rd ?kV tkrh gS [ln2 = 0.7]
(fn;k gS 'kq¼ H2O dk ?kuRo = 1gm/ml)
700 350
(A) 70 sec (B) 140 sec (C) sec (D) sec
9 9
12. Reaction mixture is titrated against standard NaOH solution at different times. If initially
10 ml of NaOH was required while after long time 100 ml of NaOH is required then find volume
of NaOH required at 230.3 sec.
vfHkfØ;k feJ.k dks fofHkUu le;ksa ij ekud NaOH foy;u ds fo:¼ vuqekfir fd;k x;kA ;fn izkjEHk esa
10 ml NaOH dh vko';drk gq bZ gks tcfd yEcs le; ds ckn 100 ml NaOH dh vko';drk gq b Z gks rks
230.3 sec ij vko';d NaOH ds vk;ru dks Kkr dhft;sA
(A) 91 ml (B) 81 ml (C) 75 ml (D) 50 ml
0999DJA110318004 LTS-25/46
iz' u
13 ,oa 14 ds fy;s vuq P Ns n
The phenomenon of intermixing of the orbitals of slightly different energies so as to redistribute
their energies, resulting in the formation of new set of orbitals of equivalent energies and shape.
Valence shell electron pair repulsion theory predicts the shape of the molecule by considering
the most stable configuration of the bond angles in the molecule.
de ÅtkZ vUrj j[kus okys d{kdksa ds fefJr gksus dk ,slk izØe ftlesa mudh ÅtkZvksa ds iqufoZrj.k ds ifj.kkeLo:i
leku ÅtkZ rFkk vkÏfr j[kus okys d{kdksa ds u;s leqPp; dk fuekZ.k gksrk gS ] ladj.k dgykrk gS
la;kstdrk dks'k izfrd"kZ.k fl¼kUr }kjk] v.kqvksa esa ca/k dks.kksa ds lokZf/kd LFkk;h vfHkfoU;kl ij fopkj djrs gq, v.kqvksa
dh vkÏfr dk iwokZuqeku fd;k tkrk gSA .
13. In which of the following, d x2 -y2 of the underlined atom participate in hybridisation?
fuEu esa ls dkuS lh Lih'kht esa js[kkafdr ijek.kq dk d x2 - y2 d{kd ladj.k eas Hkkx ysrk gS ?
(A) SNF3 (B) XeF2 (C) SOF4 (D) XeF4
14. In which of the following bond angle order between bonds around underlined atom is CORRECT
js[kkafdr ijek.kq ds pkjksa vksj mifLFkr ca/kksa ds e/; ca/k dks.k ds lUnHkZ eas] fuEu esa ls dkuS lk Øe lgh gS &
(A) OCl2 < H2O (B) NH3 > PH3
(C) N(CH3)3 > N(SiH3)3 (D) OCl2 < SCl2
LTS-26/46 0999DJA110318004
s u lwpha gAS lwfp;ksa ds fy, dksM ds fodYi (A), (B), (C) vkSj (D) gaS ftuesa ls dso y ,d lgh gAS
15. List-I/lw p h -I List-II/lw p h -I
(Ionic crystals) (Nearest distance between two cations in
(vk;fud fØLVy) terms of edge length (a) of unit cell)
(bdkbZ lSy ds fdukjs dh yEckbZ (a) ds inksa esa nks /kuk;uks a
ds chp fudVre nwjh)
(P) NaCl (1) a/ 2
(Q) ZnS (2) a/2
(R) CsCl (3) a/ 3

(S) Na2O (4) a
(A) P ® 1; Q ® 1; R ® 4; S ® 2 (B) P ® 2; Q ® 3; R ® 1; S ® 4
(C) P ® 1; Q ® 2; R ® 3; S ® 2 (D) P ® 4; Q ® 3; R ® 2; S ® 1
0999DJA110318004 LTS-27/46
16. List-I List-II
(Species) (Characteristics)
(P) BrF5 (1) Bond angle > 90°
(Q) XeO2F2 (2) d x2 -y2 orbital participated in
hybridisation
(R) NH Å
4
(3) maximum lone pair of electron
present on central atom out of given
species
(S) XeF5! (4) Only d z2 orbital participated in
lwph-I lwp h-II
(Lih'kht ) (vfHky{k.k)
(P) BrF5 (1) ca/k dks.k > 90°
(Q) XeO2F2 (2) d x2 - y2 d{kd ladj.k esa Hkkx ysrk gS
(R) NH4Å (3) nh xbZ Lih'kht es a ds U æh; ijek.kq ij
(S) XeF5! vf/kdre ,dkadh bysDVªku ;qXe j[kus okyh
Lih'kht
(4) dsoy d z d{kd ladj.k esa Hkkx ysrk gS
2
(A) P ® 2; Q ® 4; R ® 3; S ® 1 (B) P ® 3; Q ® 4; R ® 2; S ® 1
(C) P ® 2; Q ® 4; R ® 1; S ® 3 (D) P ® 4; Q ® 3; R ® 2; S ® 1

[k.M II es a dks b Z iz ' u ugha gS A
LTS-28/46 0999DJA110318004
1. An element A (molecular weight 80 gm/mole) crystallize in BCC and FCC lattice. If density of
FCC lattice is 4 gm/cm3 and distance between next nearest neighbour in BCC is d than what is
3 2 ´ 10 7 d (in cm) .
,d rRo A (vkf.od Hkkj 80 gm/mole) BCC rFkk FCC tkyd esa fØLVyhd`r gksrk gAS ;fn FCC tkyd dk ?kuRo
4 gm/cm3 gS rFkk BCC esa S h ds e/; dh nwjh d gS rks 3 2 ´ 10 7 d (cm esa) dk eku D;k g\
vxys fudVre iMkl S
t 15
2. In first order reaction (A ® P) calculate if fraction of reactant is decayed in 't' time
t1/ 2 16
where t1/2 is half life.
t 15
izFke dksfV vfHkfØ;k (A ® P) esa] t dk eku Kkr dhft;s ;fn 't' le; esa fØ;kdkjd dk Hkkx {kf;r gksrk
1/ 2 16
gS ] tgk¡ t1/2 v¼Zvk;q gSA
0999DJA110318004 LTS-29/46
3. The energy of activation for a reaction is 10 kJ/mol. The presence of catalyst lowers the energy
of activation by 75%. Find the factor by which rate of reaction increases at 27ºC due to catalyst.
(Take R = 25/3 J/mol-k)
If your answer is ex then fill x in OMR sheet
,d vfHkfØ;k ds fy;s lafØ;.k ÅtkZ 10 kJ/mol gSA mRizsjd dh mifLFkfr ls lafØ;.k ÅtkZ esa 75% deh gksrh gSA
ml dkjd dks Kkr dhft;s] ftlds }kjk 27ºC ij mRizjs d ds dkj.k vfHkfØ;k dh nj c<+rh gAS
(fn;k gS R = 25/3 J/mol-k )
;fn vkidk mÙkj ex gS rks OMR 'khV esa ‘x’ Hkfj;s A
4. Find the number of chemical species, in which 2pp–3dp back bond is present
B(OH)3, N(SiH3)3, P(CH3)3, N(GeH3)3, BeCl2, O(SiH3)2, OCl2, BCl3
fuEu esa ls ,slh jklk;fud Lih'kht dh la[;k crkbZ;s ftuesa 2pp–3dp i'p ca/ku mifLFkr gAS
B(OH)3, N(SiH3)3, P(CH3)3, N(GeH3)3, BeCl2, O(SiH3)2, OCl2, BCl3
5. From given species number of paramagnetic species is/are
NO2 ,O22- ,N 2+ ,NO+ ,CO
fuEu esa fdruh vuqpqEcdh; Lih'kht mifLFkr g@S gSa\
NO2 ,O22- ,N 2+ ,NO+ ,CO
6. In the given following, find out the total number of compounds having more covalent than ZnCl2.
CuCl, HgCl2, GaCl3, AlBr3, CdCl2, CaCl2, BaCl2, KCl
ZnCl2 dh rqyuk esa vf/kd lgla;kstdrk j[kus okys fuEu fn;s x;s ;kSfxdksa dh dqy la[;k crkbZ;s
CuCl, HgCl2, GaCl3, AlBr3, CdCl2, CaCl2, BaCl2, KCl
LTS-30/46 0999DJA110318004
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
darkened
iz'u esa nks dkWye gSa ] dkWye -I rFkk dkWye -II
dkWye-I esa pkj izfo"V;k¡ (A), (B), (C) rFkk (D) g Sa
dkWye-II esa ik¡p izfof"V;k¡ (P), (Q), (R), (S) rFkk (T) g Sa
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
dkWye-I dh izfof"V (A) izfof"V;ksa (Q), (R) rFkk (T) ls lqesfyr gks ] rks bu rhuksa cqycqyksa dks vks-vkj-,l- esa dkyk
vadu ;kstuk :
0999DJA110318004 LTS-31/46
1. Column-I (Order - nA ® P) Column-II
(A) Zero (P) Reaction complete in finite time
1
(B) One (Q) v/s time graph is straight line
[A]nt -1
(C) Two (R) Half life increases when [A]0 decreases

(D) Half (S) Rate of reaction decrease during reaction
(T) May be elementry reaction
dkWye -I (dksfV - nA ® P) dkW ye-II
(A) 'kwU; (P) vfHkfØ;k fuf'pr le; esa iw.kZ gks tkrh gS
1
(B) ,d (Q)
[A]nt -1
v/s le; dk xzkQ lh/kh js[kk gS
(C) nks (R) tc [A]0 ?kVrk gS v¼Z vk;q c<+rh gS

(D) vk/kk (S) vfHkfØ;k ds nkSjku vfHkfØ;k dh nj ?kVrh gS
(T) izkFkfed vfHkfØ;k gks ldrh gS
LTS-32/46 0999DJA110318004
PART-3 : MATHEMATICS
Hkkx-3 : xf.kr
correct.
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gaSA ftuesa ds o y ,d gh lgh gSaA
1. The line joining A(3,1) and B(5,3) is rotated about the mid point C of AB in the anticlockwise
direction through 135º. The coordinates of B in the new position are-
A(3,1) rFkk B(5,3) dks feykus okyh js[kk dks AB ds e/; fcUnq C ds lkis{k okekorZ fn'kk esa 135º dks.k ls ?kqekbZ tkrh
gAS ubZ fLFkfr esa B ds funsZ'kkad gksaxs -
(
(A) 4,2 + 2 ) (
(B) 4 - 2,2 ) (
(C) 3 - 2 2,1 ) (
(D) 4,2 - 2 )
x+y x+y
2. Let y = y(x), y(1) = 1 and y(e) = e2. Consider J = ò xy
dy, I = ò 2 dx , J – I = g(x) and g(1) = 1,
x
then the value of g(e) is -
ekuk y = y(x), y(1) = 1 rFkk y(e) = e2 gAS ekuk J = ò x + y dy, I = ò x +2 y dx , J – I = g(x) rFkk g(1) = 1 g]S
xy x
rks g(e) dk eku gksxk -
(A) 3e + 1 (B) e + 1 (C) e2 – e + 2 (D) e2 + e – 2
0999DJA110318004 LTS-33/46
x 2 + 8x + 15
3. ò x+4
dx is equal to -
x 2 + 8x + 15
ò x+4
dx gksxk -
(A) x 2 + 8x + 15 + tan -1 x 2 + 8x + 15 + C (B) x 2 + 8x + 15 - tan -1 x 2 + 8x + 15 + C

(C) x + 4 + tan -1 x 2 + 8x + 15 + C (D) x + 4 - tan -1 x 2 + 8x + 15 + C
(1 - tan 2 x).cosec2xdx
4. ò sec 2 x
is equal to
(1 - tan 2 x).cosec2xdx
ò sec 2 x
cjkcj gksxk
ln | sin 2x | ln | cos 2x | ln(tan x) ln | cos x + sin x |

(A) +C (B) +C (C) +C (D) +C
2 2 2 2
5. ò ( 2 - x tan x ) cos xdx is equal to -
ò ( 2 - x tan x ) cos xdx dk eku gksxk &
(A) x sin x + C (B) - x sin x + C (C) 2x cos x + C (D) - x cos x + C

cosec x dx
6. ò ( 2 cosecx + cot x ) is equal to -
cosec x dx
ò ( 2 cosecx + cot x ) dk eku gksxk -
2 æ xö 1 æ xö
(A) tan -1 ç tan ÷ + c (B) tan -1 ç tan ÷ + c
3 è 2ø 3 è 2ø
2 æ tan x / 2 ö 1 æ tan x / 2 ö
(C) tan -1 ç ÷+c (D) tan -1 ç ÷+c
3 è 3 ø 3 è 3 ø
LTS-34/46 0999DJA110318004
darkened.
izR;sd iz'u ds fy, vks-vkj-,l- ij lkjs lgh mÙkj (mÙkjksa ) ds vuq:i cqycqys (cqycqyksa) dks dkyk djsaA
7. If lines x = a + m ; y = –2 ; y = mx ; are concurrent (where m is negative), then the possible
value(s) of 'a' is/are -
;fn js[kk;sa x = a + m ; y = –2 ; y = mx ; laxkeh (tgk¡ m ½.kkRed g)S gks] rks 'a' dk@ds laHko eku gksxk@gksaxs -
(A) 3 (B) 2 2 (C) 2 (D) 0
y
8. Consider the line ax + = 1 . The sum of intercepts of the line on coordinate axes can not have
a
the value:-
y
ekuk js[kk ax + =1 gAS funsZ'kh v{kksa ij js[kk }kjk dkVs x;s vUr%[k.Mksa ds ;ksxQy dk eku ugha gks ldrk gS :-
a
1 1
(A) 1 (B) – (C) 3 (D)
2 3
0999DJA110318004 LTS-35/46
9. If line (a + b)x + (b + c)y + a – c = 0 (where a < b < c) is as shown in figure, then which of the
following can be correct-
;fn js[kk (a + b)x + (b + c)y + a – c = 0 (tgk¡ a < b < c) fp=kuqlkj gks] rks fuEu esa ls dkuS lk lR; gks ldrk g-S
y
x
(0,0)
(A) |a| < |b| < |c| (B) |a| > |b| > |c| (C) |a| > |c| > |b| (D) |c| > |a| > |b|
3
10. If area of the triangle formed by the points A(3, 0), B(0, 3) & P(a, b) is sq. units, then identify
2
the correct statement(s)
(A) locus of P will be a union of two parallel lines
(B) Locus of P will be a union of two perpendicular lines
(C) Locus of P is given by x2 + y2 + 2xy – 6(x + y) + 8 = 0
(D) Locus of P is given by x2 – y2 + 2y – 6x + 8 = 0
3
;fn fcUnq A(3, 0), B(0, 3) rFkk P(a, b) }kjk fufeZr f=Hkqt dk {ks=Qy oxZ bdkbZ gks] rks lgh dFku@dFkuksa dks
2
igpkfu;sA
(A) fcUnq P dk fcUnqiFk nks lekUrj js[kkvksa dk la?k gksxk
(B) fcUnq P dk fcUnqiFk nks yEcor js[kkvksa dk la?k gksxk
(C) fcUnq P fcUnqiFk] x2 + y2 + 2xy – 6(x + y) + 8 = 0 }kjk fn;k tkrk gS
(D) fcUnq P fcUnqiFk] x2 – y2 + 2y – 6x + 8 = 0 }kjk fn;k tkrk gS
LTS-36/46 0999DJA110318004
correct.
izR;sd iz'u esa pkj mÙkj fodYi (A), (B), (C) vkjS (D) gaS ftuesa ds o y ,d lgh gSaA
x4
Let ƒ,g,h be 3 functions such that ƒ'(x) > 0 & g(x) > 0 " x Î R where ò ƒ(x).g(x)dx = 4
+C &
ƒ(x) g(x)
ò g(x) dx = ò h(x) dx = ln | x | + C , x ¹ 0.
On the basis of above information, answer the following questions :
x4
ekuk lHkh x Î R ds fy, ƒ,g,h rhu Qyu bl izdkj gS fd ƒ'(x) > 0 rFkk g(x) > 0 g]S tgk¡ ò ƒ(x).g(x)dx = +C
4
ƒ(x) g(x)
rFkk ò g(x) dx = ò h(x) dx = ln | x | + C , x ¹ 0 gAS
mijksDr tkudkjh ds vk/kkj ij ] fuEu iz'uksa ds mÙkj nhft, :
11. ò ƒ(x).g(x).h(x)dx is equal to -
ò ƒ(x).g(x).h(x)dx dk eku gksxk -

x5 x6 x7 x8
(A) +C (B) +C (C) +C (D) +C
5 6 7 8
12. ƒ(x), g(x), h(x) are in -
(A) A.P. (B) G.P. (C) H.P. (D) None of these
ƒ(x), g(x), h(x) gksaxs -
(A) lekUrj Js.kh esa (B) xq.kksÙkj Js.kh esa (C) gjkRed Js.kh esa (D) buesa ls dksbZ ugha
0999DJA110318004 LTS-37/46
x 2 ( x sec 2 x + tan x ) x2
Let ò dx = 2ln ƒ(x) - + k (where k is constant of integration) .
( x tan x + 1)
2
g (x)
On the basis of above information, answer the following questions :
x 2 ( x sec 2 x + tan x ) x2
ekuk ò dx = 2ln ƒ(x) - + k gS (tgk¡ k lekdyu vpj g)
S A
( x tan x + 1)
2
g (x)
mijksDr tkudkjh ds vk/kkj ij ] fuEu iz 'uksa ds mÙkj nhft , :
13. ƒ(x) is a/an -
(A) bounded function (B) even function (C) odd function (D) periodic function
ƒ(x) gksxk -
(A) ifjc¼ Qyu (B) le Qyu (C) fo"ke Qyu (D) vkorhZ Qyu
g(x) - 1
14. lim is equal to -
x ® 0 ƒ(x) - 1
(A) 0 (B) 1 (C) 2 (D) does not exist

g(x) - 1
lim dk eku gksxk -
x ® 0 ƒ(x) - 1
(A) 0 (B) 1 (C) 2 (D) fo|eku ugha

LTS-38/46 0999DJA110318004
s u lwpha gAS lwfp;ksa ds fy, dksM ds fodYi (A), (B), (C) vkSj (D) gaS ftuesa ls dso y ,d lgh gAS
15. Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
(P) An equilateral triangle has one vertex at (0,0) and (1) 1
another at 3, 3 ( ) the x-coordinate of third vertex is
(Q) (1,–2), (3,6), (5,10), (3,y) in order are the vertices of a (2) 2
parallelogram, then y is
(R) x-coordinate of circumcentre of triangle with vertices (3) 3
(–2,–3), (–1,0), (7,–6) is
(S) y-coordinate of a point which divides the line segment (4) 4
joining (5,–2) and (9,6) internally in the ratio 3 : 1, is
(A) P ® 1; Q ® 4; R ® 3; S ® 2 (B) P ® 4; Q ® 3; R ® 1; S ® 2
(C) P ® 3; Q ® 2; R ® 3; S ® 4 (D) P ® 3; Q ® 1; R ® 4; S ® 2
lwph-I dks lwph-II ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn, u, dksM dk iz;ksx djds lgh mÙkj pqfu;s %
lwph-I lwp h-II
(P) fdlh leckgq f=Hkqt dk ,d 'kh"kZ (0,0) ij rFkk vU; 'kh"kZ (1) 1
(3, 3 ) ij gks ] rks rhljs 'kh"kZ dk x-funsZ'kkad gksxk

(Q) (1,–2), (3,6), (5,10), (3,y) Øe esa ,d lekUrj prqHkqZt ds 'kh"kZ (2) 2
gks] rks y dk eku gksxk
(R) 'kh"kZ (–2,–3), (–1,0), (7,–6) }kjk fufeZr f=Hkqt ds ifjdsUæ (3) 3
dk x-funsZ'kkad gksxk
(S) (5,–2) rFkk (9,6) dks feykus okys js[kk[k.M dks 3 : 1 esa (4) 4
vUr%foHkkftr djus okys fcUnq dk y-funsZ'kkad gksxk
(A) P ® 1; Q ® 4; R ® 3; S ® 2 (B) P ® 4; Q ® 3; R ® 1; S ® 2
(C) P ® 3; Q ® 2; R ® 3; S ® 4 (D) P ® 3; Q ® 1; R ® 4; S ® 2
0999DJA110318004 LTS-39/46
16. Number of points of intersection of (|x – 1| – 3)2 + |y|2 = 25 with line L is.
Match List-I with List-II and select the correct answer using the code given below the list.
js[kk L ds lkis{k (|x – 1| – 3)2 + |y|2 = 25 ds izfrPNsn fcUnqvksa dh la[;k gksxh
lwph-I dks lwph-II ls lqesfyr dhft, rFkk lwfp;ksa ds uhps fn, u, dksM dk iz;ksx djds lgh mÙkj pqfu;s %
List-I/lw p h -I List-II/lw p h -II
(P) If L º 2x – y + 2 = 0 (1) 1
;fn L º 2x – y + 2 = 0
(Q) If L º 2x – 3y + 10 = 0 (2) 2
;fn L º 2x – 3y + 10 = 0
(R) If L º 3x – 4y + 5 = 0 (3) 3
;fn L º 3x – 4y + 5 = 0
(S) If L º 3x – 4y + 31 = 0 (4) 4
;fn L º 3x – 4y + 31 = 0
(A) P ® 1; Q ® 4; R ® 3; S ® 2 (B) P ® 4; Q ® 3; R ® 1; S ® 2
(C) P ® 3; Q ® 4; R ® 1; S ® 2 (D) P ® 2; Q ® 3; R ® 2; S ® 1

[k.M II es a dks b Z iz ' u ugha g S A
LTS-40/46 0999DJA110318004
1. A rectangle PQRS has sides PQ = 11 and QR = 5. A triangle ABC has P as orthocentre, Q as
circumcentre, R as mid point of BC and S as the foot of altitude from A. Then length of BC is
k, where k/4 is equal to
,d vk;r PQRS ftldh Hkqtk PQ = 11 rFkk QR = 5 gAS f=Hkqt ABC ftldk yEcdsUæ P, ifjdsUæ Q, Hkqtk BC
dk e/; fcUnq R rFkk A ls 'kh"kZyEc dk ikn S gAS rc BC dh yEckbZ k g]S tgk¡ k/4 dk eku gksxk
(x - 4 ) dx l ( x6 + 2)
m
6
n
2. Let
ò = + C , (l,m,n Î R), then lm is equal to
(x + 2 ) .x 4
1/ 4
6 xn
(x - 4 ) dx l ( x6 + 2)
m
6
n
ekuk ò = + C , (l,m,n Î R) gks] rks dk eku gksxk
(x + 2 ) .x 4 lm
1/ 4 n
6 x
dx
3. Let ò ( x + 1) = ƒ(x) + C where ƒ(0) = –ln2 & ƒ æç - 1 ö÷ = ln æç k - 3 ö÷ , then k is equal
x + x +1
2
è 2ø è 2ø
to
dx
ekuk ò ( x + 1) = ƒ(x) + C , tgk¡ ƒ(0) = –ln2 rFkk ƒ æç - 1 ö÷ = ln æç k - 3 ö÷ gks] rks k dk eku gksxk
x + x +1
2
è 2ø è 2ø
0999DJA110318004 LTS-41/46
4. If (0, a) lies inside the triangle formed by the lines y + 3x + 2 = 0, 3y – 2x – 5 = 0 and
4y + x – 14 = 0 then sum of all the integralvalues of a is
;fn (0,a), js[kkvksa y + 3x + 2 = 0, 3y – 2x – 5 = 0 rFkk 4y + x – 14 = 0 }kjk fufeZr f=Hkqt ds vUnj dh
vksj fLFkr gks ] rks a ds lHkh iw.kk±d ekuksa dk ;ksxQy gksxk
(4 + 3x)dx x-k
5. Let ò (x = ln + C , then k2 + l2 is equal to
3
- 2x - 4) x + kx + l
2
(4 + 3x)dx x-k
ekuk ò (x = ln + C gks] rks k2 + l2 dk eku gksxk
3
- 2x - 4) x + kx + l
2
6. Let m and m2 are slopes of lines represented by the line pair qx2 – 2pxy + y2 – 2x + 3y + l = 0,
q + q 2 + 6pq
then value of is
p3
ekuk m rFkk m2 mu js[kkvksa dh izo.krk;sa g]S ftudks js[kk ;qXe qx2 – 2pxy + y2 – 2x + 3y + l = 0 }kjk iznf'kZr djrs
g]S rks q + q 3+ 6pq dk eku gksxk

2
p
LTS-42/46 0999DJA110318004
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
darkened
iz'u esa nks dkWye gaS] dkWye -I rFkk dkWye -II
dkWye-I esa pkj izfo"V;k¡ (A), (B), (C) rFkk (D) gSa
dkWye-II esa ik¡p izfof"V;k¡ (P), (Q), (R), (S) rFkk (T) gSa
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
dkWye-I dh izfof"V (A) izfof"V;ksa (Q), (R) rFkk (T) ls lqesfyr gks] rks bu rhuksa cqycqyksa dks vks-vkj-,l- esa dkyk
vadu ;kstuk :
0999DJA110318004 LTS-43/46
1. Column-I Column-II
(A) If the image of (3, 8) in the line x + 3y = 7 is (a,b), (P) 3
then a – b is equal to
(B) If the points (l,l), (l,2l) & (2l,l) enclose a triangle (Q) 4
of area 18 sq. units and (a,b) is its centroid then
|a |+|b|
is equal to
4
(C) If 5m + 2c – 7 = 0, then the straight line (R) 6
y = mx + c always passes through the point
(a,b), then |a + b| is equal to
(D) Area of the triangle formed by the lines (S) Odd number
x2y+ x2–y3+3y2–4=0 is equal to
(T) Prime number
dkW ye-I dkW ye-II
(A) ;fn (3, 8) dk js[kk x + 3y = 7 esa izfrfcEc (a,b) g]S rks (P) 3
a – b dk eku gksxk
(B) ;fn fcUnqvksa (l,l), (l,2l) rFkk (2l,l) }kjk ifjc¼ f=Hkqt dk {ks=Qy (Q) 4
|a |+|b|
18 oxZ bdkbZ rFkk (a,b) bldk dsUæd gS] rks dk eku gksxk
4
(C) ;fn 5m + 2c – 7 = 0 gks] rks ljy js[kk y = mx + c lnoS (R) 6
fcUnq (a,b) ls xqtjrh gS ] rks |a + b| dk eku gksxk
(D) js[kkvksa x2y+x2–y3+3y2–4=0 }kjk fufeZr f=Hkqt dk {ks=Qy gksxk (S) fo"ke la[;k
(T) vHkkT; la[;k
LTS-44/46 0999DJA110318004
Que. No. Category-wise Marks for Each Question / oxkZuqlkj izR;sd iz'u ds vad Maximum
Section Type of Full Marks Partial Marks Zero Marks Negative Marks of the
Que. iw.kZ vad vkaf'kd vad 'kwU; vad Marks section
[k.M iz'u dk iz'uksa ½.k vad [k.M esa
izdkj dh vf/kdÙke vad
la[;k
+3 0 –1
Single If only the bubble If none In all
correct option corresponding to of the other
,dy lgh the correct option bubbles is cases
I(i) fodYi 6 is darkened — darkened vU; lHkh 18
;fn flQZ lgh fodYi ds ;fn fdlh Hkh ifjfLFkfr;ksa
vuq:Ik cqycqys dks cqycqys dks dkyk esa
dkyk fd;k gS ugha fd;k gS
+4 0
One or more If only the bubble(s) In all
correct corresponding other
option(s) to all the correct cases
,dy ;k ,d ls option(s) is(are) vU; lHkh
I(ii) 4 — — 16
vf/kd lgh darkened ifjfLFkfr;ksa
fodYi ;fn flQZ lkjs lgh fodYi esa
(fodYiksa) ds vuq:Ik
cqycqys (cqycqyksa) dks
dkyk fd;k x;k gS
Paragraph +3 0
Based If only the bubble In all
(Single corresponding to other
correct the correct option cases
I(iii) option) 4 is darkened — vU; lHkh — 12
vuqPNsn ij ;fn flQZ lgh fodYi ds ifjfLFkfr;ksa
vk/kkfjr vuq:Ik cqycqys dks esa
(,dy lgh dkyk fd;k gS
fodYi)
Matching +3 0 –1
Lists Type If only the bubble If none In all
(Single corresponding to of the other
correct option) the correct option bubbles is cases
I(iv) lqpha lqesyu 2 is darkened — darkened vU; lHkh 6
izdkj ;fn flQZ lgh fodYi ds ;fn fdlh Hkh ifjfLFkfr;ksa
(,dy lgh vuq:Ik cqycqys dks cqycqys dks dkyk esa
fodYi) dkyk fd;k gS ugha fd;k gS
+4 0
Single digit If only the bubble In all
Integer corresponding other
(0-9) to correct answer cases
III ,dy vadh; 6 is darkened — vU; lHkh — 24
iw.kk±d ;fn flQZ lgh mÙkj ds ifjfLFkfr;ksa
(0-9) vuq:Ik cqycqys dks esa
dkyk fd;k gS
+8 +2 0
If only the bubble(s) For darkening a bubble In all
corresponding to corresponding to each other
all the correct correct match is cases
Matrix match(es) is(are) darkened vU; lHkh
IV Match Type 1 darkened izR;sd lgh feyku ifjfLFkfr;ksa — 8
lqesfyr izdkj ;fn flQZ lkjs lgh feyku ds vuq:i cqycqys esa
(feykuksa) ds vuq:Ik dks dkyk djus ij
cqycqys (cqycqyksa) dks
dkyk fd;k x;k gS
0999DJA110318004 LTS-45/46
NAME OF THE CANDIDATE / ijh{kkFkhZ dk uke .............................................................................

FORM NO. / QkW e Z uEcj .............................................
I have read all the instructions I have verified the identity, name and Form
and shall abide by them. number of the candidate, and that question
eSau s lHkh funs Z' kks a dks i<+ fy;k gS vkS j eS mudk paper and ORS codes are the same.
vo'; ikyu d:¡ xk@d:¡ xhA eSa us ijh{kkFkhZ dk ifjp;] uke vkSj QkWeZ uEcj dks iw jh rjg
tk¡p fy;k gS ,oa iz' u i= vkSj vks - vkj- ,l- dks M nksuks a leku gSaA
____________________________ ____________________________
Signature of the Candidate / ijh{kkFkhZ ds gLrk{kj Signature of the Invigilator / fujh{kd ds gLrk{kj
Corporate Office : ALLEN CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan) INDIA 324005
+91-744-2757575 dlp@allen.ac.in www.dlp.allen.ac.in, dsat.allen.ac.in
LTS-46/46 Your Target is to secure Good Rank in JEE 2019 0999DJA110318004
Distance Learning Programmes
(Session-2018-19)
ALL INDIA TEST SERIES
ABOUT FEEDBACK SYSTEM

Dear Student,
We request you to provide feedback for the test series till you have appeared. Kindly answer the questions
provided on the reverse of paper with honesty and sincerely.
Although our test series questions are extremely well designed and are able to improve speed, accuracy &
developing examination temperament, yet we are always open to improvements.
If you have not prepared well for today's test and if you are not feeling good today, then do not blame test series
for it.
We strive to prepare you for all kinds of situations and facing variations in paper, as this can also happen in Main
exam. It is important for you to concentrate on your rank.
Go through the feedback form thoroughly and answer with complete loyalty. Darken your response (2, 1, 0) in
OMR sheet corresponding to :
Questions
1. Any problem in subscription of test series:
[2] Not at all [1] Some time [0] Problem faced
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[2] As per schedule [1] Some time deviate from schedule [0] Always delay
3. Test paper timing :
[2] Comfortable [1] Average [0] Need to be change
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[2] Good and approachable [1] Average in terms of approach [0] difficult to reach
5. Are you satisfy with result analysis :
[2] Outstanding [1] Average [0] Below average
6. The level of test paper [meet all the requirement of competitive examination]
[2] Outstanding [1] Average [0] Below average
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[2] Negligible [1] Are very less [0] Maximum
8. Do you think our test series is able to improve speed, accuracy & developing examination temperament?
[2] Yes [1] Partly [0] Not at all
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[2] Always good and prompt [1] Some time delay [0] Not satisfactory
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LEADER TEST SERIES / JOINT PACKAGE COURSE

CHEMISTRY : Chemical Bonding, Solid state, Chemical kinetics

MATHEMATICS : Point and Straight Line, Indefinite integration

SOME USEFUL CONSTANTS

· Boltzmann constant k = 1.38 × 10–23 JK–1

Space for Rough Work / dPps dk;Z ds fy, LFkku

(A) 5 3 m / s2 (B) 2.5 m/s2 (C) 10 m/s2 (D) 5 m/s2

(A) 30° (B) 45° (C) 60° (D) 90°

(A) FB = FA (B) PB = PA (C)PB = 2PA. (D) FB = 2FA

Space for Rough Work / dPps dk;Z ds fy, LFkku

(P) Variation of velocity of lift with time (1)

fy¶V ds osx esa le; ds lkFk ifjorZu

(Q) Variation of power delivered by tension (2)

(S) Variation of acceleration of lift with time (4)

fy¶V ds Roj.k esa le; ds lkFk ifjorZu

Space for Rough Work / dPps dk;Z ds fy, LFkku

Space for Rough Work / dPps dk;Z ds fy, LFkku

Space for Rough Work / dPps dk;Z ds fy, LFkku

,d vfHkfØ;k ds fy,, nj = k[A] [B]2/3. lgh fodYi g@S gaS :-

(C) NO ¾¾® NO! (D) O3 ¾¾® O3!

Space for Rough Work / dPps dk;Z ds fy, LFkku

(R) CsCl (3) a/ 3

SECTION-II : Numerical Value Type (Up to second decimal place)

(C) Two (R) Half life increases when [A]0 decreases

(C) nks (R) tc [A]0 ?kVrk gS v¼Z vk;q c<+rh gS

(A) x 2 + 8x + 15 + tan -1 x 2 + 8x + 15 + C (B) x 2 + 8x + 15 - tan -1 x 2 + 8x + 15 + C

ln | sin 2x | ln | cos 2x | ln(tan x) ln | cos x + sin x |

ò ( 2 - x tan x ) cos xdx dk eku gksxk &

(A) x sin x + C (B) - x sin x + C (C) 2x cos x + C (D) - x cos x + C

ò ƒ(x).g(x).h(x)dx dk eku gksxk -

(A) 0 (B) 1 (C) 2 (D) does not exist

(A) 0 (B) 1 (C) 2 (D) fo|eku ugha

(3, 3 ) ij gks ] rks rhljs 'kh"kZ dk x-funsZ'kkad gksxk

SECTION-II : Numerical Value Type (Up to second decimal place)

Space for Rough Work / dPps dk;Z ds fy, LFkku

g]S rks q + q 3+ 6pq dk eku gksxk

NAME OF THE CANDIDATE / ijh{kkFkhZ dk uke .............................................................................

Space for Rough Work / dPps dk;Z ds fy, LFkku

ABOUT FEEDBACK SYSTEM

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