Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 30-12-18
Time: 09:00 AM to12:00 Noon CODE-B Max.Marks:360
KEY SHEET
CHEMISTRY
1 2 2 2 3 1 4 1 5 1

6 4 7 1 8 4 9 3 10 1

11 2 12 1 13 4 14 2 15 1
16 4 17 2 18 4 19 2 20 1

21 4 22 3 23 1 24 3 25 3

26 1 27 1 28 1 29 3 30 4

MATHS
31 2 32 1 33 2 34 1 35 1

36 1 37 4 38 3 39 4 40 2

41 1 42 3 43 2 44 1 45 2
46 2 47 2 48 3 49 4 50 4

51 4 52 2 53 1 54 3 55 1

56 3 57 1 58 4 59 1 60 1

PHYSICS
61 4 62 2 63 1 64 3 65 1

66 2 67 4 68 1 69 2 70 3

71 3 72 2 73 2 74 2 75 4
76 4 77 4 78 3 79 1 80 4

81 4 82 3 83 4 84 1 85 3

86 3 87 2 88 2 89 3 90 1
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
SOLUTIONS
CHEMISTRY
1. BaSO4 has lowest solubility in water.
2. At constant pressure ,addition of inert gas equilibrium shift towards more volume

3. 3  2 1 6

4. ncert
5. Syn – addition take place.
 6. TeF6  H 2 O 
 H 2TeO4  HF
 SiCl4  H 2O 
 H 4 SiO4  HCl
SF6 & NF3 cannot
7. Glucose
8. stability of carbo cation
9. 1,2 and 4 are correct
10. Palladium complexes of the type  Pd  C6 H 5  2  SCN  2  and  Pd  C6 H 5  2  NCS  2  are
linkage isomers.
40  2  2  0.2 
11. At high P  P V  b   RT  T   1854 K
0.082
12. Anti – Markovnikoff’s addition take place (Peroxide effect operates).
13. Since oxide of the element A is ionic and basic, therefore, the element A can be alkali
metal (group 1 such as Na). Oxide of B is amphoteric, the element B can be from p 
block such as group 13 (All). The oxide of C is a giant molecule and can have a three
dimensional network solid such as SiO2 (C from group 14). Thus, elements A, B and
C have atomic numbers in the order:
14. Combustion of benzene is represented by
15
C6 H 6  l   O2  g  
 6CO2  g   H 2O  l 
2
15
Δn  6   3/ 2
2
From ΔH  ΔU  Δng RT
H  U  ng RT
3
ΔH  ΔU    8.314  103  300
2
3
3741.3  10  3.741

15. G 0  12  F  E 0  636.9kJ  637 kJ

16. Brass and gun metal contains Cu and Zn .

17. Bond length Li  Li  H  H (because Li atom is larger in size).
Further, Li2 has two electrons in the antibonding σ1*s with H 2 has none.
Hence, Li2 is less stable than H 2 .

Sec: Sr. ICON ALL Page 2

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
Boron  B has size inbetween that of H and Li . Bonding molecular orbitals than Li2 .
Hence, B2 is more stable than Li2 but less stable than H 2 . Thus, the order of stability
is H 2  B2  Li2 .
18.
O O
H2S2O7  HOS OS OH

O O

CH 2 NHCH 3

19.
2 2
20. Sulphides of Cu and Hg are precipitated in acidic medium.
21. Quartz is a three dimentional silicote.
22. On dilution number of ions decrease in unit volume hence specific conductance decreases. But
separation between ions also increase hence equivalent conductance increase.
23. La  OH  2 is more basic than Lu  OH  3
24. Ais acetylene and B is Benzene
25. ncert
26. Larger the hydrophobic fragment of surfactant, easier will be the micellisation, smaller
the critical micelle concentration. Therefore, CH 3 CH 2 15 N  CH 3 3 Br  will have the
lowest critical micelle concentration.

27. Central metal atom of chlorophyll is magnesium.

Central metal atom of blood pigment is iron.
Central metal atom of Wilkinson catalyst is rhodium.
Central metal atom of Vitamin B12 is cobalt.
28. The balanced redox reaction is
2 MnO4  5C2O42  16 H   2 Mn 2   10CO2  8 H 2O
29. Carboxylic acids
30. 350  500  B

350 7
XB  
500 10
Sec: Sr. ICON ALL Page 3
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
7 3
X A 1 
10 10

450  PA  350

PA  100

100  450 XA '

100 2
XA '  
450 9
PHYSICS
2 2
2 2  3 x  4 y  7 2 2  1 3x  4 y  7 
31.  5x  10   5 y  15  or  x  2   y  3  
2  or
4 5
1 3x  4 y  7
 x  2 2   y  3 2 
2 5
It is an ellipse, whose focus is  2, 3 , directrix is 3 x  4 y  7  0, and eccentricity is
1 3  2  4  3  7
. Length of perpendicular from the focus to the directrix is 5
2 5
a a 10
or  ae  5 or 2a   5 or a 
e 2 3
so, the length of the major axis is 20/3.
32. S  5,0 is focus  ae  5 ....1
9 a 9
x   ... 2
5 e 5
1   2  a 2  9
1   2
5
e
3

b  a 2 e 2  1  b 2  16
2

a 2  b 2  9  16  7
x 2  x  1 cot 1 x
33. Let I   .e dx
x2  1
Put x  cot t   cosec 2 t dt  dx
Now, 1  cot 2 t  cosec 2 t

 I 

et cot 2 t  cot t  1 
 cosec2 t dt 
2


1  cot t
   e  cosec t  cot t  dt
t 2

Sec: Sr. ICON ALL Page 4

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s


  et cot t  cosec2 t dt 
 et cot t  C
1 1
 e cot x  x   C  A  x  .e cot x  C
 A x  x
2
34. t1  t 
t
4
t12  t 2  2  4
t
4 4
t 2  2  2 t 2. 2  4
t t
Minimum value of t12  8
35. Since, intercepts are equal in magnitude but opposite in sign, therefore
 dy 
 dx   1
P
dy
Now,  x2  5x  7  1
dx
dy
 x2  5x  7  1
dx
 x  2 or 3
36. At x  0, f  x  is not differentiable. However, f  x  has a local maximum at x  0 .

37. f  x   x 2   a 2  7  x  15a

 f  2  0

 4  2  a 2  7   15a  0

 2a 2 15a  18  0
  a  6  2a  3  0

3 
 a  ,6
2 
38. Since 1  x  2 or 0  x  1  1 ,
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
2 2
 x 2  2 x    x  1  1   x  1   1  0  1  1
   
 2 1
1  4 x , 0  x  2

 1
 f  x    4 x 2  1,  x 1
 2
 1 1 x  2

Therefore, graph of f  x is as follows.

1
It is clear from graph that f  x  is discontinuous at x  1 and not differentiable at x  and
2
x  1.
789 787  8
39. x 8
8
54  
  8    10
8
Now variance   2
2 2 2 2 2
 7  8  8  8   9  8   7  8  8  8
2 2 2
  7  8  10  8   8  8

8
1  0  1  1  0 1 4  0 8
 2   1
8 8
 
4 4
      
40. Let I   4 x   x ln 1  tan x  dx   4   x x ln 1  tan   x  dx
0
4  0
4   4 

4
 
 4ln 2 x   x dx  I
0
4 

4
 
 I  2ln 2 x   x dx
0
4 
3
 ln 2
192
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
41. Given equation xy  yz  0
 y x  z  0

 y  0 or x  z  0

Represents planes which have direction ratio of normal to the plane respectively
 0,1, 0  and 1, 0,1 .
 a1a2  b1b2  c1c2  0.1  1.0  0.1  0

So, given equation represents a pair of perpendicular planes.

42. Equation of the plane is
3x  4 y  12 z  13  0
3  4  12 p  13  9  12  13
7
 20  12 p  8  p  1,
3
     
43. Since a and b are mutually perpendicular unit vectors so a , b and a  b are three  
mutually perpendicular unit vectors.
    
 c  α a  βb  γ a  b  
2 2 2  2
 c  α2 a  β2 b  γ2 a  b
   
 a.b  0, b . a  b  0, a. a  b  0
   
 
    
 1   2   2   2 .......(i)  a  1, b  1. c  1, a  b  1
 
  
Now, c .a  cosθ [  c is inclined at an angle θ to a ]
    
 
 αa  βb  γ a  b .a  cosθ



2
 α a  cosθ b .a  0, a  b .a  0 
 
 
 2
 α  cosθ  ii  a  1  1 2

   
Also, c , b  cosθ [ c is inclined at an angle θ to b ]
    
 
 αa  βb  γ a  b .b  cosθ 
2    
 β b  cosθ  a.b  0, a  b .b  0
   
 2
 β  cosθ ...... iii   b  12  1
 
Substituting the values of α and β from  ii  and  iii  in  i  , we get:
γ 2  1  α 2  β 2  1  cos 2 θ  cos 2 θ  1  2cos 2 θ   cos 2θ .
44.  ~ r ~ p  ~ q    ~ r ~  p  q   p  q  r .(see formulae)
Sec: Sr. ICON ALL Page 7
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
20 18 16 14 224
45. If E be he event that no pair is selected, then P (E)  . . . 
20 19 18 17 323
224 99
 reqd. prob.  1  P(E)  1   .
323 323
2
46.   
h o  f o g  x   ho g x 2  1  h 

 x2  1  
 
 1  h x 2  x 2

2
 
Since x  0  h x  x . 2 2

47. 9000  9  9  8  7  4464

48. Let Z  a  ib, b  0 where Im Z  b
5
Z 5   a  ib  a 5  5 C1a 4bi  5 C2 a 3b 2i 2  5 C3a 2b 3i 3  5 C4 ab 4i 4  5 C5i 5b 5
Im Z 5  5a 4b  10a 2b 3  b5
4 2
Im Z 5  a  a
y  5    10    1
Im5 z  b  b
2
 a
Let    x  say  , x  R 
 b
2
y  5 x 2  10 x  1  5  x 2  2 x   1  5  x  1   4
 

Hence ymin  4
3
49. For OA, A, OA1   1 km .
tan 600

3
For OB1 , B, OB1   3km
tan 300
As a distance of 3  1  2 km is covered in 5 seconds.
Therefore the speed of the plane is
2  3600
 1440 km / hr
5
50. (i) If a, b, c are in GP, then they can be taken as a, ar , ar 2 where r ,  r  0 is the
common ratio.
x  x  .......  xn
(ii) Arithmetic mean of x1 , x2 ,.........xn  1 2
n
2
Let a, b, c be a, ar , ar , where r  N
abc
Also, b2
3
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
 a  ar  ar 2  3  ar   6
 ar 2  2ar  a  6
6
  r  1 2 
a
Since, 6/ a must be perfect square and a  N .
So, a can be 6 only.
 r  1  1  r  2
a 2  a  14 36  6  14
And  4
a 1 7
51. Let S  2  3  6  11  18  ....  Tn
Or S  2  3  6  11  ......  Tn
On subtracting, we get
0  2  1  3  5  7  ...  Tn
 Tn  2  1  3  5  . n  1 term 
n 1
 2  2   n  1  1 2
2 
2
Tn  2   n  1
2
 T50  2   50  1  49 2  2
52. Given,  
3  i   a  ib  c  id    ac  bd   i  ad  bc 

53. Equation of line parallel to X  axis and passing through p  h, k  is

y  k ......(i)
And given equation of lines, y  x .......(ii)
x  y  2 ......(iii)
Let ABC be the triangle formed by the points of intersection of the lines (i), (ii) and
(iii) as shown in figure,
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
Then, A  k , k  , B 1,1 , C  2  k , k 
k k 1
1
 Area of   1 1 1  4h 2
2
2k k 1
Applying C1  C1  C2 , we get
0 k 1
1
0 1 1  4h 2
2
2  2k k 1
1
  2  2k  k  1  4h 2
2
  k  1 2  4h 2
 k  1  2 h or k  1  2h
 k  2h  1 or k  2 h  1
Hence, locus of  h, k  is y  2 x  1 or y  2 x  1
54. The given system is consistent. Therefore,
1 1 1
Δ  2 1  c  0
b 3b  c
Or c  bc  6b  b  2c  3bc  0
Or 3c  4bc  5b  0
5b
Or c 
4b  3
Now, c  1
5b
 1
4b  3
5b
Or 1 0
4b  3
b3
Or 0
4b  3
 3 
 b    ,3
 4 
x  a2 ab ac
55. We have f  x  ab xb 2
bc
ac bc x  c2
1 0 0 x  a2 ab ac x  a2 ab ac
 f '  x  ab x  b2 bc  0 1 0  ab x  b2 bc
ac bc x  c2 ac bc x  c 2 0 0 1

Sec: Sr. ICON ALL Page 10

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
x  b2 bc x  a2 ac x  a2 ab
  
bc x  c2 ac x  c2 ab x  b2
       
  x  b2 x  c 2  b 2c 2    x  a 2 x  c 2  a 2c 2    x  a 2 x  b 2  a 2b 2  
 3x 2  2x a 2
 b2  c 2 
 cos 2 θ cosθsin θ   cos 2 φ cos φsin φ 
56. AB   2  
cosθsin θ sin θ   cos φsin φ sin 2 φ 
cos 2 θ cos 2 φ  cosθ cos φsinθ sin φ cos 2 θ cos φsin φ  cosθsin θsin 2 φ 
 2 2 2 2 
 cosθsin θ cos φ  sin θ cosφsin φ cosθ cos φsin θsin φ  sin θsin φ 
 cosθ cos φ  cos  θ  φ   cosθsin φ  cos  θ  φ   
 
 sin θ cosφ  cos  θ  φ   sin θsin φ  cos  θ  φ   
 cosθ cos φ cosθ cosφ 
  cos  θ  φ   
 sin θ cos φ sin θsin φ 
π
AB  0  cos  θ  φ  0  θ  φ   2n  1 , n  Z
2
57. Sol: C0  C1  C2  ......Cn  256
 2n  28
 n8

Here constant term is T5 8 C4  24  1120

58. Given curves
y  x 1 .....(i)
and y  3  x .....(ii)
The graph of the curves is given below

 The required area

0 1 2

1
 3  x    x  1    3  x    x  1dx    3  x   x  1dx
0 1
0 1 2
   2  2 x  dx   2 dx    4  2 x dx
1 0 1
2 0 1 2
 2 x  x    2 x 0   4 x  x 2   4 sq units.
1 1

59. Let the equation of the circle through  a, b be

x 2  y 2  2 gx  2 fy  c  0 .... i 
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
So, a 2  b 2  2 ag  2bf  c  0 ... ii 
Since circle (i) cuts x2  y 2  k 2 orthogonally, we have
2 g  0  2 f  0  c  k 2 or c  k 2
Putting c  k 2 in (ii), we get

2ag  2bf  a 2  b 2  k 2  0 
So, the locus of the centre   g ,  f  is
 
2ax  2by  a 2  b 2  k 2  0 or 2ax  2by  a 2  b 2  k 2  0  
60. we have, y ' y tan x  2x sec x
dy
  y tan x  2 x sec x
dx
Which is a form of linear differential equation
Where, P   tan x and Q  2 x sec x

IF  e 
tan xdx
  elogcos x  cos x
So, the solution of given differential equation is
y cos x   2 x sec x cos xdx  c

y cos x  x 2  C

When, x  0 and y  0, then C=0

 y  x 2 sec x
2
     2 2
 y      sec   2
4 4 4 16 8 2

PHYSICS
NBA
61. Induced current, i 
R
NBA

Rt
2
500  3 105    10   2 104
i  2.9  103  3 mA
2  0.5
62. When the coil is connected to dc source, the final current is decided by the resistance
of the coil
10
 r  4
2.5

Sec: Sr. ICON ALL Page 12

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
When the coil is connected to ac source, the final current is decided by the resistance
of the coil
10
 z  5
2
2 2
But Z   r    X L  X L2  52  42  9

X L  3

  L  2 fL  3

 2 50 L  3
 L  3 / 100 Henry
      
63.  
F  dl  B , F  FAC  FCD  FDA  0

0i 2 107  30
64. Bdueto straight wire   2
 3 104 T
2 r 2 10
Bexternal  4  104 T

Bnet  32  4 2  10 4  5  10 4 T

65. u  15 cm f  10cm

1 1 1
Using   we get, v  30cm
v u f

v
 m  2
u
66. By conservation of linear momentum

u  5v  2 ... i 
By Newton’s experimental law of collision
uv2 .... ii 
Using Eqs. (i) and (ii), we have v  1 m / s and u  3 m / s
1 2
Kinetic energy of the centre of mass  msystem vCM  0.75 J
2
67. Weight of lift  Mg
Maximum tension  nMg
nMg  Mg
 Maximum acceleration 
M
 n  1 g
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
And maximum retardation = g
Corresponding velocity  time graph for shortest time will be as follows:

vm vm
Here  n  1 g  or t1  (1)
t1  n  1 g
v v
And g  m or t 2  m (2)
t2 g
Area under v  t graph is total displacement h .
1
Hence h   t1  t 2  v m
2

68. d  1   50  8 0.01  1.42 mm

r  0.71 mm  0.071 cm
S  2 rl  3.834 cm2
With significant figures 3.8 cm2 .
69. When mass of 700 gm is removed, the left out mass  500  400 gm oscillates with a
period of 3 sec.

 3  t  2
 500  400 ........(i)
k
When 500 gm mass is also removed, the left out mass is 400 gm.
400
 t '  2 .......(ii)
k
3 900
   t '  2sec
t' 400
Am
70.  0.75
Ac
 Am  0.75 Ac  0.75  12  9V .

71. The charges, Q2  Q3.

The potential difference between the plates,
Q2 Q2  Q2  Q2  Q3 
V   
C 2C  2C 
72. BC, CD and BA are the known resistances. Thus the unknown resistance ha to be
connected between A and D
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
73. In steady state capacitor is fully charges and is treated as open circuit, so no current
flows through branch containing in steady state, So, the circuit can be redrawn as

Potential difference across capacitor in steady state

 V  6  V  6V

(-ve sign signifies that left hand plate is of negative polarity)

Charge  CV  1 6  6C
74. In steady state current through capacitor is zero. For zero deflection VA  VB
q q R C
So, IR1  And IR2   1  2
C1 C2 R2 C1

75. Momentum of electron, pe  2 meV

Momentum of proton, p p  2 M eV
p h / pp pe m m m
    or  p   e 
e h / pe ph M M M

76. y1  A  B, y2   A  B   C , y   A  B  C   D .
77. Applying principle of energy conservation,
Energy of proton  total B.E. of 2   energy of Li 7
 8  7.06  7  5.6  56.48  39.2  17.28 M eV
78. Intensity at the centre of the pattern will be zero, if path difference at the centre is  / 2
. Now, the path difference introduced by glass plate of thickness t is    1 t
 
    1 t  or t  .
2 2    1
79. The person will catch the ball if his speed and horizontal speed of the ball are same
v 1
i.e., v0 cosθ  0  cosθ   cos600  θ  600 .
2 2
80. Consider a small element of the liquid of length dr at a distance r from O . Mass of
element is m  Aρdr .
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
Outwards force (centrifugal force) acting on the element is
dF  mrω2  Aρω2 r d r
Integrating from r  L / 2 to r  L, we have
L L
2 r2 2
F  Aρω  r d r  Aρω
L/2
2 L/2
3
 Aρω2 L2
8
F 3
 pressure at P   ρω2 L2
A 8
1
81. P  a b c d 1
3 2 2

1
ln P  3 ln a  2ln b  ln c  1ln d
2
ΔP  Δa   Δb  1 Δc Δd
3  2   
P  a   b  2 c d
 Percentage error in P
1
 31%  2  3%   4%  2%   3  6  2  2 %
2
 13%
82. v0  1650 Hz
B1 or the first boy is the source of the sound and B2 is the listener. v s is the
component of the velocity of the source along the source – listener axis (SL axis).
Here, vs  4 2 cos 450  4 m / s

 v  vL 
Using Doppler’s effect formula    0
 v  vA 
v  334 m / s, vs  4 m / s, vL  0
 334  334
   1650 Hz   1650 Hz  1670 Hz .
 334  4  330

83. As T  0, so U  0
Pressure is increasing, so volume will decrease. The work done will be negative
Also PV constant.
84. Let the minimum speed imparted to the particle of mass m so that it just reaches
surface of earth is v . Applying the principle of conservation of energy,
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s
1 2  3 GM  GM
mv    m   m0
2  2 R  R
GM
Solving, we get v  .
R
85. Process AB is isobasic, AC isothermic and CB isochoric.
2
86. v1  5 gR  2 gR
5

Now,
v22  v12  2 g  R  R sin  
2
v 2
 2 gR  2 gR sin 

mv22
N  mg sin θ 
R
Put N  0
mg sin   2 1  sin 
sin   2 1  sin  
2  2
sin      sin 1  
3  3
87. 4 P  800,
 P  200 N
P
Now 0.80  out
Pin
P 200
 Pin  out   250 N .
0.8 0.8
88. Charge +Q will flow into earth.

kQ kQ kQ kQ
VC    VA  
r b a b
Potential at B is zero.
89. Let us consider a differential element dl . Charge on this element.
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-B(11th Jan)Key & Sol’s

 q 
dq    dl
 r 
q
  rd  dl  rd 
r
q
   d
 
Electric field at O due to dq is
1 dq 1 q
dE  . 2  . 2 d
4 0 r 4 0  r
The component dE cos will be counter balanced by another element on left portion.
Hence resultant field at O is the resultant of the component dE sin  only.

q
E   dE sin    2 2
sin  d
0
4 r 0

q 
 2 2   cos 0
4 r 0
q q
  1  1  
4 2 r 2 0 2 2 r 2 0
The direction of E is towards negative y-axis.
 q 
E   2 j
2 0 r 2
90. By the principal of conservation of angular momentum
I  60  I 2  90
2I
Final moment of inertia. I 2 
3
2I I
Change in moment of inertia  I  
3 3