Escolar Documentos
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in Dissociated Air f
NELSON H. KEMP,* PETER H. ROSE/ AND RALPH W. DETRA*
f
= diffusion coefficient
= thermal diffusion coefficient
= Eq.(7)
T HE THEORY of h e a t transfer a t a stagnation point
in a dissociating gas h a s been discussed b y F a y
a n d Riddell. 1 T h e y considered t h e mechanism of h e a t
g = Eq.(8)
transfer, with the pertinent physical and chemical
h = enthalpy per unit mass of ith component
h = enthalpy per unit mass of t h e mixture, including dis- effects which arise because of gas dissociation. I t was
sociation energy, Xci(hi — hi0) shown t h a t a similarity variable could be found, such
hi0
= heat evolved in the formation of component i at 0°K.,
t h a t t h e equations for t h e stagnation-point b o u n d a r y
per unit mass
= average atomic dissociation energy times atom mass layer with a r b i t r a r y recombination r a t e could be reduced
hD
fraction in external flow to ordinary differential equations. F a y and Riddell
H = h + (l/2)u2 pointed out t h a t t h e stagnation point appeared to be
k = thermal conductivity t h e only case in which t h e boundary-layer equations
I = PM/' PwP<w admitted this great simplification without further
Li = Lewis Number Dipcp/k = Dipa/fi
approximation. E v e n for t h e cone and flat plate, this
UT = thermal Lewis Number DiTp cp/k = DiTpor/ii
reduction is only possible for t h e extreme cases of v e r y
L = Lewis Number for atom molecule mixture
M8 Mach Number of moving shock in shock tube, referred fast or v e r y slow a t o m recombination rate, correspond-
=
to speed of sound in quiescent gas in front of it ing t o a b o u n d a r y layer, either "frozen" or in t h e r m o -
P = pressure d y n a m i c equilibrium.
Pi = initial pressure in shock tube (measured in cm. of mer- Once a stagnation-point t h e o r y is developed, t h e next
q = heat-transfer rate step is to extend t h e t h e o r y to regions a w a y from t h e
qi = vector diffusion velocity, Eq. (1) stagnation point. T h e r e are certainly regimes of flight,
r = cylindrical radius of body, recover}^ factor such as high altitudes, where t h e b o u n d a r y layer will
R = body-nose radius in meridian plane remain l a m i n a r for some distance a w a y from t h e stag-
n a t i o n point, a n d a laminar t h e o r y is, therefore, of
Received May 29, 1958.
f This work was performed during June, 1956-June, 1957. I t interest.
was sponsored by t h e Ballistic Missile Division, Air Research While t h e r e is a great deal of l i t e r a t u r e on compres-
and Development Command, USAF, under Contract AF04(645)- sible laminar b o u n d a r y layer, v e r y little of it is appli-
18. cable to t h e problem a t h a n d . T h e distinguishing fea-
The numerical calculations were performed efficient^ by Rob-
tures of t h e present problem, caused b y t h e v e r y high
ert Laubner, and many helpful discussions were held with F. R.
Riddell and J. A. Fay. flight velocity, are t h e dissociation a n d t h e large r a t i o
* Principal Research Scientist. of external to wall e n t h a l p y (or t e m p e r a t u r e ) . These
421
422 JOURNAL OF T H E AERO/SPACE S C I E N C E S —JULY, 1959
•conditions dictate large variations of fluid properties of incidence. Results for two-dimensional bodies
across t h e b o u n d a r y layer. T h e variable property could be obtained b y t h e same method.
which distinguishes this from a low-speed case is t h e There are several ways to check t h e local similarity
product of density, p, and viscosity /x, which m a y v a r y assumption theoretically. One would be to solve t h e
b y a factor of 5 or more instead of being nearly con- complete partial differential equations. Another would
stant. Most previous investigations, such as t h a t of be to compute t h e terms neglected in these equations
Cohen and Reshotko 2 and t h a t of Levy, 3 t r e a t this prod- in a n y particular case, and compare t h e m with t h e
uct as a constant. Consequently, their work cannot terms retained. A third is to make use of the momen-
be used in the present case without a careful examin- t u m and energy integral equations which are often used
ation of its validity. H e a t transfer b y atom diffusion is to construct approximate methods for predicting bound-
also a new phenomenon arising in the hypersonic case. ary-layer characteristics. These equations represent
Romig and Dore 4 have considered a dissociating gas conservation of m o m e n t u m and energy on t h e average
in thermodynamic equilibrium, b u t only for a flat across t h e b o u n d a r y layer, and contain the nonsimilar
plate with constant external flow properties and the terms which are dropped in the local similarity solution
particular case of equal heat transfer b y thermal con- described here. In Lees' approximate solution of the
duction and atomic diffusion. We wish here to allow similarity differential equations, he takes the wall en-
a variation of external properties suitable to t h e nose t h a l p y gradient constant around t h e body, so t h e non-
regions of blunt bodies, and to consider more general similar term in the energy integral equation is iden-
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relations between thermal conduction and atomic tically zero. T h e exact solutions of these differential
diffusion. equations presented in the present work, on the other
hand, lead to boundary-layer characteristics which
Lees 5 has dealt with heat transfer to highly cooled
v a r y around t h e body, and t h u s afford t h e possibility
bodies in dissociating flow. H e made use of an assump-
of computing the nonsimilar terms in the integral equa-
tion of "local similarity." At each point on t h e body,
tions, and t h u s estimating the validity of t h e local
the boundary layer is assumed to be described b y ordi-
similarity assumption in any particular case.
nary differential equations involving one independent
similarity variable, with b o u n d a r y conditions and In addition to theoretical checks, comparison with
parameters depending on local external and wall con- experimental results is presented in this paper for b o t h
ditions. This assumption is t a n t a m o u n t to dropping hemisphere cylinders and flat-nosed bodies. T h e ex-
certain terms in the complete differential equations, as perimental results were obtained in shock tubes at high
will be shown below. Lees made a further approxi- stagnation enthalpies. T h e technique employed was
mation b y not actually solving the ordinary differential the same as used for the stagnation point measurements
equations resulting from the local similarity assump- discussed in reference 8. Only a brief description of
tion. H e gave a careful discussion of the case of high the experimental techniques is given.
wall cooling and concluded t h a t the pressure gradient
did not have a significant effect on heat transfer. H e (2) BOUNDARY-LAYER EQUATIONS
also concluded t h a t the variation of pp, across the bound-
ary layer could be approximated sufficiently well b y T h e boundary-layer equations suitable for t h e axi-
taking it constant at the external value. H e then symmetric flow of dissociating air over a b o d y of revolu-
made use of the Cohen and Reshotko (pp constant, no tion are given in reference 1. T h e air is represented
dissipation) value of the nondimensional wall enthalpy as a mixture of "air molecules" and "air a t o m s , " the
gradient for the flat plate, t h u s taking it to be a con- differences between oxygen and nitrogen being ac-
stant over the whole body. counted for b y using average properties for the air
particles. T h e diffusion velocity, measured with refer-
Probstein 6 has proposed an extension of Lees' work ence to the mass average velocity, is then taken as
in which the wall enthalpy gradient is found b y solving
the energy differential equation b y iteration, using qt = -(Dt/ct) grad c{ - (D?/T) grad T (1)
Cohen's and Reshotko's velocity profiles and starting
T h e first t e r m is t h e concentration diffusion in terms of
with their enthalpy profile for pp constant. H e found
the mass fraction ct of t h e i t h component. T h e second
t h a t only one or two iterations are necessary for good
term is t h e thermal diffusion (pressure diffusion is
convergence in most practical cases.
neglected) and the D's are the diffusion coefficients.
In the present work, the local similarity differential I t is assumed t h a t each component of t h e air is a
equations are solved exactly, with variable external perfect gas with enthalpy hif so t h a t t h e enthalpy of
pressure gradient parameter, variable p/x, and inclusion the mixture is
of the dissipation term. Lewis N u m b e r effects are also
h = 2 CiQit — ht0)
discussed. This is accomplished numerically b y an ex-
tension of the method which F a y and Riddell 1 used at where h^ is t h e heat evolved in the formation of the
the stagnation point. T h e solutions, which depend on rth component at 0°K.
the local external flow conditions, v a r y around t h e body, T h e usual boundary-layer coordinate system is intro-
in contrast to the constant values used b y Lees. Atten- duced with x measured along t h e b o d y surface from the
tion is restricted to bodies of revolution at zero angle nose and y normal to the surface, and r denoting the
L A M I N A R HEAT T R A N S F E R 423
the mixture is a known function of the usual thermo- stagnation point, at which Eqs. (10) and (11) also be-
dynamic variables (say, p and h). For nonequilibrium come similar. T h e external velocity ue m a y be written
situations, an additional equation for ct must be con- ue = x(due/dx)s and from Eq. (5) we easily find t h a t
sidered [Eq. (14) of reference 1]. In the present paper,
P = 2{d In ujd In £) = 1/2 (13)
attention will be focused on the equilibrium boundary
layer. Some remarks about the possible applicability In this case, Eqs. (9) and (10) reduce to
of the results to other cases will be made later.
We now proceed, as in reference 1, to introduce a VfJn+ffn + ( V 2 ) [(Pes/p) - A 2 ] = 0 (14)
transformation of the independent variables, which fe»„ +fgv + {(l/cr^Ciesm - ht«)/He] X
includes the H o w a r t h and Mangier transformations, [(Lt- l)siv + LiTsidv/d]}v = 0 (15)
as suggested b y Lees :5
These equations (with Li = 0) are the ones t h a t F a y
and Riddell have solved for the equilibrium case in
£(*0 = I PwVwuer2dx, d^/dx = plD\xwuer2 (5)
Jo reference 1.
T h e purpose of the present work is to derive informa-
v(x, y) = (uer/VW I f>dy, drj/dy = puer/V2{j (6) tion about laminar heat-transfer rates on blunt bodies
Jo away from the stagnation point b y reducing Eqs. (10)
We also choose dimensionless dependent variables and (11) to ordinary differential equations, like Eqs.
based on conditions at the edge of the b o u n d a r y layer, (14) and (15), and then solving t h e m in the same m a n -
as follows: ner as the latter equations were solved in reference 1.
This is accomplished b y the introduction of the idea of
u/ue = fv, f = I fvdr] (7) ' local similarity.''
Jo
g = H/He, 6 = T/Te, st = ct/cic (8) (3) LOCAL SIMILARITY
The functions / , g, 6, and st depend on both £ and rj.
When boundary-layer characteristics, especially heat-
The quantities at the edge of the b o u n d a r y layer are,
transfer rates, are desired for bodies with varying ex-
of course, functions of x only, except for He, which is a
ternal flow properties, we are confronted with t h e full
constant, and is t h e total enthalpy of the inviscid flow.
Eqs. (10) and (11). A reasonable approximation which
(We assume t h a t the flow at the edge of t h e b o u n d a r y
reduces t h e m to ordinary differential equations is
layer came through t h e normal shock near t h e axis of
clearly extremely useful, since partial differential equa-
revolution.) tions are difficult to handle numerically. Such an
With these transformations, the continuity Eq. (2) is approximation is t h a t of local similarity, as discussed
b y Lees, 5 and b y F a y and Riddell. 1 I n this approx-
pv = -r~lM^m)^ + Wmv] (9)
imation, at any point x, t h e dependence of t h e de-
In addition, we obtain the following transformed dif- pendent variables on £ is taken to be such t h a t their
ferential equations, with P r a n d t l N u m b e r a = cvp,/k, derivatives, with respect to £, m a y be neglected. There-
Lewis Number Lt = Dipcp/k and / = p\xf'pw\xw. fore, the right-hand sides of Eqs. (10) and (11) are taken
to be zero. Further, t h e terms on the left which depend
Momentum:
on £, arising from t h e external flow or wall conditions,
(//,,), + / / „ + 2(d In ujd In f) X are assumed to have their local values. Then, the equa-
KPe/p) ~ fv2l = 2W« ~ ftM (10) tions again become ordinary differential equations in rj
424 J O U R N A L OF T H E A E R O / S P A C E S C I E N C E S — JULY, 1959
and shows t h e dependence on 0 of t h e enthalpy gradient. moves t h e points down approximately t h e same
Note t h a t t h e curve for 0 = 1 / 2 differs slightly from amount as t h e fluid property modification moved
t h a t given in reference 1, b u t t h e difference is negligible them up.
in t h e range of applicability of E q . (21). T h e net result of both modifications to t h e solutions
Having found t h e pressure gradient effect on t h e of t h e stagnation equations is only a small change in
stagnation-point equations, let us now go on to t h e the value of gvW/(l — gw), even for t h e largest value of
other two added effects which appear in t h e local simi- u2/He. For ue2/He = 1.5, t h e changes range from
larity equations. T h e first is, of course, t h e presence + 1 per cent for high wall cooling (gw = 0.0164) t o
of t h e dissipation t e r m which appears as t h e last one — 6 per cent at lower cooling (gw = 0.1682). I t would
in t h e energy E q . (19). This term, which introduces thus appear, at least for values of t h e P r a n d t l N u m b e r
the dissipation parameter ue2/He, is zero at t h e stagna- near 0.71, t h a t t h e value of gvW/(l ~ gw) is only slightly
tion point. affected b y t h e value of ue2/He, and mainly b y t h e pres-
T h e second added effect is a more subtle one, involv- sure gradient parameter 0. Thus, at any point on t h e
ing t h e fluid properties, as given in Eq. (20). There body, a useful approximation is to use t h e value of
they are taken t o depend on g, t h e dimensionless stag- &JW>/(1 ~ gw) appropriate to t h e local 0 and t h e stagna-
nation enthalpy. This is clearly correct at t h e stagna- tion value of t h e pn ratio especially for values of u2/He
tion point. However, elsewhere they should depend below unity and for high wall cooling. This inde-
instead on t h e dimensionless static enthalpy h, related pendence of t h e p\x ratio represents a considerable
tog by simplification of t h e heat-transfer calculations, because
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L = 1.4. Since the Newtonian law probably over- Near t h e stagnation point ue = x(due/dx)s, r = x9
estimates the expansion, this represents an upper limit and £ = pwspwsx^(due/dx)s/4. so t h a t
to the change in Lewis N u m b e r factor of 3 per cent.
I t would, therefore, appear t h a t the value of the cor- rpwpwuj\2$> = v2pwspws(due/dx)s (26)
rection factor at the stagnation point is a satisfactory For cold walls—that is, where no dissociation occurs—
one to use for engineering purposes over the whole body. the summation term in t h e heat-transfer r a t e vanishes,
Any more detailed study of this point, involving actual and the use of Eq. (26) in Eq. (25) gives t h e expression
solution of local-similarity equations for L F^ 1, pre- for qs.
sents a large computing problem which does not appear Since it has been shown t h a t effects as Lewis N u m b e r
justified at this time. are accounted for b y t h e stagnation point behavior, a
T h e question of heat transfer when the boundary convenient way of finding heat transfer is to calculate
layer is not in equilibrium can also be clarified b y refer- t h e heat-transfer distribution q/qs. For a wall on
ence to the stagnation-point results of reference 1. which no recombination occurs, for example, Eqs. (25)
There it was shown that, although the mechanism was and (26) give
different, the total heat-transfer r a t e was substantially
the same for equilibrium flow, frozen flow, and all Q/& = (rPwuwue/V2£){2Pwspws(due/dx)s}~a/2) gvW/gvWS
intermediate cases. There is no reason to expect this (27)
result to change as one moves around the body. There-
fore, it appears t h a t the equilibrium results of this To evaluate q/qs from a formula like Eq. (42) is quite
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paper m a y be used even for nonequilibrium thermody- simple using the results of the previous section. T h e
namical situations, provided the wall does not inhibit velocity and wall conditions around the b o d y must be
recombination of atoms. found, as well as t h e distribution of pressure gradient
parameter /3. Then the curve-fit of Fig. 1 can be used
(5) CALCULATIONS OF H E A T - T R A N S F E R R A T E to find gvW/gvWS b y use of
0.4
PRESENT THEORY.
-0-M 8 =l2, P, = ICM
%i
* i\
the calculations of t h e present method, except near
EQUILIBRIUM INVISCID FLOW 90°. T h e discrepancy there can be attributed to t h e
q/q c °<4Dr&\ 1
F I G . 3. Heat-transfer distribution on hemisphere cylinder. for qs is too low b y a factor (pene/PwVw).®'1, in addition
to having no Lewis N u m b e r term. For the example
and Eq. (28) in Eq. (27), q/qs can be found as a function of Fig. 3, (peVe/PivVw)*0'1 = 0.876 and the Lewis N u m b e r
of x. qs is obtained from Eq. (63) of reference 1, for factor for L = 1.4 and thermodynamic equilibrium is
equilibrium flow, or Eq. (65) for frozen flow. 1.078. Including a slight difference in the constants,
the value of qs is t h u s larger t h a n Lees' b y a factor 1.3.
(6) R E S U L T S OF CALCULATIONS In order to test the effect of a more rapidly varying
pressure distribution, the ratio q/qs was also calculated
As one example of t h e use of formulas (27) and (28), for the flat-nosed b o d y shown in Fig. 4. Shock t u b e
a case for a hemisphere cylinder in a shock tube was conditions corresponding to stagnation point simula-
calculated. T h e case chosen was a shock M a c h N u m - tion of 14,000 ft./sec. at 80,000 ft. altitude were used
ber, Ms — 12, and an initial pressure, pi = 1 cm. Hg. (Ms = 9.5, pi = 1 cm. Hg, simulated equilibrium y of
Equilibrium stagnation conditions are then ps = 2.242 1.195.) T h e pressure distribution used is shown in
X 107 dynes per cm. 2 , Tes = 6,945°K., (equivalent to a Fig. 4. I t was obtained in the shock t u b e from M a c h
flight velocity of 18,000 ft./sec. at 70,000 ft. altitude). line measurements and was faired into the subsonic p a r t
T h e "free-stream" to stagnation pressure ratio is of a wind-tunnel distribution obtained at a M a c h N u m -
P™/Ps = 0.1087. T h e wall temperature was taken ber of 4.0 on a similar model. T h e velocity gradient
as a constant 300 °K. at the stagnation point was adjusted according to the
T h e body was assumed to have a Newtonian pressure analysis given in reference 9 because the accuracy of
distribution, p/ps 1 - (1 - pjp8) sin 2 (x/R). the wind-tunnel measurements near the stagnation
Fig. 2 shows an experimental pressure distribution ob- point leave it in doubt.
tained on a hemisphere-cylinder in t h e shock t u b e using T h e calculation was done b y means of a program for
Mach line measurements. T h e results from a n u m b e r t h e I B M 650 computer which finds q/qs from E q s .
of experiments indicate t h a t this formula fits t h e d a t a (27) and (28), as well as all t h e pertinent inviscid flow
within the limits of experimental accuracy. properties for an arbitrary body shape. T h e pressure
Three different thermodynamic assumptions were distribution and stagnation conditions, as well as the
used to find the inviscid flow: (a) thermodynamic body shape, are t h e i n p u t d a t a . T h e program uses
equilibrium corresponding to N B S data; 7 (b) constant
7 to represent equilibrium, y = 1.126; and (c) con-
stant 7 to represent gas composition frozen at t h e SHOCK TUBE M $ = 103, p,« 5 c
stagnation point, y = 1.38.
The results for the heat-transfer distribution calcu-
O TOP SURFACE "! MACH LINE
lation according to Eqs. (27) and (28) are shown in 0 BOTTOM SURFACE J MEASUREMENTS
Fig. 3. Only the curve for thermodynamic equilibrium
WIND TUNNEL
is shown because the curves from assumptions (b) and
(c) would be almost indistinguishable from it. This
indicates t h a t for expansions of t h e magnitude obtained
kum ug a""0"
in the shock tube (pm/ps of order 0.1) t h e thermody-
0
namic assumption has little effect on q/qs. Another 5 1.0 1.5 2.0 2.5 3.0
shock M a c h Numbers from 7.0-10.0 a t two initial A rough evaluation was made of Eq. (31) for the
pressures, and t h e results are shown in Fig. 5. T h e case presented in Fig. 3. T h e results showed t h a t t h e
heat transfer appears to reach a m a x i m u m value ap- nonsimilar t e r m was less t h a n 1 per cent of gvWo/<r u p
proximately 50 per cent higher t h a n t h e stagnation to 25°, rose to 10 per cent near 60°, and then climbed
value in the vicinity of the sonic point, which occurs rapidly, reaching 17 per cent at 70°. This would
near the 25° point of the arc. indicate t h a t similarity was valid u p to around 60° at
T h e measurements and theory shown in Fig. 5 agree least, b u t might be in doubt in t h e region of 7 0 ° - 9 0 ° .
quite well, except on the corner where t h e experimental
Comparison of the local similarity theory with experi-
results are 25 per cent higher t h a n t h e theory and seems
m e n t in Fig. 3 indicates t h a t the theory somewhat over-
to indicate a breakdown of local similarity due to the
estimates the value of q/qs compared with the mean of
rapid change in t h e flow as it expands about the sharp
the experimental data. However, t h e scatter is such
corner.
t h a t it is difficult to estimate t h e limit (in x/R) of
validity of the similarity assumption. There seems to
(8) L I M I T A T I O N S OF T H E M E T H O D be some evidence t h a t t h e agreement is worse near
80°-90°. However, experimental difficulties in t h a t
T h e principal theoretical assumption made in t h e region, as mentioned above, m a y cause most of t h e
method proposed here for calculating h e a t transfer is discrepancy.
t h a t of local similarity. Because certain terms were
neglected in t h e differential equations, t h e resulting On the flat-nosed body of Fig. 4, t h e corner presents
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-0.6
0.76(7 (PwsVws) " (PesVes) ' He(l ~ gws) X REFERENCES
1
(due/dx)s 1/2
[1 + (L« - 1) (hDs/He)} Fay, J. A., and Riddell, F. R., Theory of Stagnation Point
Heat Transfer in Dissociated Air, Journal of the Aeronautical
where a is 0.52 for t h e r m o d y n a m i c equilibrium and Sciences, Vol. 25, No. 2, pp. 73-85, February, 1958.
2
Cohen, C. B., and Reshotko, E., Similar Solutions for the
0.63 for frozen flow.
Compressible Laminar Boundary Layer with Heat Transfer and
T h e independence of heat-transfer distribution from Pressure Gradient, NACA T N 3325, 1955.
3
t h e local pn ratio is very convenient, because, combined Levy, S., Effect of Large Temperature Changes {Including
with t h e definition of /3, it means t h a t only t h e pressure Viscous Heating) Upon Laminar Boundary Layers with Variable
and external velocity m u s t be calculated around t h e Free-Stream Velocity, Journal of the Aeronautical Sciences, Vol.
21, No. 7, pp. 459-474, July, 1954.
body, n o t t h e external density or viscosity. T h e former 4
Romig, M. F., and Dore, F. J., Solutions of the Compressible
two are comparatively easy to o b t a i n — t h r o u g h a New- Laminar Boundary Layer Including the Case of a Dissociated
tonian approximation, for example—while t h e l a t t e r Free Stream, Convair Report No. ZA 7-012, August 4, 1954, San
require use of t h e r m o d y n a m i c properties a n d t r a n s p o r t Diego, Calif.
5
coefficients a t v e r y high t e m p e r a t u r e s . Lees, L., Laminar Heat Transfer Over Blunt-Nosed Bodies at
Hypersonic Flight Speeds, Jet Propulsion, Vol. 26, No. 4, pp.
Calculations using this m e t h o d are compared with
259-269, 274, April, 1956.
shock t u b e experiments on a hemisphere cylinder and 6
Probstein, R. F., Method of Calculating the Equilibrium
on a flat-nosed cylinder with corner radius one q u a r t e r Laminar Heat Transfer Rate at Hypersonic Flight Speeds, Jet Pro-
of its cylindrical radius. T h e calculations a n d experi- pulsion, Vol. 26, No. 6, pp. 497-499, June, 1956.
7
Hilsenrath, J., and Beckett, C , Tables of Thermodynamic
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