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• Freestyle Photographic
RAW CHEMICALS & SUPPLIES
• B&H Photo
Before you can mix your own film and paper • Bostick & Sullivan
developers, stop bath, and fixer, you will need
some raw chemicals. I selected the formulas in If you know of other reliable sources that are not
this publication based on ease of mixing, listed, send me a note and let me know so that I
reliable formula, and ability to acquire the raw can update the list.
chemicals and some supplies.
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Black and white film developers typically consist Kodak’s commercial developer, D-76 undiluted
of three main components: developing agent or 1:1 is still the standard by which all other
(e.g., metol), alkaline agent/accelerant (e.g., developers are judged.3
borax) and a means to delay oxidation of the
D-76 falls into the solvent (fine grain) developer
developing agent (e.g., sodium sulfite).
category. This category of developers get their
Metol and hydroquinone are common black name because chemicals are used to reduce
and white developing agents. Metol is an the appearance of grain by dissolving some of
organic compound and a colorless salt. Metol is the silver grains in the film making them appear
known to be a good choice for continuous tone less grainy and smaller.
and has been widely used in commercial
With D-76H you can expect finer grain than a
formulas for many years before Kodak
non-solvent developer while still achieving full
discontinued it. Metol is a highly versatile
emulsion speed, excellent gradation and
developing agent and a standard that I keep in
shadow detail, with a slight penalty in
my darkroom. I use Metol in both film
sharpness.
developer formulas in this publication because I
like the results and it is one of the best eco- One of the important benefits of this formula is
friendly choices. that you will not be discharging hydroquinone
into the waste water and the environment.
FILM TESTING Google hydroquinone and you will understand
As with any film developer, it is important to why this is good.
know your proper film speed (EI) and
D-76 was introduced by Kodak in 1927 and was
development times in order to create high
a breakthrough in the movie industry. It was the
quality negatives whether you are printing in the
first fine grain developer that did not destroy
darkroom, scanning for digital editing, or both.
sharpness. Over 90 years later, D-76 is still the
If you want a simple and highly effective visual-
standard for all developers because film
based method for confirming your exact film
manufacturers won’t produce a film that won’t
speed and proper development times, I have a
perform well in D-76.3
video workshop that walks large format
photographers through the entire process. The current commercial formula for D-76
contains some unspecified agents that are used
D-76H FILM DEVELOPER for managing hard water, preserving the
The D-76H formula by Dr. Grant Haist is a very developer in the package, and increases its
versatile black and white film developer formula ability to dissolve when mixing. None of these
that is easy to make and provides reliable and additives are included or required in my opinion
consistent results. There are only three when mixing your own version of D-76H as a
ingredients. one-shot developer.
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sulfite dissolves a small amount of silver and Dissolve 2.5g Metol in a separate and clean
reveals the latent image on the film which graduate with distilled water and then add to
otherwise would not be available for main 1000ml beaker
development. The end result is an effective gain
Dissolve 100g Sodium Sulfite in a separate and
in film speed. It wasn’t until 50 years later that
clean graduate with distilled water and then add
researchers fully understood this principle and
to main 1000ml beaker
effect.
Dissolve 2g Borax in a clean and separate
The formula presented in this publication was
graduate using distilled water and then add to
the result of Dr. Grant Haist’s research. Haist
the main 1000ml beaker
eliminated the hydroquinone and increased the
metol by .5 gram to achieve indistinguishable Add chilled distilled water to the main 1000ml
results from the original formula. The pH levels beaker to make 1000ml at 20C.
will rise during storage, but are negligible
Tip: I keep a one gallon jug of distilled water in
because of the absence of hydroquinone. I see
this as a mute point because I only mix and use the darkroom refrigerator at all times for this
the developer on demand as a one-shot purpose.
solution and white you can store D-76H, I think D-76H Usage
this defeats the purpose of mixing your own
developer on demand as needed. The D76-H formula can be used as a stock
solution or 1:1. I personally use it as a one-shot
If you choose to store D-76H, the stock solution developer diluted at 1+1 because I believe I get
will last several months if kept in bottle filled to even better shadow detail.
the top and sealed with a tight cap and stored
at room temperature or a little below. To establish the correct development time for
your black and white film, you really should
The D-76H Formula properly test your film to identity the true film
• Metol - 2.5g speed (EI) and then validate (N) normal, (N+)
• Sodium Sulfite (anhydrous) - 100g expanded, and (N-) contracted development
• Borax (decahydrate) - 2g times.
• Distilled water to make 1 liter If you are a roll film user or you don’t need
accurate or repeatable results with your films,
You could think of D-76H as a Borax accelerated use the Massive Dev Chart development times
version of D-23. I share the formula for D-23 in for D-76 as a good starting place. Since D-76 is
the next section. the standard for all B&W film developers, the
Mixing Instructions technical information sheet for your specific film
will have a suggest development time. A good
Heat 500ml of distilled water to 52C/125F in a strategy is to rate your roll film at two-thirds or
clean 1000ml+ graduate
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one-half box speed and develop for 10% less D-23 creates negatives that allow you to print
than the suggest time. brilliant highlights with open shadows.
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your film per the manufacturer technical placed in Solution B while the low values
information sheet. (shadows) continue to develop.
I primarily use D-23 for negatives when I want I think that is incredibly useful and once you find
excellent separation of shadow values and your sweet spot with DD-23, you can create
brilliant highlights. expressive images that I believe you were
unable to create before.
I can use the divided-bath formula that includes
borax to increase contrast and density for my I like to use this method with large format sheet
platinum and AZO printing based on film in trays and also with Kodak Ektascan B/RA
development times in each bath. X-Ray film.
In the DD-23 formula, you add borax back into Developer (Solution B)
the formula, but separate it into a second tray
• Borax (decahydrate) - 2g
versus adding it to the core developer formula
• Water to make 1 liter
like in D-76H.
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Process to Make Solution B Based on the contrast of my negative being
developed, normal, expanded, or contracted, I
Dissolve 2g of Borax in 1000ml of distilled water
vary my times in Solution A and you will notice
heated to 52C/125F
that my time in Solution B remains constant at 3
Note: the amount of Borax in Solution B is a minutes.
topic of debate. I tested formulas ranging from
Below are my personal development times for
2g to 10g and I settled on 2g for my formula,
FP4+ and HP5+ using DD-23 in trays:
but I encourage you to investigate and conduct
your own tests. You have enough information in • Normal: 10 min in A + 3 min in B
this publication to conduct your tests and either • N+1: 12 min in A + 3 min in B
adopt my formula or make your own variation. • N+2: 15 min in A + 3 min in B
• N-1: 8 min in A + 3 min in B
DD-23 Usage
• N-2: 6 min in A + 3 min in B
I have found that my large format Ilford HP5+
and FP4+ sheet film develops to my satisfaction If you are trying to take full advantage of the
with DD-23. two-bath compensating effect (control
highlights and keep open shadows), then you
I frequently use HP5+ sheet film in my 8x10 and can explore minimal agitation in Solution B.
11x14 large format view cameras and FP4+ in
my 4x5, 5x7, and 8x10 cameras. This is to help ensure that development only
continues in Solution B where it was not
When I process my films in trays, either in my exhausted in Solution A (highlights).
regular darkroom, on in my film changing tent
when I am on the road. Most divided bath developers have the
developer in Part A and the accelerant in Part B.
For tent processing, I have three trays lined up Because of the amount of sodium sulfite in
(Solution A - Solution B - TF-3 Fixer). I have Solution A; your film is actually being
included the formula for TF-3 in this publication. developed without the need for an accelerator.
When I am working in my regular darkroom, I When you move your sheet film to Solution B
have another tray of distilled water to place the (borax), this is where the magical compensating
freshly developed negative into before moving effect happens because the developer agent
to the film washer. (metol) is quickly exhausted in the high values
If I am on the road, I just wash my films by (dense areas), and the lower values (shadows)
placing them in trays and letting them soak and will continue to develop. This is the entire
periodically agitate for about an hour until they reason I use DD-23 as a large format
are fully cleared. If I am in my darkroom, I have photographer.
a film washer that I use. This basically means that you are developing for
your high values in Solution A and shadow
values in Solution B.
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You can develop a single sheet of film or another period of time. Start with times in the
multiple sheets at a time using the shuffle range of 1 to 3 minutes and evaluate your
method. negatives.
Your agitation method will impact your After development, I move immediately to TF-3
development times and negatives, so keep this which effectively eliminates the need for a stop
in mind when establishing your development bath and hypo-clearing agent and also
times. significantly reduces my washing times. I can
even develop my negatives on the road in my
For normal and expanded development (N and
Harrison dark tent which makes this a very user
N+), I place a sheet of film in Solution A and
friend solution in my regular darkroom or in my
continuously agitate for the first 30 seconds and
mini-darkroom in my van.
then 5 seconds every 30 seconds for N
development and 10 seconds for N+1 until the
D-72 PAPER DEVELOPER
development time is completed for this step. I
D -72 is very similar to Dektol and can be used
slowly and gently rock my tray for the entire 3
minutes in Solution B. in the same way.
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• Hydroquinone - 6g For critic acid, add 4 teaspoons per liter of
• Sodium Carbonate - 17g distilled water.
• Potassium Bromide - 1.5g
Water as a stop is also an option, although keep
• Add water to make 1 liter
in mind an acid stop bath prolongs fixer life by
maintaining its acidity.
Add water to make one liter. Selectol is usually
mixed 1:1 (one part developer to one part
water)
FIXER
When you place your film or paper into the fixer,
If you are in search of an expressive print, you the first reaction is the conversion of unused
can use D-52 and D72 as a two-bath silver bromide into an insoluble and stable
development method. compound. When fixing is completed a soluble
Develop in D-52 for half your normal time and by product is formed (sodium
then in D-72 for the other half as a starting argentothiosulfate) that is removed by washing.
place. Until the 1970's the primary agent used for
To visually understand the impact on each of fixing was sodium thiosulfate, also commonly
your prints you can develop the first print in referred to as hypo. This is no longer
D-72, and then a second identical print in D-52, recommend to be used as your primary fixer. 3
and a third one using the two-bath method and You can also use ammonium thiosulfate to
then compare them. Over time, you will get a create a rapid fixer and this is my
feel for the differences and when to use this recommendation for films and as a first bath
method. fixer when you are toning for your archival
prints. Ammonium thiosulfate saves a lot of
STOP BATH processing time and eliminates the need for a
All of the stop bath formulas can be used with stop bath and hypo clearing bath.
film or paper.
Ammoninum thiosulfate is best used as a 60%
You have a couple options to pick from for stop solution and is the basis for the formulas in this
bath formulas. The easiest method is to use publication.
regular household white vinegar because it
I provide formulas for ATF-1, TF-3, and Agfa 304.
contains acetic acid.
ATF-1 Fixer Formula
Most vinegar comes at a dilution of 5% to 10%.
Read the label, then dilute to 3%, and you have Can be used on film and paper.
made a satisfactory stop bath. If you don’t like
• Ammonium thiosulfate, 60% solution 750.0 ml
the smell of vinegar, then you can purchase
citric acid from a photo formulary. • Sodium sulfite - 48g
• Acetic acid, glacial - 36 ml
• Boric acid, granular - 30g
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Mixing Instructions Usage: Fix paper for 3 to 5 minutes. Film should
be fixed for three times the clearing time.
Add the acetic acid slowly while stirring.
Dissolve the boric acid in some hot water in a TF-3 Rapid Fixer
separate container and then add this as the final
Can be used on film and paper.
element in the formula.
This is a good formula when used as a one-shot
Usage: Dilute 1:3 for film and 1:7 for paper. Fix
on demand formula and it is what I use the most
film for 5 minutes or twice the clearing time and
because it is simple to make, very effective, and
3 minutes for prints.
saves me a lot of processing time.
Agfa 304 Rapid Fixer
This formula is similar to Photographers’
Can be used on film and paper. Formulary TF-4. However, TF-4 is more
concentrated and slightly less alkaline. TF-4 has
This fixer makes use of sodium thiosulfate and
less ammonia odor as well.
ammonium chloride to form ammonium
thiosulfate in solution. To Make 1 liter of Stock Solution
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Dissolve 60g of Sodium sulfite separately into • Always wear disposable gloves and apron
distilled water and add to the main graduate. when handling chemicals.
• Only work in spaces with sufficient ventilation.
Dissolve 5g of Sodium metaborate in distilled
• A face mask and eye protection is strongly
water and add to the main graduate.
encouraged.
Add enough distilled water to the main • Immediately wash any body area contacted
graduate to make 1000ml by chemicals.
• Never eat, drink, or smoke while handling or
If you want to make a smaller volume of 1 liter using chemicals.
working solution, divide the formula above by 5. • Store all chemicals in a safe and cool area that
For example, use 160ml of the 60% Ammonium is dark and out of range for children.
thiosulfate, 12g of Sodium sulfite, 1g of Sodium • Chemical containers must be airtight.
metaborate, and water to make 1 liter of
working solution.
MIXING TIPS
Usage: Dilute stock solution 1+4 for either film
• All trays, measuring, and storage containers
or paper or mix the 1 liter working solution as
must be incredibly clean.
discussed above.
• Measure/weigh all of your ingredients in
If possible, use a 60-second plain water rinse or disposable cups/containers before mixing.
a minimum of 5 full changes of water before • Mix chemicals in the exact order in which they
placing film or paper into the TF-3 fixer. are listed in the formula.
• Completely dissolve and mix each solution
Fix films for 3 minutes, agitating for a full 30 completely before adding the next.
seconds during each minute. Continuous • After the last chemical in the formula is
agitation in a rotary processor is ok. dissolved, complete the formula by adding
Fix paper for 1 full minute with continuous distilled water.
agitation in a tray or rotary processor.
If you have any questions, contact me and I am
REFERENCE BOOKS happy to help you.
SAFETY TIPS
• All chemicals should be considered toxic by
default and treated with respect.
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FORMULA QUICK REFERENCE CHEAT SHEET
Metol - Sodium Sulfite - Borax - Hydroquinone - Sodium Carbonate - Potassium Bromide - Citric Acid
Sodium Metaborate - Ammonium Thiosulfate 60% - White Vinegar - Distilled Water
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