Which sentence below is incorrect?

c. Pure iron is a heterogeneous mixture.

"In order to separate two substances by fractional crystallization, the two substances must differ in
which of the following? "

solubility

Which gas under a high temperature and a low pressure behaves most like an ideal gas?

c. He

What is the oxidation number for chromium (Cr) in the compound BaCrO4?

a. 6

“The rate of effusion of a gas is inversely proportional to the square root of its molar mass” is a
statement of _________________ Law.

Graham's

A book is lifted off of the floor and placed on a table that is one meter above the floor. The book has

b. gained potential energy

Sodium sulfate froms a number of hydrates. A sample of a hydrate is heated until all the water is
removed. What is the formula of the original hydrate if it loses 43% of its mass when heated?

Na2SO4 *6H2O

A liquid will boil when

a. its vapor pressure is equal to the surrounding pressure

Two balloons are at the same temperature and pressure. One contains 14g of nitrogen and the other
contains 20.0g of argon. Which of the following is true?

The average speed of the nitrogen molecules is greater than the average molecules of the argon
molecules.

A compound composed of carbon, hydrogen, and chlorine effuses through a pinhole 0.411 times as
fast as neon. Select the correct molecular formula for the compound.

CHCl3

"Nitroglycerin is made by combining glycerol, nitric acid, and sulfuric acid. What are the minimum
coefficients needed to balance the equation of this reactions?"

d. "1,3,1,1,3,1"

3 Cu(s) + 8 HNO3(aq) --> 3 Cu(NO3)2(aq) + 2 NO(g) + 4 H2O(l) Copper metal reacts with nitric acid
according to the above equation. A 0.30 mol sample of copper metal and 10.0 mL of 12 M nitric acid
are mixed in a flask. How many moles of NO gas will form?

0.030 mol

The carat is the unit of mass used by jewelers. One carat is exactly 200 mg. How many carbon atoms
are present in a 24-carat diamond?

2.4 x 1023 atoms

Which of the following bonds would you expect to be the most polar?

d. N-Bi

There are 500 g of zinc sulfide (ZnS) in a load of zinc ore. The ZnS is roasted in excess air to form zinc
oxide (ZnO) and sulfer dioxide (S)?. How many grams of zinc can be subsequently recovered if 5% of
the zinc is lost in the roasting process?

c. 320 g
Gadolinium oxide, a colorless powder which absorbs carbon dioxide from the air, contains 86.76 mass
% Gd. Determine its empirical formula.

Gd2O3

A 500-mL sample of argon at 800 torr has its absolute temperature quadrupled. If the volume remains
unchanged what is the new pressure?

3200 torr

Which of the following substances will produce a colorless aqueous solution?

Zn(NO3)2

Structural isomers have the same molecular formula but different structural formulas.

True

Assuming ideal behavior, what is the density of argon gas at STP, in g/L?

1.78 g/L

A flask has a mass of 78.23 g when empty and 593.63 g when filled with water. When the same flask is
filled with concentrated sulfuric acid, H2SO4, its mass is 1026.57 g. What is the density [g/cc] of
concentrated sulfuric acid? (Assume water has a density of 1.00 g/cm^3 at the temperature of the
measurement.)

1.840

What is the pressure in a 7.50-L flask if 0.15 mol of carbon dioxide is added to 0.33 mol of oxygen? The
temperature of the mixture is 48.0°C.

1.69 atm

"A sample of oxalic acid, H2C2O4, is titrated with standard sodium hydroxide, NaOH, solution. A total
of 45.20 mL of 0.1200M NaOH is required to neutralize20.00 mL of the acid. What is the concentration
of the acid?"

0.1356 M
The molar mass of caffeine is 194.19 g/mol and the empirical formula is C4H5N2O; therefore the
molecular formula of caffeine is C8H10N4O2.

True

The time required for a given volume of N2 to diffuse through an orifice is 35 sec. Calculate the
molecular weight of a gas which requires 50 sec to diffuse through the same orifice under identical
conditions.

d. 57.15 g/mole

Ammonia, an important source of fixed nitrogen that can be metabolized by plants, is produced using
the Haber process in which nitrogen and hydrogen combine.

N2(g) + 3H2(g) → 2NH3(g)

How many grams of nitrogen are needed to produce 325 grams of ammonia?

267

Aqueous solutions of this ion are blue.

Cu2+

"A reaction produces a gaseous mixture of carbon dioxide, carbon monoxide, and water vapor. After
one reaction, the mixture was analyzed and found to contain 0.60 mol of carbon dioxide, 0.30 mol of
carbon monoxide, and 0.10 mol of water vapor. If the total pressure of the mixture was 0.80 atm,
what was the partial pressure of the carbon monoxide?"

0.24 atm

What is the mass of an object that has a density of 13 g/mL and a volume of 10 mL?

d. 130 g/mL

"In most of its compounds, this element exists as a monatomic cation."

Ca
The executioner in charge of the lethal gas chamber at the state penitentiary adds excess dilute
sulfuric acid to 196 g of sodium cyanide. What volume [L] of HCN gas is formed at STP? The reaction is:
H2SO4 + 2 NaCN --> 2 HCN + Na2SO4

90

"When the following equation is balanced, it is found that 1.00 mol of C8H18 reacts with how many
moles of O2(g)? ___C8H18(g) + ___O2(g) --> ___CO2(g) + ___H2O(g)"

12.5 mol

"A sample of oxalic acid, H2C2O4, is titrated with standard sodium hydroxide, NaOH, solution. A total
of 45.20 mL of 0.1200M NaOH is required to neutralize20.00 mL of the acid. What is the concentration
of the acid?"

0.1356 M

0.72 g of O2 has a greater mass than 0.0011 mol of chlorophyll (C55H72MgN4O5)

False

Calculate the molar mass (g/mol) of Ca(BO2)2·6H2O.

233.79

At what temperature in °C will O2 has under a pressure of 2.4 atm? (rho of O2= 1.43 g/L)

d. 381°C

"Aluminum metal reacts with HCl to produce aluminum chloride and hydrogen gas. How many grams
of aluminum metal must be added to an excess of HCl to produce 33.6L of hydrogen gas, if the gas is
at STP?"

27g

"A 1.15 mol sample of carbon monoxide gas has a temperature of 27deg C and a pressure of 0.300
atm. If the temperature were lowered to 17 deg C, at a constant volume, what would be the new
pressure?"

0.290 atm
The ozone layer is important because...

ozone absorbs ultraviolet radiation

A steel tank containing argon gas has additional argon gas pumped into it at constant temperature.
Which of the following is true for the gas in the tank?

The gas atoms travel with the same average speed.

"For a given isotope of an element, the atomic number plus the atomic weight is 148, and their
difference is 58. How many protons does an atom of the isotope contain?"

b. 45

A carbon dioxide sample weighing 44.0 g occupies 32.68 L at 65°C and 645 torr. What is its volume at
STP?

22.4 L

Which of the following chemical formulas is incorrect?

a. CaCI

"As the pressure of a gas increases, the solubility of that gas in a liquid"

d. always increases.

"An experiment to determine the molar mass of a gas begins by heating a solid to produce a gaseous
product. The gas passes through a tube and displaces water in an inverted, water-filled bottle. Which
of the following items may be determined after the experiment is completed?"

vapor pressure of water

This element is a liquid at room temperature.

Hg
"If a sample of methane gas effuses at a rate of 9.0 mole per hour at 35 deg C, which of the gases
below will effuse at approximately twice the rate under the same conditions?"

helium gas

What is the percentage (by mass) of hydrogen in glucose (C₆H₁₂O₆)?

a. 0.067

From the following list of aqueous solutions and water, select the one with the lowest freezing point.

0.75 M (NH4)3PO4

"A reaction produces a gaseous mixture of carbon dioxide, carbon monoxide, and water vapor. After
one reaction, the mixture was analyzed and found to contain 0.60 mol of carbon dioxide, 0.30 mol of
carbon monoxide, and 0.10 mol of water vapor. If the total pressure of the mixture was 0.80 atm,
what was the partial pressure of the carbon monoxide?"

0.24 atm

"When 50.0 mL of 1.0M AgNO3 is added to 50 mL of 0.50M HCl, a precipitate of AgCl forms. After the
reaction is complete, what is the concentration of silver ions in the solution?"

0.25M

Cinnamic alcohol is used mainly in perfumery, particularly in soaps and cosmetics. Its molecular
formula is C9H10O. How many molecules of cinnamic alcohol are contained in a sample of mass 0.469
g?

2.11 x 1021

Peroxyacylnitrate (PAN) is one of the components of smog. It is a compound of C, H, N, and O.

Determine the empirical formula from the following percent composition by mass: 19.8 percent C,
2.50 percent H, 11.6 percent N, 66.1 percent O. What is its molecular formula given that its molar
mass is about 120 g?

C2H3NO5