HINTS & SOLUTIONS

CHEMISTRY
1. Cinnabar is HgS

2. pH = 12
H   1012  pH   log H  
No. of moles of = M  V
= 1012  103  1015
No. of H ions = 1015  6.022  1023


= 6.022  108

3. Al2  SO4 3  H2O 

 Al  OH3  H2SO4
weak base Strongacid

So solution is acidic

Oxidation

7 3 4
MnO4  H  C2 O4 2  
 
 Mn2   CO2  H2O

4.

Reduction

Reduction
MnO4  8H  5e 
Mn2  4H2O  2
Oxidation
C2O24 
 2CO2  2e   5

2MnO4   16H  5C2O42 

 2Mn2  10CO2  8H2O

5. This process is based on difference in fusibility of the metal and impurities. When impurities are less fusible
than metal, metal, liquation is used

7. BF3 can accept a lone pair of electrons so it acts as a Lewis acid

10. CaCO3  SiO2  CaSiO3

Flux Gangue Slag

11. Reduction of metal oxide by carbon is known as smelting

12. Na  Cl

NaCl 
molten

At anode
2Cl 
 Cl2  2e
At cathode
Na  e 
 Na
pure metal

13. One of the objective of making alloy is to increase the resistance to corrosion

15. Duralumin (alloy of Al, Cu & traces of Mg and Mn) is used to make aircrafts pressure cooker

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MATCH THE COLUMN

PART-B
1. (i) Zn  H2O 
 ZnO  H2
Steam

(ii) Na2O  H2O  NaOH

(iii) F2  H2O 
HF  O2
(iv) Cl2  Al  AlCl3

Cl
Cl
Al Cl Al Cl
Cl
Cl

2. (i) CCl4 is a covalent compound which is insoluble in polar solvent

O
H2 O  H
(ii) H
H H

(iii) KCl  H2O  K   Cl

KCl conducts electricity in polar solvent due to formation of ions. It is a ionic compound, so has higher
melting point.
(iv) Graphite is a covalent compound which has high melting point and it is insoluble in polar solvent.

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MATHEMATICS
1. A
sec   tan   2
1 sin 
 2
cos  cos 
5sin2    sin   3  0
3
sin   1,
5
2. A
2tan 
tan2 
1  tan2 
45
Let   ,2  
2
2  22  4(1)( 1)
tan    2 1
2(1)
3. B
Apply basic proportionality theorem
Apply Pythagoras theorem to find AC.
Then apply basic proportionality theorem, i.e.,
CE/EB = CD/DA
4. C
Triangle PDR, QDP and QPR are similar.
Triangles AED and EFB are similar.
5. A
 ab 
loga  logb  logc  log  
 c 
and log1  0.
6. D
Adding 1 on both sides
and the 1 on the left side is expressed as logx  y (x  y) .
7. A
1
sin  
2
st nd
sin is positive in 1 and 2 quadrant only
 5 13 
sin   , , ,17 .
6 6 6 6
8. D
AB BD

AC DC
8 8x

7 7x
8x  7x  10
15x  10
2
x
3
16 14
BD  ,DC 
3 3
AI AC 21 3
  
ID CD 14 2
9. A
(1  2)(1  2)  (3  4)(3  4)  ......(49  50)(49  50)  512
 11  2......  50  512
50  51
  512
2

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 51 25
10 A
x
cot  
h
px
cot  
h
p
cot    cot 
h
1 1 p
 
tan  tan  h
p tan  tan 
h
tan   tan 
11 B
h
3
x
1 h

3 x  150
h
 h 3  150
3
150 3  2h  h  75 3  129.9  130
12 D
h  125 3
ht
sin30o 
hyp
1 75 3
  hyp  150 3
2 hyp
13. A
6 4
  x  4.5
x 3
14. B
10 BD

14 DC
10 x
  x  2.5
14 6  x
BD  2.5, BC  3.5
15. D
10 12  x
  x  18
6 x
PART-B
1. A  Q; B  R; C  P; D  S
2. A  S; B P ; C  R; D  Q

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PHYSICS
1. C P100307
q.V.B  mgcos 
q(0  gsin .t).B  mgcos 
mcot 
t 
qB
2. D P100307
From energy conservation
From P + 0 Q
V  2gRsin 
Force, equation into radial direction
mv 2
N  qvB  mgsin  
R
N  3mgsin   qB 2gR 

3. B P100208
Given resistance of each part will be

12 4
6 6


A 6 6 B A 6 6 B

A 4 6 B
Req = 10 

4. D P100210
P 4.5
Current in the bulb    3A
V 1.5
1 .5
Current in 1  resistance   1 .5 A
1
Hence total current from the cell i  3  1.5  4.5 A
By using E  V  ir  E  1.5  4.5  (2.67)  13.5 V
5. B P101606
o
Resistance of CDarm = 2r cos 72 = 0.62r
Resistance of CBFC branch
1 1 1 1  2 .62  A
i
     r r
R 2r 0 .62r r  2  0 .62  72°
B r C D r E
1 2 .62 1 .24 r
 R 
R 1 .24 r 2 .62 r r
1.24 r F H J
Equivalent R'  2 R  r  2  r
r
2.62 r
r r
 2 .48  G I
 r  1   1 .946r
 2 . 62 
Because the star circuit is symmetrical about the line AH
 Equivalent resistance between A and H
1 1 1 R' 1.946
   Req   r  0.973r
Req R ' R ' 2 2
6. B P100308
dB
As x increases so increases i.e. induced emf (e) is negative. When loop completely entered in the
dt
magnetic field, emf = 0
dB
When it exit out x increases but decreases i.e.e is positive.
dt
7. B P100307
mv
r= r P
qB
Particle excutes circular motion so direction of velocity changes so momentum is not constant.
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8. A P100206
2
Here, E  2V , 1   1 A and r  1
2
Therefore, V  E  ir  2  1  1  1V
9. C P101708
Presence of magnetic flux cannot produce current.
10. B P100307
11. C P100307
12. C P100307
Sol. 10 & 11
In magnetic field A
mv
R  1m
qB R
R/2
2m 300 600
T  0.2  P
qB 3
R/2 R
In electric field 2 R/2
qE
Acceleration a 
2
=10 m/s
m O
v 2 sin2 
Now, PA '  maximum height   3.75m
2a
 y-co-ordinate of A ' is 4.25 m
v sin  3
T'  time elapsed in E is half the time of flight  
a 2
T
 time t =  T '  0.97 sec
6

12. Here the proton has no acceleration so E  B  0.

When E  0 but B  0, but parallel to the motion of proton, there will be no force acting.
When E  0 and B  0 and E, B and motion of proton v  are mutually perpendicular, there may be no net
force. Forces due to E and B cancel each other.
13. C P100307
F  q v  B  or F  qvB sin

F will be maximum. when   90 o

14. D P100307
mv
R  50cm
qB

30
sin      370
50
x1  R(1  cos )  0.1m
15. D P100307

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1. (A) – P; (B) – Q; (C) – S; (D) – R P100206

E E i1-i3 E
On solving by KVL we get, i1  , i2  
R R
i3
E b R1
i3 
R i1 E i1-i2 Ei1
2E a R3
 i1  i2  and i1  i3  0 i2
R
R2
So reading of ammeter A1 is E/R = 4/3
A2 is 2E/R = 8/3, A3 is zero and Vab = 4V
2. (A)-R, (B) - P, (C) - S, (D) – Q P100307
(A) Initially an electric force acts on particle and after entering in magnetic field, a magnetic force acts on
particle. So correct option is (R)
(B) Electric and magnetic force acts on particle at 90º to each other so motion of particle is parabola.
(C) Magnetic and electric force act perpendicular to velocity of particle, so motion is parabolic
(D) Motion of particle is helical.

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