Solutions

1
AITS-FT-I-(Paper-2)-PCM (Sol.)-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS

FULL TEST – I
PAPER-2
Q. Q. Q.
ALL INDIA TEST SERIES
PHYSICS CHEMISTRY MATHEMATICS

No. No. No.
1. C 24. C 47. C
2. A 25. B 48. B
3. C 26. C 49. B
4. C 27. D 50. D
5. A 28. C 51. A
6. D 29. B 52. C
7. B 30. A 53. D
8. B 31. D 54. D
9. ABC 32. ABC 55. BC
10. BD 33. D 56. ABCD
11. ABCD 34. ABCD 57. AC

12. ABC 35. ACD 58. AB
13. A 36. A 59. D
14. A 37. A 60. B
15. B 38. A 61. A

16. B 39. B 62. B
17. C 40. A 63. A
18. D 41. D 64. D
19. 4 42. 9 65. 1

20. 3 43. 9 66. 4
21. 4 44. 6 67. 8

22. 3 45. 7 68. 1
23. 2 46. 7 69. 7
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2
Physics PART – I
SECTION – A
gt12 2h 2h
1. For the 1st ball, 4h =  t1  2 & For second ball t 2 
2 g g
2h 2d 2h
also  2 2 h  d  h d h
g g g
mA  4T  mA2
2. From F.B.D. we get
mA  2T  T  mA1
a1 T 4T
A B
mA
2T mg a2
On solving these two we get

aA = 4g
3. Zero error = +4  0.01 = +0.04 mm
Measured diameter = M.S.R. + L.C.  C.S.R.
= (50.5) mm + (0.01mm)  18 = 2.68 mm
 Actual diameter = 2.68 - (0.04) = 2.64 mm
16V0
4. When radius of curvature is minimum v is  to a & it is at t =
25g
5. Since shell is earthed its potential is zero

KQ1 K  2Q  Q1
 0 -Q
R 2R
Q
2Q
 Q1  Q A B
R
Hence 3Q will flow to the earth. 2
3 1 1
6.   (1)

2v 1 45 2R
3 1
  (2)

2v1 6R
from (1)and (2)
R  30 cm
dv
7. F.v  k  .m .v  k
dt
t m vt m  6M 6M 
0 dt  k v i vdv  2k  R  r 
6Mm  1 1 
t   
2k  R r 
3
8. F.B.D. of the ball in the frame of the container is as shown in the figure
2 mg
mg
 Distance from B = 5m
Qi2 1 2 1 2
10.  Li i  Limax
2c 2 2
Imax  2 amp
2
Qi2 1 2 Qmax
Also,  Li i 
2c 2 2c
du
11.  F  0 (For equilibrium)
dy
Particle is performing simple harmonic motion
12. dQ   4m  s  dT1    2m  2s  dT2

 KAt
On solving we get Tf  Ti e 2 msl
Temperature of point P remains constant
13. If x be the initial length of the gas chambers & A be the area of cross section of the cylinder then,
V
x  0 Also P0 A = 2kx
A
P0
 2kx  P0V0  2kx 2
x
1 2 1
 k  2x   K 4 x 2  2kx 2  P0V0
2 2
v
14. Similarly, Pf A  2k f
A
V0
P0 A  2k
A
Pf Vf P
  P  0v
P0 V0 V0
Now  Q = dU + W
5
2  PV  P0V0   w
= 2 1 1
 12P0V0
15 – 16.P= mv &
P2 1
 mV 2
2m 2
P2
E 
2m
P2
E radon 
2M
Also
4
P2 P2 mM
  E  P  2E
2m 2M mM
m  4.002mu, M  222.017mu
m  6.64  10 27 kg
1 4v 2
17 – 18. g sin . 2  2R .....  I 
2 g cos 2 
R
h
R 
R 
2
v  Rg sin  .....  2 
From (1) and (2) tan   1
SECTION – C
2.5
T 0.75  3.9m / s  4m / s
19. v 
 0.125
0.75
20.  Angular separation is directly proportional to wave length
21. 2  3
2x
3x x
A
2x 3 2 3x
4 volt
2x  4
1 p
x 
3 q
pq  4
8QE 2
22.    I       2 
mR T
 T  2
 P + n is 3
 r 2 dB
23. Now i 
R R dt
  M  B  2mgr
r 2 dB 2
.r .4  2mg.r
R dt
2 r 4
4 .8t  2mg.r
R
t  2sec
5
Chemistry PART – II
SECTION – A
24. CHCl 3  CCl 3  H 


CHF3  CF3  H 
 CCl 3 is more stable than CF3 due to P  d  bonding hence CHCl 3 is more acidic, not CHF3
so, (I) is incorrect.
 In chlorobenzene C  Cl bond length decreases due to resonance and hence its dipole
moment is lesser than chlorocyclohexane ii is also incorrect.
 Dipole moment of fluoromethane is lesser than chloromethane due to very small size of F. ii is
also incorrect.
 Carbon and nitrogen atom containing organic compound gives positive test for nitrogen in
lassaigne’s test
 Dipole moment of difluoromethane is more than dichloromethane .
CH 2F2 CH 2Cl 2
  1.97D 1.60D
25.
A. - B. COOH C.
COO
- HOOC
OOC
2
26. At very high concentration R. O. R = K RCHO  [OD ]2
Mech.
O -
OD O
C -
OD C or
C
H - H H
O
O-
(At very high concentration of OD-)

-
O H
O -
O H
C C O
r.d.s
- H C - + C
O
O H
-
-OD D2 O
DO
H
C H
At very high concentration =

r. o. r =
6
-
O
CHO
C
K'
H
O-
CHO CHO 2
K eqb -
= K' OD
2
CHO 2
-
= K' Keqb OD
2
CHO 2
-
= K OD
27. Ni(CO)4
Fe(CO)5 Extent of synergic bonding M - C bond strength CO bond strength
Cr(CO)6
-
V(CO) 6
Cr(CO) 6 Extent of synergic bonding M - C bond strength CO bond strength

+
Mn(CO) 6
28. It is a semi pinacol – pinacolone type reaction and product is formed after formation of
carbocation and its rearrangement by ring expansion.
+
1HNO2 -H
+
2.
+
OH NH2 OH OH
O
29. 2r  4; n  4

Total energy required + Total energy released = 0
 1 
 2  4.526ev  NA    2  13.6N A    2  13.6   1    N A   30.87  x  NA   0
  16  
x2
30. AgBr  Agaq .  Braq.
K sp   Ag   Br  

Ag   2NH3   Ag  NH3 2 
7

 Ag  NH3  2 
Kf   2
 1 108
 Ag   NH3 

Let s be the solubility of AgBr in NH3, then [Br-] = [Ag+] + [Ag(NH3)2]+ = S

Since , almost all Ag+ in solution state passes to [Ag(NH3)2]+ as Kf is very high. Thus
[Ag+]<<<[Ag(NH3)2]+
 [Br-] = [Ag(NH3)2]+ = S
 Ag (NH )  
3 2
Now Ksp = [Ag ] [Br ] = 
+ -
2
  Br  
 
K f   NH3 
Since [NH3] = 0.4 M
S S
5  1013  2
1.0  108   0.4 
S 2  8  10 6
S  2.82  103 M
31. Fe  Fe 2  2e G10  2  E10  F ............  i 

Fe 2  Fe 3  e G20  1 E20  F .............(ii)
Fe  Fe 3   3e G30  3  E30  F ...........(iii)
Subtracting equation (i) from equation (ii), we get
Fe 2  Fe 3  e
G30  G10  3E30 F  2E10 F ............(iv)
Comparing (ii) and (iv)
G20  G30  G10
E 20 F  3E30 F  2E10 F

E 30  E20  2E10 / 3 
32. Crystal is FCC
33. 2MnO4  5H 2O2  6H   2Mn 2  5O2  8H2O
34. O g   e   Og  H  ve

Og  e   Og2 H  ve
O g   2e   Og2 H  ve
O2g   O2g   e   Electron removed from  2P *
y or * 2Px 
O g   O 
g  e 
 Electron removed from 2P 
H 2g   H2g   e   Electron removed from 1s 
H g   Hg   e   Electron removed from 1s 
35. O
CH3
P1
CH3
8
O
CH3
P2
CH3
O
P3 CH3 R R CH3
Q 3 H3C S S CH3
O
P4 CH3
36. Me Me Me
O O O
Cl - -
NH2 NH2 -
-NH3
- NH2
H -Cl
-
-NH2 NH3
Me
O
NH2
37.
Cl
-
NH2
9
PV
38.  Z At very low P or P  0, Z = 1
nRT
39. PV  RT (for 1 mole of gas)
 P V  R T
 V  R R.V
or    P  RT
 T P
 V 
 
 T P 1
or   
V T
P .V  V .P  0
 V  V
  
 P T P
Also  V 
 
 P T 1
or    
V P
 P

 T
40-41. Alkaline gas C with NaOH indicates that solid should be ammonium salt. Heating the salt, a
colorless non-reacting gas D is formed. The gas D may be nitrogen . The compound may thus be
NH 4 NO2 . Reactions involved are as follows.
HCl
NH 4 NO2   NH 4Cl  HNO2
A
2HNO2  H2O  2NO  O 
2NO  2 O   2NO2 
B
BrownGas
NH 4 NO2  NaOH  NaNO2  H2O  NH3 
C
heat
NH 4 NO2 (s) 
 N2(gas)  2H2O(gas) 
A D
 N2 is a diamagnetic Gas
 Bond order of N2  3
SECTION – C
42. (A), (B), (C), (D), (E), (F), (G), (H) & (I) gives iodoform test
Br O
-
OH (aq.)
(G) H3C C CH3 H3C C CH3
Br
OH- (aq.) -
(I) H3C C OEt H3C C O + EtOH
O O
it show iodoform test
10
43. G & J have zero dipole moment

F H
Cl Cl Cl
C C C C  I I 
Cl Cl Cl
H F
A, B, C, D, E, F, H, I have nonzero dipole moment
44. Correct statements: A, C, D, G, H, I

Incorrect statements: B, E, F
45. A, B, C, D, G, H, I show mutarotation. A sugar whose IUPAC name ends with the suffix ose is a
reducing sugar and they do mutarotation
46. Monochlorination
Cl
Cl
Cl
Dichlorination
Cl Cl
Cl Cl Cl Cl
Cl
Cl Cl Cl
Cl Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
A, B, C, D, E, F, J are correct.
11
Mathematics PART – IIII
SECTION – A
1  3 1  3  32 3n  1
47. S  1   ......................  
2! 3!  3  1 n!
1 n 3 r  1 1  3r 1 

2 r 1 r!
   
2  r! r! 
1 1
n 2
 
lim  Sn    e3  1   e  1   e3  e   8.59
 2
 Sn   8
4 3 2
48. Let f  x   a  x  2   b  x  2   C  x  2   d  x  2   1
2
f  x   12  x  2   12  x  2   2
f '' 1  26
49. Let En denote the event that the score is n

En  En  2  H  En 1  T 
1
P  En   Pn 2  Pn1 
2
1 1
Pn  Pn 1  Pn 1  Pn  2
2 2
1 1
 Pn 2  Pn 3  P2  P1
2 2
1 3
As, P1  P  T    P2  P   T  T   H 
2 4
1
 Pn  Pn 1  1
2
2
2 1 2  1  2
 Pn    Pn 1       Pn  2  3 
3 2 3  2   
n 2
 1  2 1 1 2
    P1       
 2  3 2 2 3
2 1
P100  
3 3.2100
50. x  1   x  x
1 1 1
3
1  3   3
   
 1  1
x 5  3  1  x 5  3   x 2
  x 
1
 lim x5  3   0
x 0
x 
12
51. Re quired number of ways  coefficiant of x150 in

3
x 0
 x  x 2 ............x 50  x 0
 x  x 2 .......x100 
153 102
c150  3 c 99 52 c 49  3.51 c 48
 70176  40375  110551
x
 dx   dx 
52. e xy  xy 2  y 3 e
y
y  x  0
 dy   dy 
 x
 
d exy  d  e y   0
 
 
x
e xy  e y  c  0
A B  1
53. Normal through given point be the axis of

=0
parabola, y +1
x+
y – 2= - 4(x – 1) (-1, 0)
4x + y = 6
(1, 2)
 29 14 
P , 
 17 17 
(3, 1)
y-2
x+
5=
0
4y = x + 1
54. Let a, b, c are the roots of equation

a0 x 3  a1x 2  a2 x  a3  0
Then, s1  5 s2  12, s 3  25
Now, a0 s1  a1  0  a1  5a0
13
a0 s2  a1s1  2a2  0  a 2  a0
2
5
a0 s3  a1s2  a 2 s1  3a3  0  a3  a0
6
13 5
x 3  5x 2  x 0
2 6
6x 3  30x 2  39x  5  0
 6x 4  30x 3  39x 2  5x  0
257
6s4  30s3  39s2  5s1  0  s4 
6
13
5  b 5  b

55. tan   a  r ar
2
b  5
1 2 2
a r
2
Now,a2   r  4   52
 r 2  9  8r
2
b  5 9
O
r
(0, -b)T 
1 S 2
P Q (a1-5) R
(01- 5) (a + r, -5)
(a - r, -5)
x x
2 2 2
56.  g  t  dt  2  K x  2   2K tdt
0 0
x
Let f  x    2k 2 t  g  t   dt  2
0
As, 2K 2 t and g  t  are continuous

 2K 2 t  g  t   is also continuous
f  0   2, lim f  x   
x 
As f  x  changes its sign

 f  x   0 for some x  R & K  R
     

57. DA  a, DB  b, DC  c
    
 
AD.BC  a . c  b  A
 
 a.c  a.b
Q
0 P
    D
Hence, AD r BC  AB  CD G
 1     1   B

Now, PG   3a  2b  c & DQ  a  b
6 2
  
   C
Let a  b  c  K
 K  3
 PG  & DQ  K
2 2
  1    1  

 PG.DQ   3a  2b  c . a  b
6 2
  
5  5 
cos         cos 1  
6 3 6 3
14
58. f  x   x 2  7x  13
In both cases gain > loss Gain
4 4 Gain
 P   f  x  dx & Q   f  x  dx
Loss Loss
3 3
3 3.5 4
59. & 60.

As, f  x   x & cos n  1   cos n  1   2cos n  .cos 
fn 1  x   fn 1  x   2x.fn  x 
1
fn  x    fn 1  x   fn 1  x  
2x 
Now, Put x  cos ,  x 2  1  isin 
10 10
x  x2  1   x  x2  1  10 10
  cos   isin     cos   isin  
 2cos 10   2f10  cos    2f10  x 
61. & 62.

1
1 Put  2x  3  6 t
x 1 3
 2  Put t
1 x
63. & 64.

x  3 y  4 z 1
equation of line L 2 is  
1 3 1
1 equation of plane containing L1 & L 2
x  3 y 1 z  2
0 3 1  0  y  3z  5  0
1 6 2
3 4 1
1 7
 2  volume of tetrahedron  5 4 1 
6 3
7 7 0
SECTION – C
65. equation of chord whose mid  point is  t, K  t 

2
tx K  t  y t 2 K  t 
   ......  i 
8 2 8 2
 2, 1 satisfy  i

 5t 2   6  8K  t  4 K 2  K  0 
15
For two distinct chords,

D0
2
 6  8K   
 4.4.5 K 2  K  0
2
 4K  4K  9  0
1  10 1  10 
K ,   ab 1
 2 2 
b b
66. Let f  x   ax2  c f '  x   2ax 
x x2
1 2
 b 3  b 3 b 27ab2
f '  x   0, x     a    1
c  4
 2a   2a  c3
 b  3
 
 2a 
67. xyz 1
 y  z  z  x  x  y  2
Let y  z  A, z  x  B, xy C
1  x 1  y 1  z   B  C  C  A  A  B 
 1  x 1  y 1  z   8  x  y  y  z  z  x  ......  i
As,  x  y  y  z  z  x   1  x 1  y 1  z 
 1   x  y  z    xy  yz  zx   xyz
 xy  yz  2x  xyz
1 1 1 
 x  y  y  z  z  x   xyz     1
x y z 
 xyz  x 1  y 1  z 1  1
1
x 1  y 1  z 1  x  y  z 
Now,  
3  3 
  x  y  y  z  z  x   8xyz ........ ii 
 1  x 1  y 1  z   8.8xyz
 1  1  1
 1  x   1  y   1  z   64
   
22
 B   10 
68.  
adj I  2A 1      
 A   8 
 
cos3  sin3 
69.   3
9a 5b
9a 5b
  56
cos  sin 
9a 5b
1
 1
 56
  9a  3   5b  3
2 2 3
  2
 9a    5b     56 
3 3
 

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ANSWERS, HINTS & SOLUTIONS

PHYSICS CHEMISTRY MATHEMATICS

10. BD 33. D 56. ABCD

11. ABCD 34. ABCD 57. AC

15. B 38. A 61. A

18. D 41. D 64. D

19. 4 42. 9 65. 1

21. 4 44. 6 67. 8

23. 2 46. 7 69. 7

On solving these two we get

5. Since shell is earthed its potential is zero

12. dQ   4m  s  dT1    2m  2s  dT2

20.  Angular separation is directly proportional to wave length

24. CHCl 3  CCl 3  H 

(At very high concentration of OD-)

At very high concentration =

Cr(CO) 6 Extent of synergic bonding M - C bond strength CO bond strength

29. 2r  4; n  4

30. AgBr  Agaq .  Braq.

Let s be the solubility of AgBr in NH3, then [Br-] = [Ag+] + [Ag(NH3)2]+ = S

31. Fe  Fe 2  2e G10  2  E10  F ............  i 

34. O g   e   Og  H  ve

43. G & J have zero dipole moment

44. Correct statements: A, C, D, G, H, I

Mathematics PART – IIII

49. Let En denote the event that the score is n

51. Re quired number of ways  coefficiant of x150 in

53. Normal through given point be the axis of

54. Let a, b, c are the roots of equation

As, 2K 2 t and g  t  are continuous

As f  x  changes its sign

     

59. & 60.

 2cos 10   2f10  cos    2f10  x 

61. & 62.

63. & 64.

65. equation of chord whose mid  point is  t, K  t 

For two distinct chords,

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