Itp

DATE : 28-04-14 CODE - A
VIBRANT ACADEMY
(India) Private Limited
A-14(A), Road No.1, Indraprastha Industrial Area, Kota-324005 (Raj.)
Tel.:(0744) 2428664, 2428666, 2423406, 3205261, 3205262 Fax: 2423405
Email: admin@vibrantacademy.com Website : www.vibrantacademy.com
IRP TEST–1 (COURSE-2014)

JEE Advance (Paper-1)
Time : 3 Hours Maximum Marks : 240
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
A. General :
1. This booklet is your Question Paper containing 57 questions. The booklet has
32 pages.
2. The question paper CODE is printed on the right hand top corner of this sheet and
on the back page (page no. 32) of this booklet.
3. The question paper contains 3 blank pages for your rough work. No additional sheets
will be provided for rough work.
4. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
5. Fill in the boxes provided below on this page and also write your Name and VA
Roll No. in the space provided on the back page (page no. 32) of this booklet.
6. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided

separately.
7. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE BOOKLET.
8. Do not open the question-paper booklet before being instructed to do so by the invigilators.
B. Question paper format  Read the instructions printed on the back page

C. Marking scheme  (page no. 32) of this booklet.
Name of the candidate VA Roll Number
I have read all the instructions and I have verified all the information filled
shall abide by them. in by the candidate.
.......................................................... ............................................................
Signature of the Candidate Signature of the invigilator
USEFUL DATA
Atomic weights: H = 1, He = 4, Li = 7, g = 10 m/s2 , B = 11, C = 12, N = 14, O = 16, F = 19, Ne = 20, Na = 23,
Mg = 24, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Ar = 40 , Ti = 48, Cr = 52, Mn = 55, Fe = 56,
Co = 59, Cu = 63.5, Zn = 65.5, Br = 80, Mo = 96, Ag = 108, I = 127, Ba = 137, U = 238
PART I : MATHEMATICS
SECTION - I
Single Correct Choice Type
This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
1. Let f(x) = ||x2 – 10x + 21| – p| ; then the exhaustive set of values of p for which f(x) has exactly 6 points of non-
derivability ; is :
(A) (4, ) (B) (0, 4) (C) [0, 4] (D) (–4, 4)
z  
2. Which of following represents arg   ?
 – 1 4
z
y-axis
(0, 0) (1, 0)
(A) x-axis (B) x only
(0, 0) (1, 0)
/4
/4
(C) x only (D) either (b) or (c)

(0, 0) (1, 0)
Space For Rough Work
Vibrant Academy (I) Pvt. Ltd. "A-14(A)" Road No.1, Indraprastha Industrial Area, Kota (Raj.) Ph. 0744-2423406 [IRP-1,P-1-A-2]
MATHEMATICS
3. The line 3 x  y  2 touches the hyperbola 2x2 – y2 = 8 at the point

(A) 2 3 , 4  
(B) – 2 3 , 4  
(C) 2 3 , – 4  
(D) – 2 3 , – 4 
4. The number of different permutations of all the letters of the word PERMUTATION such that any two consecutive
letters in the arrangement are neither both vowels nor both identical is
(A) 63 × 6  5 (B) 8  6  5 (C) 57  5  5 (D) 7  7  5
5. If x, y  R, satisfy the equation

x  4 2  y 2 = 1 then the difference between the largest and smallest value
4 9
x2 y2
of expression  , is
4 9
(A) 2 (B) 4 (C) 6 (D) 8
MATHEMATICS
SECTION - II
Comprehension Type
This section contains 2 paragraphs. Based upon the first paragraph, 2 multiple choice questions and based
upon the second paragraph 3 multiple choice questions have to be answered. Each of these questions has
four choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
Paragraph for Question Nos. 6 to 7
For the curve sinx + siny = 1 lying in the first quadrant there exists a constant  for which
2
lim x d y = L (not zero)
x 0
dx 2
6. The value of 
1 1 3
(A) (B) (C) (D) 2
2 2 2
7. The value of L
1 1 1
(A) (B) 1 (C) (D)
2 2 2 2 3
MATHEMATICS
Let f and g be two differentiable functions such that
f(x) = g(1) sinx + (g(2) – 1) x
   
g(x) = x2 – f   x + f  – 
2  2
8. The number of solution(s) of the equation f(x) = g(x) is/are
(A) 1 (B) 2 (C) 3 (D) infinite
g(cos x )    2 
9. If  f ( x)  x dx = cosx + n (h(x)) + C where C is constant and h   = 1 then h  is
2  3 
1
(A) 3 2 (B) 2 3 (C) 3 (D)
3

10. If (x) = f –1(x) then    1 equals to
2 
 
(A) 1 (B) (C) 1 (D) 0
2 2
MATHEMATICS
SECTION - III
Multiple Correct Choice Type
answer, out of which ONE OR MORE is/are correct.
11. The locus of points of intersection of the tangents to x2 + y2 = a2 at the extremeties of a chord of circle
x2 + y2 = a2 which touches the circle x2 + y2 – 2ax = 0 is/are
(A) y2 = a(a – 2x) (B) x2 = a(a – 2y) (C) x2 + y2 = (x – a)2 (D) x2 + y2 = (y – a)2
x  3/2 
–1 x   C, where C is any arbitrary constant, then
12. For a > 0, if    a3 – x 3
dx  A sin
 B 
 
2 1
(A) A  (B) B = a3/2 (C) A  (D) B = a1/2
3 3
MATHEMATICS
13. Which of the following conclusion(s) hold(s) true for a non-zero vector a .
(A) a · b  a · c  b  c (B) a  b  a  c  b  c
(C) a · b  a · c and a  b  a  c  b  c (D) â  b̂  â  b̂  â · b̂  0
p  qx  x 2 , x  2
14. Let the funciton f be defined by f ( x )   . Then
2px  3qx 2 , x  2
4
(A) f(x) is continuous in R if 3p + 10q = 4 (B) f(x) is dfferentiable in R if p = q =
13
(C) If p = –2, q = 1, then f(x) is continuous in R (D) f(x) is differentiable in R if 2p + 11q = 4
MATHEMATICS
SECTION - IV
Integer Answer Type
This section contains 5 questions. The answer to each of the questions is a single-digit integer, ranging from
0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened. For
example, if the correct answers to question numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then
the correct darkening of bubbles will look like the following :
In all cases round answer to nearest integer value (if required)
X Y Z W
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
15. Given that the three points where the curve y = bx2 – 2 intersects the x-axis and y-axis form an equilateral
triangle. Find the value of 2b.
MATHEMATICS
16. The plane denoted by 1 : 4x + 7y + 4z + 81 = 0 is rotated through a right angle about its line of intersection
with the plane 2 : 5x + 3y + 10 z = 25. If the plane in its new position be denoted by  and the distance
of this plane from the origin is 53 k where k  N, then find k.
17. Let f(x) be a differentiable function in [–1, ) and f(0) = 1 such that
t 2 f ( x  1) – ( x  1) 2 f ( t ) lnf ( x ) – ln2
Lim  1. Find the value of Lim .
t  x 1 f ( t ) – f ( x  1) x 1 x –1
MATHEMATICS
18. In an arithmetic sequence an , let a1 > 0 and 3a8 = 5a13. If Sn be the sum of first n terms, then find the value
of n  N for which Sn is maximum.
19. If the quadratic equation ax2 + bx + c = 0 has equal roots where a, b, c denotes the lengths of the sides
opposite to vertex A, B and C of the ABC respectively. Find the number of integers in the range of
sin A sin C
+
sin C sin A
PART II : PHYSICS
SECTION - I
20. A block of mass m is lying on a wedge having inclination angle  = tan–1(1/5). Wedge is moving with a
constant acceleration a = 2 m/s2. The minimum value of coefficient of friction , so that m remains stationary
w.r.t. to wedge, is :
2 5
(A) (B) m
9 12 2
a = 2 m/s
1 2 
(C) (D)
5 5
21. It is possible to project a particle on a level ground with a given velocity in 2 possible ways so as to have the
same range R. The product of corresponding times of flight is then
R 2R R
(A) (B) (C) (D) None of these
g g 2g
PHYSICS
22. A particle is moving in a circular path. The acceleration and momentum of the particle at a certain moment
are a  ( 4 î  3 ĵ ) m/s2 and p  (8 î  6 ĵ ) kg-m/s. The motion of the particle is

(A) Uniform circular motion (B) Accelerated circular motion
(C) de-accelerated circular motion (D) We can not say anything with a and p only
23. A child is sliding down a slide in a playground with a constant speed.

Statement-1 : His kinetic energy is constant.
Statement-2 : His mechanical energy is constant.
(A) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
24. A particle moves in a circle with a uniform speed, when it goes from a point A to a diametrically opposite point
B. The momentum of the particle changes by p A  p B  2 kgm / s( ĵ ) and the centripetal force acting on it
changes by F A  FB  8N ( î ) where î, ĵ are unit vectors. Then the angular velocity of the particle is
(A) Dependent on its mass (B) 4 rad/sec
(C) 2/ rad/sec (D) 16 rad/sec
PHYSICS
SECTION - II
Comprehension Type
An equilateral prism ABC is placed in air with its base side BC lying horizontally along X-axis as shown in the
figure. A ray given by 3 z  x  10 is incident at a point P on face AB of prism
25. Find the value of  for which the ray grazes the face AC
1 2 3 3
(A) (B) (C) (D)
3 3 2 4
3
26. Find direction of the finally refracted ray if  
2
(A) 90° from AC (B) 60° from AC (C) 90° from BC (D) None of these
PHYSICS
Two moles of an ideal monoatomic gas is taken along the path ABC as shown in following figure.
Given TB = 2TA
P
C
A B
T
TA TB TC
27. Increase in internal energy in AB process is
9 3 3
(A) 3 RTA (B) RT
TA (C) RTB (D) RT
TA
4 4 2
28. Choose the correct option

5
(A) TC = 3TA (B) TC = T (C) TC = 4TA (D) TC = 4TB
2 B
29. Work done by the gas in process ABC

(A) 2RTA (B) –2RTA (C) 4RTA (D) None of these
PHYSICS
SECTION - III
30. The figure shows the potential variation along x-axis due to two point charges Q1 and Q2 placed on x-axis.
Examining this plot we can deduce that
y
x
Q1 Q2
V
x
A B C
(A) |Q1| > |Q2|

(B) C is a point of stable equilibrium for a positive charge for displacement along x-axis
(C) B is stable equilibrium point for positive charge for displacement along x-axis
(D) Work done by electric forces in bringing an electron from point A to C through any path is negative
31. For the system shown in figure, m1 > m2 > m3 > m4. Initially, the system is
at rest in equilibrium condition. If the string joining m4 and ground is cut,
then just after the string is cut (Choose the correct option(s))
m3
(A) m1, m2, m3 remain stationary.
(B) The value of acceleration of all the 4 blocks can be determined.
(C) m4 remains stationary. m2
m4
(D) m4 accelerates. m1
Ground
PHYSICS
V
32. For an ideal gas, VT diagram is given by :
2V0 B
(A) The maximum pressure during A – B – C – D is at D.
(B) The maximum pressure during A – B – C – D is at C.
V0 D
(C) No work is done by gas from A – B – C – D. A C
(D) Positive work is done by gas from A – B – C – D.
T
T0 2T0 4T0
33. Two projectiles are thrown at the same time from two different point. The first projectile thrown from the origin
has initial velocity 3 î  3 ĵ with respect to earth. The second projectile has initial velocity a î  b ĵ with respect
to earth thrown from the point (10, 5). ( î is a unit vector along horizontal, ĵ along vertical). If the projectiles
collide after two second, then the
1 1
(A) Value of a is –2 (B) Value of a is (C) Value of b is (D) Value of b is –2
2 2
PHYSICS
SECTION - IV
Integer Answer Type
X Y Z W
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
34. As shown in figure, there is a thick spherical shell with the walls coated with 'lamp black'. A point source
which generates thermal energy at a constant rate 'P' is placed at the centre S of the shell. Derive an
expression for the temperature T at point X in steady state, where SX = 1.5 R. Your expression would be as
follows :
1/ 4
 P   P 
T=  2
    . R
 16R   3 x KR 
S X
Here K is the coefficient of thermal conductivity of material
2R
of shell and  is Stefan's constant. Find the value of x.
PHYSICS
35. Two identical flasks contain same number of hydrogen molecules. They are connected by a pipe with a valve.
The rms speed of molecules in first flask is 400 m/s. The valve is suddenly opened so that the gases mix.
There is no heat loss to the surroundings. The rms speed of molecules now in the mixture is 500 m/s. If the
rms speed of molecules in the 2nd flask before mixing was 100 17 x m/s, Find the value of x.
36. At what maximum mass M (in kg) will bars not slide over each other, if the coefficient of friction between the
bars is equal to  = 1/8, and the coefficient of friction on the plane is equal to zero? Threads are massless
and inextensible, pulleys are ideal.
m2 = 2 kg
m1 = 1 kg
PHYSICS
37. An object O is located 40 cm from the first of two thin converging lenses (each of focal length 20 cm), as
shown in the figure below. If speed of the right lens is 7 cm/s rightwards, speed of final image is 7x/4 cm/s at
the instant shown, find the value of x.
20 cm
v = 7 cm/s
O
40 cm
f1 = 20 cm f2 = 20 cm
38. A point object is at the origin. A convex lens of focal length 20 cm is placed at x = +30 cm. A plane mirror is
placed so that it is perpendicular to the principal axis and the final image is formed at infinity. The distance
of mirror from origin is x/10 m, find the value of x.
PART III : CHEMISTRY
SECTION - I
39. The octahedral complex/complex ion which shows both facial and meridional isomers is
(A) Tris(glycinato)cobalt (lll) (B) Tris(ethylenediamine)cobalt (lll) ion
(C) Dichlorobis(glycinato)cobalt (lll) ion (D) Tris(oxalato)cobalt (lll) ion
O O
Aldol
40. Product (A + B)
condensation
O
(A Triketone compound)
The relationship between products A & B is :
(A) Positional isomers (B) Diastereomers
(C) Enantiomers (D) No isomeric relationship
CHEMISTRY
41. Aqueous solution of a metal ion ‘A’ on reaction with KI gives green ppt ‘B’ and the aqueous suspension of B
when heated produces a red precipitate with finelly distributed black particles. Then ‘A’ is
(A) Pb2+ (B) Cu2+ (C) Hg2+ (D) Hg22+
42. Conversion of boron trifluoride to tetrafluoroborate accompanies :

(A) increase in symmetry and bond elongation
(B) Increase in symmetry and bond contraction
(C) Decrease in symmetry and bond contraction
(D) Decrease in symmetry and bond elongation
43. The radioactive decay of 35X88 by a beta emission produces an unstable nucleus which spontaneously emits
a neutron. The final product is
87 88 88
(A) 35X89 (B) 36 Y (C) 37 Z (D) 34 W
CHEMISTRY
SECTION - II
Comprehension Type
For a gas (A2B4) dissociate according to following equation.
A2B4(g)  A2(g) + 2B2(g)
Informaitons :
(i) At t = 0, reaction started with 1 mole of A2B4 and observed molecular weight = 100
Molecular weight A 2B 4
(ii) Molecular Weight A  5
2
(iii) At t = 10 min, Molecular weight = 50

(iv) At t = 20 min, Molecular weight = 40
On the basis of given informations and observations answer the following questions :
44. Atomic weight “B” is
(A) 10 (B) 20 (C) 30 (D) 40
45. Determine rate of disappearance of A2B4 between t = 10 min. to t = 20 min. If it is assumed that it disappears
uniformly during this time interval
(A) 2.25 mol min–1 (B) 1.25 mol min–1 (C) 0.25 mol min–1 (D) 0.025 mol min–1
CHEMISTRY
Carbonyl compounds having -hydrogen in presence of dilute base give -hydroxy carbonyl compound after
heating -elimination takes place and removal of –H2O molecule occur. This reaction is known as aldol
condensation.
O3/Zn KOH
(C5H10) A+ B C
Alkene having Amm.
9(–H) 
AgNO3
Ag D
46. What is compound A and B respectively

O
O
(A) O and (B) O and
O
O
(C) and O (D) +
O
H H
47. What is compound D
O O O O
|| || || ||
(A) CH3 – CH2 – C – CH = CH – C – CH3 (B) CH 3 – C – CH = CH – C – CH 3
O CH 3 O
|| | ||
(C) CH3 – C – CH3 (D) CH3 – C = CH – C – CH3
48. When compound B reacted with NaOI then which products are formed?
O O
||   ||  
(A) CH 3CH 2 – C – O Na , CHI3 (B) CH 3 – C – O Na , CH3I
O O
||   ||  
(C) H – C – O Na , CHI3 (D) CH 3 – C – O Na + CHI3
CHEMISTRY
SECTION - III
49. Correct order(s) is/are
(A) H2O > NH3 > HF > CO2 : Melting point
(B) CH4 > SiH4 > GeH4 > SnH4 : Ease of liquefaction
(C) HI > HBr > HCl > HF : Reducing character
(D) H2NCONH2 > RCOR > CH4 : Solubility in water
50. Select the correct statement(s)

(A) n/p ratio increases during -emission.
(B) In -emission from a nucleus, the atomic number of the daughter element decreases by one.
(C) Lesser the value of binding energy per nucleon for a nucleus, greater is the stability of nucleus.
(D) Correct order of ionisation power  >  > 
CHEMISTRY
51. The table shows specific rotations for the anomers of D-mannose and the value after muta rotation. Calculate
the percentage of -D-mannose and -D-mannose present at equilibrium.
Specific Specific Rotation
Rotation After mutarotation
(Degreesº) (Degreesº)
-D-mannose +29.3 +14.5
-D-mannose –16.3 +14.5
(A)  67% of -D-mannose (B)  60% of -D-mannose
(C)  33% of -D-mannose (D)  40% of -D-mannose
52. Vander Waal’s constant for three different gases are given :
Gas a b
P 3 0.025
Q 10 0.030
R 6 0.035
Which of these is correct
(A) P is most easily liquefiable gas (B) Q has minimum critical temperature
(C) R has maximum molecular volume (D) Q has maximum Boyle’s temperature
CHEMISTRY
SECTION - IV
Integer Answer Type
X Y Z W
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
53. Find the numbr of molecular species having at least one bond angle equal to 90º.
SF4 , PF2Cl3 , XeO64– , IF7 , CF5 , CF3 , XeF4 , IO2F2– , XeO3F2.
CHEMISTRY
54. A mixture of two isotopes, 40X and 42X has a specific activity of 0.495 NA dps. Calculate the wt % of 40X in
mixture. (Given : decay constant of 40X and 42X are 10 and 21 s–1 respectively and NA = 6 × 1023).
55. Maximum number of atoms that can lie in a plane in the stable configuration of S2F10 molecule.
56. A sample of pitch blend has amount of 206Pb equivalent to one-fifth of the amount of 238U (by mole).
If age of mineral (in yr.) is represented as z × 10y then calculate the value of (y / z).
(Given :  (238U) = 2 × 10–9 years–1 ; ln 2 = 0.7 ; ln 3 = 1.1 ; ln 5 = 1.6)
CHEMISTRY
CH2–OH CH2–OH
H H H OH
H H
57. (A) OH H (B) OH H
HO OH HO H
H OH H OH
CH2–OH CH2–OH CH2–OH

H OCH3 HO OH
H H H
(C) OH H (D) OH H OH H
HO H H H
H OH H OH H OH
HOCH2 O H HOCH2 O H
H H OH H
(E) H OH (F) H OH
HO OH H OH
HOCH2 O OH H O OH
H H OH HO H
(G) H H (H) HOCH2
HO OH H H
Calculate the number of reducing sugar = x

Calculate the number of sugar in which molecular weight increases by 210, whenever it undergo acetylation
reaction with acetic anhydride = y
So x – y =
DATE : 28-04-14 CODE - A
Name of the candidate VA Roll Number
B. Question paper format :

9. The question paper consists of 3 parts (Physics, Chemistry and Mathematics).
Each part has 4 sections.
10. Section I contains 5 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out of which only one is correct.
11. Section II contains 2 paragraphs. Based upon the first paragraph, 2 multiple choice
questions and based upon the second paragraph 3 multiple choice questions have to
be answered. Each of these questions has four choices (A), (B), (C) and (D), out of
which only one of correct.
12. Section III contains 4 multiple choice questions. Each question has 4 choices
(A), (B), (C) and (D) for its answer, out of which one or more is/are correct.
13. Section IV contains 5 questions. The answer to each of the questions is an

integer, ranging from 0 to 9. The answer will have to be appropriately bubbled in the
ORS as per the instructions given at the beginning of the section.
C. Marking Scheme :
14. For each question in Section-I, you will be awarded 3 marks if you have darkened
only the bubble corresponding to the correct answer and zero mark if no bubbles are
darkened. In all other cases, minus one (–1) mark will be awarded.
15. For each question in Section-II, you will be awarded 3 marks if you have darken
darkened. In all other cases, minus one (–1) mark will be awarded.
16. For each question in Section-III, you will be awarded 5 marks if you have darken
darkened. No negative marks will be awarded in this Section.
17. For each question in Section-IV, you will be awarded 6 marks if you darken the
bubble corresponding to the correct answer and zero mark if no bubbles is darkened.
In all other cases, minus one (–2) mark will be awarded.

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DATE : 28-04-14 CODE - A

IRP TEST–1 (COURSE-2014)

6. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided

7. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE BOOKLET.

(C) x only (D) either (b) or (c)

Space For Rough Work

(A) 63 × 6  5 (B) 8  6  5 (C) 57  5  5 (D) 7  7  5

5. If x, y  R, satisfy the equation

Space For Rough Work

Space For Rough Work

Space For Rough Work

(C) a · b  a · c and a  b  a  c  b  c (D) â  b̂  â  b̂  â · b̂  0

(C) If p = –2, q = 1, then f(x) is continuous in R (D) f(x) is differentiable in R if 2p + 11q = 4

Space For Rough Work

Space For Rough Work

of this plane from the origin is 53 k where k  N, then find k.

Space For Rough Work

Space For Rough Work

are a  ( 4 î  3 ĵ ) m/s2 and p  (8 î  6 ĵ ) kg-m/s. The motion of the particle is

23. A child is sliding down a slide in a playground with a constant speed.

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figure. A ray given by 3 z  x  10 is incident at a point P on face AB of prism

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28. Choose the correct option

29. Work done by the gas in process ABC

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(A) |Q1| > |Q2|

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

42. Conversion of boron trifluoride to tetrafluoroborate accompanies :

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(iii) At t = 10 min, Molecular weight = 50

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46. What is compound A and B respectively

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50. Select the correct statement(s)

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Space For Rough Work

Space For Rough Work

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CH2–OH CH2–OH CH2–OH

Calculate the number of reducing sugar = x

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B. Question paper format :

13. Section IV contains 5 questions. The answer to each of the questions is an

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