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Intense research in household cleaning offers more innovative Wirtschaftlichkeit, Umweltverträglichkeit sowie dem rückläufi-
cleaning solutions. Over the half of consumers worldwide favor gen Interesse an der Verwendung von traditionellen Flüssig-
functionality over \natural" and \multipurpose" claims in und Pulverwaschmitteln. Markenwert und -integrität erwiesen
Tenside Surfactants Detergents downloaded from www.hanser-elibrary.com by Hanser - Library on November 18, 2016
household care products. Due to rapid urbanization, emergence sich überraschenderweise ebenfalls als wichtig. Die Forschun-
of small pack size, current environmental pressures and price es- gen ergaben, dass viele Verbraucher Haushaltsgeräte mit gerin-
calation of petrochemical feedstock, the demand for sustainable gem Wasser- und Energieverbrauch bevorzugen. Da gemäß den
laundry and dishwashing products is developing rapidly. The Statistiken die Hälfte des Gesamttensidverbrauchs aus Haushalts-
user-centered researches revealed that the increase in per capita anwendungen, speziell der Haushaltswäsche und des Geschirr-
income and wide range of choices, greatly influence consumers spülens, stammt, wird erwartet, dass die auf natürlichen Pro-
interactions with products as expenditure for household laundry dukten basierenden und aus Biomasse erzeugten Tenside den
and increase the number of sophisticated consumers. Dish- Reinigungsmarkt weiter antreiben werden.
washing accounts for barely more than 0.5 % of total per capita
expenditure. Low energy as well as water consumption, high Stichwörter: Verbraucherverhalten, asiatische Verbraucherinter-
performance values are very important for the consumers when essen, europäische Verbraucherinteressen, amerikanische Ver-
purchasing automatic washing appliances. Multi-usability and braucherinteressen, Geschirrspülgewohnheiten, Grüner Trend
efficiency capture continuously the attention of the consumers bei Reinigen
For personal use only.
mestic labor, a gap between men’s and women’s average ducts or services [19, 20]. Thus, the significant factors that
time spent in unpaid work like home laundry and dishwash- have an influence on the consumer purchasing behavior
ing has decreased [2, 6, 7]. Thus it increases the demand of are personal (demographics), psychological (motives, aware-
significant change in the out-sourcing of domestic cleaning ness, knowledge, perception, personality, lifestyle, attitude)
services [7]. During the last 10 years, there has been an opti- and social (opinion, culture, reference groups) [21].
mization of the household washing processes in terms of Various models discussed the influences of the specific life-
energy and resource efficiency. In fact, the needs and expec- styles of consumer, production and consumption system and
tations of the consumers have recently been more diverse. psychological motives on household laundry and dishwash-
People spend less time doing household chores and concern ing and how they indirectly impact the usage of resources
themself less with performance differences of conventional [22, 23]. Figure 2 represents the Blackwell’s model of consu-
products [1, 8]. In general, the enormous increase in the en- mer decision making. This model was created to describe
vironmental awareness leads to new regulations on cleaning the increasing, fast growing body of knowledge concerning
product release management, energy and resource saving. consumer behavior and consists of four stages: viz input,
Particularly, the homecare sector has been increasingly regu- information processing, decision variables and variables in-
lated and tightened biodegradability requirements in the ac- fluence decision process. The inputs include marketing sti-
tive ingredients of washing detergents. While considering muli and other stimuli which include promotion, price, and
these constraints, cost is also an important factor and forces quality. The second stage is the information processing stage
Tenside Surfactants Detergents downloaded from www.hanser-elibrary.com by Hanser - Library on November 18, 2016
manufacturers for offering a cheaper alternative with satisfy- which includes attention, exposure, comprehension, accep-
ing properties without compromising their eco concerns. tance and retention. The information that they get through
That is, detergent companies are always looking for ways to these stimuli gets stored in their memory and they use it
improve the formula of household laundry and dishwashing for the decision making process which includes steps like
products as per the consumer needs. problem recognition, search of alternatives, evaluation of al-
Laundry washing and dishwashing have been among an ternatives, purchase, consumption and post consumption
individual’s important task in their day-to-day activities. De- evaluation which leads to satisfaction or dissatisfaction. The
tergents occupy an important role in those tasks. The surfac- variables influencing the decision process are classified as en-
tants detergents become an inevitable part in fabric care and vironmental influences and individual differences. In this
home care products. Surfactants are amphiphilic organic case, the environmental influences can be social class and
molecules, used in detergents, intentially added to achieve family influences and individual differences can be the moti-
cleaning, rinsing and fabric softening due to its relative sur- vation factor, knowledge, attitude and believes [8, 18]. It is
face active properties [9 – 16]. As the name itself indicated also evident that stresses on water conservation issues [22,
For personal use only.
the laundry care products intended to clean and treat cloth- 24], energy demand and related CO2 emissions also indirectly
ing, there are variations in their specific uses viz., laundry impact on consumer choices [25 – 28]. Pakula and Stam-
detergents, fabric softeners, bleach, fabric protector and spe- minger estimate that 20 000 000 000 m3 water and about
cialty products such as pre wash additives, fine washable de- 100 TWh of electricity are annually consumed worldwide for
tergent and starch. laundry washing in a washing machine. Also, the consumers
The laundry detergents formulated for washing clothes do not fully use the rated capacity of their washing machine.
typically contain detergent surfactants. The detergents are The measurement study shows that for an average washing
the cleaning formulations, which may not fully remove all machine capacity of 5 kg, consumers consider an average
of the stains, but produced clean stuffs while washing. To load of 3,7 kg to be a full load [22, 28].
improve the washing performance, builders (phosphates, Consumer preferences vary significantly from country to
carbonates, citrates, aminocarboxylates, organics, silicates, country particularly when it comes to detergent formats
polycarboxylates), bleaching agents, enzymes and fillers in and brand images [29]. It is decided by the ways by which
various proportions are added to the detergents [1]. The they wash their clothes/dishes [30]. Many parts of the world
cleaning products are available in a variety of packages in are still using hand dishwashing formats mostly liquids [24].
the form of powder, tablets, liquids or paste [17]. Understanding the dynamics that go through a potential
This review has been written to highlight the consumer customer’s thought process before a potential purchase to
behavior on household laundry and dishwashing. Better un- become a customer, will allow businesses to capture a share
derstanding of consumer behavior will help in developing of any market. By actively taking cognizance and developing
strategies for successful marketing and thus enhancing the strategies that allow a ’capturing’ of a potential customer, a
sustainability of home care sector. new business venture can obtain a larger client base and
brand loyalty, thus enjoying organic growth [1].
2 Consumer behavior/perception in homecare laundry/ The analysts forecast the global laundry cares market to
dishwashing grow at a CAGR (compound annual growth rate) of 5 % dur-
ing 2014 – 2019 [31, 32]. The country-wise analysis is given
Consumer behavior is defined as activities that people un- below.
dertake when overtaking, consuming and disposing of pro-
duct and services [17]. Consumer preferences and selection 2.1 Household laundry habits in various countries
towards a cleaning product are influenced by individual’s
moral values, ideological characteristics, philanthropic im- 2.1.1 India
pulses and sense of common destiny with family, clan, tribe,
ethnic group or other forms of community [18, 19]. More- The Indian consumer markets pose fascinating challenges.
over, consumer purchasing behaviors are not permanently The development of modern urban life style, rise of disposa-
fixed and often change over time depending on the purchas- ble income, economic growth and increase in consumer
ing trends of the consumers. Consumer purchasing behav- awareness have affected the buyer behavior in cities, towns,
ior, on the other hand, become the decision making process even rural areas [30, 31]. The Indian purchase of washing
and physical, mental and emotional activities involved while products are mainly determined by price, quality, fragrance
selecting, purchasing, using and disposing of either pro- and promotion [1, 32].
India is a country with a population of 1 030 million peo- graphic studies revealed that consumers from Indian cities
ple. According to the study reports, India is set to grow into prefer more sophisticated, branded products whereas low/
the fifth largest consumer market in the world by 2025 with middle income consumers prefer unbranded or low priced
$1.5 trillion value worth detergent industry [1, 32]. In India, brand products. Consumers from the region of low levels
people belonging to different income levels and rural con- of urbanization need economy brands. Affluent urban con-
sumers constitute of 70 % of population used different sumers are open to trying new products – automatic deter-
brands and formats. Fabric care and wash market have a gents and consumers of high level of education who have
very promising future in India, with the growing population product awareness prefer mid priced premium products for
and rising income levels of the middle class consumers their laundry uses [33].
[1, 32, 33]. According to India News Network Digest, 1994, Growing awareness about hygiene and healthy living has
in those earlier days, Indians prefer the bar format over the led to high demand for laundry care items. They are not
powder since they felt the rubbing action is essential for ef- only used for cleaning clothes but also used to prevent fab-
fective cleaning. The simple shift at the more traditional end rics from being damaged. The demand for liquid detergent,
of the laundry market, away from bar soaps to more sophis- fabric conditioners and fabric softeners has increased across
ticated hand washing detergents, is a small but important the world [1]. Indian consumers generally associated heat
indicator of India’s consumer revolution [1]. The consumers with hygiene and thus only washed clothes in hot water
Tenside Surfactants Detergents downloaded from www.hanser-elibrary.com by Hanser - Library on November 18, 2016
can spend more part of their disposable income in keeping when someone was ill. Also, according to Euromonitor In-
their clothes clean by using different products that are ternational (2013), almost 73.8 % of consumers in India are
offered by the fabric care and wash market. Detergent using LDP (Laundry detergent powder) for both hand and
brands in India are continuously upgrading their products machine wash. The detergent market in India is expected
to cater the increasing demand of quality washing powders to have a growth rate of 7 – 9 % per year in terms of volume
such that they could offer a host of benefits in a single [1].
wash [1]. The Indian washing powder markets in 2010 was The detergent market in India is divided into three seg-
3,364 000 tones. The Indian rural demand for washing pow- ments viz., premium, mid-range and popular. The market
der has increased by 83 % in last ten years [1, 33]. The info- share of the detergents in the premium segment is 15 %
For personal use only.
and that of the mid-range and popular are 40 % and 45 % re- European Union [35]. These detergent formats are widely
spectively. These detergent brands are considered organized preferred because of their convenient use with front-loading
players in the industry and comprise 60 % of the total mar- washing machines since the number of households owning
ket. The remaining 40 % of the market is saturated with re- washing machine still increasing in European countries. In
gional and small unorganized markets [1, 32, 33]. Larger ci- fact, the statistical studies revealed that the washing ma-
ties have a higher penetration of washing machines. But chine ownership of households in Europe is almost 100 %
Urban India accounts for only 33 % of the population and [36]. The trend of lower wash temperatures has given rise
27.5 % householders own a washing machine. Moreover al- to an increase in liquid detergents or powder detergents
most all washing machine owners generally choose short with high solubility. Some powders without water-insoluble
washing cycles to save time and effort [33]. There is still little zeolite, have also minimized solubility problems at lower
gaps in Indian laundry knowledge i. e., hand wash deter- temperatures.
gents are also used in washing machines [1, 33]. Moreover, consumer survey report from ten European
countries (Czech Republic, Denmark, France, Sweden, Hun-
2.1.2 Malaysia gary, Finland, Italy, Spain, Poland and Germany) covering
almost 75 % of the population revealed a very high level of
Based on the current recorded Malaysian population of awareness of the consumer towards the environmental as-
29.91 million, the calculated market size for laundry deter- pects [37].
Tenside Surfactants Detergents downloaded from www.hanser-elibrary.com by Hanser - Library on November 18, 2016
preferred format for laundry detergent although there is an coin operated Laundromats – an expensive alternative to pri-
increasing market pressure from liquid detergents due to vate ownership of washers and dryers – because the pur-
economic reasons. Generally, in Asia, the evolution in the chase of washers and dryers requires larger sums of disposa-
detergent consumption habits and improvement in the stan- ble income and/or access to \credit."
dard of living due to modernization are the contributing fac- In the last ten years, liquid detergents in the United
tors that drive significant growth in the laundry detergent States have grown to their almost 70 % market share and
business [1]. this volume has triggered changes in surfactants usage.
Alkyl ether sulfate (AES) consumption is increasing more
2.1.3 China rapidly than any other surfactant including linear alkyl sul-
fonate (LAS). The trend in the part few years might be due
China’s demand for Laundry Care Products has grown at a to the federal legislation on low – water use efficiency stan-
fast pace in the past decade. In the next decade, both pro- dards for residential washing machines. Two surfactants,
duction and demand will continue to grow [1]. The Chinese methyl-branched alkyl sulfate (AS) and so-called modified
economy maintains a high speed growth which has been LAS (MLAS), were developed and will meet the demands of
stimulated by the consecutive increases of industrial output, U.S consumers. Methyl-branched AS was developed to im-
import & export, consumer consumption and capital invest- prove detergency and especially to dissolve powder deter-
ment for over two decades. The most commonly used pro- gents quickly [35].
duct for laundry is detergent powder viz. 67 % use it in the The market for green household cleaning products in the
machine and 54 % use it for hand wash, followed by 34 % U.S grew at a blistering pace between 2007 and 2010, cooled
liquid detergents for machine wash and 34 % bars for hand off, and actually declined from 2010 to 2014 at a compound
washing [34]. The least popular choice for both (machine annual growth rate (CAGR) of 2 %. Packaged Facts estimates
wash and hand wash) is a 2-in-1 detergent and fabric condi- total retail sales, including both household cleaners and
tioners. Generally, infant and children clothes are hand laundry products, at $600 million in 2014. The green market
washed and pre-treated and delicate materials like wool are remains a niche, accounting for about 3 % of the total house-
pre-rinsed while machine wash. In China, still hand wash- hold cleaner and laundry product market [38].
ing is more common than machine wash. Moreover, Chi-
nese consumers require some safety, healthy, potential solu- 2.1.6 Japan
tion for removing stains and prefer washing products to
avoid excessive rubbing [34]. Since the first concentrated powder detergents was launched
in 1987 in Japan, concentrated powders have consistently
2.1.4 Europe played a leading role, especially for the past 10 years [35].
These seems to have been almost no change in product form
In Western Europe, detergents in the form of liquid are very segments but surfactant-wise, a major change occurred
popular than powders which is indicated by its expanding around 2001. The new millennium saw a new generation
shares. Tablets and sachets are relatively new product for- of powder detergents suited to new washing machines de-
mats in the market but they are highly preferred and suc- veloped to save time, water and used low mechanical force
cessful in the United Kingdom and other countries in the for less damage to clothes. This movement resulted in sig-
[1, 35]. The solubility of powders is regarded as the driving our bodies, we are very open to the possibility of absorbing
force behind the trend towards liquid detergents. In 2001 these substances through the skin. Cell membrances absorb
and 2002, two new technological solutions were introduced selectively electrically charged material. However, cell mem-
to improve powder detergent solubility in the Japanese and branes will absorb oily, non-polar substances simply through
the U.S. markets [35]. contact. The studies on the actual interaction of surfactant-
The first is the development of new manufacturing pro- detergents, at the cellular levels reveals that when surfac-
cesses to make quick-dissolving particles infused with high- tants are applied to the skin but then later washed off, not
er contents of alcohol ethoxylate (AE) [35, 39, 46]. By these all of the surfactant is removed. These substances do not
new manufacturing processes, the highly porous detergent merely adhere to the surface of the skin but in time they pe-
particles are produced with AE. In addition they can retain netrate it and eventually penetrated deeper layers to the liv-
lots of liquid surfactant without adding any oil-absorbent ing cells. Thus, the consideration about the toxicity of sur-
materials. Thus, facilitate superior washing results with factants and other non-polar molecules which are part of
higher solubility and by the reduction of the total formula- the laundry detergents have been increased tremendously.
tion amount of surfactants [1, 35, 39]. But, AE can work Sugar-based surfactants are a class of renewable derived sur-
more effectively in powders than in liquid detergents. face active molecules and some of them viz., alkyl poly-
Second is the modification in the hydrophobic group of glucosides (APGs) outperform traditional ones such as SLS
Tenside Surfactants Detergents downloaded from www.hanser-elibrary.com by Hanser - Library on November 18, 2016
conventional anionic surfactants in order to decrease the and sodium lauryl ether sulphate on mildness [47 – 49], es-
Krafft point and to increase the detergent solubility. i. e., In sential oil solubility [49 – 51], cleaning ability at lower con-
2002, methyl-branched alkyl sulfates with these longer alkyl centration[52 – 54], higher foam [49], lesser irritations [54,
chains were introduced in the U.S. which results in the im- 55].
provement of hard water tolerance and solubility [35, 46].
This substitution allows for the increase of the surface active 3.1 Sustainable consumers and household laundry/
2-phenyl body ratio, which has a relatively high Krafft point. dishwashing
The laundry detergents be used very frequently includes
brighteners and fragrances. These are suspected toxins. Be- According to industry reports, the biodegradability of surfac-
cause detergents contact our clothing, and clothing contacts tants used in household laundry/dishwashing are adequate
For personal use only.
Figure 4 The opinion of consumers from various countries (Australia, New Zealand, China, Hungary, United States, Russia, Latin America, Japan, Korea and
Middle East) regarding the way of cleaning dishes (hand or dishwasher) to achieve better cleaning results and lesser water and energy consumption [43]
when the sewage is properly treated. Even then also, some of consumers have concerns towards environment [1, 42, 43].
the anionic surfactant molecules still under use will indeed Based on the survey conducted by Accenture in 2010, the
pass through the sewage treatment process unchanged percentage of the consumers who would to pay extra for
[1, 35]. These molecules are not necessarily benign in nat- green products is 98 % in China and in India, it is 84 %.
ure, and all have been shown to exhibit toxic effects at suffi- The recent AOCS survey from 2012 supports this issue as
cient concentrations [35, 39]. Anionic surfactants, the major well. All these surveys reveal the consumers’ willingness to
cleaning agent in most laundry detergents are not generally purchase green products even in higher prices.
absorbed by inorganic solids. Cationic surfactants, on the
other hand, are strongly absorbed by solids, particularly 5 Conclusion
clays. There is also a significant degree of absorption of both
anionic and non-ionic surfactants in the activated sludge Growing awareness about hygiene and healthy living has led
and organic river sediments [54, 55]. It is a well known fact to a high demand for laundry care products. The move to-
that surfactants which contain branched hydrophobes are wards more sustainable products both in laundry as well as
not as easily biodegraded as the more common surfactants dishwashing becomes a global trend. There is an increased
which contain simple linear hydrophobes [50, 55]. Cationic demand for liquid detergents, fabric conditioners and fabric
surfactants with a branched hydrophobic part are mostly softeners across the world.
used as a fabric softener (di-hydrogenated tallow alkyldi-
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37. Heissler, H. and Lavemann, E.: Energy efficiency in domestic appliances and Dr. Rashmi Tyagi completed her Ph. D.in Chemistry in 1990 and obtained her-
lighting, Proceedings 5th International conference (EEDAL) 2009, Berlin, Ger- second Master and second Ph. D.in Chemical T echnology in 2003 and 2005 re-
many. DOI:10.2788/58128 spectively form HBTI Kanpur. She isworking as Assistant Professor, in Department
38. Euromonitor International. (2013) US consumer laundry study. Retreived from ofChemical Engineering,Jaypee University of Engineering & Technology, Guna Mad-
http://www.biosciences.dupont.com/file admin/userupload/live/ hya Pradesh, India since 2006.
Duppont-U.S-Laundry-Study-infographic.pdf
39. Tumadori, M.: Trends and technological development in laundry products in
Japan, Journal of Oleo Sci. 50 (2001) 367 – 373. DOI:10.5650/jos.50.367 D. Geetha completed her graduation and post graduation from Bharathidasan Uni-
40. Staps, F. and Betafib, M. C. F.: A novel structurant of renewable origin, 62nd. versity, Tiruchirappalli, Tamil Nadu. She has completed her M.Phil. from Annamalai
SEPAWA congress and European detergents conference, 2015, Fulda, University,Chidambaram,T amil Nadu. At presentshe is perusing her Doctoral pro-
Germany. gramme from Department of Chemical Engineering, Jaypee University of Engineer-
41. Ferrieux, S., Shulman, J. and Madrigal, L.: Biodegradable, low foam surfactants ing & Technology, Guna, M. P. India.
for automatic dishwashing applications, Conference of SEPAWA Nordic Sec-
tion, Malmo, Sweden 2013.
42. Brückner, A. and Stamminger, R.: Consumer-relevant assessment of automatic
dishwashing machines by a new testing procedure for automatic programmes,
Energy Efficiency 8 (2015) 171 – 182. DOI:10.1007/s12053-014-9284-4