Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr.ICON ALL Date: 26-12-18
Time: 09:00 AM to12:00 Noon Max.Marks:360
KEY SHEET
MATHS
1 4 2 2 3 4 4 3 5 1

6 3 7 2 8 3 9 2 10 1

11 3 12 1 13 1 14 2 15 3
16 3 17 2 18 1 19 3 20 2

21 4 22 4 23 2 24 3 25 3

26 4 27 2 28 2 29 2 30 3

PHYSICS
31 1 32 2 33 3 34 4 35 1

36 1 37 2 38 2 39 3 40 3

41 4 42 4 43 1 44 3 45 3

46 2 47 4 48 3 49 2 50 1

51 3 52 1 53 3 54 3 55 1

56 4 57 3 58 2 59 3 60 4

CHEMISTRY
61 4 62 1 63 3 64 3 65 4

66 2 67 3 68 4 69 2 70 1

71 4 72 4 73 3 74 4 75 1
76 3 77 1 78 2 79 3 80 2

81 4 82 3 83 4 84 1 85 3

86 4 87 2 88 1 89 3 90 4
Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
SOLUTIONS
MATHS
7 7
3
1. x = a - x \ x is an integer \ a = r3 + r = 812
r =1 r =1
2. f x 4sin x - 7 in not continuous when 4sin x = 0,1,2,3,4
3. use AM - GM in equality
1 - log x
4. x2 dx . Now put
log x
=t
4 x
log x
-1
x
1 2 1 - x2
5. + x 2 x e- x dx = e dx
0 0

dy
6. Differentiating xy = 2 xy + x 2 \ d xy = 0
dx

7. Given curve is symmetrical about both the axis and y = x 1- x 2 cuts x - axis in
0, 0 , 1,0

8. Taking cross product with a , a r b =a c b and expand.

9. Standard problem

10. LHS = tan 4 x + cot 4 x + 1 3 \ y= , hence x

p p
2 4
11. Standard problem
12. P a, b, -c , Q -a, b, c , R a, -b, c
a b c
\G= , , \ A, o, G are collinear points
3 3 3
13. Using multinomial theorem coefficient of x 4 = 8085
14. Use KA = K 6 A as A is 6 6 and AdjA = A n-1
15. a + b = P, ab = -444. p = -22.3.37 p Then By inspection
a = 3.37, b = -4 p a + b = - p
3a + b a + b a + 3b 15
16. a, x, y, z , d are in AP xyz = . . =
4 2 4 2
1 1 1 1 1
a, x, y, z, f are in HP , , , , an in AP
a x y 2 f
3
32 ab 18
In this case xyz = = Multiplying ab = 27
a + 3b a + b 3a + b 5

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
2 3
17. a - 2, ar - 7, ar - 9, ar - 5 are in AP Solving r = -2, a = -3
18. Write the Truth table
18 18
2
19. Given xi - 8 = 9, xi - 8 = 45 .
i =1 i=1
18 18
2
d i
= 45, di = 9
i =1 i =1
1 2
Variance = di 2 - d
18
20. A - lost card , B - drawn card is spade
1 12
P A = ,P B / A =
4 51
P A P B/ A
Required Prof P A / B =
P A B/ A +P A P B/ A
7
21. Desired number = coeff . of x10 in x + x2 + x3
7
= coeff . of x3 in 1 + x + x 2

22. Verify R, S , T property

2
l1 m1 n1 1 0 0
23. D2 = l 2 m2 n2 = 0 1 0 = 1
l3 m3 n3 0 0 1
24. For DBoC , A is orthocenter etc. Find area of DABC
3
25. P is a point on the perpendicular bisector of BC and at a distance of BC = 15
2
\P 3,2 - 2, 3 or P - 3, 2 + 2 3 Use A and B an on the same side of BC

26. Draw the diagram It flows that MA.MP = MQ.MY

And MP.MB= MX.MQ
27. Centre is C 1 + r , o , r being the radius Eaution of circle is x - r -1 2 + y 2 = r 2
Equation of parabola is y 2 = 4 x subtracting and discriminate =0 r=4
28. Product of ^lr drawn from foci upon tangent is square of semi minor axis- b2
Distance between foci = 2ae.
29. x = cos q , y = sin q \ l = 2 cleanly from 2,0 , S11 < 0 . 2 tangents are possible

x4 x3 x2
30. Take f x = a +b +C + dx + e use Rolles MVT in -1, 0
4 3 2

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
PHYSICS
31. Q = CV
Q = 40 10-6 F
DQ DC DV
= +
Q C V
0.1 0.2 1 2
= + DQ = + Q
2.0 20 20 200
DQ = 2.4 10-6 F
2r 2r 2 10
32. V= t= = = 10sec
t V 2
33.
A K C

y
P
Q
q
l

D
M

l2 = k 2 + y2
dl dy
2l = 2y
dt dt
l dy dy u
= = Vm
y dt dt cos q
34. dW = Fdx
L
W= Fdx
o

ax 2 bx3 L
W= + |O
2 3

ax 2 bL3
W= +
2 3
AB
35. U=
r12 r 6
-

du u
F =- Hence U co ns tan t =0
dr r

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
1/6
2A
r=
B

36. F = -kx - L2 xsg

F = - K + L2sg x

3 d 2x
Lr 2
= - K + L2sg x
dt
d2x K sg
2
=- 3
+ x
dt rL rL

K sg
w= 3
+
rL Lr

1 K sg
n=
2p rL3 Lr
+

1 1 2K 2K
37. K= IW 2 K= LW L= L=
2 2 w 2pn
L1 K n L L
= 1. 2 =4 L2 =
L2 K 2 n1 L2 4

Gm 2
38. mrw2 =
r2
1 r3 4 w2 r
r 3a 2 r2 =
r23 w2 41/3
=
w

2 H -D
39. x =V t x = 2 gD
g

x = 2 D H -D
40. Number of divisions=- 100R
Number of divisions -70S
Number of divisions -75S
x2 > x3 > x4
1
41. Qcdd = Qhot 2000 20 + m 80 = 5000 1 20
2
80 m = 8 104 m = 1000 gm = 1kg
mice = 2 - 1 = 1kg
mwater = 5 + 1 = 6 kg

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
42. PV = nRT
105 30 = n1R 290

105 30 = n2 R 300

-3 105 10
n2 - n1 = 6.0231023
8.314 300 290

n2 - n1 = -2.5 1025

43. \ displacement s = o Q w = 0

I
44. T = 2p
M .BH

45. Bnet = o i12 + i22

m
2r
10% 10%
46. 100 90 81
decays decayes

1
47. 2 = w + mv2 - 1
2
hv 1
\ E = hv = Ea
l l
E2 100 4
= 1=
l
=
E1 l2 75 3
8 1 2 4
Q = w + m 2v 2 Q E2 = E1
3 2 3
Q From 1 & 2 w = 1.8w .
I
48. Q nd =
n. A.e
Total no of free electrons N = n A l
Total linear momentum P = N .m.vd
I
= n. A .l.m.
nA. e
I
Q l = 1m =l =I /S
e/m
49. F = E .q
V V
= .q 4.8 10-19 = 1.6 10-19 V = 15volt
d 5

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
50. Even through emf is induces in the copper ring, but there is no induced current
because of cut in the ring. Hence nothing opposes the free fall of magnet. Hence a = g
P P 1
51. QI= = 2
= e o Eo2C
A 4pr 2
2P P
Q Eo =
4pe or 2C 2pe o r 2C
=

52. Let ‘a’ be slit width , then YDSE for 10th maxima
10lD
X = 10b =
d
X 10l
But q1 = = -1
D d
2l
In single slit diffraction width of central maximam is q 2 = - 2
a
But q 2 = q1
2l 10l
Q =
a d
a = d / 5 = 0.2m
x 10 x
53. QC= V=
t1 t2
1 V 10t1
Q sin C = = =
m C t2

10t1
Q C = sin-1
t2
54. Q w = Q VD -VC

Q Vc = 0

q q q 1 1
VD = - = -
4pe o .3L 4peo L 4peo 3L L
\ w = QVD
55. T sin q = F
T cos q = mg
Q F = mgTanq
Eq = mgTanq
s q
= Tanq
2eo mg
saTanq

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
56. y = A. B + C = A + B + C = A + B.C
57. Population benefitted = Area P.d
= pd 2 population density
mv 2 max
58. Q T = mg cos q + ' T ' is maximum for q = O o
L
2
mvmax mr 2 w2
Q Tmax = mg + = mg +
L L
2
mr 2 g r
= mg + Q w= g / L = mg 1 +
L L L

59. From point of suspension at a distance ‘x’, weight is or tension T = m L - x g

QV = T /m = L- x g
dx dx
QV = = L- x g dt =
dt L- x g
o 0 O
dx 1 L-x
Qt= dt = = =2 L/ g
L- x g g 1/ 2
L L L
3l
60. Q e = BlV Qe= B XW .dx
2l
3l
x2 1
= B.W = BW . 9 l 2 - 4l 2
2 2
2l
5
= BW l 2
2
CHEMISTRY
61. CrZ = 24 1s 2 2s 2 2 p6 3s 2 3 p 6 4s1 3d 5 = 12
2 2 2 2 2 1 1

62. Dipole moment is a vector quantity

CH 3C l 1.94 D
CH 2C l 2 1.60 D
CHC l 3 1.03D
CCl4 'O ' D

63. One gram equivalent of oxygen = 8g

At STP 32g oxygen 22.4l 8 g oxygen 5.6 L

64. Heat of neutralisation is heat released when one gram equivalent of acid is completely

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
neutralized by one gram equivalent of base in dilute solution
65. The P H of buffer solution do not change upon dilution
66. NH 4 HS s NH 3 g + H 2S g

Units of Kc moel 2 L-2

Be Mg Ca Ba
67. Density g / cc
1.85 1.74 1.55 3.61

68. In Si-H bond, hydrogen with draws electrons and Si- Si bond is weakened. C-H bond
is almost non polar Hydrogen cannot – withdraw electrons . C-C bond is strong so
silanes are good readucing agents and not hydrocarbon
69. Serine HOCH 2 CH NH 2 COOH

70. Lower the PKa value stronger is acid

Inductive effect decreases as distance from source increases
71. 2 - oxopen tan al is CH 3CH 2CH 2 - C- C H
|| ||
O O
72. Basis Huckel’s rule
73. Bakelite and polysiloxanes are common thermo setting polymers
74. Ranitidine is an antihistamine. ranitidine can also be used as an antacid because of
presence of -NH - group in its molecule
75. Ag 2CrO4 Brick red precipitate
76. In tertiary butyl alcohol alkyl group is highly branched and hence almost approaches
spherical shape- As a result – non polar part of the molecule becomes less prominent
and hence it can have stronger intermolecular hydrogen bonds with water molecules
on the other hand n- butyl alcohol has predominantly non polar character
77. It is Tischenko reaction
78. X Ammonium phthalate
Y Phthalamide
Z 10 Amine
Follow Gabriel phthalimide synthesis
79. Thorpe reaction Nitrites containing a - hydrogen undergo self condensation much
like aldol condensation in presence of C2 H 5ONa to form b - lminonitriles. This on
hydrolysis give b - Keto nitriles

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Sri Chaitanya IIT Academy 26-12-18_Sr.ICON ALL_JEE-Main_GTM-3_Key & Sol’s
80. PH 3 NH 3 - 34.5 C
PH 3 - 87.5 C
AsH3 - 62.4 C
SbH 3 - 18.4 C
81. XeO3
82. Oxidizing power of halogens F2 > Cl2 > Br2 > I 2 The halogen which comes on top in
VIIA group should act as oxidizing agent
2+
83. Fe H 2O 6
sp3d 2
84. Siderite FeCO3
85. Compound X is urea
Isotonic solutions have equal osmotic pressure and same molar concentration
2 6
60 = M M = 180
100 100
1000 1000
86. ZEffective of carbon atoms in diamond cubic
=Z Effective in fcc unit cell + ZEffective in alternate tetrahedral voids
1 1
= 8 +6 + 1 4 =8
8 2
87. In a first order reaction time taken for 75% of reaction will be double when compared
to time taken for 50% reaction
88. Cr2O7-- + 14 H + + 6e- 2Cr 3+ + 7 H 2O one mole of dichromate = 6 moles of
electrons
= 579000 coulombs
One centi mole of Cr2O7- to Cr 3+ = 5790 columns
1
1 0.1 1 1
1
x x1 P1 n 2 = 10 n 1 1 n
89. = KP n n=3
0.2
= =
m x2 P2 80 2 8
2
90. Un known vessel known vessel
V1 = VL V2 = 4 L
P1 = Oatm P2 = 10atm
O V + 10 4 40
3= = = 9.3L
V +4 V +4
P 1V1 + P2V2
The average presence P of mixture of gases from two vessel P =
V1 + V2

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