Test

MONTHLY ASSESSMENT TEST (IIT-2020)
FIITJEE MONTHLY ASSESSMENT

TEST PHYSICS, CHEMISTRY & MATHEMATICS
MONTHLY ASSESSMENT
CM – TEST - IV CODE: 115435
Time Allotted: 3 Hours Maximum Marks: 240
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examina tion Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
BATCHES –1820
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Section.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each section is further divided into three parts: Part-A , Part-B & Part-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Part-A (01 – 8) contains 8 multiple choice questions which have only one correct answer. Each question
carries +3 marks for correct answer and – 2 mark for wrong answer.
Part -A (09 – 12) contains 4 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
(ii) Part -B (01 – 02) contains 2 Matrix Match Type questions containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each question
carries +8 marks for all correct answer. For each correct row +2 marks will be awarded and –1 mark for
each row matched incorrectly.
(iii) Part -C (01 – 06) contains 6 Numerical based questions with single digit integer as answer, ranging from 0
to 9 and each question carries +4 marks for correct answer and – 1 mark for wrong answer.
Name of the Candidate :__________________________________________
Batch :___________________ Date of Examination :___________________
Enrolment Number :______________________________________________
FIITJEE Patna Centre, 2nd floor, Saday Bhawan, Marwari Awas Complex, Fraser Road, Patna, Ph. : 9534599992, 9534699992
e-mail – info.patna@fiitjee.com , website: www.fiitjee.com
Section – 1: PHYSICS
Part A – (i): (Only one option correct Type)
This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. A cylindrical tube of cross – sectional area A has two

air tight frictionless pistons at its two ends. The
pistons are tied with a straight piece of metallic wire.
The tube contains a gas at atmospheric pressure P0 A A
and temperature T0. If temperature of the gas is
doubled then the tension in the wire is
(A) 4 P0A (B) P0 A/2 (C) P0A (D) 2P0A
2. An ideal monoatomic gas is undergoing a cyclic P

process as shown in the figure. Then choose the C
correct statement 3P0
(A) work done by the gas in process CA is negative 450
B
(B) heat is rejected by the system in process BC 450
(C) work done by the gas in the cyclic process is positive
(D) internal energy of the gas decreases in process AB P0
A
T0 2T0 T
P
3. One mole of an ideal gas at temperature T 1 expends according to the law = a ( cons tan t ) . The work
V2
done by the gas till temperature of gas becomes T 2 is:
1 1 1 1
(A) R ( T2 − T1 ) (B) R ( T2 − T1 ) (C) R ( T2 − T1 ) (D) R ( T2 − T1 )
2 3 4 5
4. A rod of length l (laterally thermally insulated) of uniform cross sectional area A consists of a material whose
Ko
thermal conductivity varies with temperature as K = where K0, a & b are constants. T1 and T2 (<
a + bT
T1) are the temperature of two ends of rod. Then rate of flow of heat across the rod is
AK 0  a + bT1  AK 0  a + bT2  AK 0  a + bT1  AK 0  a + bT2 
(A)   (B)   (C) ln   (D) ln  
bl  a + bT2  bl  a + bT1  bl  a + bT2  al  a + bT1 
Space for Rough Work
5. A cylinder made of perfectly non conducting material closed at both ends is divided into two equal
parts by a heat proof piston. Both parts of the cylinder contain the same masses of a gas at a
temperature t0 = 270C and pressure P0 = 1 atm. Now if the gas in one of the parts is slowly heated to t
= 570C while the temperature of first part is maintained at t0 the distance moved by the piston from the
middle of the cylinder will be (length of the cylinder = 84 cm)
(A) 3 cm (B) 5 cm (C) 2 cm (D) 1 cm
6. The relation between U, p and V for an ideal gas in an adiabatic process is given by relation U = a + bPV.
Find the value of adiabatic exponent (  ) of this gas.
b +1 b +1 a +1 a
(A) (B) (C) (D)
b a b a+b
7. A ideal monoatomic gas is carried around the cycle P

ABCDA as shown in the fig. The efficiency of the gas B
C
3P0
cycle is
P0 D
A
V
V0 2V0
4 2 4 2
(A) (B) (C) (D)
21 21 31 31
8. An ideal monoatomic gas is confined in a horizontal

cylinder by a spring loaded piston (as shown in the
figure). Initially the gas is at temperature T 1, pressure
P1, and volume V1 and the spring is in its relaxed
state. The gas is then heated very slowly to
temperature T2 pressure P2 and volume V2. During
this process the piston moves out by a distance x.
Ignoring the friction between the pistor and the
cylinder, the correct statement is
1
(A) If V2 = 2V1 and T2 = 3T1, then the energy stored in the springs is P1V1
4
(B) If V2 = 2V1 and T2 = 3T1, then the change in internal energy is 3P1V1
7
(C) If V2 = 3V1 and T2 = 4T1, then the work done by the gas is P1V1
3
17
(D) If V2 = 3V1 and T2 = 4T1, then the heat supplied to the gas is P1V1
6
Part A – (ii): (One or more options correct Type)

This section contains 04 multiple choice questions. Each question has four choices (A), (B) , (C) and (D) out of
which ONE or MORE are correct.
9. An ideal gas example in such a way that PV2 =

constant throughout the process.
(A) The graph of the process of T – V diagram is a parabola
(B) The graph of the process of T – V diagram is a hyperbola
(C) Such an expansion is possible only with heating
(D) Such an expansion is possible only with cooling
10. A vertical cylinder with heat – conducting walls is closed at the bottom and is fitted with a smooth light
piston. It contains one mole of an ideal gas. The temperature of the gas is always equal to the
surrounding’s temperature, T0. The piston is moved up slowly to increase the volume of the gas to  times.
Which of the following is correct?
(A) Work done by the gas is RT0 in 
(B) Work done against the atmosphere is RT0 (  − 1)
(C) There is no change in the internal energy of the gas
(D) The final pressure of the gas is 1(  − 1) times its initial pressure
11. 2 moles of a monoatomic gas are expanded to double its initial volume, through a process P/V = constant. If
its initial temperature is 300 K, then which of the following is true.
(A) T = 900K (B) Q = 3200R (C) Q = 3600R (D) W = 900R
12. A room air conditioner is modelled as a heat engine

run in reverse. An amount of heat Qin is absorbed
from the room at a temperature T L by the cooling
coils which contains a working gas; this gas is Room
compressed adiabatically to a temperature T H; then
the gas is compressed isothermally in a coil outside
Heating
coil
Pump Cooling
of the house, giving off an amount of heat Qout; the
gas expands adiabatically back to a temperature T L coil
and the cycle is repeated. An amount of energy W is Valve
input into the system in every cycle through an
electric pump. This model describes the air
conditioner with the best possible efficiency. The
outside air temperature is T H and the inside air
temperature is TL. The air conditioner unit consumes
electric power P. Assume that the air is dry
sufficiently so that no condensation of water occurs
in the cooling coils of the air conditioner. Which of
the following may be the rate at which heat is
removed from the room?
P  TL  3P  TL   TL  3P  TL 
(A)   (B)   (C) P   (D)  
2  TH − TL  4  TH − TL   TH − TL  2  TH − TL 
Part B – (iii): (Matrix Match Type)

This section contains 2 Matrix Match questions. Each question has statements given in 2 columns. Statements in
the first column have to be matched with statements in the second column. There may be One or More than one
Correct. `
1. A monoatomic ideal gas is taken through a cyclic P

C
process ABCDEA. ABCDEA is circular path. If work 3P0
done in is denoted by W and Q is the heat absorbed B D
by the gas in each process, then in process.
P0
Area under P – V curve is equal to work done by the A
gas.
V0 3V0 V
Column – I Column - II
(A) AB (p) W>0
(B) BC (q) W<0
(C) CD (r) Q  0
(D) DA (s) Q  0
(t) U  0
2. A non – conducting, movable piston separates a non

– conducting container in two equal parts each of
volume V0. A diatomic gas is filled in the left part and P0, V0, T0 P0, V0, T0
a monoatomic gas is filled in the right part of the
container. Initially both the gas have temperature T 0
and pressure P0. Now the gas on the left is heated
slowly until the gas on the right is compressed to
V
volume 0 .
8
Pr = Final pressure of the gas on the right side
n = Number of moles of diatomic gas
Q = Total heat given by the heater
TL = Final temperature on the left side
Column – I Column - II
(A) Pr (p) 60
P0
(B) nRT0 (q) 32
P0 V0
(C) Q (r) 1
P0 V0
(D) TL (s) 152
T0
(t) 90
Part C (Integer value correct Type)

This section contains 6 questions. The answer to each question is a Single digit integer, ranging from 0 to 9(both
inclusive).
1. A rod of length 40 cm has the coefficient of linear expansion 1 = 6 × 10–6/ºC. Another rod of length
= 10  K cm has the coefficient of linear expansion 2 = 4 × 10–6/ºC. If the difference in the lengths of the
213
two rods always remain same at all temperatures, then the value of K is  = .
68
2. 600 J of heat is added to a monatomic gas in a process in which the gas performs a work of 150 J. The
molar heat capacity for the process is K  R. Find the value of K?
3. The internal energy of a gas is given by U = 2PV. It expands from V 0 to 2V0 against a constant pressure P0.
The heat absorbed by the gas in the process is K  P0V0. Find the value of K?
4. A diatomic ideal gas is heated at constant volume until the pressure is doubled and again heated at
19
constant pressure until volume is doubled. The average molar heat capacity for whole process is .
K R
Find the value of K?
3
5. Heat is generated uniformly per unit volume inside a spherical volume of radius 1m at rate of 20 W / m .
1
The thermal conductivity of the spherical volume in W / mK . If the outer surface temperature of the
6
sphere is 200C. If the temperature of the centre of the sphere is x 10 ( in degree centigrade), find x .
6. A sample of ideal gas is expanded to twice of its original volume of 1m3 in a quasi-static process for which
P = v 2,  = 3  105 Pa / m6 as shown in fig. Work done (in 105J) by expanding gas is
P f
3 3
1m 2m V
Section – 2: CHEMISTRY
1. The correct order of decreasing basicity of the compound is:
F3C ⎯ N ⎯ CF3
N
CF3
N N H
(I) (II) (III) (IV)
(A) I > II > III > IV (B) III > II > IV > I (C) II > IV > III > I (D) IV > III > II > I
2. The most stable resonating structures of following compound is
O N N O
+
- - + - -
(A) O N + N O (B) O N N O
+
-
+ + - +
(C) O N (D) N O O N N O
-
3. Which of the following statements would be true about this compound?
NO 2
5
1 3
O 2N NO 2
Br
(A) All three C – N bonds are of same length
(B) C1 – N and C3 - N bonds are of same length but shorter than C5 – N bond
(C) C1 – N and C3 – N bonds are of same length but longer than C 5 – N bond
(D) C1 – N and C3 – N bonds are of different length but both are longer than C5 – N bond
4. Which of the following compounds does not have any geometrical isomer?
(A) Cl (B) Cl (C) Cl (D) Cl
Cl
Cl Cl Cl
Cl
Cl Cl Cl
5. Total number of optically active isomers having molecular formula C7H16 are
(A) 2 (B) 4 (C) 6 (D) 8
6. Which of the following is not true for
(A) It's IUPAC name is 3-Hydroxypropanoic acid

(B) It's anti form is most stable
(C) Intramolecular H-bonding exist in it's gauche form
(D) It has two types of staggered forms
7. What is the correct IUPAC name of the following structure
(A) 3-Amino-3-Bromo-5-oxocyclohexane-1-ol
(B) 3-Amino-4-Bromo-5-hydroxycyclohexane-1-one
(C) 5-Amino-4-Bromo-3-hydroxycyclohexane-1-one
(D) 2-Bromo-3-hydroxy-5-oxocyclohexan-1-amine
8. Arrange the following in increasing order of their acid strength

OH OH OH HO
NO 2
NO 2 NO 2
I II III IV
(A) I < II < III < IV (B) IV < III < II < I (C) I < II < IV < III (D) I < III < II < IV

9. Which of the following compounds show tautomerism?

(A) (B) O
HO NO
H2N C NH2
(C) CH3 − CH2 − CH = NH (D) O
H N
O N O
10. Identify the compounds which exhibit geometrical isomerism.

F H
(A) C C C C (B) H Me
C C C
H F
Br Et
Cl H
(C) (D)
N
Me
11. Which of the following is/are correct?

(A) CCl3 is more stable than CF3 .
O O
(B) Dipole moment of is greater than
Ph C Ph
(C) CH3 − C  N behave both as a nucleophile and an electrophile

(D) Hydration effect destabilize dimethyl ammonium in more than trimethyl ammonium ion.
12. Which of the following option is incorrect

(A) Staggard from is always more stable than Gauche form
COOH OH
OH
(B) is less acidic than COOH
H COOH H COOH
C C
(C) has less Ka1 than
C C
H NH2 H2N H
Br
(D) has zero dipole moment
CH2 CH2
Br

Correct.
1. Match the following: From the following flow chart:
Column – I Column – II (Property)

(A) H3C CH3 (p) shows geometrical isomerism
C
Cl
Cl
(B) H3C Cl (q) can rotate plane polarised light

C C C C
Cl CH3
(C) CH3 (r) has plane of symmetry
CH3
(D) (s) has chiral centres
(t) has sp carbon atom
2. Match the following: From the following flow chart:
Column – I Column – II
(A) (p) All C – atom are sp2 hybridised
(B) (q) Aromatic
(C) (r) Resonance possible
(D) (s) Diamagnetic
(t) Thermodynamically more stable than

benzene

inclusive).
1. How many structural isomers are possible for the molecule having molecular formula C 4H6?
2. How many compounds are stable after deprotonotion?
N (i) - (i) (iii) (iv)
(v) (vi) (vii) (viii)

N
-
+ H
(ix)
3. How many compounds are planar?
(i) H2C = C = CH2 (ii) H2C = C = C = CH2
(iii) H2C = C = O (iv) NC − HC = CH − CN

HOOC CN
SO3H
(v) (vi)
NO 2 F CN
Me Me
N
(vii) (viii) Me Me
(ix) (x)
4. How many compounds from following exhibit d-orbital resonance?

- +
NH3 PH3
− −
(i) CCl3 (ii) (iii) (iv) CF3
(v) PF3 (vi) Cl − O − Cl (vii) Br − S − Br (viii) ( SiH3 )3 N
(ix) SiH3NCO
5. How many alkens, from the following are more stable than ?
(i) (ii) (iii) (iv)
CH3 Et
Et
6. For the given compound X, the total number of optically active stereoisomers is________.
H3C HO
This type of bond indicates that the configuration
at the specific carbon and the geometry of the
double bond is fixed
This type of bond indicates that the configuration
H3C
HO
at the specific carbon the geometry of the double
bond is NOT fixed
Section – 3: MATHEMATICS
1. The number of ways in which 9 identical balls can be placed in three identical boxes is
9! 9!
(A) 55 (B) (C) (D) 12
( 3!) ( 3!)
4 3
2. Let A be the set of 4- digit number a1,a2 ,a3 ,a 4 where a1  a2  a3  a 4 , then n(A) is equal to
(A) 126 (B) 84 (C) 210 (D) none of these
3. On a railway there are 15 stations .the number of type of tickets required in order that it may be possible to
book for a passenger from every station to every other is ..
15! 15! 15!
(A) (B) 15! (C) (D)
2! 13! 13!2!
4. Number greater than 7000 and divisible by 5 that can be formed using only the digits 3, 5, 7, 8 and 9, no
digit being repeated is
(A) 46 (B) 48 (C) 72 (D) 42
5. Number of ways in which AAABBB can be placed in the squares of the figure as shown so that no row
remains empty, is
(A) 2430 (B) 2160 (C) 1620 (D) none of these
 1  1 1 n −1  1 1 1
6. nC1 −  1 +  nC2 +  1 + +  nC3 + ........ + ( −1)  1 + + + ..... +  nCn is
 2  2 3  2 3 n
1 1 1
(A) (B) (C) (D) none of these
n +1 n+2 n
( )
500
7. The number of irrational terms in the expansion of 4
9 +68 is
(A) 459 (B) 250 (C) 40 (D) 460
8. C30 + C13 + C32 + ... + Cn3 is equal to the coefficient of xpyq in the expansion of [(1 + x)(1 + y)(x + y)] n then p + q
=
(A) n (B) 2n – 1 (C) 2n – 2 (D) 2n

9. If  = x1x2x3 and  = y1y2y3 be two three digits numbers, the number of pairs of  and  can be formed so
that  can be subtracted from  without borrowing is
(A) 2!10!10! (B) (45) (55)2 (C) 32.53.112 (D) 136125
10. Let n be a ;positive integer with f ( n ) = 1!+ 2!+ 3!+ ........................... + n! and p(x) ,q(x) be poly normal in x
such that f ( n + 2 ) = p(n)f ( n + 1) + q ( n ) n  1 then
(A) p(x) = x + 3 (B) q(x) = -x -2 (C) p(x) = -x -2 (D) q(x) = x + 3
11. The number of ways of arranging the letters AAAAA, BBB, CCC, D, EE & F in a row if the letters C are
separated from one another is
12! 13! 14! 15! 13! 12! 13
(A) 13 C5 (B) (C) (D) − − C2
5! ( 3!) 2! 5!3!2! 5!3!
2
5!3!2! 5!3!3!2! 3!3!2!
12. The sum of the co-efficient in the expansion of (1 + ax – 2x2)n is

(A) +ve, when a < 1 and n = 2 k, k  N (B) –ve, when a < 1 and n = 2k +1, k  N
(C) +ve, when a > 1 and n  N (D) zero, when a = 1

Correct.
1.
Column - I Column – II
(A) The total number of selections of atleast one of (p) Greater than 50
the fruits which can be made from 3 bananas,
4 apples and 2 oranges is
(B) If 7 points out of 12 are in the same straight (q) Greater than 100
line, then the number of triangles formed is
(C) The number of ways of selecting 10 balls from (r) Greater than 150
unlimited number of red, black, white and
green balls is
(D) The total number of proper divisors of 38808 is (s) Greater than 200
(t) Greater than 300
2. Consider the word “HONOLULU”.

Column - I Column – II
(A) Number of words that can be formed using the (p) 26
letters of the given word in which consonants &
vowels are alternate is
(B) Number of words that can be formed without (q) 288
changing the order of vowels is
(C) Number of ways in which 4 letters can be (r) 840
selected form the letters of the given word is
(D) Number of words in which two O’s are together (s) 900
but U’s are separated is
(t) 144

inclusive).
1. Total number of ways cans three persons throw a die each to have total score of 11 is 9 n. then find value
of n....
2. The remainder when 22003 is divided by 17 is
10 10
n
3. The value of 
i=0 j=0
10
Ci 10 C j −  10 Ci 10 C j is n Cr then the value of   is
i j r
4. If the number of ordered triplets (a, b, c) such that L.C.M (a, b) = 1000, L.C.M (b, c) = 2000 and L.C.M (c, a)
= 2000 be N then sum of digits of N is/are _______________
5. Let N is the total number of four digit natural number beginning with 1, that has exactly two identical digits.
Then the sum of digits of N is ____________
6. The total number of integers between 1 and 3600 that are relatively prime to 3600 is q. The value of q – 950
is (where a, b are relatively prime if LCM of a and b is ab) ________
FIITJEE
MONTHLY ASSESSMENT
PHYSICS, CHEMISTRY & MATHEMATICS
CM – TEST – IV [BATCHES – 80]
Answer Key
PHYSICS (SECTION – I) CHEMISTRY (SECTION – II) MATHEMATICS (SECTION – III)
1 C P111205 1 B C111302 1 D M111216
2 B P111209 2 D C110308 2 C M111206
3 B P111209, P111220 3 C C110308 3 C M111206
4 C P111221 4 D C111402 4 D M111206
5 C P111208 5 B C111404 5 C M111215
6 A P111211 6 B C111304 6 C M110414

P111220,
7 A 7 B C111304 7 B M110410
P112324, P111209
8 B P111209 8 D C111302 8 D M110414
9 BD P111205 9 ABCD C111402 9 BCD M111206
10 ABC P111209, P112310 10 ACD C111403 10 AB M110414
11 ACD P112318 11 ABC C111301 11 AD M111224
12 ABC P112323 12 ABCD C111405 12 ABCD M110415

A – qs A–q C111403 A–p M111204
B – pr P112319 B – prt C111404 B – pqr M111211
1 1 1
C – pr P112312 C – pqs C111404 C – pqrs M111210
D – qs D – pq C111404 D–p M111214
A–q A – pqrs A–t M111206
C113612
B–r B – prs B–r M111206
2 P112313 2 C111801 2
C–s C – pqrs C–p M111210
C110308
D–p D–s D–s M111206
1 6 P111203 1 8 C111401 1 3 M111206
2 2 P111207 2 4 C111301 2 8 M110414
3 3 P112311 3 5 C113612 3 2 M110414
4 6 P111207 4 6 C113601 4 7 M111206
5 4 P112326 5 7 C111706 5 9 M111206
6 7 P112312 6 7 C111404 6 9 M111211
FIITJEE
MONTHLY ASSESSMENT
PHYSICS, CHEMISTRY & MATHEMATICS
CM – TEST – IV [BATCHES – 80]
HINT & SOLUTION
Physics
Single Correct
P
1. = const.
T
P0 P
=
T0 2T0
P = 2P0
P0A
2P0A
T
 T = P0 A
2. In process BC
du = ve and dw = −ve
Hence d is negative.
v2
w=  av dv
2
3.
v1
=
3
(
a 3
v 2 − v13 )
R ( T2 − T1 )
=
3
d K A dT
4. =− 0
dt a + dT dx
T
d 2
dT

dt 0
dx = −K 0 A 
T1
a + bT
R  330 R  3w
5. =
   
A + x A − x
2  2 
x = 2cm
6. u = a + bnRT
dv
= bnR = nCv
dt
Cp b +1
Cv = bR and Cp = ( b + 1) R   = =
Cv b
7. W = 2P0 V0
15P0 V0
Qin = 3P0 V0 +
2
21
= P0 V0
2
W 2P0 V0  2 4
= = =
Qin 21P0 V0 21
8. Work done by all the forces on the system is zero.
Multi Correct
9. PV 2 = const.
PV.V = const.
nRT.V = const.  TV = const.
10. Work done by the gas

Vf
W = RTIn
Vi
P
11. = const.
V
Ti = 300K
Tf = 1200K
T = 900K
W =  Pdv = 900R
dv = 2700R
d = V + W = 3600R
Qout Tout
12. = and Qout = Qin + W
Qin Tin
 TL 
Qin = W  
 TH − TL 
Qin ( TL )
=P
t ( TH − TL )
Matrix Match
1. If volume of the gas decreases, work done by the gas is negative and if volume of the gas increase, work
done by the gas is positive.
2. Final pressure of both the part will be same and the gas in the right part of the piston follow adiabatic
process.
Integer
1. l2 − l1 = l0 − l0  + t l0  2 − l0  l 
By the condition given in the question,
l2 − l1 = l0 − l0
l01
 t l0 2 − l01  = 0  l0 =
2
l0 = 60cm
2. U = 600 − 150 = 450 J

450 450  (  − 1) 450 ( 5/3 − 1) 300
 T = = = =
mcv nR nR nR
 molar specific heat
Q 600
C= =  R = 2R
nT 300
3. W = P0V = P0V0
and U = 2P0 ( 2V0 − V0 ) = 2P0V0
 Q = W + U = 3P0V0
4. Let initial pressure, volume, temperature be P0, V0, T0 indicated by state A in P–V diagram. The gas is
then inochorically taken to state B (2P0, V0, 2T0) and then taken from state B to state C (2P0, 2V0, 4T0)
isobarically. P
2T0 4T0
Total heat absorbed by 1 mole of gas 2P0
B
B
= Cv(2T0 – T0) + Cp (4T0 – 2T0)
P0 T0
5 7 19 A
= R T0 + R × 2T0 = RT0
2 2 2 V
V0 2V0
Total change in temperature from state A to C is
T = 3T0
19
RT0
Q 19
 Molar heat capacity = = 2 = R.
T 3T0 6
5. 4
Let  be the heat generated per unit volume per sec.
4  dT 
  r 3 = k 4 r 2  − 
3  dr 
dT  r
− =
dr 3k
wr 2
T =− +C
6k
At r = R, T = 20 C
0
 R2
TC = 20 + = 400 C
6k
6. 7
2
v 3
v2
w =  v dv = 2
= 7  105 J
v1
3 1
Chemistry
Single Correct
1. (III) is most basic (I) is least basic because of strong (-I) effect.
2. All atoms have complete octet structure.
3. Due to SIR effect.
4. Cl Exchange of both – Cl will produce same molecule.

Cl
Cl e-mail – info.patna@fiitjee.com , website: www.fiitjee.com
5.
*
* *
6. O
H
C O
H O
1 2 3 H H
HO C CH2 CH2 OH H
H H
O H H
H
7. Br
HO 4
NH 2
5 3
6 1 2
8. Apply SIR and mesomeric effect
Multi Correct
9.
(A) H O N O O N OH
(B) H2N C NH 2 H2N C NH
O OH
O OH
(D) H N
N
O N O
HO N OH
H
10. F H H H
(A) C C C C and C C C C
H F F
Trans cis F
Cl H H
N N
(C) and
Me Cl Me
(D) has 4 geometrical isomers.
− −
11. (A) CCl3 is more stable than CF3 due to p − d resonance. -
O O
O
|| +
(B) Dipole moment of is greater than Ph − C − Ph due to aromatic nature as
(C) CH3 − C  N : ⎯⎯
→ Doner
H3C C N
-
Nu
+ +
(D) Hydration effect stablises ( CH3 )2 NH2 more than ( CH3 )3 NH.
12. (A) Gauche form is more stable when intramolecular H – bond exists.
(C) H COOH is more acidic than H COOH
C C
C C
H NH 2 H2N H
Matrix Match
13. A → q; B → p, r, t; C → p, q, s; D → p, q.
14. A → p, q, r, s; B → p, r, s; C → p, q, r, s; D → s.
Integer
15. CH3 CH2C  CH, CH3 − C  C − CH3 , CH2 = CH − CH = CH2

CH3 CH2
CH3 , , ,
16. (I), (III), (IV) and (V) become aromatic after deprotonation.
17. (II), (III), (IV), (VI) and (IX) are planar molecule.
18. (I), (III), (V), (VI), (VIII) and (IX) exhibit d – orbital resonance.
19. (II), (III), (IV), (V), (VI), (VII) and (IX) are more stable.
OH OH
20. OH
H H
H Pe Pe
Pe HO HO
HO H
H H
OH OH
OH
HO HO
HO Pe
H Pe H
H Pe
H H
H
(optically active) (optically active)
(optically active)
OH OH OH
H H H
Pe Pe Pe
HO HO HO
H H H
OH H H
Pe
HO HO HO Pe
H Pe H H
H OH OH
(optically active) (optically active) (optically active)
OH
H
Pe
HO
H
where Pe represents n - pentyl.

H
Pe
HO
H
OH
(optically active)
Mathematics
Part – A
Single Correct
1. 9=0+0+9=0+1+8=0+2+7=0+3+6
=0+4+5=1+1+7=1+2++=1+3+5
=1+4+4=2+3+4=2+5+2
=3+3+3
10  9  8  7
2. C4  1 =
10
= 210
4  3  2 1
3. C2  2
15
4.
4 digit nos 5 digit nos
5 5
3 3 2 4 3 2 1
18 24
18 + 24 = 42
5. Two rows having one black only have two cases

(A) both letters are same &
(B) both letters are different.
 1 1 1 n
Tr = ( −1)
r −1
6.  1 + 2 + 3 + ... + r  Cr
 
1
 ( −1) (1 + x + x )
r −1
Tr = 2
+ ... + x r −1 nCr dx
0
500 500
 41 1
  1 1

7.  9 + 86  =  3 2 + 22 
   
500 − r
500  1 r
General tern = Cr .  3 2  .2 2
 
 500 − r  r 
   
= 500Cr .3 2 .2 2 
500 – r & r should be even
Multi Correct
9. y1 > x1; y2 > x2 & y3 > x3
10. let p(x) = ax + b & q(x) = cx + d

& get a, b, c & d by coefficient comparison
11. total arrangement – A & ‘C’ are together

Exactly 2 ‘C’ are together
12. sum of coefficients = (1 + a – 2)n

= (a – 1)n
Matrix Match
1. (A) (3 + 1)(4 + 1)(2 + 1) – 1 = 59
12  11 10 7  6  5
(B) 12
C3 − 7C3 = −
6 6
= 220 – 35 = 185
(C) x1 + x2 + x3 + x4 = 10 xi  0
(D) 38808 = 23.32.72.11
Total no. of divisors = (3 + 1)(2 + 1)(2 + 1)(1 + 1)
= 4  3  3  2 = 72
2. Arrangement of (p + q + r) objects in which p are alike of kind 1, q are alike of kind 2 & r are alike of kind 3
is
(p q + r )
p!q ! r !
Integer
1. 11 = (1 + 5 + 5) = (1 + 4 + 6) = (2 + 4 + 5) = (2 + 3 + 6)
2. 22003 = 23 (24)500 = 23[17 – 1]500
( )
10 18 10
 Ci .10C j −  10Ci .10C j = 

2
10 10
3. Ck
i =0 j =0 ij k =0
4. LCM (ab) = 1000 = 23  53

So ab = 2k1 + 3.5 k2 + 3
3!
5. 10
C3 .3!+ 10C2 .  2 = 1080
2!
6. 3600 = 24 . 32 . 52
So, q = 3600 – numbers divisible 2 or 3 or 5

Test

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MONTHLY ASSESSMENT TEST (IIT-2020)

FIITJEE MONTHLY ASSESSMENT

Time Allotted: 3 Hours Maximum Marks: 240

B. Filling of OMR Sheet

Name of the Candidate :__________________________________________

Batch :___________________ Date of Examination :___________________

Enrolment Number :______________________________________________

1. A cylindrical tube of cross – sectional area A has two

(A) 4 P0A (B) P0 A/2 (C) P0A (D) 2P0A

2. An ideal monoatomic gas is undergoing a cyclic P

Space for Rough Work

7. A ideal monoatomic gas is carried around the cycle P

8. An ideal monoatomic gas is confined in a horizontal

Part A – (ii): (One or more options correct Type)

9. An ideal gas example in such a way that PV2 =

12. A room air conditioner is modelled as a heat engine

Part B – (iii): (Matrix Match Type)

1. A monoatomic ideal gas is taken through a cyclic P

2. A non – conducting, movable piston separates a non

Space for Rough Work

Part C (Integer value correct Type)

Space for Rough Work

1. The correct order of decreasing basicity of the compound is:

2. The most stable resonating structures of following compound is

Space for Rough Work

6. Which of the following is not true for

(A) It's IUPAC name is 3-Hydroxypropanoic acid

7. What is the correct IUPAC name of the following structure

8. Arrange the following in increasing order of their acid strength

Space for Rough Work

Part A – (ii): (One or more options correct Type)

9. Which of the following compounds show tautomerism?

(C) CH3 − CH2 − CH = NH (D) O

10. Identify the compounds which exhibit geometrical isomerism.

11. Which of the following is/are correct?

(C) CH3 − C  N behave both as a nucleophile and an electrophile

12. Which of the following option is incorrect

Part B – (iii): (Matrix Match Type)

1. Match the following: From the following flow chart:

Column – I Column – II (Property)

(B) H3C Cl (q) can rotate plane polarised light

(C) CH3 (r) has plane of symmetry

(D) (s) has chiral centres

(t) has sp carbon atom

Space for Rough Work

2. Match the following: From the following flow chart:

(B) (q) Aromatic

(C) (r) Resonance possible

(D) (s) Diamagnetic

(t) Thermodynamically more stable than

Part C (Integer value correct Type)

2. How many compounds are stable after deprotonotion?

N (i) - (i) (iii) (iv)

(v) (vi) (vii) (viii)

Space for Rough Work

3. How many compounds are planar?

(i) H2C = C = CH2 (ii) H2C = C = C = CH2

(iii) H2C = C = O (iv) NC − HC = CH − CN

4. How many compounds from following exhibit d-orbital resonance?

(v) PF3 (vi) Cl − O − Cl (vii) Br − S − Br (viii) ( SiH3 )3 N

Space for Rough Work

(i) (ii) (iii) (iv)

Space for Rough Work

Batch :_ Date of Examination :_