1. what volume would be occupied by this quantity?

(1
Of the following name/symbol combinations of gallon = 3.7854 liters)
elements, which one is WRONG? (a) 7.646 x 1011 liters
(a) uranium/U (b) 8.388 x 109 liters
(b) sulfur/S (c) 1.287 x 109 liters
(c) nitrogen/N (d) 5.336 x 1010 liters
(d) potassium/K (e) 4.870 x 109 liters
(e) iron/I 9.
2. Identify the INCORRECT statement.
Of the following symbol/name combinations of (a) Helium in a balloon: an element
elements, which one is WRONG? (b) Paint: a mixture
(a) C/carbon (c) Tap water: a compound Mixture of Various
(b) B/barium Dissolved Solids and Carbon Dioxide and Oxygen.
(c) F/fluorine (d) Mercury in a barometer; an element
(d) N/nitrogen 10.
(e) U/uranium An unused flashbulb contains magnesium and
3. oxygen. After use, the contents are changed to
The chemical symbol for manganese is magnesium oxide but the total mass does not
(a) Mn change. This observation can best be explained by
(b) Mo the
(c) Ma (a) Law of Constant Composition.
(d) Ga (b) Law of Multiple Proportions.
(e) Mg (c) Avogadro's Law.
4. (d) Law of Conservation of Mass.
The number 0.005436 has how many significant 11.
figures? Which answer includes all the following that
(a) 7 are chemical changes and not physical changes?
(b) 3 I. freezing of water
(c) 4 II. rusting of iron
(d) 5 III. dropping a piece of iron into hydrochloric acid
(e) 6 (H2 is produced)
5. IV. burning a piece of wood
The number 10.00 has how many significant figures? V. emission of light by a kerosene oil lamp
(a) 1 (a) III and IV
(b) 2 (b) II and V
(c) 3 (c) I, II, III, IV, and V
(d) 4 (d) II, III, and V
(e) 5 (e) II, III, IV, and V
6. 12.
What is the volume of a 2.50 gram block of metal Which response lists all of the following properties
whose density is 6.72 grams per cubic centimeter? of sulfur that are physical properties and not other
(a) 16.8 cubic centimeters properties?
(b) 2.69 cubic centimeters I. It reacts with hydrogen when heated.
(c) 0.0595 cubic centimeters II. It is a yellow solid at room temperature.
(d) 0.372 cubic centimeters III. It is soluble in carbon disulfide.
(e) 1.60 cubic centimeters IV. Its density is 2.97 g/cubic centimeter
7. V. It melts at 112 degrees C.
A cube of 1.2 inches on the side has a mass of 36 (a) II, III, IV, and V
grams. What is the density in g/cm3? (b) II, IV, and V
(a) 21 (c) I
(b) 2.2 (d) II, III, and IV
(c) 30. (e) III, IV, and V
(d) 1.3
(e) 14 13.
8. The formula weight of the compound, Al2(SO4)3
Nitric acid is a very important industrial chemical: 18H2O is:
1.612 x 1010 pounds of it were produced in 1992. If (a) 394.4 g
the density of nitric acid is 12.53 pounds/gallon, (b) 666.4 g
 (c) 110,900 g
(d) 466.8 g 21.
(e) 561.2 g Which one of the samples has the largest mass?
14. (a) 1 mol of CO2(g)
The weight of a millimole of (NH4)2HPO4 is: (b) 1 mol of UF6(g)
(a) 132 g (c) 1 mol of CH3COCH3(l)
(b) 114 g (d) 1 mol of He(g)
(c) 1.14 x 10-3 g (e) all have the same mass
(d) 0.132 g 22.
(e) 6.02 x 1020 g Which of the following statements is(are) FALSE?
15. 1. The percent by mass of each element in a
How many moles of alanine, C3H7NO2, are there in compound depends on the amount of the
159 g of alanine? compound.
(a) 1.42 x 104 2. The mass of each element in a compound
(b) 1.78 depends on the amount of the compound.
(c) 0.992 3. The percent by mass of each element in a
(d) 0.560 compound depends on the amount of element
(e) 3.31 present in the compound.
16. (a) 2 and 3
How many atoms are in one mole of CH3OH? (b) 1 only
(a) 6 (c) 1 and 2
(b) 6.0 x 1023 (d) 1, 2 and 3
(c) 12.0 x 1023 (e) another combination
(d) 3.6 x 1024 : 6.02x10^23 * 6 Atoms (1C, 4H, 1 O) 23.
(e) 3 Guanidin, HNC(NH2)2, is a fertilizer. To three
17. significant figures, what is the percent by mass of
The mass in grams of 2.6 x 1022 chlorine atoms is: nitrogen in the fertilizer?
(a) 4.4 (a) 45.2%
(b) 11 (b) 49.4%
(c) 0.76 (c) 54.8%
(d) 1.5 (d) 65.1%
(e) 3.2 (e) 71.1%
18. 24.
How many aluminum atoms are there in 3.50 grams Calculate the percent, by weight, of carbon in 154 g
of Al2O3? of C4H8O3?
(a) 4.13 x 1022 (a) 46%
(b) 4.90 x 1022 (b) 31%
(c) 2.07 x 1022 (c) 72%
(d) 1.68 x 1022 (d) 27%
(e) 2.45 x 1022 (e) 55%
19. 25.
Which one of the samples contains the most atoms? Analysis of a sample of a covalent compound
(a) 1 mol of CO2(g) 3 showed that it contained 14.4% hydrogen and 85.6%
(b) 1 mol of UF6(g) 7 carbon by mass. What is the empirical formula for
(c) 1 mol of CH3COCH3(l) 10 the compound?
(d) 1 mol of He(g) 1 (a) CH
(e) all contain the same number of atoms (b) CH2
(c) CH3
20. (d) C2H3
Which one of the samples contains the (e) none of these
most molecules? 26.
(a) 1 mol of CO2(g) An oxide of lead contains 90.65% Pb, by weight. The
(b) 1 mol of UF6(g) empirical formula is:
(c) 1 mol of CH3COCH3(l) (a) Pb
(d) 1 mol of He(g) (b) PbO
(e) all contain the same number of molecules (c) Pb3O4
(d) Pb2O3
(e) PbO2
27. The stoichiometric coefficient for oxygen gas O2 is:
A 0.500 g sample of a compound containing only (a) 1
antimony and oxygen was found to contain 0.418 g (b) 4
of antimony and 0.082 g of oxygen. What is the (c) 3
simplest formula for the compound? (d) 7
(a) SbO (e) 5
(b) SbO2 33.
(c) Sb3O4 When iron pyrite (FeS2) is heated in air, the process
(d) Sb2O5 known as "roasting" forms sulfur dioxide and iron(III)
(e) Sb2O3 oxide. When the equation for this process is
28. completed and balanced, using the smallest whole
A compound contains, by mass, 40.0% carbon, 6.71% number coefficients, what is the coefficient for
hydrogen, and 53.3% oxygen. A 0.320 mole sample "O2"?
of this compound weighs 28.8 g. The molecular _4__ FeS2 + _11_ O2 __ SO2 + ___ Fe2O3
formula of this compound is:
(a) C2H4O2 (a) 2
(b) C3H6O3 (b) 4
(c) C2H4O (c) 7
(d) CH2O (d) 8
(e) C4H7O2 (e) 11
29. 34.
What mass of cerussite, PbCO3, would contain 35.0 How many moles of KBrO3 are required to prepare
grams of lead? 0.0700 moles of Br2 according to the reaction:
(a) 27.1 g KBrO3 + 5KBr + 6HNO3 6KNO3 + 3Br2 + 3H2O
(b) 45.1 g
(c) 42.4 g (a) 0.210
(d) 35.6 g (b) 0.0732
(e) 51.7 g (c) 0.0704
30. (d) 0.220
Balance the following equation with the smallest (e) 0.0233
whole number coefficients. Choose the answer that 35.
is the sum of the coefficients in the balanced Which of the following statements is FALSE for the
equation. Do not forget coefficients of "one." chemical equation given below in which nitrogen gas
PtCl4 + XeF2 PtF6 + ClF + Xe reacts with hydrogen gas to form ammonia gas
assuming the reaction goes to completion?
(a) 16 N2 + 3H2 2NH3
(b) 22 (a) The reaction of one mole of H2 will produce 2/3
(c) 24 moles of NH3.
(d) 26 (b) One mole of N2 will produce two moles of NH3.
(e) 32 (c) One molecule of nitrogen requires three
31. molecules of hydrogen for complete reaction.
Balance the following equation with the smallest (d) The reaction of 14 g of nitrogen produces 17 g of
whole number coefficients. Choose the answer that ammonia.
is the sum of the coefficients in the balanced (e) The reaction of three moles of hydrogen gas will
equation. Do not forget coefficients of "one." produce 17 g of ammonia.
Cr2(SO4)3 + RbOH Cr(OH)3 + Rb2SO4 36.
Calcium carbide, CaC2, is an important preliminary
(a) 10 chemical for industries producing synthetic fabrics
(b) 12 and plastics. CaC2 may be produced by heating
(c) 13 calcium oxide with coke:
(d) 14 CaO + 3C CaC2 + CO
(e) 15
32. What is the amount of CaC2 which can be produced
Balance the following equation using minimum from the reaction of excess calcium oxide and 10.2 g
integral coefficients: of carbon? (Assume 100% efficiency of reaction for
NH3 + O2 NO2 + H2O purposes of this problem.)
(a) 18.1 g
 (b) 28.4 g
(c) 20.8 g
(d) 19.8 g 41.
(e) 27.2 g The limiting reagent in a chemical reaction is one
37. that:
Calculate the mass of hydrogen formed when 25 (a) has the largest molar mass (formula weight).
grams of aluminum reacts with excess hydrochloric (b) has the smallest molar mass (formula weight).
acid. (c) has the smallest coefficient.
2Al + 6HCl Al2Cl6 + 3H2 (d) is consumed completely.
(e) is in excess.
(a) 0.41 g 42.
(b) 1.2 g If 5.0 g of each reactant were used for the the
(c) 1.8 g following process, the limiting reactant would be:
(d) 2.8 g 2KMnO4 +5Hg2Cl2 + 16HCl 10HgCl2 + 2MnCl2 +
(e) 0.92 g 2KCl + 8H2O
38.
When 12 g of methanol (CH3OH) was treated with (a) KMnO4
excess oxidizing agent (MnO4-), 14 g of formic acid (b) HCl
(HCOOH) was obtained. Using the following chemical (c) H2O
equation, calculate the percent yield. (The reaction is (d) Hg2Cl2
much more complex than this; please ignore the fact (e) HgCl2
that the charges do not balance.) 43.
3CH3OH + 4MnO4- 3HCOOH + 4MnO2 What mass of ZnCl2 can be prepared from the
(a) 100% reaction of 3.27 grams of zinc with 3.30 grams of HCl?
(b) 92% Zn +2HCl ZnCl2 + H2
(c) 82%
(d) 70% (a) 6.89 g
(e) 55% (b) 6.82 g
39. (c) 6.46 g
A commercially valuable paint and adhesive stripper, (d) 6.17 g
dimethyl sulfoxide (DMSO), (CH3)2SO, can be (e) 6.02 g
prepared by the reaction of oxygen with dimethyl 44.
sulfide, (CH3)2S, using a ratio of one mole oxygen to How many grams of NH3 can be prepared from 77.3
two moles of the sulfide: grams of N2 and 14.2 grams of H2? (Hint: Write and
O2 + 2(CH3)2S 2(CH3)2SO balance the equation first.)
(a) 93.9 g
If this process is 83% efficient, how many grams of (b) 79.7 g
DMSO could be produced from 65 g of dimethyl (c) 47.0 g
sulfide and excess O2? (d) 120.0 g
(a) 68 g (e) 13.3 g
(b) 75 g 45.
(c) 83 g Silicon carbide, an abrasive, is made by the reaction
(d) 51 g of silicon dioxide with graphite.
(e) 47 g SiO2 +3C SiC + 2CO
40.
The formation of ethyl alcohol (C2H5OH) by the If 100 g of SiO2 and 100 g of C are reacted as far as
fermentation of glucose (C6H12O6) may be possible, which one of the following statements will
represented by: be correct?
C6H12O6 2C2H5OH + 2CO2 (a) 111 g of SiO2 will be left over.
If a particular glucose fermentation process is 87.0% (b) 44 g of SiO2 will be left over.
efficient, how many grams of glucose would be (c) 82 g of C will be left over.
required for the production of 51.0 g of ethyl alcohol (d) 40 g of C will be left over.
(C2H5OH)? (e) Both reactants will be consumed completely,
(a) 68.3 g with none of either left over.
(b) 75.1 g 46.
(c) 115 g Calculate the mass of 6.00% NiSO4 solution that
(d) 229 g contains 40.0 g of NiSO4?
(e) 167 g (a) 667 g
 (b) 540 g When 250. mL of a 0.15 M solution of ammonium
(c) 743 g sulfide (NH4)2S is poured into 120. mL of a 0.053 M
(d) 329 g solution of cadmium sulfate CdSO4, how many grams
(e) none of these of a yellow precipitate of cadmium sulfide CdS are
47. formed? The other product is (NH4)2SO4. (Hint: Write
How many grams of water are contained in 75.0 out and balance the equation. Is this a limiting
grams of a 6.10% aqueous solution of K3PO4? reagent problem? )
(a) 75.0 g (a) 5.4 g
(b) 73.2 g (b) 0.92 g
(c) 70.4 g (c) 2.6 g
(d) 68.1 g (d) 1.9 g
(e) 62.8 g (e) 530 g
48. 54.
The mass (in grams) of FeSO4 7H2O required for What alkaline earth metal is located in period 3?
preparation of 125 mL of 0.90 M solution is: (a) Li
(a) 16 g (b) Na
(b) 25 g (c) Ca
(c) 13 g (d) Mg
(d) 31 g (e) Sr
(e) 43 g 55.
49. Which of the following is classified as a metal?
What is the molarity of phosphoric acid in a solution (a) Ge
labeled 20.0% phosphoric acid (H3PO4) by weight (b) As
with a density = 1.12 g/mL? (c) F
(a) 0.98 M (d) V
(b) 2.3 M (e) Ar
(c) 2.7 M 56.
(d) 3.0 M Which of the following is a weak acid?
(e) 3.6 M (a) H2SO4
50. (b) HClO3
How many mL of 17 M NH3 must be diluted to 500.0 (c) HF
mL to make a 0.75 M solution? (d) HCl
(a) 13 mL (e) HNO3
(b) 22 mL 57.
(c) 39 mL Which one of the following is likely to be the most
(d) 73 mL soluble base?
(e) none of these (a) Ca(OH)2
51. (b) Cu(OH)2
How many grams of Ag2CO3 are required to react (c) Ga(OH)3
with 28.5 mL of 1.00 M NaOH solution? (d) Zn(OH)2
Ag2CO3 +2NaOH Ag2O + Na2CO3 + H2O (e) Zr(OH)3
(a) 7.87 g 58.
(b) 3.93 g Which one of the following statements is TRUE?
(c) 15.7 g (a) One mole of any acid will ionize completely in
(d) 10.8 g aqueous solution to produce one mole of H+ ions.
(e) 8.16 g (b) Solutions of weak acids always have lower
52. concentrations of H+ than solutions of strong acids.
How many milliliters of 0.200 M NH4OH are needed (c) There are several common acids that are
to react with 12.0 mL of 0.550 M FeCl3? insoluble.
FeCl3 + 3NH4OH Fe(OH)3 + 3NH4Cl (d) All of the IA and IIA metal hydroxides are soluble.
(e) All weak acids are insoluble.
(a) 99.0 mL 59.
(b) 33.0 mL Consider the following reaction:
(c) 8.25 mL NH3(g) + H2O(l) NH4+(aq) + OH-(aq)
(d) 68.8 mL Which one of the following statements is false?
(e) 132 mL (a) The double arrows indicate that ammonia, NH3, is
53. only very slightly soluble in water.
(b) The reaction is reversible.
 (c) When ammonia is added to water, NH4+ and OH- (b) H+(aq) + KOH(s) K+(aq) + H2O(l)
ions are produced in a 1:1 ratio. (c) CH3COOH(aq) + KOH(s) KCH3COO(aq) + H2O(l)
(d) When solutions of NH4Cl and NaOH are mixed, (d) CH3COO-(aq) + H+(aq) + K+(aq) + OH-
some ammonia is produced. (aq) K+(aq) + CH3COO-(aq) + H2O(l)
(e) Ammonia is considered to be a weak base. (e) CH3COOH(aq) + OH-(aq) CH3COO-(aq) +
60. H2O(l)
Which one of the following salts is insoluble? 66.
(a) NH4Cl What is the net ionic equation for the acid-base
(b) Ca(NO3)2 reaction that occurs when nitric acid is added to
(c) BaCO3 Carbonates except for Sodium and copper(II) hydroxide?
Potassium are insoluble (a) H+(aq) + OH-(aq) H2O(l)
(d) Na2S (b) 2H+(aq) + Cu(OH)2(s) Cu2+(aq) + 2H2O(l)
(e) Zn(CH3COO)2 (c) 2HNO3(aq) +Cu(OH)2(s) Cu(NO3)2(s) + 2H2O(l)
61. (d) 2H+(aq) + 2NO3-(aq) + Cu2+(aq) + 2OH-
What salt is formed in the following acid/base (aq) Cu(NO3)2(s) + 2H2O(l)
reaction? (e) 2H+(aq) + 2NO3-(aq) + Cu2+(aq) + 2OH-
HClO3 + Ba(OH)2 (aq) Cu2+(aq) + 2NO3-(aq) + 2H2O(l)
(a) BaCl2 67.
(b) ClOBa Which of the following statements is FALSE given the
(c) H2O following net ionic equation?
(d) BaClO3 H3PO4(aq) + 3OH-(aq) PO43-(aq) + 3H2O(l)
(e) Ba(ClO3)2 (a) If all the water evaporated a way, the salt
62. remaining could possibly be Na3PO4.
The precipitate formed when barium chloride is (b) The acid, H3PO4, is a weak electrolyte.
treated with sulfuric acid is _______ . (c) The base involved must be a strong soluble base.
(a) BaS2O4 (d) This is classified as a neutralization reaction.
(b) BaSO3 (e)This could be the net ionic equation for
(c) BaSO2 H3PO4 reacting with Al(OH)3. Weak Acid and weak
(d) BaSO4 base produces a reversible reaction
(e) BaS 68.
63. Which of the following statements is FALSE given the
The spectator ion(s) in the following reaction is/are: following net ionic equation?
Na2CO3(aq) + Ba(NO3)2(aq) BaCO3(s) + 2H+(aq) + Cu(OH)2(s) Cu2+(aq) + 2H2O(l)
2NaNO3(aq) (a) If all the water evaporated away, the salt
(a) Na+ and Ba2+ remaining could possibly be CuS.
(b) Ba2+ and CO32- (b) The acid involved must be a strong electrolyte.
(c) CO32- and NO3- (c) The base, Cu(OH)2, is an insoluble base.
(d) Na+ only (d) This could be the net ionic equation for
(e) Na+ and NO3- HNO3 reacting with Cu(OH)2.
64. (e) This is classified as a neutralization reaction.
Which one of the following statements is FALSE? 69.
(a) For the reaction of a strong acid with a strong Determine the oxidation number of carbon in K2CO3.
soluble base, the net ionic equation is always (a) 0
H+ + OH- H2O (b) +2
(b) "Spectator ions" appear in the total ionic (c) +4
equation for a reaction, but not in the net ionic (d) -2
equation. (e) some other value
(c) HF, HCl, and HNO3 are all examples of strong 70.
acids. HF is not a strong acid. Which assignment of oxidation number
(d) Titration is a process which can be used to is INCORRECT for the blinking element?
determine the concentration of a solution. (a) K2Cr2O7; +6
(e) In a neutralization reaction, an acid reacts with (b) NH3; +3
base to produce a salt and H2O. (c) H2PO2-; +1
65. (d) SeO32-; +4
What is the net ionic equation for the acid-base (e) Cu(NO3)2; +2
reaction that occurs when acetic acid and potassium 71.
hydroxide solutions are mixed? Consider the following reaction:
(a) H+(aq) + OH-(aq) H2O(l) 4NH3 + 5O2 4NO + 6H2O
 The element being oxidized and the oxidizing agent (d) the same number of protons and neutrons.
are: (e) the same mass number.
(a) N and NH3
(b) N and O2 78.
(c) O and NH3 The neutral atoms of all of the isotopes of the same
(d) O and O2 element have
(e) H and NH3 (a) different numbers of protons.
72. (b) equal numbers of neutrons.
Given that the Activity Series is: Na>Mg>Cu>Ag>Au, (c) the same number of electrons.
which one of the following answers represents the (d) the same mass numbers.
ions that would not be displaced from aqueous (e) the same masses.
solution (reduced) by metallic magnesium? 79.
(a) Na+ What is the atomic weight of a hypothetical element
(b) Cu2+ consisting of two isotopes, one with mass = 64.23
(c) Cu2+ and Au+ amu (26.0%), and one with mass = 65.32 amu?
(d) Cu2+, Ag+ and Au+ (a) 65.3 amu
(e) Na+, Cu2+, Ag+ and Au+ (b) 64.4 amu
73. (c) 64.9 amu
Which name/formula combination is WRONG? (d) 65.0 amu
(a) phosphorous acid / H3PO4 (e) 64.8 amu
(b) nitrogen oxide / NO 80.
(c) acetate ion / CH3COO- Naturally occurring rubidium consists of just two
(d) sodium chromate / Na2CrO4 isotopes. One of the isotopes consists of atoms
(e) calcium hypobromite / Ca(BrO)2 having a mass of 84.912 amu; the other of 86.901
74. amu. What is the percent natural abundance of the
Which name/formula combination is WRONG? heavier isotope?
(a) chlorous acid / HClO2 (a) 15%
(b) dinitrogen tetroxide / N2O4 (b) 28%
(c) ammonium nitrate / NH4NO3 (c) 37%
(d) copper(II) periodate / CuIO4 (d) 72%
(e) potassium permanganate / KMnO4 (e) 85%
75. 81.
Which of the following has a positive charge? What is the frequency of light having a wavelength
(a) proton of 4.50 x 10-6 cm?
(b) neutron (a) 2.84 x 10-12 s-1
(c) anion (b) 2.10 x 104 s-1
(d) electron (c) 4.29 x 1014 s-1
(e) atom (d) 1.06 x 1022 s-1
76. (e) 6.67 x 1015 s-1
Rutherford carried out experiments in which a beam 82.
of alpha particles was directed at a thin piece of The emission spectrum of gold shows a line of
metal foil. From these experiments he concluded wavelength 2.676 x 10-7 m. How much energy is
that: emitted as the excited electron falls to the lower
(a) electrons are massive particles. energy level?
(b) the positively charged parts of atoms are moving (a) 7.43 x 10-19 J
about with a velocity approaching the speed of light. (b) 5.30 x 10-20 J
(c) the positively charged parts of atoms are (c) 6.05 x 10-19 J
extremely small and extremely heavy particles. (d) 3.60 x 10-20 J
(d) the diameter of an electron is approximately (e) 5.16 x 10-20 J
equal to that of the nucleus. 83.
(e) electrons travel in circular orbits around the Which of the responses contains all the statements
nucleus. that are consistent with the Bohr theory of the atom
77. (and no others)?
Consider the species 72Zn, 75As and 74Ge. These (1) An electron can remain in a particular orbit as
species have: long as it continually absorbs radiation of a definite
(a) the same number of electrons. frequency.
(b) the same number of protons. (2) The lowest energy orbits are those closest to the
(c) the same number of neutrons. nucleus.
 (3) An electron can jump from the K shell (n = 1 (e) 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3
major energy level) to the M shell (n = 3 major
energy level) by emitting radiation of a definite 89.
frequency. Which of the following electron configurations is
(a) 1,2,3 correct for nickel?
(b) 2 only (a) [Ar] 4s1 3d8
(c) 3 only (b) [Kr] 4s1 4d8
(d) 1,2 (c) [Kr] 4s1 3d8
(e) 2,3 (d) [Kr] 4s2 3d8
84. (e) [Ar] 4s2 3d8
The Heisenberg Principle states that _____________. 90.
(a) no two electrons in the same atom can have the The outer electronic configuration
same set of four quantum numbers. ns2np4 corresponds to which one of the following
(b) two atoms of the same element must have the elements in its ground state?
same number of protons. (a) As
(c) it is impossible to determine accurately both the (b) Ca
position and momentum of an electron (c) Cr
simultaneously. (d) Br
(d) electrons of atoms in their ground states enter (e) S
energetically equivalent sets of orbitals singly before 91.
they pair up in any orbital of the set. In the ground state of a cobalt atom there are _____
(e) charged atoms (ions) must generate a magnetic unpaired electrons and the atom is _____.
field when they are in motion. (a) 3, paramagnetic
85. (b) 5, paramagnetic
Which statement about the four quantum numbers (c) 2, diamagnetic
which describe electrons in atoms is incorrect? (d) 0, diamagnetic
(a) n = principal quantum number, n = 1, 2, 3, ...... (e) 2, paramagnetic
(b) l = subsidiary (or azimuthal) quantum number, l = 92.
1, 2, 3, ... , (n+1) Which one of the following sets of quantum
(c) ml = magnetic quantum number, ml = (-l), .... , numbers could be those of the distinguishing (last)
0, .... , (+l) electron of Mo?
(d) ms = spin quantum number, ms = +1/2 or -1/2. (a) n = 4, l = 0, ml = 0, ms = +1/2
(e) The magnetic quantum number is related to the (b) n = 5, l = 1, ml = 9, ms = -1/2
orientation of atomic orbitals in space. (c) n = 4, l = 2, ml = -1, ms = +1/2
86. (d) n = 5, l = 2, ml = +2, ms = -1/2
Which atomic orbital is spherical in shape? (Note: (e) n = 3, l = 2, ml = 0, ms = +1/2
you should know and be able to recognize the 93.
shapes of the s orbital, px, py, and pz orbitals, and dxy, How many p electrons are there in an atom of
dyz, dxz, dx2-y2 and dz2 orbitals.) rubidium?
(a) 2s (a) 12
(b) 3p (b) 18
(c) 3d (c) 24
(d) 4f (d) 9
(e) they are all spherical (e) 6
87. 94.
The maximum number of electrons that can be A neutral atom of an element has 2 electrons in the
accommodated in a sublevel for which l = 3 is: first energy level, 8 in the second energy level and 8
(a) 2 in the third energy level. This information
(b) 10 does not necessarily tell us:
(c) 6 (a) the atomic number of the element.
(d) 14 (b) anything about the element's chemical
(e) 8 properties.
88. (c) the total number of electrons in s orbitals.
The ground state electron configuration for arsenic is: (d) the total number of electrons in p orbitals.
(a) [Ar] 4s2 4p13 (e) the number of neutrons in the nucleus of an
(b) [Kr] 4s2 4p1 atom of the element.
(c) 1s2 2s2 2p6 3s2 3p6 3d12 4s2 4p1 95.
(d) 1s2 2s2 2p6 3s2 3p6 4s2 3d8 4p5
 The atom having the valence-shell configuration Which of these isoelectronic species has
4s2 4p5 would be in: the smallest radius?
(a) Group VIA and Period 5 (a) Br-
(b) Group IVB and Period 4 (b) Sr2+
(c) Group VIB and Period 7 (c) Rb+
(d) Group VIIA and Period 4 (d) Se2-
(e) Group VIIB and Period 4 (e) They are all the same size because they have the
96. same number of electrons.
Select the term best describing the series of 103.
elements: Mn, Fe, Co, Ni, Cu. Which of the following elements has the greatest
(a) d-transition metals attraction for electrons in a covalent bond?
(b) representative elements (a) Ge
(c) metalloids (b) As
(d) alkaline earth metals (c) Se
(e) halogens (d) Br
97. (e) Bi
Which element has the largest atomic radius? 104.
(a) Li Which statement is wrong?
(b) Na (a) The atomic weight of carbon is about 12.
(c) Rb (b) The most stable ion of lithium is Li+.
(d) F (c) A phosphorus atom is larger than an antimony
(e) I atom.
98. (d) The radius of a sodium atom is larger than that of
Which of the following terms accurately describes a sodium cation.
the energy associated with the process: (e) Oxygen has a less negative electron affinity than
Li(g) Li+(g) + e- fluorine.
(a) electron affinity 105.
(b) binding energy All of the following properties of the alkaline earth
(c) ionization energy metals increase going down the group except
(d) electronegativity (a) atomic radius
(e) none of these (b) first ionization energy
99. (c) ionic radius
The species that contains 24 protons, 26 neutrons (d) atomic mass
and 22 electrons would be represented by the (e) atomic volume
symbol: 106.
(a) 50V3+ Which of the following is an ionic hydride?
(b) 26Cr2+ (a) PH3
(c) 50Cr2+ (b) H2S
(d) 50Mn2+ (c) HI
(e) none of these (d) KH Alkali | Alkali Earth Metals + Hydrogen
100. (e) CH4
Which element has the lowest first ionization energy? 107.
(a) He Which of the following is the most basic oxide?
(b) Ne (a) N2O3
(c) Ar (b) N2O5
(d) Kr (c) P4O6
(e) Xe (d) P4O10
101. (e) Bi2O5
Which element has the highest first ionization
energy? (Note: this is an exception to the general
trend - see notes- you may be responsible for this.)
(a) Be
(b) B
(c) C
(d) N
(e) O
102.
ANSWER KEY 57. A
58. B
1. E 59. A
2. B 60. C
3. A 61. E
4. C 62. D
5. D 63. E
6. D 64. C
7. D 65. E
8. E 66. B
9. C 67. E
10. D 68. A
11. E 69. C
12. A 70. B
13. B 71. B
14. D 72. A
15. B 73. A
16. D 74. D
17. D 75. A
18. A 76. C
19. C 77. C
20. E 78. C
21. B 79. D
22. B 80. B
23. E 81. E
24. A 82. A
25. B 83. B
26. C 84. C
27. E 85. B
28. B 86. A
29. B 87. D
30. A 88. E
31. B 89. E
32. D 90. E
33. E 91. A
34. E 92. C
35. E 93. B
36. A 94. E
37. D 95. D
38. C 96. A
39. A 97. C
40. C 98. C
41. D 99. C
42. D 100. E
43. D 101. D
44. B 102. B
45. D 103. D
46. A 104. C
47. C 105. B
48. D 106. D
49. B 107. E
50. B
51. B
52. A
53. B
54. D
55. D
56. C