G10 CHEMISTRY 2018-2019 END OF THE YEAR EXAMINATION REVISION HOMEWORK

Class :_______________ Name:________________ Marks:___________________/59

Exercise covering:
Unit1 lab safety and skills & Unit 3 Kinetics , Unit2 elements and compounds ,Unit 4 Quantitative
chemistry Unit 5 Energetics
Unit2 Elements and compounds
Check list .. I need to be able to
√
 Define and give examples of element, compound and mixture
 Periodic table [group 1-18 and period]
 Elements in periodic table (name and symbol)

 Identify metals and non-metals in the Periodic Table

 Structure of an atom (determine number of proton, electron and neutron)

 Formation of an ion [cation and anion]
 Electron configuration of atoms and ions in s p d form (atomic number < 20)

 Writing chemical formula of ionic compounds [reference to ion table]

 Draw Lewis diagram for simple molecules [for example: HCl, CH4, CH2Cl2]

Question one
For the elements and ions given below, complete the table [4]
Name Symbol Atomic # Atomic mass # of p # of n Electron configuration
Sodium Na 11 23 11 12 1s22s22p63s1

oxygen O 8 16 8 8 1s22s22p4

aluminium
Al3+ 13 27 13 14 1s22s22p6
ion

fluoride ion F- 9 19 9 10 1s22s22p6

Question TWO
Complete the table below by naming or writing the chemical formula of the compound [5]

Element Name Chemical Name

/ion formula
P Phosphorus CH3COOH Ethanoic acid/acetic acid
K potassium Zn(NO3)2 Zinc nitrate
Pb lead PbCl2 Lead chloride
O2- Oxide ion Mg(HCO3)2 Magnesium bicarbonate
Na sodium Fe(OH)3 Iron (III) hydroxide

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Unit1 lab safety and skills & Unit 3 Kinetics
Check list .. I need to be able to
√
 Take reading from the scientific equipment
 Write chemical equations for: metal + acid ; Acid + base [neutralisation reaction, possible bases
are: metal hydroxide, metal carbonate, metal bicarbonate, metal hydroxide]
 Define the term “activation energy”, and “rate of reaction”
 Factors affect the rate of reaction and justification for each
 The use of catalyst and how it works
 Describe the rate of reaction with respect to time in relation to collision theory
 Calculate rate of reaction from a graph (for example v(H2) gas vs time graph)
Scientific Investigation
 Write the aim for an investigation
 State the variables [independent / dependent / control variable] (What and How)
 Draw scientific drawings for common lab equipment
 Present answers to the correct significant figure
 Read off data from scaled equipment (ie thermometer, burette) and plot a graph
 Graph interpretation and draw a conclusion including a link between processed data to a scientific
context (theory)

Question 1 [Total 8 marks]

[4]

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Question 2 [Total 23 marks]

1. A student wants to investigate the relationship between the concentration of sulfuric acid and the rate of
reaction between 2.00 g of zinc metal and 25.0 cm3 sulfuric acid. The student decides to measure the rate of
the reaction using the water displacement method.

a. Draw and label an appropriate equipment setting for this experiment. Include all necessary equipment. [2]

b. The student completed the experiment and began to complete the report. Help the student to complete the
report by correcting the sections already completed and completing those that were not completed yet.

i). Student’s aim: the aim of the experiment is to investigate the effect of concentration on the rate of reaction.
Your corrected aim: [2]

The aim of the experiment is to investigate the effect of concentration of 25.0 cm3 of sulfuric acid on
the rate of reaction between 2.00 g of zinc and sulfuric acid by measuring the amount of hydrogen
gas produced using the water displacement method.

ii ). Independent variable: concentration [2]

Your corrected IV:
Concentration of sulfuric acid; changed by diluting sulfuric acid to 2.00 mol dm−3 ,1.5 mol dm−3,1.00
mol dm−3,0.5mol dm−3 , 0.1mol dm-3

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 iii) Dependent variable: Rate of reaction [2]
Your corrected DV:

Rate of reaction in cm3 H2 s−1. Determined by graphing volume of H2 produced versus

time and using the graphs to compare the rates. This can be done by finding the average
rate, or even better, drawing a tangent line to each graph and finding the slope of the
tangent line. Comparison can also be made by choosing a time and looking at how much
H2 has been produced for each reaction at that time.

iv). Controlled variables [2]

Control variables How it is controlled

Volume of sulfuric acid Keep the volume the same
Temperature Do reaction at room temperature
Particle size of zinc Keep the same size particles
Mass of zinc Keep the mass the same

Your corrected control variables:

Control variables How it is controlled

Volume of sulfuric acid Measure 25.0 cm3 using a graduated cylinder
Temperature Use a thermometer to monitor the temperature or
use the A/C to keep the room temperature at
25°C
Particle size of zinc Use powdered zinc
Mass of zinc Measure 2.00g of zinc using an electronic
balance

c. Quantitative data [2]

Title: the rate of reaction for zinc and sulfuric acid
Time Volume of H2 produced
1.0 mol dm sulfuric acid
−3
2.0 mol dm−3 sulfuric acid
0 0 0
10 10 20
20 30 40
30 40 50
40 50 55
50 55 55
60 55 55
Your corrected data table considering the following equipment was used

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 Table 1. Volume of H2 gas produced in 60 seconds for the reaction of 2.00 g of zinc
and 25.0cm3 of 1.00 mol dm−3 and 2.00 mol dm−3 sulfuric acid using water
displacement method.
Time (s ± 0.01 Volume of H2(g) produced (cm3 ± 0.5 cm3)
s) 1.0 mol dm−3 sulfuric acid 2.0 mol dm−3 sulfuric acid
0.00 0.0 0.0
10.00 10.0 20.0
20.00 30.0 40.0
30.00 40.0 50.0
40.00 50.0 55.0
50.00 55.0 55.0
60.00 55.0 55.0

d. Plot a graph based the data provided [5]

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 e. Write a conclusion [2]
The aim of the experiment is to investigate the effect of concentration of 25.0 cm3 of sulfuric acid
on the rate of reaction between 2.00 g of zinc and sulfuric acid by measuring the amount of
hydrogen gas produced using the water displacement method.

As we can see from the graph, at 20.0 seconds _____ cm3 of H2 has been produced from reaction
with 1.00 mol dm−3 sulfuric acid and _______ cm3 of H2 has been produced from reaction with 2.00
mol dm−3 sulfuric acid. Furthermore, analyzing the rates at 30 seconds by finding the slope of the
tangent line shows that the rate for 1.00 mol dm−3 sulfuric acid is ______ and for 2.00 mol dm−3
sulfuric acid is _____. From this data, it appears that the reaction rate is greater if the
concentration of sulfuric acid is greater.
This fits with the collision theory. As the concentration increases there are more particles to
collide with one another so the frequency of collision increases. If the frequency of collisions
increases the frequency of successful collisions will also increase, increasing the rate of the
reaction.

f. Provide one systematic and one random error for the experiment, state and explain their impact on precision
and/or accuracy, and how the errors could be improved. [4]

No standard answer
Don’t forget to explain the impact and improvement instead of only stating the error, impact and
improvement without justification

Example :Human time action limitation

Random error:
Measuring the time and volume of gas produced. There is large error in measuring the time and
volume produced.
Impact:
A person cannot read the time and volume at the same the exact same time. This results in a large
amount of uncertainty in the time at which the volume was read. This will cause the volume of
hydrogen gas collected smaller or bigger than actual value, and the rate of reaction will be
smaller or bigger than actual value, it will decrease the precision of the data.
Improvement:
Set up a video camera and record a video of the volume changing. Can then analyze the video to
obtain the volumes by pausing the video at certain time intervals and reading the measurement.

There are others, these are examples. Some other examples:

o Gas loss from the rubber stopper or delivery tube
o gas loss from having the rubber stopper off to put in the acid
o uncertainty in measuring the volume of acid – use a pipette or burette

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 Unit4 Quantitative chemistry
Check list .. I need to be able to
√
 Calculation using n = c x V ; n = m / M
 State the unit for M, n and c
 Stoichiometry and titration calculation using U/K rule
 Present answers to the correct significant figures

 Error propagation including calculation of percentage error

 Percentage discrepancy calculation

Question1 [Total 5 marks]
1. a) Write the chemical equation for a reaction between sulfuric acid and NaOH and name the type of reaction [1]

2NaOH(aq) ＋ H2SO4 (aq) --> Na2SO4 (aq)＋ H2O (l)

b) The exact concentration of sulfuric acid can be determined by titrating sulfuric acid with a known
concentration of NaOH. Using the data provided below. Determine the concentration of sulfuric acid used.
Present your answer to the correct significant figures.
20.0 cm3 of sulfuric acid is titrated against 0.865 mol dm-3 NaOH solution.
Titre values were: 18.5 cm3 , 17.9 cm3 , 17.8 cm3 , 17.5 cm3 , 17.8 cm3 [4]

V average(NaOH)=17.8 cm3+17.7 cm3+17.8 cm3/3

=17.7666cm3
n(NaOH)=0.865mol.dm-3 x 17.7666 x 10-3 dm3
=1.54 x 10-2 mol
n(H2SO4)= 1/2 n(NaOH)
= 1/2 X 1.5368 x 10-2 mol = 7.684 x 10-3 mol
c(H2SO4)=n/v
=7.684 x 10-3 mol/20 x10-3 dm3
=0.3842 mol =0.384 mol dm-3

Question2 [Total 3 marks]

A solution of 20.0 cm3 of 0.250 mol dm-3 lead(II) nitrate is added to a large volume of 0.500 mol dm-3 potassium
iodide solution to produce a brilliant yellow precipitate of lead (II) iodide. Determine the mass of precipitate
formed. Present your answer to the correct significant figure. [3]

Pb(NO3)2 (aq) + 2KI (aq)  PbI2 (s) + 2KNO3 (aq)

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Unit5 Energetics

Check list .. I need to be able to

√
 Identify reactions as exothermic or endothermic with justification
 Draw and label an energy profile diagram for exothermic and endothermic
 Give examples of exothermic and endothermic reaction and justify with an explanation in
relation to heat absorbed / lost
 Calorimetry calculation involving ∆H = q/ n and q = m x c x T with c(H2O) = 4.18 J℃-1g-1
 Evaluate good practices of experiment in the aspect of equipment selection, technique used
and controlled variables
 Define precision and accuracy, systematic error and random error
 Identify systematic, and random errors. For each error, state its impact associate to precision
or accuracy of the result and provide valid suggestion for the improvement

Check point #1 Identify reactions as exothermic and endothermic [5 marks]

Check point #2 Energy profile diagram[2 marks]

Refer to the example in check point #1 (a) to complete an energy profile diagram
Label: enthalpy, reaction progress, ∆H, Ea, enthalpy of the reactants, enthalpy of the product

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Check Point #3 ∆H calculation
∆H = q/ n

where q = mx c x T n= m/M
Exam Reminder:
1. Must check for significant figure. Only need to present your final answer to the correct significant figure
2. Must show working to your calculation. DO NOT combine equations together and present them as one.
3. Must present your final answer with an unit (kJ , kJ mol-1)
4. DO NOT forget the sign for ∆H
Exercise:

a) Calculate how much energy is released when 3.60 g of H2O is formed by the decomposition of
hydrogen peroxide [2]

n(H2O) = 3.60 g / 18.0 g mol-1

= 0.2 mol

q = n x H
= 0.2 mol x 98.2 kJ mol-1
= 19.6 kJ

b). Calculate the mass of hydrogen peroxide that must decompose to produce 600 kJ of energy [2]

n(H2O2) = 600 kJ / 98.2 kJ mol-1

= 6.11 mol

m(H2O2) = 6.11 mol x (34.0 gmol-1)

= 207 g

Answer: a) 19.6kJ b) n(H2O2) = 6.11 mol ; m(H2O2) = 207g

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