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Paper 2
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-C.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
1. Section–A (01 – 08, 21 – 28, 41 – 48) contains 24 multiple choice questions which have one or
more correct answer. Each question carries +4 marks for correct answer and –2 marks for
wrong answer.
Section–A (09 – 12, 29 – 32, 49 – 52) contains 12 paragraphs with each having 2 questions with
one correct answer. Each question carries +4 marks for correct answer and –2 marks for wrong
answer.
2. Section–C (13 – 20, 33 – 40, 53 – 60) contains 24 Numerical based questions with answers as
numerical value from 0 to 9 and each question carries +4 marks for correct answer. There is no
negative marking.
Enrolment No.
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AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/18 2
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2
Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6 1019 C
Mass of electron me = 9.1 1031 kg
Permittivity of free space 0 = 8.85 1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
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Physics PART – I
SECTION – A
(One or More than one correct type)
This section contains 8 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
b2 b2
(A) y (t)2 (B) y (t)
8a 2a
mb 2 2 mb2 2
(C) F (D) F
4a 8a
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AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/18 4
(A) T1 2 (B) T1 2
g 2g
L
(C) T2 2 (D) T2 2
6g 3g
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7. In Bohr model of hydrogen atom, let R, v and E represent the radius of robit, speed of the
electron and total energy of electron respectively. Which of following quantities are directly
proportional to quantum number n?
(A) vR (B) RE
v R
(C) (D)
E E
8. A neutron having kinetic energy E0 collides with singly ionised He atom at rest and move along
initial direction. Which of the following statement(s) is/are true for the above mentioned collision.
(A) Collision will be perfectly inelastic if E0 = 17 eV
(B) Collision will be perfectly inelastic is E0 = 8.16 eV
(C) If E0 = then ploton of wavelength = 500 nm is observed just after the collision if E0 = 8.16
eV.
(D) Perfectly elastic collision is not possible.
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Paragraph type
This section contains 2 paragraphs, each describing theory, experiments, data etc. Four questions relate
to the two paragraphs with two questions on each paragraph. Each question has ONLY ONE correct
answer among the four given options (A), (B), (C) and (D).
9. System is initially released from rest in the position shown. Initial acceleration of block A is:
g
(A) zero (B)
2
3g 4g
(C) (D)
7 7
10. The system is allowed to fall. Find the speed of block A at the instant when string connected to
the bead B makes an angle 37 with vertical.
5ag
(A) ag (B)
17
27ag ag
(C) (D)
68 2
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11. The upper piston is pulled up slowly by 16 cm and held there. The displacement of the lower
piston till it reaches new equilibrium state is:
(A) 2 cm (B) 4 cm
(C) 8 cm (D) 12 cm
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SECTION – C
(Single digit integer type)
This section contains 8 questions. The answer to each question is a single Digit integer ranging from 0 to
9, both inclusive.
13. A uniform rod of mass m, length rotates about its end point O in
A C
horizontal plane. If the rod is rotating with a constant angular
O
speed on a frictionless surface and the ratio of restoring force
F n /3
developed in the rod at points A and C is A 1 , where ‘n’
FC 27 /2
is an integer value, find n.
15. Figure shows a metal rod of uniform cross section area A, with T0 (A) (B)
variable thermal conductivity given by k(x) k 0 sec x . If
6L
the end A is maintained at temperature T0, the rod carries a
I0L
thermal current I0 (from B to A) in steady state and ;
k 0 AT0 3
x=0 x=L
find the temperature of the end B of the rod. Let’s say this
temperature is kT0, find integer value k.
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20. A tube with thin but uniform cross section has two
arms, one straight, other shaped as a semicircle of
radius r. Initially both arms carry an ideal fluid upto a
height R. Now the equilibrium is disturbed by pushing
the fluid in the left arm by a small amount. Fluid is
then released and allowed oscillate. Neglect any
friction or viscous forces. If the time period of
oscillations is found to be R
nR 30
T n ; find the integer value n.
3g
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Chemistry PART – II
SECTION – A
(One or More than one correct type)
This section contains 8 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
A is
HO NH2
HO
22. 100 ml of 0.05 M CuSO4(aq) solution was electrolysed using inert electrodes by passing current
till pH of the resulting solution was 2. The solution after electrolysis was neutralized and then
treated with excess of KI and formed I2 titrated with 0.04 M Na2S2O3. Calculate the required vol. in
ml of Na2S2O3.
(A) 112.5 ml (B) 100 ml
(C) 125 ml (D) none of these
HO H HO H
H CH3 H OH
OH CH3
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24. X Z
C C C
1 2 3
Y
The electron cloud of C1 – C2 is present in the plane of paper than which of the following is
incorrect?
(A) Z is perpendicular to the plane of paper.
(B) X is present in the plane of paper.
(C) bond of C2 – C3 is perpendicular to the plane of paper.
(D) electron cloud of C2 – C3 bond and X is present in same plane.
25. H3C Me
O Me
Y KOH/EtOH
X H3C
Z
CHO O
Me Me
Choose the correct option (s)
(A) Me O (B) Y is O3/(CH3)2S
X is
Me
CH3
(C) (D) Me O
Z is X is
26. How many of the following reaction(s) have sum of co-efficient of reactants after balancing either
3 or 4.
(A) FeSO4
Fe2 O3 SO2 SO3 BrO Br H2 O
(B) Br2 OH
(C) Cl2 SeO32 H2O SeO 42 Cl H (D) Cl2 IO3 OH Cl IO4 H2 O
heat
27. COOH2 X gas Y gas Z gas
Y and Z both are polar and neutral, X is non polar and acidic. Z gas is condensed and formed
liquid having pH = 7. The hybridization state of X, Y and Z are respectively.
(A) sp, sp2, sp3 (B) sp2, sp3, sp3d
3
(C) sp, sp, sp (D) sp2, sp2, sp3
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Paragraph type
This section contains 2 paragraphs, each describing theory, experiments, data etc. Four questions relate
to the two paragraphs with two questions on each paragraph. Each question has ONLY ONE correct
answer among the four given options (A), (B), (C) and (D).
5
2 moles of He gas r are initially at a temperature of 27oC and occupy a volume of 20 L. The gas is
3
first expanded at constant pressure until the volume is doubled, then undergoes reversible adiabatic
change until the temperature returns to its initial value.
V V
(C) P
(D) P
V
V
32. What are the initial pressure and final volume of gas?
(A) 2.46 atm, 110 L (B) 4.9 atm, 113.13 L
(C) 2.46 atm, 113.13 L (D) 4.9 atm, 110 L
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AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/18 14
SECTION – C
(Single digit integer type)
This section contains 8 questions. The answer to each question is a single Digit integer ranging from 0 to
9, both inclusive.
33. Total number of moles of EDTA4– required to produce octahedral complex with Mg2+ is
34. Number of moles of NaOH required for complete neutralization of H+ in solution which is formed
by complete hydrolysis of 1 mole of PCl5.
35. If 2s – 2p mixing is not operative the diamagnetic species among the following is/are
H2 ,H2 ,Li2 ,B2 ,C2 ,N2 ,O 2 ,F2
36. Find total number of d-electron(s) in metal ion complex [M(NH3)4]2+. [EAN of metal = 35]
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37. Equal volumes of 0.2 M KI solution and 0.1 M HgI2 solution are mixed. Find the van’t Hoff factor
of the resulting solution.
38. In the monochlorination of 3-methylpentan, let x be the number of pairs of isomers which exist as
enantiomers, y be the number of pairs of isomers which exist as diastereomers, z be the number
of isomers which are achiral. Calculate the value of x + y + z.
39. What is the number of carbon present in the final product of given synthesis?
excess HI Mg CO
A
ether B
2
H O
P
3
40. In 1 litre saturated solution of AgCl [Ksp = 1.6 × 10-10], 0.1 mole of CuCl [Ksp = 1 × 10-6] is added.
The resultant concentration of Ag+ in the solution is 1.6 × 10-x M. The value of x is
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SECTION – A
(One or More than one correct type)
This section contains 8 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
41. Consider f as a twice differentiable function such that f(x) + f(x) = –x g(x)f(x) x 0 where,
g(x) 0 x 0, then ( x 0)
(A) (f(x))2 + (f(x))2 is a non increasing function
(B) (f(x))2 < 3(f(0))2 + (2f(0))2
(C) |f(x)| , is a fixed real constant
1
(D) lim f x sin exist
x x
42. Consider P, Q, R to be vertices with integral coordinates and (|PR| + |RQ|)2 < 8. Area (PQR) +
1, then
(A) R can be a right angle
(B) PQR can be isosceles
(C) P, Q, R can lie on a square
(D) P, Q, R can lie on circle centred on midpoint of line segment PQ
43.
Consider vectors a , b , c ; p b c a c a b ; q a c b a b c ; r b a c b c a , then
(A) p c 0
(B) p, q, r can form a triangle
(C) A a B b C c and P p Q q R r are similar
(D) p, q, r are collinear
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44. Consider an equation z1997 = 1 (z is a complex number). If , are its two randomly chosen roots.
‘p’ denotes the probability that 2 3 , then
a 1
(A) p ,aI (B) lies in [5, 15)
1996 p
1 83 1
(C) is 8 is divisible by 2 (D) 2 is 6
p 50 p
45. Let ABCD be a quadrilateral with CBD = 2ADB, ABD = 2CDB, AB = BC, then
(A) AD = CD (B) ADB = CDB
2
(C) CBD = ABD (D) ADC is
3
46. If, f: (0, ) (0, ) for which there is a positive real number ‘a’ such that it satisfies differential
a x
equation f , then
x f x
(A) f(x) can be linear
1/n
(B) f(x) can be a functional of the type m x ; m R+, n I+
(C) f(x) can be positive
(D) f(x) can be twice differentiable
47. A variable plane passes through the point (1, 2, 3) and meets the coordinate axis is P, Q, R.
Then, the locus of the point common to the planes through P, Q, R parallel to coordinate planes
(A) contains point (3, 6, 9) (B) passes through (0, 0, 0)
1 1 1 x 1 y 2 z 6
(C) is 1 (D) contains line
x y z 2 4 15
48. Consider a, b, c, d, e, f, g, h to be eight distinct alphabets then the number of ways in which they
can be divided in 4 – parts is
(A) 1260 if exactly 2 – parts are equal
(B) 1701 in total
(C) 280 if its divided into two partitions of 3 and two of 1
(D) 210 if all parts are equal
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Paragraph type
This section contains 2 paragraphs, each describing theory, experiments, data etc. Four questions relate
to the two paragraphs with two questions on each paragraph. Each question has ONLY ONE correct
answer among the four given options (A), (B), (C) and (D).
Read the following write up carefully and answer the following questions:
Consider a function f: R R; f(x2 + y f(z)) = x f(x) + z f(y) x, y, z R
50. If g(x) = |f(x)| + f(|x|) then (f(x) = 0 x R is not considered part of solution set)
(A) g(x) is not continuous x R
(B) g(x) is differentiable except at two points x R
(C) g(x) is differentiable at x = sin ( n, n I)
(D) g(x) is non differentiable at integers
Read the following write up carefully and answer the following questions:
Let A0, A1, ..... An – 1 be a n-sided polygon with vertices as 1, , 2, ....., n – 1. Let B0, B1, ....., Bn – 1 be
2 2
another polygon with vertices 1, 1 + , 1 + 2, ....., 1 + n – 1 cos isin
n n
Ar. A 0 , A1, A 2 , A 3
51. For n = 4, is , then
Ar. B0 , B1, ....., B3
3
(A) [] > 3 (B) I
2
(C)
I (D) is irrational
3
Ar. A 0 A1 A 2
52. is
Ar. B0 B1 B2
(A) less than 1 (B) an irrational number
(C) lies in (0, ) (D) less than
2
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SECTION – C
(Single digit integer type)
This section contains 8 questions. The answer to each question is a single Digit integer ranging from 0 to
9, both inclusive.
1 1
2
x x f x
2
53. For continuous function f: [0, 1] R; A = f x dx ; B = dx then, maximum
0 0
1
value of A – B is where is _____
4
55. Consider a equation x 3 3x x 2 such that x is a real number then sum of its positive roots is
where is _____
2
x2 y2
57. Consider an ellipse 1 and ABCD be a quadrilateral circumscribing the ellipse. Let S be
25 16
3
one of its focii, then ASB + CSD = where, is _____
58. Consider a parabola y2 = 8x. If PSQ is a focal chord of the parabola whose vertex is A and focus
S, V being the middle point of the chord such that PV2 = AV2 + ·AS2 where is _____
f x f x f x
59. If (0, 1) and f: R R and lim f x 0 , lim 0 , then lim where
x x x x x
2 + 7 is _____
60. Let f: [a, b] R be a function, continuous on [a, b] and twice differentiable on (a, b). If, f(a) = f(b)
and f(a) = f(b), then consider the equation f(x) – (f(x))2 = 0. For any real the equation has
atleast M roots where 3M + 1 is _____
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