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! The 4He isotope has the lowest know boiling point, 4.12 K, at
which point it is called He-I.
• On cooling to 2.178 K a phase transition to He-II occurs.
• He-II has an expanded volume, almost no viscosity, and
is superconducting.
• He-II can readily flow uphill to equalize volumes in
adjacent vessels.
• It cannot be stored in glass Dewars, because it leaks
through glass into the evacuated space, posing an
explosion risk.
D4h D4h
C3v C4v
1
J. F. Lehman, D. A. Dixon, G. J. Schrobligen, Inorg. Chem., 2001, 40, 3002.
2
R. D. Burbank, W. E. Falconer, W. A. Sunder, Science, 1972, 178, 1285.
XeO3 and Its Anions