FT 01.

raw
PDF 01-089-2803 Co O Cobalt Oxide
12000
PDF 01-078-1970 Co3 O4 tricobalt tetraoxide | Cobalt Oxide
PDF 01-077-2176 K2 O potassium dioxide | Potassium Oxide
11000 PDF 00-004-0858 Al2 O3 γ-Al2 O3 | Aluminum Oxide

10000

9000

8000

7000
Counts

6000

5000

4000

3000

2000

1000

0
10 20 30 40 50 60 70 80 90

2Theta (Coupled TwoTheta/Theta) WL=1.54060

Yes 0 PDF 01-089-2803 Pattern List #5 FT 01.raw #1 PDF 01-089-2803 Cobalt Oxide Co O Indexed 25.9299 %
Yes 1 PDF 01-078-1970 Pattern List #5 FT 01.raw #1 PDF 01-078-1970 tricobalt tetraoxide | Cobalt Oxide Co3 O4 Blank 86.6505 %
potassium dioxide | Potassium
Yes 2 PDF 01-077-2176 Pattern List #5 FT 01.raw #1 PDF 01-077-2176 K2 O Indexed 5.4282 %
Oxide
Yes 3 PDF 00-004-0858 Pattern List #5 FT 01.raw #1 PDF 00-004-0858 γ-Al2 O3 | Aluminum Oxide Al2 O3 Low precision 31.9350 %

3.820 12.02 % 1.0000 Yes 1.54060 Hexagonal P63mc (186) 3.21000 5.24000 2
5.290 29.00 % 1.0000 Yes 1.54060 Cubic Fd-3m (227) 8.08500 8
3.910 2.46 % 1.0000 Yes 1.54060 Cubic Fm-3m (225) 6.09000 2
(1) 56.53 % 1.0000 Yes 1.54060

46.76 5.322 No F26= 318.4(0.0028, 29)

528.49 6.053 No F30= 999.9(0.0002, 30)
225.87 1.385 No F20= 999.9(0.0002, 20)
0.00 No
 Co O
Cobalt Oxide 2.77994 32.173 615 1 0 0
2.62000 34.196 438 0 0 2
2.45575 36.561 999 1 0 1
1.90666 47.658 213 1 0 2
1.60500 57.363 306 1 1 0
1.47897 62.777 284 1 0 3
1.38997 67.309 39 2 0 0
1.36861 68.504 196 1 1 2
Hexagonal 74.93 1.34351 69.968 92 2 0 1
P63mc (186) 46.76 1.31000 72.033 15 0 0 4
5.32 1.22787 77.709 29 2 0 2
1.18502 81.088 14 1 0 4
3.820
1.08762 90.184 62 2 0 3
3.21000 1.05072 94.297 19 2 1 0
1.03021 96.785 52 2 1 1
5.24000
1.01487 98.755 27 1 1 4
1.00000 2
0.98063 103.537 39 1 0 5
1.63240
0.97522 104.347 20 2 1 2
0.95333 107.804 5 2 0 4
0.92665 112.460 24 3 0 0
0.90036 117.639 59 2 1 3
0.87362 123.705 31 0 0 6
0.87362 123.705 31 3 0 2
ANX: AX
Analysis: Co1 O1 0.83680 134.007 24 2 0 5
Formula from original source: Co O 0.83319 135.193 6 1 0 6
ICSD Collection Code: 43458
0.81964 140.036 7 2 1 4
Calculated Pattern Original Remarks: Wurtzite type
Minor Warning: No e.s.d reported/abstracted on the cell dimension. No R 0.80250 147.429 17 2 2 0
factors reported/abstracted
Wyckoff Sequence: b2(P63MC)
Unit Cell Data Source: Powder Diffraction

Structure
Publication: Nature (London)
Detail: volume 193, page 867 (1962)
Authors: Redman, M.J., Steward, E.G.
Primary Reference
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
318.4 (0.0028,29)
 Co3 O4
Cobalt Oxide 4.66788 18.997 13 1 1 1
2.85848 31.267 280 2 2 0

tricobalt tetraoxide 2.43772 36.841 999 3 1 1

2.33394 38.543 81 2 2 2
2.02125 44.804 176 4 0 0
1.85483 49.076 30 3 3 1
1.65034 55.647 76 4 2 2
1.55596 59.348 216 5 1 1
Cubic 240.8 1.42924 65.225 314 4 4 0
Fd-3m (227) 528.49 1.36661 68.618 2 5 3 1
6.05 1.34750 69.731 1 4 4 2
1.27835 74.109 23 6 2 0
5.290
1.23295 77.329 65 5 3 3
8.08500 1.21886 78.393 33 6 2 2
1.16697 82.613 17 4 4 4
1.13213 85.750 3 7 1 1
1.00000 8
1.08040 90.955 28 6 4 2
1.00000
1.05258 94.079 113 7 3 1
1.01063 99.317 32 8 0 0
0.98774 102.496 4 7 3 3
0.98045 103.563 1 6 4 4
0.95283 107.887 14 8 2 2
0.93357 111.199 51 7 5 1
ANX: AB2X4
Analysis: Co3 O4 0.92741 112.319 14 6 6 2
Formula from original source: Co3 O4 0.90393 116.896 17 8 4 0
Delete duplicate: Delete: See PDF 01-078-1969; WFM 12/04
0.88744 120.454 2 9 1 1
ICSD Collection Code: 63165
Calculated Pattern Original Remarks: Refinement for short angular range 0.88215 121.668 1 8 4 2
10 - 90 deg 0.86186 126.699 5 6 6 4
Wyckoff Sequence: e c b(FD3-MS)
Unit Cell Data Source: Powder Diffraction 0.84754 130.699 29 9 3 1
0.82517 137.975 76 8 4 4
0.81257 142.875 3 7 7 1

Structure
Publication: J. Appl. Chem.
Detail: volume 20, page 394 (1987)
Authors: Will, G., Masciocchi, N., Parrish, W., Hart, M.
Primary Reference
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
999.9 (0.0002,30)
 K2 O
Potassium Oxide 3.51606 25.310 883 1 1 1
3.04500 29.307 999 2 0 0

potassium dioxide 2.15314 41.925 607 2 2 0

1.83620 49.607 303 3 1 1
1.75803 51.973 179 2 2 2
1.52250 60.788 71 4 0 0
1.39714 66.918 95 3 3 1
1.36177 68.896 166 4 2 0
Cubic 94.2 1.24312 76.581 110 4 2 2
Fm-3m (225) 225.87 1.17202 82.180 60 5 1 1
1.38 1.07657 91.371 29 4 4 0
1.02940 96.887 55 5 3 1
3.910
1.01500 98.737 59 6 0 0
6.09000 0.96291 106.254 39 6 2 0
0.92872 112.079 21 5 3 3
0.91810 114.072 35 6 2 2
1.00000 2
0.87902 122.403 11 4 4 4
1.00000
0.85277 129.188 36 7 1 1
0.84453 131.595 30 6 4 0
0.81381 142.360 59 6 4 2

ANX: A2X
Analysis: K2 O1
Formula from original source: K2 O
ICSD Collection Code: 60489
Calculated Pattern Original Remarks: DIS O2( with disorderly orientation
in halide position. Stable from 590 to 645K, m.p
919 K, 645-719 K: trigonal (2nd ref., Tomaszewski)
Minor Warning: No R factors reported/abstracted. Magnitude of e.s.d. on
cell dimension is >1000 ppm
Wyckoff Sequence: b a(FM3-M)
Unit Cell Data Source: Single Crystal

Structure
Publication: Acta Crystallogr.
Detail: volume 5, page 851 (1952)
Authors: Carter, G.F., Margrave, J.L., Templeton, D.H.
Primary Reference
Publication: Golden Book of Phase Transitions, Wroclaw
Detail: volume 1, page 1 (2002)
Authors: Carter, G.F., Margrave, J.L., Templeton, D.H.
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
999.9 (0.0002,20)
 Al2 O3
Aluminum Oxide 2.75000 32.533 10
2.43000 36.963 60

γ-Al2 O3 2.30000 39.134 60

2.20000 40.991 5
2.00000 45.306 100
1.97000 46.035 60
1.55000 59.599 10
1.40000 66.763 100
101.96 1.15000 84.107 20
0 1.00000 100.762 10

-1.000

Deleted Or Rejected By: Delete: Berry parcel of August 6, 1957

General Comments: α alumina monohydrate heated for 1 hour at 600 C
in moving air

Primary Reference
Publication: Ind. Eng. Chem.
Detail: volume 42, page 1398 (1950)
Authors: Stumpf et al.

CuKα1 Not specified

1.54060