Chem 10X Data Sheet

1 1. Periodic Table of the Elements 18 4. Formation Constants Kf

1
Values in brackets indicate the mass 2 Ag(CN)2– 1.3 x 1021
H He Ag(NH3)2+ 1.6 x 107
1.008 2 number of the longest lived or best 13 14 15 16 17 4.003
3 4 known isotope. 5 6 7 8 9 10 Ag(S2O3)23– 1.0 x 1013
Li Be B C N O F Ne Al(OH)4– 1.0 x 1033
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 Cd(CN)42– 6.3 x 1018
11 12 13 14 15 16 17 18
Cd(NH3)42+ 1.0 x 107
Na Mg Al Si P S Cl Ar
22.99 24.31 3 4 5 6 7 8 9 10 11 12 26.98 28.09 30.97 32.07 35.45 39.95 Co(NH3)63+ 1.0 x 1034
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Cr(OH)4– 4.0 x 1028
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Cu(CN)43– 1.0 x 1023
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.61 74.92 78.96 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Cu(NH3)42+ 2.0 x 1013
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Fe(CN)63– 1.0 x 1044
85.47 87.62 88.91 91.22 92.91 95.94 (99) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 Fe(CN)64– 2.5 x 1035
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 HgCl42– 7.7 x 1014
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Hg(CN)42– 3.1 x 1041
132.9 137.3 138.9 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 89 104 105 106 107 108 109 110 111 112 114 HgI42– 6.3 x 1030
Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Uuu Uub Uuq Mg(EDTA)2– 1.3 x 109
(223) (226) (227) (261) (262) (266) (264) (277) (268) (281) (272) (285) (289) Ni(NH3)42+ 7.9 x 107
58 59 60 61 62 63 64 65 66 67 68 69 70 71 Pb(OH)3– 7.9 x 1013
Lanthanide Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Zn(CN)42– 1.6 x 1020
series 140.1 140.9 144.2 (145) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Zn(NH3)42+ 7.8 x 108
Actinide Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Zn(OH)42– 6.3 x 1014
series 232.0 231.0 238.0 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)

2. Acid Ionization Constants @ 25°C (Kw = Ka Kb = 1.0 x 10–14) 3. Solubility Product Constants Ksp
Acetic acid 1.9 x 10–5 Hydrofluoric acid 7.0 x 10–4 AgBr 5.0 x 10–13 Co(OH)3 4.0 x 10–45
Ammonium ion 5.5 x 10–10 Hydrogen peroxide 2.2 x 10–12 Ag2CO3 8.5 x 10–12 Cr(OH)3 1.6 x 10–30
Anilinium ion 2.4 x 10–5 Hydroxylammonium ion 1.0 x 10–6 AgCl 1.8 x 10–10 Cu(OH)2 2.2 x 10–20
Benzoic acid 6.7 x 10–5 Hypochlorous acid 3.7 x 10–8 Ag2CrO4 1.1 x 10–12 CuS 6 x 10–36
Carbonic acid K1 4.3 x 10–7 H2S K1 9.0 x 10–8
K2 5.6 x 10–11 K2 1.0 x 10–15
AgI 8.5 x 10–17 Fe(OH)3 4 x 10–36
Chloroacetic acid 1.5 x 10–3 Methylammonium ion 2.5 x 10–11 Ag3PO4 1.4 x 10–16 Hg2Cl2 1.3 x 10–18
Citric acid K1 8.7 x 10–4 Nitrous 7.2 x 10–4 Ag2S 6 x 10–50 HgS 1.2 x 10–52
K2 1.8 x 10–5 Oxalic K1 6.0 x 10–2 Al(OH)3 2.0 x 10–32 MnS 3.0 x 10–13
K3 4.0 x 10–6 K2 6.0 x 10–5 BaCO3 5.1 x 10–9 Ni(OH)2 2.8 x 10–16
Dichloroacetic acid 5.0 x 10–2 Phenol 1.3 x 10–10 BaCrO4 1.2 x 10–10 PbCl2 1.6 x 10–5
EDTA K1 7.0 x 10–3 Phosphoric acid K1 7.1 x 10–3 BaSO4 1.1 x 10–10 PbO2 3.2 x 10–66
K2 2.0 x 10–3 K2 6.3 x 10–8 Bi2S3 1 x 10–97 PbS 7 x 10–28
K3 7.0 x 10–7 K3 4.2 x 10–13 CaCO3 4.8 x 10–9 PbSO4 1.6 x 10–8
K4 6.0 x 10–11 Pyridinium ion 5.9 x 10–6
Formic acid 2.0 x 10–4 Sulfuric acid K2 1.2 x 10–2
CaF2 4.9 x 10–11 Zn(CN)2 3.0 x 10–16
Hydrazinium ion 3.3 x 10–9 Trichloroacetic acid 2.0 x 10–1 Cd(OH)2 5.9 x 10–15 Zn(OH)2 3.6 x 10–16
Hydrocyanic acid 7.0 x 10–10 Trimethylammonium ion 1.6 x 10–10 CdS 2.0 x 10–28 ZnS 2.0 x 10–28
5. Pauling’s Electronegativities 6. Color Wheel

7. Spectrochemical Series
Strong field CO > CN– > NO2– > en > NH3 > NCS– > H2O > C2O4–2 > OH– > F– > NO3– > Cl– > SCN– > S–2 > Br– > I– weak
Strong field Co3+ > V3+ > Cr3+ > Fe3+ > V2+ > Fe2+ > Co2+ > Ni2+ > Mn2+
 10. Standard Enthalpy of formation (kJ mol–1). All elements ΔHf = 0
o
8. Standard Reduction Potentials (V)

Li+ + e– → Li –3.040 Br (g) 112 C2H4 (g) 52 NO2 (g) 33 Br– (aq) –122
K+ + e– →K –2.931 C (g) 717 C2H5OH (g) –235 N2O4 (g) 9 Cl– (aq) –167
Ca2+ + 2 e– → Ca –2.868 Cl (g) 122 C2H6 (g) –85 PCl3 (g) –287 CO32– (aq) –677
Na+ + e– → Na –2.710 F (g) 79 C3H8 (g) –105 PCl5 (g) –375 F– (aq) –333
Mg2+ + 2 e– →Mg –2.372 H (g) 218 CO (g) –111 PH3 (g) 23 I– (aq) –55
Al3+ + 3 e– → Al –1.662 I (g) 107 CO2 (g) –394 SO2 (g) –297 OH– (aq) –230
K (g) 88 HBr (g) –36 CCl4 (l) –135 S2– (aq) 33
2 H2O + 2 e– → H2 + 2 OH– –0.828
N (g) 473 HCl (g) –92 CH3OH (l) –238 SO42– (aq) –909
Zn2+ + 2 e– → Zn –0.762
Na (g) 107 HCN (g) 135 C2H5OH (l) –278 AgBr (s) –100
Cr3+ + 3 e– → Cr –0.744 O (g) 249 HF (g) –271 C6H6 (l) 49 AgCl (s) –127
Fe2+ + 2 e– → Fe –0.447 P (g) 315 HI (g) 26 H2O (l) –286 Cdiamond (s) 1.9
Cr3+ + e– → Cr2+ –0.407 S (g) 279 H2O (g) –242 H+ (aq) 0 KCl (s) –437
Cd2+ + 2 e– → Cd –0.403 CH3Cl (g) –81 H2S (g) –21 K+ (aq) –252 KF (s) –567
Co2+ + 2 e– → Co –0.280 CH4 (g) –75 NH3 (g) –46 NH4+ (aq) –133 NaCl (s) –411
PbCl2 + 2 e– → Pb + 2 Cl– –0.268 C2H2 (g) 227 NO (g) 90 Na+ (aq) –240 NaF (s) –574
Ni2+ + 2 e– → Ni –0.257
11. Absolute Entropy S° (J mol–1 K–1) at 25 °C
Sn2+ + 2 e– → Sn –0.137
Pb2+ + 2 e– → Pb –0.126 Cl2 (g) 223 BF3 (g) 254 C2H6 (g) 229 NH3 (g) 192
2 H+ + 2 e– → H2 0.000 F2 (g) 203 CH3COOH (g) 282 C3H8 (g) 270 NO (g) 211
Sn4+ + 2 e– → Sn2+ 0.151 H2 (g) 131 CH3OH (l) 127 C6H6 (g) 269 NO2 (g) 240
Cu2+ + e– → Cu+ 0.153 N2 (g) 192 CH4 (g) 186 CO (g) 198 N2O4 (g) 9
SO42– + 4 H+ + 2 e– → 2 H2O + H2SO3 0.171 O2 (g) 205 C2H2 (g) 201 CO2 (g) 214 PCl3 (g) 312
AgCl + e– → Ag + Cl– 0.222 Cgra (s) 5.7 C2H4 (g) 219 HCl (g) 187 PCl5 (g) 365
Hg2Cl2 + 2 e– → 2 Hg + 2 Cl– saturated 0.241 P4 wh (s) 164 C2H5OH (g) 283 HF (g) 174 SO2 (g) 248
Hg2Cl2 + 2 e– → 2 Hg + 2 Cl– standard 0.268 S8 red (s) 254 C2H5OH (l) 161 H2O (g) 189 SF6 (g) 292
Cu2+ + 2 e– → Cu 0.342
Cu+ + e– → Cu 0.521 o
12. Standard Gibbs Energy of formation (ΔGf in kJ mol–1)
I2 + 2 e– → 2 I– 0.536
O2 + 2 H+ + 2 e– → H2O2 0.695 Br (g) 82 C2H4 (g) 68 NO2 (g) 51 Br– (aq) –104
Fe3+ + e– → Fe2+ 0.771 C (g) 671 C2H5OH (g) –169 N2O4 (g) 98 Cl– (aq) –131
Hg22+ + 2 e– → 2 Hg 0.797 Cl (g) 106 C2H6 (g) –33 PCl3 (g) –268 CO32– (aq) –528
Ag+ + e– → Ag 0.799 F (g) 62 C3H8 (g) –23 PCl5 (g) –305 F– (aq) –279
Hg2+ + 2 e– → Hg 0.851 H (g) 203 CO (g) –137 PH3 (g) 25 I– (aq) –52
2 Hg2+ + 2 e– → Hg22+ 0.920 I (g) 70 CO2 (g) –394 SO2 (g) –300 PO43– (aq) –1019
NO3– + 4 H+ + 3 e– → NO g + 2 H2O 0.957 K (g) 61 HBr (g) –53 CCl4 (l) –65 S2– (aq) 86
Br2 + 2 e– → 2 Br– 1.087 N (g) 456 HCl (g) –95 CH3OH (l) –166 SO42– (aq) –745
Pt2+ + 2 e– → Pt 1.180 Na (g) 77 HCN (g) 125 C2H5OH (l) –175 AgBr (s) –97
MnO2 + 4 H+ + 2 e– → Mn2+ + 2 H2O 1.224 O (g) 232 HF (g) –273 C6H6 (l) 124 AgCl (s) –110
O2 + 4 H+ + 4 e– → 2 H2O 1.229 P (g) 278 HI (g) 1.7 H2O (l) –237 Cdiamond (s) 2.9
Cr2O72– + 14 H+ + 6 e– → 2Cr3+ + 7 H2O 1.232 S (g) 238 H2O (g) –229 H+ (aq) 0 KCl (s) –409
Cl2 + 2 e– → 2 Cl– 1.358 CH3Cl (g) –58 H2S (g) –34 K+ (aq) –284 KF (s) –538
Au3+ + 3 e– → Au 1.498 CH4 (g) –51 NH3 (g) –16 NH4+ (aq) –79 NaCl (s) –384
C2H2 (g) 209 NO (g) 87 Na+ (aq) –262 NaF (s) –544
MnO4– + 8 H+ + 5 e– → Mn2+ + 4 H2O 1.507
MnO4– + 4 H+ + 3 e– → MnO2 + 2 H2O 1.679
13. Bond Energies (kJ mol–1) 14. Miscellaneous Constants
Au+ + e– → Au 1.692
O N C S F Cl NA = 6.022 x 1023 mol–1
Ce4+ + e– → Ce3+ 1.720
H 463 391 413 368 563 432 h = 6.626 x 10–34 J s
H2O2 + 2 H+ + 2 e– → 2 H2O 1.776
C 358 305 346 272 489 328 c = 2.998 x 108 m s–1
F2 + 2 e– →2 F– 2.866 N 222 163 305 275 192 F = 96487 C mol–1
S–S 251 C=N 615 C=C 611 g = 9.807 m s–2
9. Water Vapor Pressure (torr)
S–F 327 C≡N 891 C≡C 825 q = 1.602 x 10–19 C
0°C 4.6 21° 18.7 30° 31.8 60° 149.4 S–Cl 271 N=O 607 C=O 749 RH = 2.178 x 10–18 J
5° 6.5 22° 19.8 35° 42.2 70° 233.7 Si–Si 176 Si–H 318 Si–O 452 R = 0.08206 L atm mol–1 K–1
10° 9.2 23° 21.1 40° 55.3 80° 355.1 = 8.314 J mol–1 K–1
15° 12.8 24° 22.4 45° 71.9 90° 525.8 1 atm = 760 torr = 101.3 kPa
20° 17.5 25° 23.8 50° 92.5 100° 760.0 1 cal = 4.184 J
TK = TC + 273.15