Escolar Documentos
Profissional Documentos
Cultura Documentos
2635-2646, 1995
~ ) Pergamon Copyright © 1995 Elsevier Science Ltd
Printed in Great Britain. All rights reserved
0017-9310/95 $9.50 + 0.00
0017-9310(94)00346-7
and
STEPHEN WHITAKERI"
Department of Chemical Engineering, University of California at Davis, Davis, CA 95616, U.S.A.
Abstract--The momentum transfer condition that applies at the boundary between a porous medium and
a homogeneous fluid is developed as a jump condition based on the non-local form of the volume averaged
momentum equation. Outside the boundary region this non-local form reduces to the classic transport
equations, i.e. Darcy's law and Stokes' equations. The structure of the theory is comparable to that used
to developjump conditions at phase interfaces, thus experimental measurements are required to determine
the coefficientthat appears in the jump condition. The development presented in this work differs from
previous studies in that the jump condition is constructed to join Darcy's law with the Brinkman correction
to Stokes' equations. This approach produces a jump in the stress but not in the velocity, and this has
important consequencesfor heat transfer processes sinceit allows the convectivetransport to be continuous
at the boundary between a porous medium and a homogeneous fluid.
2635
2636 J.A. OCHOA-TAPIA and S. WHITAKER
NOMENCLATURE
A~a area of the/3-a interface contained (va) n superficial average velocity in the
within the averaging volume [m2] q-region [m s-1]
total surface area of the large-scale <v~>s excess surface velocity [m s-']
averaging volume, ~//~ [m2] x, y rectangular coordinates [m]
Ao, that portion of ~¢o~contained in the m- x position vector locating the centroid of
region [m2] the averaging volume [m]
An that portion of ~¢oocontained in the y position vector relative to the centroid
q-region [m2] of the averaging volume [m]
A~n area of the m-q interface contained ~/~ averaging volume [m3]
within ~ ~~ large-scale averaging volume [m3]
<S> excess Brinkman stress [N m -2] V~, volume of the ~o-region contained in
D diameter of the averaging volume ~ [m3]
having the form of a disk [m] V, volume of the q-region contained in
g gravity vector [ms -2] ~ / / [m3]
h depth of fluid channel [m] V~ volume of the/3-phase contained
H depth of porous medium [m] within the averaging volume ~ [m3].
I unit tensor
i,j unit base vectors in the x- and Greek symbols
y-direction, respectively. /3 the adjustable coefficient in the
Ks Darcy's law permeability tensor [m2] representation for the excess
Darcy's law permeability tensor in the stress
homogeneous o~-region [m2] A thickness of a disk that represents an
L~ characteristic length associated with averaging volume [m]
the velocity [m] 6 thickness of the interfacial region [m]
Lvl characteristic length associated with e~ porosity or volume fraction of the
the gradient of the velocity [m] /3-phase
L~ characteristic length associated with ea,o porosity in the homogeneous portion
the porosity [m] of the m-region
Lpa characteristic length associated with 2 unit tangent vector to the ~o-q interface
the pressure gradient [m] pa viscosity of the/3-phase [Ns m -z]
fp characteristic length associated with p~ density of the/3-phase [kg m 3].
the/3-phase in the m-region [m]
unit normal vector directed from the Subscripts
/3-phase toward the a-phase fl identifies a quantity associated with
IIcon unit normal vector directed from the the r-phase
m-region toward the q-region flcr identifies a quantity associated with
P projection tensor the fl-a interface
P~ pressure in the/3-phase [N m -2] q identifies a quantity associated with
(p:>~ intrinsic average pressure [N m 2] the q-region
<p~>~ intrinsic average pressure in the m identifies a quantity associated with
~o-region IN m -2] the m-region
intrinsic average pressure in the o97 identifies a quantity associated with
q-region [N m -2] the 09-7 boundary
<p~> ea(pa>~ superficial average pressure e identifies a length scale associated with
IN m -21 the porosity
ro radius of a spherical averaging volume pl identifies a length scale associated with
[m] the gradient of the pressure
<T>~ excess surface stress [N m -2] s identifies a surface vector or tensor
<T>B excess bulk stress [N m -2] v identifies a length scale associated with
v# velocity vector in the/3-phase [m s -I] the velocity
van fluid velocity vector in the q-region vl identifies a length scale associated with
[m s-i] the gradient of the velocity
<vS intrinsic average velocity [m s 1] oo identifies a quantity associated with
<v~> e~(vp) ~ superficial average velocity the large-scale averaging volume.
[m s -1]
<v~>~ superficial average velocity in the Superscripts
m-region [m s-1] fl identifies an intrinsic volume average.
Momentum transfer at the boundary--I 2637
y =h " ~ N N N ~ ~ ~ N ~ ~ ~ ~ ~
y=0
y= -H
Here we must remark that, while inertial effects may Here V~(x) is the volume of the fl-phase contained
be negligible in the homogeneousco-regionand in the within the averaged volume illustrated in Fig. 1. The
homogeneous~-region,it is possible that inertial effects position vectors used in equation (6) are identified in
will not be negligible in the boundary region. In that Fig. 2, where we have indicated that x represents the
region the curvature of the streamlines will be of the vector locating the centroid of the averaging volume,
order of the pore or particle diameter and this may and that y~ represents the vector locating points in the
lead to non-zero values of the inertial terms, pv- Vv. fl-phase relative to the centroid. Equation (6) clearly
The boundary condition at y = - H has been ex- indicates that volume averaged quantities are associ-
pressed by equation (5) in a form that is suitable for use ated with the centroid and that integration is carried
with Darcy's law, thus we have used <va) to represent out with respect to the components of y~.
the superficialvolmne averaged velocity defined by The boundary conditions given by equations (4)
and (5) are an indication of the mismatch of length-
I
<v~>lx = 7 fJ v ~ v,(x+ya) dVy. (6) scalesthat one often encounters in transport problems
that involve a porous medium. The point boundary
2638 J.A. OCHOA-TAPIA and S. WHITAKER
<v~>ix = ~ [ v , l x + Y ~ "Vv~lx
1
,gl--- boundary region ,~ <v'>/~lx = V-~]v~o,) vp(x+yp) dVy. (19)
(17)
vfA tta
na~'vpdA = 0. (24)
this result represents the Brinkman [15] correction and between a porous medium and a homogeneous fluid
that the viscosity associated with this term is the fluid or in the boundary region between a porous medium
viscosity, p~, which need not be corrected in any way. and a homogeneous solid. In such regions the second
While the superficial velocity is preferred because of viscous term is the same order of magnitude as the
its solenoidal characteristic, the intrinsic pressure is Brinkman correction and one is not justified in
preferred because it more closely resembles the pres- neglecting #e(Vee) • IV(aft- 1 (Vfl))]. W e will refer to this
sure that one could measure or the pressure that one latter term as the second Brinkman correction. A key
could impose as a boundary condition. This requires point to remember about equation (34) is that no
that we make use of the analogous form of equation length-scale constraints have been imposed and this
(20) for the pressure means that it is valid everywhere in the system illus-
trated in Fig. 1.
(Pc) = ee(Pe) ~ (29) At this point it is convenient to divide equation (34)
in order to express equation (28) as by ee and express the result in a compact form
+ ge (VveIx+y.-- V<ve)e [=)] dA. (34) The first two constraints given in equation (38) are
analytical in nature [16-18] and from those devel-
Here we have been forced to introduce the intrinsic opments one can deduce that r0 should be replaced by
average velocity in order to arrange the integral in A when the disk illustrated in Fig. 1 is used in the
equation (30) in terms of quantities that appear in the averaging process. The third constraint in equation
closure problem for Darcy's law [14]. The first viscous (38) is more intuitive in nature [19] ; however, recent
term that appears in equation (34) is usually referred numerical simulations [20-22] have verified that con-
to as the Brinkman correction, and this term is often straint for spherical averaging volumes. On the basis
included in the analysis of flow in the boundary region of both analysis and intuition, we are inclined to
2642 J.A. OCHOA-TAPIA and S. WHITAKER
fAn,O'<v~>,~dA+f
d Aom
n~'<v~)o, d A = 0 (52) and normal to the curve C, while V~ has been used to
represent the surface gradient operator that is given
explicitly in terms of the gradient operator and the
projection tensor according to
IAn~. <v~>. d A + | n,t~" <v~>. dA = 0. (53)
J A~ V~ = P'V, P = I-n~,n~,. (58)
Here we have used A ~ = A ~ to represent the area of Since the limits of integration over A , , are arbitrary,
the dividing surface contained within the volume Y~oo. we extract the following jump condition from equa-
and the convention associated with the unit normal tion (57)
vectors at the dividing surface is that n~, = - n . ~ . (<v~>~- <vp>,) "n~ = V~- (6<v¢>0
Returning to equations (52) and (53). it is impor-
tant to remember that the values of (v~>~ and <v~>, at the co--r/interface. (59)
in the interfacial region are not necessarily equal to
While the surface velocity, <v~>~, may be important
the actual physical value which is represented every-
at the boundary between a porous medium and a
where by (vt~>. If we subtract equations (52) and (53)
homogeneous solid [9], and is certainly important at
from equation (50). we can arrange the result in the
a fracture between two porous media [24], it would
following form
appear to be unimportant at the fluid-porous medium
interface illustrated in Fig. 1.
fA~, n ~ " ((V, >~,-- (vt~>~) dA
3.3. Momentum equation
In order to develop the momentum jump condition,
= I n~" (<v~>- <v~>~)dA we recall that the following volume averaged momen-
~A
tum equation
÷ f n," ((v~> - <v~>.)dA (54) 0 = -- V(p# >t~+ p~g + e~-~#~V2<vt~>
~A
and this suggests, that we define an excess surface - - ~./fl~f 1 ( V E i l ) ' [V(efl 1 <Vfl>)] --~fl~l~fl (60)
velocity according to is valid everywhere, and that in the co- and q-regions
the momentum equations are given by
3.2. Definition co-region : 0 = - V(p~ >~,+ p~g + ~-~ #~V 2<v~>~
fA n'°"" ( < v ' > ~ - <v'>") d A - ~c n~" (6<vB>~) d~r = 0 In equation (61) we need not rearrange the first Brink-
t~ man correction since ea,ois a constant in that equation.
To develop the jump condition we form the integral
(56)
of equation (63) over ~ and the integrals of equa-
and we can apply the surface divergence theorem [23] tions (61) and (62) over V~ and 1/",, respectively. We
to obtain then subtract the latter from the former to obtain
Momentum transfer at the boundary--I 2641
,~ V . ( v ~ ) d V = 0 (49)
(69)
--fvolas[*8 - K~-2 "<vs>~] dV
Use of these three definitions leads to a momentum
jump condition of the form
- fv./~8 [(]Ds] d V
B.C.1
no," [ - I((p8 )~ - (Ps>~) + P8 (e~-~V(v8 >~,- V<v8>,) l
+ fv~ [Yseti-~(V In e8) 2<v8)] d V
= Vs" (5<T>s)-n~." (<T>.)+no.- ( ( a ) )
(66)
3.5. Negligible excess stresses
B.C. 1
so that the integrands in the integrals over Vo and V, n,o. • [ - I(<p8>o
13 8
- <P8)7) --1
+ #8 (es* V(vs>~
both tend to zero in the homogeneous parts of the co-
and q-regions, respectively. This means that the terms -V(vs),) ] = 0 at the co-q boundary. (72)
on the right hand side of equation (65) can be rep-
This boundary condition would be consistent with the
resented in terms of excess functions.
use of equations (46) and (48) and would be referred
to as the Brinkman solution [10] for the stress jump
3.4. Definitions condition. For the uniform flow illustrated in Fig. 1,
We define an excess surface stress according to the normal component of equation (72) reduces to
condition that contained a j u m p in both the stress and difference between the two shaded areas, i.e. A~-A2.
the velocity. While the Beavers and Joseph model has We can represent the excess function according to
enjoyed considerable success in the treatment of fluid
3('Va)ox = C(('Va)~ly=o-('Va)rly=o ) (78)
mechanics problems, the velocity j u m p leaves much
to be desired in terms of heat transfer processes [25]. in which C is an adjustable parameter. It should be
clear that the difference between the two extrapolated
values of (qJa) is an appropriate scaling factor;
4. GENERAL FORM FOR THE EXCESS STRESS however, it does not necessarily represent the complete
On the basis of the definitions of the excess surface functional dependence of 6(qu~)ox.
stresses given by equations (67) and (68) we propose
the following representations : 4.3. Excess Brinkman stress
Extracting a plausible representation for the excess
4.1. Excess surface stress Brinkman stress presents a problem because of the
V~(6(T), = n~r • [--I((p~)~ -- (p~),~) highly non-linear dependence upon the void fraction.
If we restrict our thoughts to the tangential com-
+kta(e~L~V(va)~-e~r~V(va)r)] "C (74) ponent of the velocity we can argue that ~ 3 ( v ~ ) is a
in which the tensor C is a dimensionless adjustable slowly varying function of position and this encour-
tensor coefficient on the order of unity. ages us to express the integrand in equation (70) as
#fl~- 1 (V In ea) 2(va) = #B(Vea) 2(e~-3(va)). (79)
4.2. Excess bulk stress
The idea that e~-3 (va) is a slowly varying function is
n , r • (T)B = 6/~D" [K~2 • (va),] (75)
based on the form of the Blake-Kozeny correlation
in which D is a dimensionless adjustable tensor [26] and it suggests a representation of the excess
coefficient on the order of unity. In order to clarify Brinkman stress given by
the choice of these two representations, we consider
the one-dimensional example based on the function
n~." <a>
(~Fa) that has the following property : = #ar-~A-(eao~-~ar)E(e~3(va)~+e~3(va)~) (80)
((~),o y <~ --6/2 in which e~ 3 has only been included for clarity since
(q'~) = ~
((qJ~)r y ~> +3/2" (76) this term is equal to one.
Since the form of the excess surface stress is identical
The excess function associated with (qJa) is defined to the left hand side of equation (70), the effect of
by Vs" (6(T)s) will be lost in the stress j u m p condition
because of the adjustable nature of the coefficients in
6<%)~x = f0/~ (<'ep)- (,I,~)~) dy equations (75) and (80), thus we can substitute these
latter two equations into equation (70) to obtain
dividing
8tt~faee + ~a(~;2 V(va )~ - V(va)0] • ,~
I
I = - V a r 2 " D" [Kh-J • (va),o ]
I
+/~a3-12 • A" (ea,o- 1)2 (e~-3(va)~ + (va)r) (82)
............. ..[
and can be simplified by noting that nor" 2 is zero
and that the velocities (va), o and (va) r are equal as
I ~v,~o],~0 i (v,>~l,°0 indicated by equation (71). This leads to the following
form :
If we scale the thickness of the interfacial region 2. G. S. Beavers and D. D. Joseph, Boundary conditions
according to 5 = Ox/(Kpo), we can express the tan- at a naturally permeable wall, J. Fluid Mech. 30, 197-
207 (1967).
gential component of our j u m p condition for the stress 3. R. E. Larson and J. J. L. Higdon, Microscopic flow near
as the surface of two-dimensional porous media--I. Axial
flow, J. FluidMech. 166, 449-472 (1987).
d 4. R. E. Larson and J. J. L. Higdon, Microscopic flow
no,." (e~-2V(va)~ -V(v#),)" 2 = • (Va)o,
x/(K#,,,) near the surface of two-dimensional porous media--II.
Transverse flow, J. FluidMech. 178, 119-136 (•987).
(84) 5. M. Sahraoui and M. Kaviany, Slip and no-slip velocity
boundary conditions at interface of porous, plain media,
in which d is a dimensionless drag vector defined by Int. J. Heat Mass Transfer 35, 927-943 (1992).
6. M. Kaviany, Principles of Heat Transfer in Porous
d = ~/(K#o,)[6 -~ 2 • A(~p,,~- 1)2 (e~-3 + l) - 3 2 " D" K~-2]. Media. Springer, New York (1991).
7. D. A. Nield and A. Bejan, Convection in Porous Media.
(85) Springer, New York (1992).
8. S. Whitaker, The species mass jump condition at a singu-
F o r the process illustrated in Fig. 1, we summarize
lar surface, Chem. Engng Sci. 47, 1677-1685 (1992).
the boundary cond~itions as 9. S. Haber and R. Mauri, Boundary conditions for
Darcy's flow through porous media, lnt. J. Multiphase
B.C. 1 Flow 9, 561-574 (1983).
10. C.W. Somerton and I. Catton, On the thermal instability
--(v#),o y=0 of superposed porous and fluid layers, Trans. A S M E
c3y Oy ~/(KB~ )
104, 160-165 (1982).
(86) 11. J. E. Maneval, M. J. McCarthy and S. Whitaker, Use of
NMR as an experimental probe in multiphase systems :
B.C.2 (v~;,~ = (v~), y = O. (87) determination of the instrument weighting function for
measurements of liquid-phase volume fraction, Water
Here we have used ,(va),o and (vB) . to represent the x- Resour. Res. 26, 2807-2816 (1990).
components of the two volume average velocity vec- 12. S.A. Altobelli, R. C. Givler and E. Fukushima, Velocity
tors and the dimensionless coefficient fl is given by and concentration measurements of suspensions by
nuclear magnetic resonance imaging, J. Rheol. 35, 721-
fl = ~/(Ka,,,)[5-'2" A" 2(e8o,-- 1)2 (e~-2 + 1) 732 (1991).
13. F. A. Howes and S. Whitaker, The spatial averaging
-62.D.Kp2.2]. (88) theorem revisited, Chem. Enyny Sci. 40, 1387 1392
(1985).
Like the dimensionless drag vector d, we expect the 14. S. Whitaker, Flow in porous media--I. A theoretical
dimensionless coefficient fl to be on the order of one, derivation of Darcy's law, Transp. Porous Media 1, 3-
and on the basis of the nature of excess functions as 25 (1986).
15. H. C. Brinkman, A calculation of the viscous force
illustrated in Fig. 5, we can expect that fl may be exerted by a flowing fluid on a dense swarm of particles,
either positive or negative. In Part II we will compare Appl. Sei. Res. A1, 27-34 (1947).
solutions of equations (45)-(48), subject to the bound- 16. M. Quintard and S. Whitaker, Transport in ordered and
ary conditions given by equations (86) and (87) with disordered porous media--I. The cellular average and
the use of weighting functions, Transp. Porous Media 14,
the experimental data of Beavers and Joseph [2].
163-177 (1994).
17. M. Quintard and S. Whitaker, Transport in ordered
and disordered porous media--II. Generalized volume
5. CONCLUSIONS averaging, Tramp. Porous Media 14, 179-206 (1994).
18. R. G. Carbonell and S. Whitaker, Heat and mass trans-
In this study we have derived a stress j u m p con-
fer in porous media. In Fundamentals o f Transport Phe-
dition for the boundary between a porous medium nomena in Porous Media (Edited by J. Bear and
and a homogeneous; fluid. The development is based M. Y. Corapcioglu), pp. 123-198. Martinus Nijhoff,
on a generally valid, non-local form of the volume Dordrecht, The Netherlands (1984).
averaged Stokes' equations, and it requires exper- 19. S. Whitaker, Advances in the theory of fluid motion in
porous media, I&EC Fundam. 61, 14-28 (1969).
imental measurements to evaluate an undetermined 20. M. Quintard and S. Whitaker, Transport in ordered and
parameter that naturally appears in the j u m p disordered porous media--III. Closure and comparison
condition. The j u m p condition is constructed in order between theory and experiment, Transp. Porous Media
to connect Darcy's law with the Brinkman correction 15, 31-49.
to the Stokes' equations, and this leads to a volume 21. M. Quintard and S. Whitaker, Transport in ordered
and disordered porous media--IV. Computer generated
averaged velocity field that is continuous. porous media, Transp. Porous Media 15, 51~0 (1994).
22. M. Quintard and S. Whitaker, Transport in ordered and
Acknowledgement--The authors gratefully acknowledge the disordered porous media--V. Geometrical results for
financial support provided by CONACyT (project 1231- two-dimensional systems, Transp. Porous Media 15, 183-
A9203) of the Mexican government. 196.
23. J. A. Ochoa-Tapia, P. Del Rio and S. Whitaker, Bulk
and surface diffusion in porous media : an application of
REFERENCES the surface averaging theorem, Chem. Engng Sci. 48,
1. D. D. Joseph and L. N. Tao, Lubrication of a porous 2061-2082 (1993).
bearing--Stokes' solution, J. Appl. Mech., 753-760 24. J. Douglas and T. Abogast, Dual porosity models for
(1966). flow in naturally fractured reservoirs. In Dynamics of
2646 J.A. OCHOA-TAPIA and S. WHITAKER
Fluids in Hierarchical Porous Media (Edited by J. H. transfer at the interface region of a porous medium, Int.
Cushman), Chap. VII. Academic Press, New York J. Heat Mass Transfer 30, 1391-1405 (1987).
(1990). 26. R. B. Bird, W. E. Stewart and E. N. Lightfoot, Transport
25. K. Vafai and R. Thiyagaaraja, Analysis of flow and heat Phenomena. John Wiley, New York (1960).