LATIHAN SOAL

Buat reaksi untuk mendapatkan senyawa dibawah ini :

1. 2-pentena {CH3CH=CHCH2CH3}

alkohol

a. CH3 –CH–CH–CH2–CH3 + KOH CH3 –CH=CH–CH2–CH3 + HCl

| |
H Cl
( 3-kloro-pentana )
H+
b. CH3 –CH–CH–CH2–CH3 CH3 –CH=CH–CH2–CH3 + H20
| |
H OH
( 3-pentanol )
Zn
c. CH3 –CH–CH–CH2–CH3 CH3 –CH=CH–CH2–CH3 + ZnCl2
| |
Cl Cl
( 2,3-dikloro-pentana)
H2
d. CH3 –C C –CH2 –CH3 H H

C=C

CH3 C2H5

( 2-pentuna ) ( cis )

NH3
CH3 –C C –CH2 –CH3 H C2H5

C=C

CH3 H
 ( 2-pentuna ) ( trans )

2. 2,3-dimetil-2-butena {(CH3)2C=C(CH3)2}

alkohol

a. ( CH3) 2 –C– C– (CH3) 2 + KOH CH3 CH3 + KCl + H2O

| |
H Cl C=C

CH3 CH3
( 3-kloro-2,3-dimetil-butana)
H+
b. ( CH3) 2 –C– C– (CH3) 2 CH3 CH3 + H2O
| |
H OH C=C

CH3 CH3
( 3-kloro-2,3-dimetil-butanol)
Zn
c. ( CH3) 2 –C– C– (CH3) 2 CH3 CH3 + ZnCl2
| |
Cl Cl C=C

CH3 CH3
( 3-kloro-2,3-dikloro-butana)
CH3
|
3. 2,3-dimetil-1,4-pentadiena{CH2=C CH2CH=CH2}
CH3
| alkohol
a. CH3–C–CH2–CH–CH2 + 2KOH CH=C–CH–CH=CH2 + 2KCL
+2H2O
| | |
Cl Cl CH3
(2,4-dikloro-4-metil-pentana)
 b. CH3
| H+
CH2–C–CH–CH–CH2 CH=C–CH–CH=CH2 + 2H2O
| | | | |
H OH H OH CH3
(4-metil-1,4-pentanol)
c. CH3
| Zn
CH2–C–CH–CH–CH2 CH=C–CH–CH=CH2 +
2ZnCl2
| | | | |
Cl Cl Cl Cl CH3
(1,2,4,5-tetrakloro-,4-dimetil-pentana)

4. 1-propena{CH2=C(CH3)CH3}
CH3
| alkohol
a. CH2–CH–CH3 + KOH CH2=CH(CH3)–CH3 + KCL + H2O
| |
H Cl
(2-kloro-propana)
CH3
| H+
b. CH2–CH–CH3 CH2=CH(CH3)–CH3 + H2O
| |
H OH
(2-propanol)
CH3
| Zn
c. CH2–CH–CH3 CH2=CH(CH3)–CH3 + ZnCl2
| |
Cl Cl
(1,2-dikloro-propana)
5. 2,4-dimetil-2-pentena
a. CH3 CH3
| | alkohol
CH3–CH–CH–C–CH3 + KOH CH3–C=CH–CH–CH3 + KCL + H2O
| | | |
H Cl CH3 CH3
(2-kloro,2,4-dimetil-pentana)

b. CH3 CH3
| | H+
CH3–CH–CH–C–CH3 CH3–C=CH–CH–CH3 + H2O
| | | |
H OH CH3 CH3
(2,4-dimetil-pentanol)

c. CH3 CH3
| | Zn
CH3–CH–CH–C–CH3 CH3–C=CH–CH–CH3 + ZnCl2
| | | |
Cl Cl CH3 CH3
(2,3-dikloro-2,4-dimetil-pentana)