28-12-18 - SR - ICON ALL - Jee-Main - GTM-5 - QP - Code-B PDF

Sri Chaitanya IIT Academy.
, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Date: 28-12-18
Time: 09:00 AM to 12:00 Noon Max.Marks:360
Name of the Candidate (in Capital letters):_______________________________________________
Roll Number : in figures
: in words______________________________________________________________
Examination Centre number:
Name of Examination Centre (in Capital letters):___________________________________________
Candidate’s Signature:_______________________ 1. Invigilator’s Signature:_____________________
Jee Main_GTM-5
Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Q’P_Code-B(09th Jan)
This booklet contains 32 printed pages. The Booklet Code
PAPER: MATHEMATICS, PHYSICS & CHEMISTRY
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2. The test is of 3 hours duration.
3. The test Booklet consists of 90 questions. The maximum marks are 360.
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having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each
correct response.
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Sec: Sr. ICON ALL space for rough work Page 2

MATHS
8
th  1 2 x 
1. If the 6 term in the expansion of  8/3  x log10  is 5600, then x
x 
equals to
1) 1 2) log10
e 3) 10 4) No such x exists
50
2. If A is a matrix such that A2  I and if  A  I   aA  bI then
2 3 4 50
 a 2  b2    a3  b3    a 4  b4  
 .....  a50  b50 
1) 0 2) 25050 3) 22001 4) 21275
3. The number of real values of '' a " for which the system of equations
2ax  2 y  3z  0, x  ay  2 z  0 and 2 x  az  0 has a nontrivial solutions
is
1) 0 2) 1 3) 2 4) 3
4. If  ,  are the roots of the equation x 2  2 x  3  0 then the equation whose
roots are P   3  3 2  5  2and Q   3   2    5 is
1) x 2  3x  2  0 2) x 2  3x  2  0
3) x 2  3x  2  0 4) x2  2 x  3  0
5. If   1  1  1  1  1  1  1  .....  0 then value of
4 3
5 7 9 11 13
1 1 1 1
    ..... is
1 3 5  7 9 11 13 15
   
1) 2) 3) 4)
8 6 4 36
6. If a1, a2 , a3 ,..... be terms of an AP
a1  a2  .....  a p p2 a6
If  , p  q then 
a1  a2  ....  aq q2 a21
41 7 2 11
1) 2) 3) 4)
11 2 7 41
7. The negation of  s    r  s  is
1) s   r 2) s   r   s  3) s   r   s  4) s  r
8. Let A and B two sets containing 2 and 4 elements respectively. The number
subsets of A  B having 3 or more elements is
1) 256 2) 220 3) 219 4) 211
9. Let N denote the set of all natural numbers and R be relation on N  N
defined by (a, b) R  c, d  if ad ( b + c) = bc (a + d) then R is
1) Symmetric only 2) Reflexive only
3) Transitive only 4) Equivalence
10. 10 sealed envelopes contain five ‘A’s, three ‘B’ s, two ‘C’s One in each.
Students ranked 1 to 10 are asked to pickup one envelope each at random in
the same ranking order i.e student ranked 1 will pickup first, one envelope
at random and then student ranked 2 will pickup one envelope from
remaining, then ranked 3 pickup one from remaining and so on. When the
8th ranked student goes to select the envelope, the probability that the
remaining three envelopes contain one A, one B, one C is ____
1 1 1 1
1) 2) 3) 4)
4 3 12 10

11. If the standard deviation of the numbers 2,3, a and 11 is 3.5 , then which of
the following is true
1) 3a 2  26a  55  0 2) 3a 2  32a  84  0
3) 3a 2  34a  91  0 4) 3a 2  23a  44  0
12. A team of four students is to be selected from a total of 12 students. The
total number of ways in which the team can be selected such that two
particular students refuse to be together and other two particular students
wish to be together only is equal to
1) 220 2) 182 3) 226 4) 495
13. The angle between the planes r .2 i  j  2k   3 and
r .3i  6 j  2k   4 is _____
16  4 1  3
1) cos1   2) sin1 3) cos1   4) cos1  
 21 21  4   4 
14. If two vertices of a triangle are 2,3 and 5, 1 , and its orthocenter is
the origin and centroid lies on the line x  y  7 , then the third vertex is
 4 112  112 64   4 12 
1)  , 2)  3)  ,  4) 9,7
 11 11   11 11 
,
11 11 
15. In a ABC is A  1, 2 and internal angular bisectors through B and C are
y  x and y  2 x then the inradius r of the ABC is

1 1 2 2
1) 2) 3) 4)
3 2 3 3

16. The locus of centres of the circles which cut the circles
x 2  y 2  4 x  6 y  9  0 and x 2  y 2  5 x  4 y  2  0 orthogonally is
________
1) 9 x  10 y  7  0 2) x  y  2  0
3) 9 x 10 y  11  0 4) 9 x 10 y  7  0
17. Length of normal chord of the parabola y 2  4 x which makes an angle of

with x-axis is
4
1) 8 2) 8 2 3) 4 4) 4 2
x2 y2
18. If a tangent of slope 2 of the ellipse 2
 2
 1 is normal to the circle
a b
x 2  y 2  4 x  1  0 then maximum value of ab is ____
1) 4 2) 2 3) 1 4) 3
19. If the eccentricity of the hyperbola x 2  y 2 sec2   5 is 3 times the
eccentricity of the ellipse x 2 sec 2   y 2  25 then a value of  is ______

   
1) 2) 3) 4)
6 4 3 12
20. In a three dimensional coordinate system P, Q and R are images of a point
Aa, b, c in the xy , the yz and zx planes respectively. If G is centroid of
triangle PQR then the area of triangle AOG is ( O origin)
1) 0 2) a 2  b 2  c 2
ab  bc  ca
3)
2 2
3

a  b2  c2  4)
3
21. The plane 4 x  7 y  4 z  81  0 is rotated through a right angle about its
line of intersection with the plane 5 x  3 y  10 z  25 . The equation of the
plane in its new position is
1) x  4 y  6 z  102 2) x  8 y  13z  103
3) x  4 y  6 z  110 4) x  8 y  13 z  106
 2 x  23 x  6 
22. Lt  

x 2  2  x
2 1 x 
1)  12 2) 4 3) 8 4) 12
 x 2  ax  1 x is rational
23. A function f  x  is defined as f  x    is
ax 2  2 x  b x is irrational

continuous at x  1 and x  2 then the point P a, blies on
1) y-axis 2) x  y  2  0
3) 2 x  y  1  0 4) 2 x  y 1  0
24. The three sides of a trapezium are equal, each being 8cm .The area of
trapezium, when it is maximum is
1) 24 3 sq.cm 2) 48 3 sq.cm
3) 72 3 sq.cm 4) 12 3 sq.cm

n x 2 1  dx  , c is constant of integration
25.  x2
     c
n x 2 1
1)
2
n x 2 1
c 2)
 x 2
1 2

2 x2 1  ln 2  1
3)
 x 2  1 ln 21
c 4)
 x 2  1 ln 2
c
2 ln 2  1 2 ln 2  1

100  10 
 tan rx dx 
26.   

0  r1
1) 0 2) 100 3)  50 4) 50
27. The area of the region of the plane bounded by max  x , y   1 and
1
xy  is ______ sq.units
2
1) 1  ln 2 2) 3  ln 2 3) 3  2 ln 2 4) 1  2 ln 2
28. If c is arbitrary constant, then the sum of order and degree of differential
equation whose general solution representing family of curves

y 2  2c x  c is 
1) 2 2) 3 3) 4 4) Can’t be determined
1 1 2
29. Number of solutions satisfying the equation   in
sin x sin 2 x sin 4 x
0, 4 is
1) 0 2) 2 3) 4 4) 6
30. The angle of elevation of a tower CD at a point A due south of it is 60 and
at a point B due west of A the elevation is 30 . If AB  3 mt then height of
the tower is _____ mt
3 3 3 6
1) 2 3 2) 2 6 3) 4)
2 4

PHYSICS
31. A variable horizontal force F = 25t acts on a block of mass 10kg kept on a
rough horizontal surface. Co- efficient of static and kinetic friction are
s  0.6 and k  0.4 . What is the velocity of the block at t = 4 second?
1) 1.6m / s 2) 3.2 m / s 3) 5 m / s 4) 6.4 m / s
32. There is an atwood – machine in a elevator going up with an acceleration
a 0  2m / s 2 . The pulley is fixed and smooth, string is ideal
m1  16kg and m 2  8kg Take g  10 m / s 2 

 
m1 a0
m2
Choose the correct statement.
1) acceleration of m1 w.r.t ground is 4m / s2

2) acceleration of m1 w.r.t elevator is 2m / s 2
3) acceleration of m1 w.r.t m2 is 8m / s 2
8
m / s2
4) acceleration of m2 w.r.t to elevator is
3
33. Initially two particles A and B are located at (0, 0) and (d, 0) respectively.
 
They start moving with velocity VA  V ˆi  V ˆj and VB   V ˆj
simultaneously. If R be the magnitude of relative separation between them

and T0 be the time when separation between them is minimum, then [ Rmin
is minimum separation between them]
d 2d
1) T0  2) T0 
5V 5V
2d
3) R min  4) R min  d
5V
34. A particle moving on a straight line has its velocity   versus displacement
(x) graph as shown.

x
Then choose the correct acceleration (a) versus displacement (x) graph.
a a
x
x
1) 2)
a a
3) 4)
35. The breaking stress for a wire of certain material and radius ‘r’ is B . If
another wire of same material but twice the radius breaks at tension F, then
F
find
 B r 2
1) 8 2) 4 3) 3 4) 2
36. A diatomic ideal gas is heated at constant volume until the pressure is
doubled and then heated at constant pressure until volume is doubled. The
average molar specific heat capacity for the entire process is
13R 19R 23R 17R
1) 2) 3) 4)
6 6 6 6
37. Two long co – axial and conducting cylinders of radius a and b (b > a) have
the gap between them filled with a material of conductivity  . A constant
potential difference V is maintained between the two cylindrical shells. The
current per unit length flowing from one cylinder to the other is
4  4  2  2 
1) V 2) V 3) V 4) V
b
l n 
b  a  b
l n 
b  a 
a a
38. In the circuit shown the current through
3 2 2
/\/\/\/\/\/\ /\/\/\/\/\/\ /\/\/\/\/\/\
/\/\/\/\/\/\
/\/\/\/\/\/\
/\/\/\/\/\/\
9V 8 8 4
/\/\/\/\/\/\ /\/\/\/\/\/\ /\/\/\/\/\/\

2 2 2
1) the 3 resistor is 0.5 A
2) the 3 resistor is 0.25 A
3) the 4  resistor is 0.50 A
4) the 4  resistor is 0.25 A
39. A wire of length L and 3 identical cells of negligible internal resistances are
connected in series. Due to the current, the temperature of the wire is raised
by T in a time t. A number N of similar cells in now connected in series
with a wire of same material and cross – section but length 2L. The
temperature of the wire is now raised by same amount  T in same time.
The value of N is
1) 4 2) 6 3) 8 4) 9
40. A compass needle is placed in the gap of a parallel plate capacitor. The
capacitor is connected to a battery through a resistance. The compass
needle
1) does not deflect
2) deflects for a very short time and then comes back to original position
3) deflects and remain deflected as long as the battery is connected
4) deflects and gradually comes to original position in a time which is large
compared to the time constant.

41. In the given circuit Zenner break down voltage the Zenner diode is 10V.
What is the current flowing through the diode.
/\/\/\/\/\/\/\
R1 500 
15 V
/\/\/\/\/\/\/\
R2 1500 
1) 3.3mA 2) 2.5mA 3) 5.5mA 4) 6.7mA

42. A particle of mass m is held is circular orbits around origin by an attraction
force F  r    D  r . Where D is a positive constant. Assuming particle obeys
Bohr’s quantization principle and taking potential energy to be zero at r = 0,
what is the value of energy of the particle in n th orbit?
1/4 1/4
nh D  n2h2D  nh D  n2h2D 
1) 2)  2  3) 4)  
 m   m  2 m  22 m 
43. The adjoining figure represents the observed intensity of X – rays emitted
by two different tubes A and B as a function of wavelength  . For the tube
A, the potential difference between the filament and target is VA and
atomic number of target is ZA . For the tube B, corresponding potential
difference is VB and the atomic number is ZB . The solid curve is for tube A
and dotted curve for tube B; then:

1) ZA  ZB ;VA  VB 2) ZA  ZB ;VA  VB
3) ZA  ZB ;VA  VB 4) ZA  ZB ; VA  VB
44. Gravitational potential on the surface of an isolated uniform solid sphere of
mass M and radius R is found to be V0 . A spherical cavity having radius R/2
is created inside the sphere which is touching the surface of original sphere.
The cavity is then filled with material having density 16 times that of
original sphere. A, B, C and D are consecutive points as shown in the figure
each R/2 apart. Gravitational potential at D is
D C B A
R/2 R/2 R/2
19 13
1) V0 2) 7V0 3) V0 4) zero
4 4
45. In the given figure a ring of mass m, is kept on a horizontal surface while a
body of equal mass ‘m’ attached through a light string, which is wounded
on the ring. When the system is released the ring rolls without slipping.
Choose the correct option. (Neglect mass of the pulley)
m
Ring Pulley
2g
1) Acceleration of the centre of mass of ring is
3
2g
2) Acceleration of the hanging body is
3
3) Frictional force (on the ring) acts towards right
4) Frictional force (on the ring) acts towards left
46. One end of an ideal spring is fixed at point O and other end is attached to a
small disc of mass m which is given an initial velocity v0 perpendicular to
its length on a smooth horizontal surface. If the maximum elongation of the
l0
spring is then ( l0 = natural length, k = stiffness of the spring) ( initially
4
the spring is in it’s natural length)

V0
O
v
1) Velocity at maximum elongation is 0
5
3v0
2) Velocity at maximum elongation is
5
5l0 k
3) v0 
12 m
l0 k
v
4) 0 
12 m
47. The chain of length L is released from rest on a smooth fixed incline with
x = 0 as shown in the figure. Determine velocity v of the chain when a half
of the length has fallen in m/s. (Neglect edge effect of inclined).
 0
30
5 3g l gl 8gl
1) gl 2) 3) 4)
8 8 8 5

48. A particle originally at rest at the highest point of a smooth vertical circle is
slightly displaced. It will leave the circle at a vertical distance h below the
highest point, such that
1) h = R 2) h = R/3 3) h = R /2 4) h = 2R
49. A source of sound of frequency 600Hz is placed inside water. The speed of
sound in water is 1500m/s and in air it is 300 m/s. The frequency of sound
recorded by an observer who is standing in air is
1) 200Hz 2) 3000Hz 3) 120Hz 4) 600Hz
50. A parallel beam of light 500nm is incident at an angle 30° with the normal
to the slit plane in a young’s double slit experiment. The intensity due to
each slit is I0 . Point O is equidistant from s1 and s2 . The distance between
slits is 1mm.
30 d D=3m O
B
Screen
1) the intensity at O is 4 I0
2) the intensity at O is zero
3) the intensity at a point on the screen 4mm from O is 4 I0
4) the intensity at a point on the screen 4mm from O is zero
51. Two coherent narrow slits emitting light of wavelength  in the same phase
are placed parallel to each other at a small separation of 3 . The light is
collected on a screen S which is placed at a distance D     from the slits.
The smallest distance x such that the P is a maxima
[exclude x = 0]
P
x
x
x x O
S1 S2
D
1) 3 D 2) 8D 3) 5 D 4) 5
2
52. Charge Q coulombs is uniformly distributed throughout the volume of a
solid hemisphere of radius R metres. Then the potential at centre O of the
hemisphere in volts is
1 Q 1 3Q 1 Q 1 3Q
1) 2) 3) 4)
4  0 8R 4 0 4R 4  0 4R 4 0 2R

53. The charge per unit length of the four quadrant of the ring is
2 ,  2,  and - respectively. The electric field at the centre is
y
2 + + 2
+
+
+
+
+ x
+
 ++ 
+
  2 2
1)  î 2) î 3)  î 4) î
2 0 R 2 0 R 4 0R 4 0R
54. The magnetic field due to a current carrying square loop of side ‘a’ at a
point P located symmetrically at a distance of a/2 from its centre (as shown)
is
P
a /2
2 0 i 0 i 2 0 i
1) 2) 3) 4) zero
3 a 6 a 3 a
55. Figure shows a circuit consisting of a series combination of alternating
voltage source, a switch, an inductor and a light bulb. The switch is closed,
and the circuit is allowed to come to equilibrium, so that the light bulb

glows steadily. Now an iron rod is inserted into the interior of the inductor
as shown
L Iron
~ S
1) The bulb gets brighter as the rod is inserted

2) The bulb brightness does not change as the rod is inserted
3) The bulb stops to glow completely in the process
4) The bulb gets dimmer, as the rod is inserted.
56. In the figure magnetic field points into the plane of paper and the rod of
length l is moving in this field such that the bottom most point has a
velocity V1 and the topmost point has the velocity V2  V2  V1  . The emf
induced is given by
x x x x
V2
x x x x
x x x x
V1
x x x x
1 1
1) BV1l 2) BV2l 3) B V2  V1  l 4) B V2  V1  l
2 2

57. A message signal of frequency 10 kHz and peak voltage of 10 volts is used
to modulate a carrier of frequency 1 MHz and peak voltage of 20 volts.
What are modulation index and side bands produced?
1) 0.5, 101 kHz, 99 kHz 2)0.5, 1010 kHz, 990 kHz
3) 2, 1010 kHz, 990 kHz 4) 0.6, 101 kHz, 99 kHz
58. If the energy, E  G p h q c r , where G is the universal gravitational constant,
h is the Planck’s constant and c is the velocity of light, then the values of p,
q and r are, respectively
1 1 5 1 1 5 1 1 3 1 1 3
1) , and 2) , and 3) , and 4) , and
2 2 2 2 2 2 2 2 2 2 2 2
59. A vessel X contains 1 mole of O2 gas (molar mass 32) at a temperature T
and pressure P. Another identical vessel Y contains one mole of He gas
(molar mass 4) at temperature 2T, then
1) pressure in the container Y is P/8
2) kinetic energy of O2 molecules = kinetic energy of He molecules
3) pressure in the container Y is 2P
8
4) kinetic energy of He molecules = (kinetic energy of O2 molecules)
5
60. A neutron collides head – on with a stationary hydrogen atom in ground
state. Which of the following statement is correct (Assume that the
hydrogen atom and neutron has same mass)
1) If kinetic energy of the neutron is less than 20.4 eV collision must be
elastic
2) If kinetic energy of the neutron is less than 20.4 eV collision may be
inelastic
3) elastic collision may be take place only when initial kinetic energy of
neutron is greater than 20.4 eV
4) Perfectly inelastic collision cannot take place

CHEMISTRY
61. A 1.000 g sample of metal M react completely with 0.81 g of chlorine gas
to yield a compound with the formula MCl2. In this process 10.0 kJ of heat
is released. Then which of the following statement is wrong?
1) The compound is an alkaline earth metal compound
2) The molecular mass of the compound is nearly 159
3) The amount of heat (in kJ) released in the formation of one mole of
compound is 1000 kJ
4) The compound gives crimson red flame colouration
62. A particular water sample has 136 ppm CaSO4 what fraction of the water
must be evaporated from the sample before solid CaSO4 begins to deposit
 Ksp of CaSO 4  9  106 
1) 20% 2) 46% 3) 67% 4) 92%
63. The ionization constants for H 2 S are K1  1.0  10 , K 2  1.0  10 14. The pH
7
of 0.005M Na2S solution is

1) 2.3 2) 11.7 3) 10.7 4) 12.7
64. If following reactions are spontaneous in forward direction, arrange
HNO2 , HF , CH 3COOH , H 2O in increasing order of acid strength
i) HNO2  HF  H 2 F   NO2
ii) CH 3COOH  HF  F   CH 3COOH 2
iii) H 2O  CH 3COOH  H 3O   CH 3COO 

1) HF  HNO2  CH 3COOH  H 2O
2) HNO2  HF  CH 3COOH  H 2O
3) H 2O  CH 3COOH  HF  HNO2
4) CH 3COOH  HNO2  H 2O  HF
65. 20 ml of 0.2M NaOH is mixed with 50 ml of 0.2M acetic acid. The P H of

ka
resulting solution is ( for acetic acid p  4.74 )
1) 3.5639 2) 5.5639 3) 4.5639 4) 2.5639
66. At a certain temp, K p for dissociation of solid CaCO3 is 4 102 atm and for
the reaction C s   CO2( g )  2CO( g ) is 2.0 atm respectively. The partial
pressure of CO at this temperature when solid C , CaO, CaCO3 are mixed

and allowed to attain equilibrium is?
1) 0.58 atm 2) 0.78 atm 3) 0.18 atm 4) 0.28 atm
67. Which of the following statement is incorrect?
1) In mono atomic gas heat capacity is independent of temperature.
2) Heat capacity per mole is an extensive property.
3) CP is always greater than CV for all type of gases.
4) In an isothermal process temperature of a system remains constant but
may or may not be similar to temperature of surrounding.

68. In a body centered cubic packing, the nearest neighbors lie along the
1) edges of the cube
2) face diagonal
3) line joining the two opposite corners of the face
4) cube diagonal
69. List - I List - II
P) 0.1M AlCl 3 aq  1) Solution with lowest freezing point
Q) 0.1MCH3COOH in benzene 2) Solution with lowest osmotic pressure

R) 0.1M Glucose(aq) 3) Van’t Hoff factor equal to 3when   1
S) 0.1M CaCl 2 aq  4) Degree of dissociation is zero
P Q R S P Q R S
1) A C D B 2) B D C A
3) D A B C 4) A B D C
70. An aqueous solution of " X " is added slowly to an aqueous solution of "Y "
as shown in List-I. The variation in conductivity of these reaction given in
List-II. Match List-I with List-II and select the correct answer using the
code given the list.

List-I List-II
(1)  C2 H 5 3 N  CH 3COOH (P) Conductivity decreases and then
X Y
increases
(2) KI  0.1M  AgNO3  0.01M  (Q) Conductivity decreases and then does
X Y
not change much
(3) CH 3COOH  KOH R) Conductivity increases and then does
X Y
not change much
(4) NaOH HI S) Conductivity does not change much
X Y
and then increase
1) 1  R;2  S;3  Q;4  P
2) 1  S;2  R;3  Q;4  P
3) 1  Q;2  R;3  S ;4  P
4)1  P;2  S;3  R;4  Q
71. Which of the descriptions (Among 1 to 4) correctly describe the following
energy diagram?
X
Y
Energy
Re action
1) A two-step exothermic reaction having an activation energy = X
2) A two-step endothermic reaction having an activation energy = Y
3) A two-step exothermic reaction having an activation energy = Y
4) A two-step endothermic reaction having an activation energy = X
72. Identify the incorrect statement amongst the following
1) Liquid nitrogen does not sticks to the polls of magnet whereas liquid
oxygen does.
2) NO2 is brown in colour at room temperature but colourless below 00C.
3) Bond order of CN and N2 are equal but CN is more reactive
4) NO+ is having lower bond strength than NO.
73. The hybridization of atomic orbitals of nitrogen in NO2 , NO3 and NH 4
respectively are
1) sp, sp 3 and sp 2 2) sp, sp 2 and sp 3
3) sp 2 , sp and sp 3 4) sp 2 , sp3 and sp

74. Which of the following are correct with respect to bond angle?
i) N(SiH3)3 > N(CH3)3 (w.r.t Nitrogen)
ii) NF3 > NH3
iii) NO 2  NO 3
iv) H2O > H2S
1) i, ii, iii, iv 2) i, iii, iv 3) ii, iii, iv 4) i, ii

75. The hydrolysis of dimethyl dichloro silane gives
1) Silicones 2) Silicates 3) SiO2 4) Silicic acid
76. An inorganic salt (A) on heating produces a colourless and odorless gas (X)
which is neutral to litmus. Gas (X) when passed into another vessel
containing lime stone and excess of coke at 1273 K produces a
well– known fertilizer. Nitrolim. Hence salt (A) may be
1) NH 4 NO3 2) Ba  N 3 2 3) LiNO3 4) Pb  NO3  2
77. Which one of the following is incorrect?

1) HOCl  HClO2  HClO3  HClO4  acidic nature
2) HClO  HBrO  HIO  acidic nature
3) F2  Cl 2  Br2  I 2  Bond dissociation energy
4) I2O5 is a very good oxidizing agent and is used in the estimation of
carbon monoxide

78. In the reaction CoCl2 NH    
3 4   Cl  CoCl3  NH 3 3   NH 3

1) Cis[CoCl2(NH3)4] give two geometrical isomers
2) trans [CoCl2(NH3)4] give two geometrical isomer
3) Cis[CoCl2(NH3)4] give only one product which is optically active
4) trans [CoCl2(NH3)4] give only one product which is optically active

79.
Select incorrect statements

1) a,b,c,d all are paramagnetic
2) Number of t2 g electrons in the order d  c  b  a
3) Both (c) and (d) show optical isomerism
4) (b) and (c) are stereoisomers
80. Which of the following is a wrong statement?
1) The value of dissolved oxygen in polluted water is <4ppm
2) COD gives the measure of organic pollution of water
3) COD value determination is based on chemical oxidation of organic
substances
4) If BOD of a river is high, it means the river is not polluted
81. H2O2 When changes from gaseous phase to solid phase. Which one of the
following statements is correct
1) The dihedral angle changes from to 900 to 1110
2) bond angle changes from 1010 to 940
3) The dihedral angle changes from 940 to 1010
4) bond angle changes from 940 481 to 1010541
82. Compound (X), C7 H8O dissolves in NaOH but not in NaHCO3 .(X) reacts
rapidly with Br2 to give (Y), C7 H 5OBr3 . Probable structure of X would be
1) 2) 3) 4)
83. Reagents required to perform the given transformation is
1) i O2  oxidationii  H3O
2) i  KMnO4 , hot ii  LiAlH 4 iii  H 3O
3) i  Hot KMnO4 ii  NaBH 4 iii  H 3O
4) i  H 2CrO4 ii CaO  NaOH , iii  NaOH

84. Glucose does not react with
1) NH 2OH 2) C6 H5 NHNH 2 3) NaHSO3 4) HCN
85. Which of the following is an essential amino acid?
1) Asparagine 2) Glutamine 3) Histidine 4) Alanine

86. In the reaction
1) 2)
3) 4)
87. The most suitable sequence of reagents to perform

this conversion is
1) HB then CH 3 3 COK / CH 3 3 C  OH
2) NBS then alcoholic KOH

3) HBr – peroxide then CH 3CH 2OK / CH 3CH 2OH
4) HBr – peroxide then CH3 3 COK / CH 3 3 COH
88. Which of the following compounds will not dissolve in aqueous NaOH?
1) 2)
3) 4)
H
NaI
H3C Br 
acetone
 [X]
C2 H5
89. In the given reaction [X] will be
H H
H3C I I CH3
C2H5 C2 H5
1) 2)
H3 C
CH3
3) Mixture of (1) and (2) 4)
90. Tautomer of which of the following can show geometrical isomerism
1) CH3–CHO 2) CH3CH2–CHO
O
3) (CH3)2CH–CH=O 4)

Read the following instructions carefully:
1. The candidates should fill in the required particulars on the Test Booklet and Answer Sheet
with Black Ball Point Pen.
2. For writing/marking particulars on the Answer Sheet, use Black Ball Point Pen only.
3. The candidates should not write their Roll Numbers anywhere else (except in the specified
space) on the Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only one option is the correct answer. 5. For
each incorrect response, ¼ (one–fourth) marks of the total marks allotted to the question
(i.e. 1 mark) will be deducted from the total score. No deduction from the total score,
however, will be made if no response is indicated for an item in the Answer Sheet.
6. Handle the Test Booklet and Answer Sheet with care, as under no circumstances (except for
discrepancy in Test Booklet Code and Answer Sheet Code), another set will be provided.
7. The candidates are not allowed to do any rough work or writing work on the Answer Sheet.
All calculations/writing work are to be done in the space provided for this purpose in the Test
Booklet itself, marked ‘Space for Rough Work’. This space is given at the bottom of each
page of the booklet.
8. On completion of the test, the candidates must hand over the Answer Sheet to the Invigilator
on duty in the Room/Hall. However, the candidates are allowed to take away this Test Booklet
with them.
9. Each candidate must show on demand his/her Admit Card to the Invigilator.
10. No candidate, without special permission of the Superintendent or Invigilator, should
leave his/her seat.
11. Use of Electronic/Manual Calculator and any Electronic device like mobile phone, pager etc. is
prohibited.
12. The candidates are governed by all Rules and Regulations of the Examination body with
regard to their conduct in the Examination Hall. All cases of unfair means will be dealt with as
per Rules and Regulations of the Examination body.
13. No part of the Test Booklet and Answer Sheet shall be detached under any circumstances.
14. Candidates are not allowed to carry any textual material, printed or written, bits of papers,
pager, mobile phone, electronic device or any other material except the Admit Card inside the
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Sri Chaitanya IIT Academy.

Name of the Candidate (in Capital letters):_______________________________________________

Roll Number : in figures

Examination Centre number:

Name of Examination Centre (in Capital letters):___________________________________________

Candidate’s Signature:_______________________ 1. Invigilator’s Signature:_____________________

2. The test is of 3 hours duration.

Sec: Sr. ICON ALL space for rough work Page 2

roots are P   3  3 2  5  2and Q   3   2    5 is

Sec: Sr. ICON ALL space for rough work Page 4

y  x and y  2 x then the inradius r of the ABC is

Sec: Sr. ICON ALL space for rough work Page 5

eccentricity of the ellipse x 2 sec 2   y 2  25 then a value of  is ______

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Sec: Sr. ICON ALL space for rough work Page 8

a 0  2m / s 2 . The pulley is fixed and smooth, string is ideal

m1  16kg and m 2  8kg Take g  10 m / s 2 

Choose the correct statement.

1) acceleration of m1 w.r.t ground is 4m / s2

Sec: Sr. ICON ALL space for rough work Page 9

/\/\/\/\/\/\ /\/\/\/\/\/\ /\/\/\/\/\/\

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1) 3.3mA 2) 2.5mA 3) 5.5mA 4) 6.7mA

Sec: Sr. ICON ALL space for rough work Page 13

R/2 R/2 R/2

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1) The bulb gets brighter as the rod is inserted

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of 0.005M Na2S solution is

ii) CH 3COOH  HF  F   CH 3COOH 2

iii) H 2O  CH 3COOH  H 3O   CH 3COO 

Sec: Sr. ICON ALL space for rough work Page 22

65. 20 ml of 0.2M NaOH is mixed with 50 ml of 0.2M acetic acid. The P H of

the reaction C s   CO2( g )  2CO( g ) is 2.0 atm respectively. The partial

pressure of CO at this temperature when solid C , CaO, CaCO3 are mixed

Sec: Sr. ICON ALL space for rough work Page 23

P) 0.1M AlCl 3 aq  1) Solution with lowest freezing point

Q) 0.1MCH3COOH in benzene 2) Solution with lowest osmotic pressure

Sec: Sr. ICON ALL space for rough work Page 24

3) sp 2 , sp and sp 3 4) sp 2 , sp3 and sp

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77. Which one of the following is incorrect?

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Select incorrect statements

1) i O2  oxidationii  H3O

2) i  KMnO4 , hot ii  LiAlH 4 iii  H 3O

3) i  Hot KMnO4 ii  NaBH 4 iii  H 3O

4) i  H 2CrO4 ii CaO  NaOH , iii  NaOH

Sec: Sr. ICON ALL space for rough work Page 29

86. In the reaction

87. The most suitable sequence of reagents to perform

2) NBS then alcoholic KOH

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Candidate’s Signature:___ 1. Invigilator’s Signature:_