IIT Academy

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IIT-JEE Chemistry Test Paper No 1
Duration 2 hrs

Note: Negative Marking exists.

Q1: The number of nodal planes in a Px orbital is :

A: One B: Two C: Three D: Zero

Q2: The number of neutrons accompanying the formation of 54Xe139 and 38Sr94 from
absorption of slow neutron by 92U235 , followed by nuclear fission is :
A: 0 B: 2 C: 1 D: 3

Q3: Among the following molecules , the one which is polar and has the central
atom with sp2 hybrid state is :
A: H2CO3 B: SiF4 C: BF3 D: HClO2

Q4: The oxidation number of sulphur in S8, S2F2, H2S respectively are :
A: 0, +1 and -2 B: +2, +1 and C: 0, +1 and +2 D: -2, +1 and -2
-2

Q5: The standard reduction potentials of Cu2+  Cu and Cu2+  Cu+ are 0.337 and
0.153V respectively. The standard electrode potential of Cu+  Cu half-cell will
be approximately :
A: 0.184V B: 0.827V C: 0.521V D: 0.490V

Q6: Number of moles of KMnO4 that will be needed to react completely with one
mole of sulphite ion in acidic solution is :
A: 2/5 B: 3/5 C: 4/5 D: 1

Q7: For the reaction, CO(g) + H2O(g) CO2(g) + H2(g) at a given temperature, the
equilibrium amount of CO2(g) can be increased by :
A: Adding a suitable catalyst
B: Adding an inert gas
C: Decreasing volume of the container
D: Increasing the amount of CO(g)

Q8: The ratio between the root mean square speed of H2 at 50 K and that of O2 at
800 K is :
A: 4 B: 2 C: 1 D: 1
4

Q9: The co-ordination number of metal crystallizing in hexagonal close packed

structure is :
A: 12 B: 4 C: 8 D: 6

Q10: The rate constant, the activation energy and Arrhenius parameter of a
chemical reaction at 250C are 3.0 × 10-4 sec-1, 104.4 kJ mol-1 and 6.0 × 1014 sec-
1
respectively. The value of the rate constant as T → ∞ is :
A: 2 × 1018 sec-1 B: 6.0×1014 sec- C: Infinity D: 3.6×1030 sec-1
1

Q11: Term catalysis was given by :

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9, Pushkaraj B, Near IDBI Bank , Gangapur Road, Nashik 422002, Tel 0253-2313555
A: Rutherford B: Berzelius C: Wohler D: Kolbe

Q12: The molecular weight of benzoic acid in benzene as determined by depression

in freezing point method corresponds to :
A: Ionization of benzoic acid
B: Dimerisation of benzoic acid
C: Trimerisation of benzoic acid
D: Solvation of benzoic acid

Q13: KF combines with HF to form KHF2. The compound contains the species :
A: K+, F- and H+ B: K+, F- and HF C: K+ and [HF2]- D: [KHF]+ and F-

Q14: Which of the following compounds is the strongest acid :

A: CH CH
B: C6H6 C: C2H6 D: CH3OH

Q15: Standard molar enthalpy of formation of CO2 is equal to :

A: Zero
B: The standard molar enthalpy of combustion
C: Sum of the standard molar enthalpies of formation of CO (g) and CO2(g)
D: Standard molar enthalpy of combustion of carbon (graphite)

Q16: Brownian movement is found in :

A: Colloidal solution B: Suspension
C: Saturated solution D: Unsaturated solution

Q17: When a solute distributes itself between two immiscible liquids in contact with
each other, a mathematical constant ratio exists between :
A: The weight of the solute in the two liquids
B: The concentration of the solute in the two liquids
C: The number of moles of the solute in the two liquids
D: The number of atoms of the solute in the two liquids

Q18: The correct order of acidic strength is :

A: Cl2O7 > SO2 > P4O10 B: CO2 > N2O5 > SO3
C: Na2O > MgO > Al2O3 D: K2O > CaO > MgO

Q19: In Goldschmidt alumino thermic process reducing agent used is :

A: Coke B: Al power C: Na D: Ca

Q20: Hydrogen will not reduce :

A: Heated cupric oxide B: Heated ferric oxide
C: Heated stannic oxide D: Heated aluminium oxide

Q21: Which of the following does not give Borax bead test
A: Chromium B: Ferrous salt
C: Sodium D: Cobalt

Q22: Volume of CO2 obtained from the complete decomposition of 20 gm CaCO3 at

S.T.P. is :
A: 4.48 litres B: 2.24 litres
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C: 22.4 litres D: 20 litres

Q23: Alums help in purifying water by :

A: Forming Si complex with clay particles
B: Sulphate part which combines with dirt and removes it
C: Aluminium ion which coagulates the mud particles
D: Making mud water soluble

Q24: The species that does not contain peroxide is :

A: PbO2 B: H2O2 C: SrO2 D: BaO2

Q25: The number of P – O – P bonds in cyclic metaphosphoric acid is :

A: Zero B: Two C: Three D: Four

Q26: The oxidation number of sulphur in S8, S2F2, H2S respectively are :
A: 0, + 1, and - 2 B: + 2, + 1, and – 2
C: 0, + 1, and + 2 D: - 2, + 1, and – 2

Q27: Molecular shapes of SF4, CF4 and XeF4 are :

A: The same with 2, 0 and 1 lone pairs of electrons respectively
B: The same with 1, 1 and 1 lone pairs of electrons respectively
C: Different with 0, 1 and 2 lone pairs of electrons respectively
D: Different with 1, 0 and 2 lone pairs of electrons respectively

Q28: If one litre of air is passed repeatedly over heated copper and magnesium till
no further reduction in volume takes place, the volume finally obtained would
be approximately :
A: 800 ml B: 200 ml C: 10 ml D: Zero

Q29: Amongst the following, the species with an atom in +6 oxidation state :
A: MnSO − B: 3−
Cr(CN) 6
4
C: 2−
NiF 6 D: CrO2Cl2

Q30: The geometry of Ni(CO)4 and [Ni(PPh3)2Cl2] are :

A: Both square planar
B: Both tetrahedral
C: Tetrahedral and square planar respectively
D: Square planar and tetrahedral respectively

Q31: In qualitative analysis NH4Cl is added before NH4OH ?

A: To decrease OH- concentration B: To increase OH- concentration
C: For making HCl D: Statement is wrong

Q32: Turpentine oil can be purified by :

A: Steam distillation B: Vacuum distillation
C: Fractional distillation D: Sublimation

Q33: The optically active tartaric acid is named as D – (+) – tartaric acid because it
has a positive :
A: Optical rotation and is derived from D – glucose
B: pH in organic solvent
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C: Optical rotation and is derived from D – (+) – glycerol – dehyde
D: Optical rotation only when substituted by deuterium

Q34: An aromatic molecule will :

A: Have 4n π electrons B: Have (4n + 2) π electrons
C: Be planar D: Be cyclic

Q35: Which one of the following alkenes will react fastest with H2 under catalytic
hydrogenation conditions :
A: R R B: R H
= =
H H R H
C: R R D: R R
= =
R H R R

Q36: The order of reactivities of following alkyl halides for a SN2 reaction is :
A: RF > RCl > RBr > RI B: RF > RBr > RCl > RI
C: RCl > RBr > RF > RI D: RI > RBr > RCl > RF

Q37: 1 – Propanol and 2 – propanol can be distinguished by :

A: Oxidation with alkaline KMnO4 followed by reaction with Fehling solution
B: Oxidation with concentrated H2SO4 followed by reaction with Fehling solution
C: Oxidation with acidic dichromate followed by reaction with Fehling solution
D: Oxidation by heating with copper followed by reaction with Fehling solution

Q38: The product(s) obtained via oxy mercuration (HgSO4 + H2SO4) of 1 – butyne
would be :
A: B: CH3 – CH2 – CH2 – CHO
O
CH3 CH2 C CH3

C: CH3CH2CHO + HCHO D: CH3CH2COOH + HCOOH

Q39: Benzoyl chloride is prepared from Benzoic acid by :

A: SOCl2 B: SO2Cl2
C: CL2; H2 D: Cl2; hv

Q40: The compound on reaction with cold nitrous acid giving oily nitrosamine is :
A: Methyl amine B: Dimethyl amine
C: Trimethyl amine D: Triethyl amine

Q41: Fats and oils are formed from :

A: Glycerol and long chain unsaturated acids only
B: Glycerol and long chain saturated acids only
C: Glycerol and long chain saturated and unsaturated acids
D: Ethylene glycol and long chain saturated and unsaturated acids

Q42: An aromatic compound will :

A: Have 4n π electrons B: Have (4n + 2) π electrons
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C: Be planar5 D: Be cyclic

Q43: RNA is Different from DNA because RNA contains :

A: Deoxyribose sugar and thymine
B: Ribose sugar and thymine
C: Deoxyribose sugar and uracil
D: Ribose sugar and uracil

Q44: Which fraction of petroleum corresponds to kerosene oil :

A: C10 – C12 B: C15 – C18
C: C1 – C4 D: C5 – C9

Q45: 10 ml of propane on combustion with an excess of oxygen will produce, how

many ml of CO2 :
A: 10 B: 30 C: 20 D: 40

Q46: The number of d-electrons retained in Fe2+ [At. No. of Fe = 26] ion is :
A: 5 B: 6 C: 3 D: 4

Q47: The correct order of hybridization of the central atom in the following species
NH3, [PtCl4]2-, PCl5 and BCl3 is :
A: dsp2, dsp3, sp2 and sp3 B: sp3, dsp2, dsp3 and sp2
C: 2 2 3
dsp , sp , sp and dsp 3
D: dsp2, sp3, sp2 and dsp3

Q48: A gas will approach ideal behaviour at :

A: Low temperature and low pressure
B: Low temperature and high pressure
C: High temperature and low pressure
D: High temperature and high pressure

Q49: The empirical formula of an acid is CH2O2, the probable formula of the simplest
acid may be :
A: CH2O B: CH2O2 C: C2H4O2 D: C3H6O4

Q50: Which one of the following is an amphoteric oxide :

A: SO2 B: B2O3 C: ZnO D: Na2O
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Answers
QNo Ans QNo Ans QNo Ans QNo Ans QNo Ans
1 A 11 B 21 C 31 A 41 C
2 D 12 B 22 A 32 A 42 B,C,D
3 A 13 C 23 C 33 C 43 D
4 A 14 D 24 A 34 B,C,D 44 B
5 C 15 D 25 C 35 B 45 B
6 A 16 A 26 A 36 D 46 B
7 D 17 B 27 D 37 D 47 B
8 C 18 A 28 C 38 A 48 C
9 A 19 B 29 D 39 A 49 B
10 B 20 D 30 B 40 B 50 C