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Problema 11.

7
Se va a destilar la mezcla siguiente en una columna de destilacion de platos operando a una presion de 1 ATM
composiciones %mol Zi,j
benceno (1) 40% 0.4
tolueno (2) 30% 0.3
o-xileno (3) 30% 0.3
La alimentacion entrara a la columna como vapor saturado aun flujo de 100 lbmol/hr.se quiere obtener un flu
con una relacion de reflujo de 1.3 y una condensacion total
Si la columna tiene 18 etapas teoricas (incluyendo el condensador y el rehervidor) y se alimenta en el plato 10
y obtenga los perfiles de T, [] y flujos de la columna, asi como calores del condensador y de el rehervidor.
Espeficicaciones
U1=70 lbmol/hr
L1=(1.3)U1=91 lbmol/hr
Presion= 1atm= 760 mmHg
V1=0
V2=L1+U1=161lbmol/hr

Plato Vj Tj[=]°F Tj[=]°K Fm Wm Um Aj


1 0 178 366.80536 0 0 70 0
2 161 184 377.82372 0 0 0 91
3 161 190 383.664922 0 0 0 91
4 161 196 382.344367 0 0 0 91
5 161 202 380.929192 0 0 0 91
6 161 208 384.604085 0 0 0 91
7 161 214 383.046625 0 0 0 91
8 161 220 387.885286 0 0 0 91
9 161 226 393.472306 0 0 0 91
10 161 232 389.844297 100 0 0 91
11 61 238 395.105121 0 0 0 91
12 61 244 399.26621 0 0 0 91
13 61 250 402.825388 0 0 0 91
14 61 256 406.329 0 0 0 91
15 61 262 409.889872 0 0 0 91
16 61 268 413.132902 0 0 0 91
17 61 274 415.591674 0 0 0 91
18 61 280 416.524363 0 0 0 91
ndo a una presion de 1 ATM:

/hr.se quiere obtener un flujo de destilado de 70 lbmol/hr operando

) y se alimenta en el plato 10, aplique el metodo de punto de burbuja


ador y de el rehervidor.
Para la ecuacion de antoine:
A B C
Benceno 15.9 2788.5 52.36
Tolueno 16.014 3096.5 53.67
O-Xileno 16.115 3395.6 59.46

CALCULO DE Bj CALCULO DE Cj
Plato 1 Plato 1
Kb,1= 1.489865984 Bb,1= -161 Cb,1= 323.8598011
Kt,1= 0.601689812 Bt,1= -161 Ct,1= 135.5742339
Kx,1= 0.208779599 Bx,1= -161 Cx,1= 49.26913267

Plato 2 Plato 2
Kb,2= 2.01155156 Bb,2= -414.8598 Cb,2= 376.6695334
Kt,2= 0.842075987 Bt,2= -226.57423 Ct,2= 160.5504471
Kx,2= 0.306019458 Bx,2= -140.26913 Cx,2= 59.70783935

Plato 3 Plato 3
Kb,3= 2.339562319 Bb,3= -467.66953 Cb,3= 364.1936058
Kt,3= 0.997207746 Bt,3= -251.55045 Ct,3= 154.6101926
Kx,3= 0.370856145 Bx,3= -150.70784 Cx,3= 57.20421417

Plato 4 Plato 4
Kb,4= 2.262072086 Bb,4= -455.19361 Cb,4= 351.1765324
Kt,4= 0.960311755 Bt,4= -245.61019 Ct,4= 148.437922
Kx,4 0.355305678 Bx,4= -148.20421 Cx,4= 54.61627526

Plato 5 Plato 5
Kb,5= 2.181220698 Bb,5= -442.17653 Cb,4= 385.7386157
Kt,5= 0.921974671 Bt,5= -239.43792 Ct,5= 164.8832605
Kx,5= 0.339231523 Bx,5= -145.61628 Cx,5= 61.54175361

Plato 6 Plato 6
Kb,6= 2.395892023 Bb,6= -476.73862 Cb,6= 370.7882681
Kt,6= 1.024119631 Bt,6= -255.88326 Ct,6= 157.7472077
Kx,6= 0.382246917 Bx,6= -152.54175 Cx,6= 58.52480815
Plato 7 Plato 7
Kb,7= 2.303032721 Bb,7= -461.78827 Cb,7= 418.7344285
Kt,7= 0.979796321 Bt,7= -248.74721 Ct,7= 180.7472726
Kx,7= 0.363508125 Bx,7= -149.52481 Cx,7= 68.309752

Plato 8 Plato 8
Kb,8= 2.600834959 Bb,8= -509.73443 Cb,8= 479.7949715
Kt,8= 1.122653867 Bt,8= -271.74727 Ct,8= 210.4892148
Kx,8= 0.424284174 Bx,8= -159.30975 Cx,8= 81.20634888

Plato 9 Plato 9
Kb,9= 2.98009299 Bb,9= -570.79497 Cb,9= 439.4303639
Kt,9= 1.307386428 Bt,9= -301.48921 Ct,9= 190.7741431
Kx,9= 0.50438726 Bx,9= -172.20635 Cx,9= 72.62852391

Plato 10 Plato 10
Kb,10= 2.729381142 Bb,10= -530.43036 Cb,10= 189.0047661
Kt,10= 1.184932566 Bt,10= -281.77414 Ct,10= 83.30283232
Kx,10= 0.451108844 Bx,10= -163.62852 Cx,10= 32.32749142

Plato 11 Plato 11
Kb,11= 3.098438789 Bb,11= -280.00477 Cb,11= 208.3792508
Kt,11= 1.365620202 Bt,11= -174.30283 Ct,11= 92.91425451
Kx,11= 0.529958876 Bx,11= -123.32749 Cx,11= 36.59095297

Platp 12 Plato 12
Kb,12= 3.416053292 Bb,12= -299.37925 Cb,12= 226.1033626
Kt,12= 1.5231845 Bt,12= -183.91425 Ct,12= 101.8001115
Kx,12= 0.599851688 Bx,12= -127.59095 Cx,12= 40.58431333

Plato 13 Plato 13
Kb,13= 3.706612501 Bb,13= -317.10336 Cb,13= 244.6300142
Kt,13= 1.668854287 Bt,13= -192.80011 Ct,13= 111.1764753
Kx,13= 0.665316612 Bx,13= -131.58431 Cx,13= 44.84755117

Plato 14 Plato 14
Kb,14= 4.010328102 Bb,14= -335.63001 Cb,14= 264.5967895
Kt,14= 1.822565168 Bt,14= -202.17648 Ct,14= 121.3756713
Kx,14= 0.735205757 Bx,14= -135.84755 Cx,14= 49.53810718

Plato 15 Plato 15
Kb,15= 4.337652288 Bb,15= -355.59679 Cb,15= 283.8132317
Kt,15= 1.989765103 bBt,15= -212.37567 Ct,15= 131.2776598
Kx,15= 0.812100118 Bx,15= -140.53811 Cx,15= 54.1411049

Plato 16 Plato 16
Kb,16= 4.65267593 Bb,16= -374.81323 Cb,16= 299.0577857
Kt,16= 2.152092784 Bt,16= -222.27766 Ct,16= 139.1895716
Kx,16= 0.887559097 Bx,16= -145.1411 Cx,16= 57.85152331

Plato 17 Plato 17
Kb,17= 4.902586651 Bb,17= -390.05779 Cb,17= 304.9960299
Kt,17= 2.281796256 Bt,17= -230.18957 Ct,17= 142.2845097
Kx,17= 0.948385628 Bx,17= -148.85152 Cx,17= 59.31044011

Plato 18 Plato 18
Kb,18= 4.999934916 Bb,18= -334.99603 Cb,18= 0
Kt,18= 2.332532946 Bt,18= -172.28451 Ct,18= 0
Kx,18= 0.972302297 Bx,18= -89.31044 Cx,18= 0
CALCULO DE Dj CALCULO DE Pj CALCULO DE qj
Plato 1 Plato 1 Plato 1
Db,1= 0 Pb,1= -2.0115516 qb,1=
Dt,1= 0 Pt,1= -0.842076 qt,1=
Dx,1= 0 Px,1= -0.3060195 qx,1=

Plato 2 Plato 2 Plato 2


Db,2= 0 Pb,2= -1.6249161 qb,2=
Dt,2= 0 Pt,2= -1.1136462 qt,2=
Dx,2= 0 Px,2= -0.973276 qx,2=

Plato 3 Plato 3 Plato 3


Db,3= 0 Pb,3= -1.138809 qb,3=
Dt,3= 0 Pt,3= -1.0293029 qt,3=
Dx,3= 0 Px,3= -0.9205741 qx,3=

Plato 4 Plato 4 Plato 4


Db,4= 0 Pb,4= -0.9989036 qb,4=
Dt,4= 0 Pt,4= -0.9769276 qt,4=
Dx,4= 0 Px,4= -0.8476579 qx,4=

Plato 5 Plato 5 Plato 5


Db,5= 0 Pb,5= -1.098106 qb,5=
Dt,5= 0 Pt,5= -1.0952968 qt,5=
Dx,5= 0 Px,5= -0.89869 qx,5=

Plato 6 Plato 6 Plato 6


Db,6= 0 Pb,6= -0.9840166 qb,6=
Dt,6= 0 Pt,6= -1.0098326 qt,6=
Dx,6= 0 Px,6= -0.8270776 qx,6=
Plato 7 Plato 7 Plato 7
Db,7= 0 Pb,7= -1.1248961 qb,7=
Dt,7= 0 Pt,7= -1.1523395 qt,7=
Dx,7= 0 Px,7= -0.9198635 qx,7=

Plato 8 Plato 8 Plato 8


Db,8= 0 Pb,8= -1.1777899 qb,8=
Dt,8= 0 Pt,8= -1.2612877 qt,8=
Dx,8= 0 Px,8= -1.0741272 qx,8=

Plato 9 Plato 9 Plato 9


Db,9= 0 Pb,9= -0.9478324 qb,9=
Dt,9= 0 Pt,9= -1.021756 qt,9=
Dx,9= 0 Px,9= -0.9753931 qx,9=

Plato 10 Plato 10 Plato 10


Db,10= -40 Pb,10= -0.4255162 qb,10=
Dt,10= -30 Pt,10= -0.4412358 qt,10=
Dx,10= -30 Px,10= -0.4317946 qx,10=

Plato 11 Plato 11 Plato 11


Db,11= 0 Pb,11= -0.8636308 qb,1=
Dt,11= 0 Pt,11= -0.6926127 qt,11=
Dx,11= 0 Px,11= -0.4354294 qx,11=

Plato 12 Plato 12 Plato 12


Db,12= 0 Pb,12= -1.0240706 qb,12=
Dt,12= 0 Pt,12= -0.8421132 qt,12=
Dx,12= 0 Px,12= -0.461359 qx,12=

Plato 13 Plato 13 Plato 13


Db,13= 0 Pb,13= -1.0925229 qb,13=
Dt,13= 0 Pt,13= -0.9570334 qt,13=
Dx,13= 0 Px,13= -0.5005271 qx,13=

Plato 14 Plato 14 Plato 14


Db,14= 0 Pb,14= -1.120174 qb,14=
Dt,14= 0 Pt,14= -1.0546479 qt,14=
Dx,14= 0 Px,14= -0.5485973 qx,14=

Plato 15 Plato 15 Plato 15


Db,15= 0 Pb,15= -1.1188684 qb,15=
Dt,15= 0 Pt,15= -1.1277887 qt,15=
Dx,15= 0 Px,15= -0.5974801 qx,15=

Plato 16 Plato 16 Plato 16


Db,16= 0 Pb,16= -1.095465 qb,16=
Dt,16= 0 Pt,16= -1.1633169 qt,16=
Dx,16= 0 Px,16= -0.6373389 qx,16=

Plato 17 Plato 17 Plato 17


Db,17= 0 Pb,17= -1.0503686 qb,17=
Dt,17= 0 Pt,17= -1.144431 qt,17=
Dx,17= 0 Px,17= -0.6528127 qx,17=

Plato 18 Plato 18 Plato 18


Db,18= 0 Pb,18= 0 qb,18=
Dt,18= 0 Pt,18= 0 qt,18=
Dx,18= 0 Px,18= 0 qx,18=
CALCULO DE qj CALCULO DE Xij NORMALIZACIÓN DE Xij
Plato 1 Plato 1
0 xb,1= 0.571415191 xb,1= 0.498689477
0 xt,1= 0.447502253 xt,1= 0.390547307
0 xx,1= 0.126916222 xx,1= 0.110763216
SUMA 1.145833666 SUMA 1
Plato 2 Plato 2
0 xb,2= 0.284066888 xb,2= 0.23090611
0 xt,2= 0.531427401 xt,2= 0.431975141
0 xx,2= 0.414732523 xx,2= 0.337118749
SUMA 1.230226812 SUMA 1
Plato 3 Plato 3
0 xb,3= 0.174819422 xb,3= 0.162149772
0 xt,3= 0.47719591 xt,3= 0.442612195
0 xx,3= 0.426120145 xx,3= 0.395238033
SUMA 1.078135476 SUMA 1
Plato 4 Plato 4
0 xb,4= 0.153510742 xb,4= 0.142138687
0 xt,4= 0.463610774 xt,4= 0.429266548
0 xx,4= 0.462885244 xx,4= 0.428594766
SUMA 1.08000676 SUMA 1
Plato 5 Plato 5
0 xb,5= 0.153679235 xb,5= 0.130867156
0 xt,5= 0.474560023 xt,5= 0.404116539
0 xx,5= 0.546075517 xx,5= 0.465016304
SUMA 1.174314774 SUMA 1
Plato 6 Plato 6
0 xb,6= 0.139949364 xb,6= 0.118515273
0 xt,6= 0.433270697 xt,6= 0.366912671
0 xx,6= 0.607635033 xx,6= 0.514572056
SUMA 1.180855094 SUMA 1
Plato 7 Plato 7
0 xb,7= 0.142222557 xb,7= 0.108903377
0 xt,7= 0.429052011 xt,7= 0.328535881
0 xx,7= 0.734677189 xx,7= 0.562560742
SUMA 1.305951756 SUMA 1
Plato 8 Plato 8
0 xb,8= 0.126431725 xb,8= 0.097446797
0 xt,8= 0.37233124 xt,8= 0.286972963
0 xx,8= 0.798680658 xx,8= 0.615580241
SUMA 1.297443623 SUMA 1
Plato 9 Plato 9
0 xb,9= 0.107346582 xb,9= 0.093661811
0 xt,9= 0.295199287 xt,9= 0.257566651
0 xx,9= 0.74356247 xx,9= 0.648771538
SUMA 1.146108339 SUMA 1
Plato 10 Plato 10
0.090054066 xb,10= 0.11325481 xb,10= 0.097257061
0.158903065 xt,10= 0.288913672 xt,10= 0.248103322
0.400706551 xx,10= 0.762320853 xx,10= 0.654639617
SUMA 1.164489336 SUMA 1
Plato 11 Plato 11
0.033963964 xb,11= 0.054523763 xb,11= 0.045947901
0.107790824 xt,11= 0.294651055 xt,11= 0.248306366
0.433922177 xx,11= 0.837468357 xx,11= 0.705745733
SUMA 1.186643175 SUMA 1
Plato 12 Plato 12
0.013998536 xb,12= 0.023806237 xb,12= 0.019507327
0.081141941 xt,12= 0.269790349 xt,12= 0.221071833
0.448883927 xx,12= 0.926777557 xx,12= 0.75942084
SUMA 1.220374143 SUMA 1
Plato 13 Plato 13
0.005689116 xb,13= 0.009577173 xb,13= 0.007544443
0.063562501 xt,13= 0.224017878 xt,13= 0.176470682
0.45589447 xx,13= 1.035838918 xx,13= 0.815984875
SUMA 1.269433968 SUMA 1
Plato 14 Plato 14
0.00219173 xb,14= 0.003558787 xb,14= 0.00267601
0.050259507 xt,4= 0.167659121 xt,14= 0.126070362
0.459430655 xx,14= 1.158667388 xx,14= 0.871253627
SUMA 1.329885296 SUMA 1
Plato 15 Plato 15
0.000786276 xb,15= 0.001220396 xb,15= 0.000879802
0.039291312 xt,15= 0.111316404 xt,15= 0.080249612
0.461378822 xx,16= 1.274590198 xx,15= 0.918870586
SUMA 1.387126998 SUMA 1
Plato 16 Plato 16
0.000262096 xb,16= 0.000388 xb,16= 0.000272219
0.029883348 xt,16= 0.063863996 xt,16= 0.044806757
0.462545757 xx,16= 1.361068668 xx,16= 0.954921024
SUMA 1.425320664 SUMA 1
Plato 17 Plato 17
8.21389E-05 xb,17= 0.000114932 xb,17= 7.98623E-05
0.021872711 xt,17= 0.02921014 xt,17= 0.020297097
0.463290688 xx,17= 1.409803885 xx,17= 0.979623041
SUMA 1.439128956 SUMA 1
Plato 18 Plato 18
3.12207E-05 xb,18= 3.12207E-05 xb,18= 2.16955E-05
0.02921014 xt,18= 0.02921014 xt,18= 0.020298278
1.409803885 xx,18= 1.409803885 xx,18= 0.979680027
SUMA 1.439045245 SUMA 1
CALCULO DE NUEVAS TEMPERATURAS
Plato 1 Plato 13
T 366.8053595 K T 402.825388 K
Xin K Y Xin K Y
0.498689477 1.489865984 0.7429804879 0.0075444433 3.7066125 0.02796433
0.390547307 0.601689812 0.234988336 0.1764706821 1.66885429 0.29450385
0.110763216 0.208779599 0.0231250999 0.8159848746 0.66531661 0.54288829
1.0010939237 0.86535647

Plato 2 Plato 14
T 377.8237205 K T 406.329 K
Xin K Y Xin K Y
0.23090611 2.01155156 0.4644795461 0.0026760104 4.0103281 0.01073168
0.431975141 0.842075987 0.3637558934 0.1260703622 1.82256517 0.22977145
0.337118749 0.306019458 0.1031648966 0.8712536274 0.73520576 0.64055068
0.9314003361 0.88105381

Plato 3 Plato 15
T 383.6649219 K T 409.889872 K
Xin K Y Xin K Y
0.162149772 2.339562319 0.3793594976 0.0008798015 4.33765229 0.00381627
0.442612195 0.997207746 0.4413763093 0.0802496122 1.9897651 0.15967788
0.395238033 0.370856145 0.1465764531 0.9188705863 0.81210012 0.74621491
0.96731226 0.90970906

Plato 4 Plato 16
T 382.3443669 K T 413.132902 K
Xin K Y Xin K Y
0.142138687 2.262072086 0.3215279552 0.0002722193 4.65267593 0.00126655
0.429266548 0.960311755 0.4122297121 0.0448067565 2.15209278 0.0964283
0.428594766 0.355305678 0.1522821538 0.9549210242 0.8875591 0.84754884
0.8860398211 0.94524369

Plato 5 Plato 17
T 380.9291922 K T 409.889872 K
Xin K Y Xin K Y
0.130867156 2.181220698 0.2854501503 7.986229701E-05 4.90258665 0.00039153
0.404116539 0.921974671 0.3725852131 0.0202970968 2.28179626 0.04631384
0.465016304 0.339231523 0.1577481893 0.9796230409 0.94838563 0.92906041
0.8157835527 0.97576578

Plato 6 Plato 18
T 384.6040846 K T 413.132902 K
Xin K Y Xin K Y
0.118515273 2.395892023 0.2839497967 2.169545648E-05 4.99993492 0.00010848
0.366912671 1.024119631 0.3757624696 0.0202982775 2.33253295 0.0473464
0.514572056 0.382246917 0.1966935818 0.979680027 0.9723023 0.95254514
0.8564058481 1.00000002

Plato 7
T 383.0466253 K
Xin K Y
0.108903377 2.303032721 0.250808041
0.328535881 0.979796321 0.3218982475
0.562560742 0.363508125 0.2044954006
0.7772016892

Plato 8
T 387.8852861 K
Xin K Y
0.097446797 2.600834959 0.2534430352
0.286972963 1.122653867 0.3221713061
0.615580241 0.424284174 0.261180954
0.8367952953

Plato 9
T 393.4723061 K
Xin K Y
0.093661811 2.98009299 0.2791209052
0.257566651 1.307386428 0.3367391437
0.648771538 0.50438726 0.3272320987
0.9430921476

Plato 10
T 389.8442965 K
Xin K Y
0.097257061 2.729381142 0.2654515874
0.248103322 1.184932566 0.2939857058
0.654639617 0.451108844 0.2953137211
0.8547510143

Plato 11
T 395.1051214 K
Xin K Y
0.045947901 3.098438789 0.1423667586
0.248306366 1.365620202 0.3390921899
0.705745733 0.529958876 0.3740162152
0.8554751636

Plato 12
T 399.2662097 K
Xin K Y
0.019507327 3.416053292 0.0666380671
0.221071833 1.5231845 0.3367331901
0.75942084 0.599851688 0.4555398729
0.85891113
Plato 2
f(T),2= -0.0685997

Plato 3

f(T),3= -0.4120472

Plato 4
f(T),4= -0.1139602

Plato 5
f(T),5= -0.1842164

Plato 6
f(T),6= -0.1435942
Plato 7
f(T),7= -0.2227983

Plato 8
f(T),8= -0.1632047

Plato 9
f(T),9= -0.0569079

Plato 10
f(T),10= -0.145249

Plato 11
f(T),11= -0.1445248

Plato 12
f(T),12= -0.1410889

Plato 13
f(T),13= -0.1346435

Plato 14
f(T),14= -0.1189462

Plato 15
f(T),15= -0.0902909

Plato 16
f(T),16=

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