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Physics PART – I
SECTION – A
(One Options Correct Type)
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and
n
(D), out of which ONLY ONE option is correct.
io
1. Two projectiles are thrown from the same point simultaneously with initial speeds u1 and
u2 at angles θ1 and θ2 with horizontal respectively If u1 sin θ1 = u2 sin θ2, then path of one
ut
projectile as seen from other will be
ol
(A) A parabola (B) A vertical straight line
(C) A horizontal straight line (D) none of above
-S
Ans. C
Sol. Vertical component of initial velocities are same. Hence, identical vertical motions.
PC
2. In order to calculate the speed of sound in nitrogen gas at 300 K, you are given that the
gas is diatomic. You will also need to know only the
(A) density of the gas at 300 K, and the mass of one mole of the nitrogen
(B) pressure of the gas at 300 K
-M
(C) molecular weight of nitrogen and the universal gas constant
(D) characteristic gas constant for nitrogen
Ans. C
e
γRT
Sol. v=
in
M
nl
3. A spring of force constant k is cut into two pieces such that one piece is double the
length of the other. Then the long piece will have a force constant of
-O
2 3
(A) k (B) k
3 2
(C) 3k (D) 6k
st
Ans. B
Sol. k′2l = k3l
Te
3
k= k
2
n
(B) A positive amount of work has been done by gravity on the bob.
(C) The tension in the string and speed of bob both may become zero
at an instant. m u0
(D) None of these.
Ans. C
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AIITS-OT-PCM-JEE(Main)/19 2
Sol. When u0 has such a value that bob will just stop when string is horizontal. Then the
situation given in option (C) will arise.
n
k k
mg mg
io
(C) (D)
2k 3k
ut
m
Ans. D
ol
Mg Mg
Sol. Kx = ; x=
-S
3 3k
6. A simple pendulum has time period T = 2s in air. If the whole arrangement is placed in a
1
PC
nonviscous liquid whose density is times the density of bob. The time period of the
2
simple pendulum in the liquid will be
2
(A) s (B) 4 s
-M
2
(C) 2 2 s (D) 4 2 s
Ans. C
e
l
Sol. T = 2π
in
geff
nl
7. A gas bubble from an explosion under water oscillate with a period T proportional to pa
db Ec where p is the static pressure, d is the density and E is the total energy of
-O
Ans. D
T ∝ Pa db Ec
Te
Sol.
T ∝ (ML−1 T −2 )a (ML−3 )b (ML2 T −2 )c
Comparing power on LHS and RHS.
n
a + b + c = 0, –a – 3b + 2c = 0, –2a – 2c = 1
pe
8. A heavy disc is thrown on a horizontal surface with an initial linear velocity of v0. It will
start pure rolling when its linear velocity becomes
v 2v 0
O
(A) 0 (B)
2 3
3v 0 5v 0
(C) (D)
5 7
Ans. B
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3 AIITS-OT-PCM-JEE(Main)/19
ft
Sol. v = vo −
m
τ = Iα
1 2f 2ft
fR = MR2 α ; αR = ; ω= ; v = ωR
2 m mR
ft 2ft
vo − = ×R
n
m mR
io
3ft mv o 2v
= vo ; t = ; v= o
m 3f 3
ut
9. A string of length 1m and linear mass density 0.01 kg m–1 is stretched to a tension of 100
ol
N. When both ends of the string are fixed, the three lowest frequencies for standing
wave are f1, f2 and f3. When only one end of the string is fixed, the three lowest
-S
frequencies for standing wave are n1, n2 and n3. Then
(A) n3 = 5n1 = f3 = 125 Hz (B) f3 = 5f1 = n2 = 125 Hz
f +f
(C) f3 = n2 = 3f1 = 150 Hz (D) n2 = 1 2 = 75 Hz
PC
2
Ans. D
m T 2m + 1 T
Sol. f= ; n=
-M
2l µ 4l µ
-1 -1
10. Two identical blocks each of mass 1 kg are join together 3ms 5ms
with a compressed spring. The system at any time after
e
(B) whatever may be the speed of the blocks the centre of mass will remain stationary
(C) the centre of mass of the system is moving with a velocity of 2ms-1
-O
(D) the centre of mass of the system is moving with a velocity of 1 ms-1
Ans. D
1 × 5 + 1 × ( −3 )
v cm =
st
Sol.
2
2
Te
=1m / s
2
11. A U tube of uniform cross section is kept in a vertical position. A liquid of mass m and
n
density d is filled in one of its limbs. This liquid will oscillate in this tube with time period T
pe
given by
m ma
(A) T = 2π (B) T = 2π
gda gd
O
m m
(C) T = 2π (D) T = 2π
g 2agd
Ans. D
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AIITS-OT-PCM-JEE(Main)/19 4
R −h
(A) 0 (B) cos−1
n
R h
h−R R −h
io
(C) cos−1 (D) sin−1
R R
ut
Ans. B
ol
R −h
Sol. sin ( 90 − θ ) =
R
-S
R
R-h
PC
90-θ
θ
-M
13. A firecracker exploding on the surface of a lake is heard as two sounds a time interval t
apart by a man on a boat close to water surface. Sound travels with a speed u in water
and a speed v in air. The distance from the exploding firecracker to the boat is (u > v)
uvt t(u + v)
e
(A) (B)
u+v uv
in
t(u − v) uvt
(C) (D)
uv u−v
nl
Ans. D
-O
x x
Sol. t1 = and t 2 =
v u
plane. vo
At some instant it has translational velocity vo and rotational
Te
O
velocity about the centre vo/2r. Find the velocity of bottom most
point A of the sphere. x′′(−
−ve) A +x →
(A) vo/2 in +ve x-direction.
n
Ans. A
Sol. Translational velocity of A = Vo (towards right)
V
Rotational velocity of A = ωR = o (towards left)
2
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5 AIITS-OT-PCM-JEE(Main)/19
15. In order to shift a body of mass m from a circular orbit of radius 2R to a higher orbit of
radius 4R around the earth, (Where R is radius and M is mass of earth) the work done
on the body is
GMm GMm
(A) (B)
8R 2R
GMm GMm
(C) (D)
n
4R R
io
Ans. A
GMm GMm GMm
ut
Sol. W=− − − =
2 ( 4R ) 2 ( 2R ) 8R
ol
16. For a given process with an enclosed one mole of
-S
2
P (N/m )
monoatomic ideal gas, the variation of its pressure (P) with
2 B
its volume (V) is as shown in the graph AB. If the
temperature of the gas at A is (To )K, then,
A
(A) the temperature at B = (2To)K
PC
1
(B) the temperature at B = (3To)K 3
V (m )
(C) the work done by gas from A to B is 1.5 J 0 1 2
(D) the change in the internal energy of the gas is 9RTo.
-M
Ans. C
Sol. PV = nRT
e
17. A tank with vertical walls is mounted so that its base is at a height H above the horizontal
ground. The tank is filled, with water to a depth h. A hole is punched in the side wall of
in
the tank at a depth x below the water surface. To have maximum range of emerging
stream, the value of x is (h > H)
nl
H−h H
(A) (B)
-O
2 2
h H+h
(C) (D)
2 2
st
Ans. D
2 ( −x + H + h)
Te
H+h
rmax at x =
pe
18. A boat carrying a number of large stone piece is floating in a water tank. What will
O
happen to the water level if the stones are unloaded into the water?
(A) rises
(B) falls
(C) remains unchanged
(D) rises till half the number of stones are unloaded and then being to fall
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AIITS-OT-PCM-JEE(Main)/19 6
Ans. B
Sol. When stones are there inside the boat. the volume of water displaced is equal to the
weight of the boat + stones. When stones are unloaded into the water the volume of
water displaced is equal to the volume of stones unloaded plus (weight of boat) /
(density of water). This time the displaced volume of water is smaller than in the first
case. Therefore the water level falls.
n
19. An open organ pipe of length L vibrates in second harmonic mode. The pressure
io
vibration is maximum
(A) at the two ends
ut
(B) at a distance L/4 from either end inside the tube
(C) at the mid-point of the tube
ol
(D) none of these
-S
Ans. B
Sol. Pressure node is formed at the both the ends and in
the middle.
PC
20. A body of mass m is falling freely through a height h from the top of a tower. The velocity
just before touching the ground is ( 3 / 2 ) gh . The work done by air drag is
-M
mgh mgh
(A) − (B) +
4 4
(C) zero (D) none of these
e
in
Ans. A
2
1 3 mgh
gh = −
nl
Sol. W = –mgh + m
2 2 4
-O
21. A man holds an umbrella at 300 with vertical to keep himself dry. He then runs at a
speed of 10 ms-1 and find the raindrops are hitting him vertically. Speed of the raindrops
wrt earth is
(A) 20ms−1 (B) 10ms−1
st
Ans. D
Sol. V = (10 3 )2 + (10)2 = 20
n
g
acceleration a = . The reaction offered by ground on the block of
2
O
mass 2 m is: a=
g
2
3mg
(A)
2
(B) mg m
mg
(C) 2mg (D) 2m
2
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7 AIITS-OT-PCM-JEE(Main)/19
Ans. D
g
Sol. T – mg = m
2
mg
N = 2 mg – T =
2
n
23. A cubical frame is made by connecting 12 identical uniform
E F
io
conducting rods as shown in the figure. In the steady state
the temperature of junction A is 1000 C while that of the G is
A B
ut
00 C . Then, a
(A) H will be Hotter than B
00C
ol
(B) Temperature of F is 400 C H G
(C) Temperature of D is 66.670 C
-S
D a C
(D) Temperature of E is 500 C
Ans. B
I
PC
Sol. 100°C – Ir – r − Ir = 0°C
2
⇒ Ir = 40°C ; ∴ tF = 0° + Ir = 40°C -M
24. What change in surface energy will be noticed when a drop of radius R splits up into
1000 droplets of radius r, surface tension of T?
(A) 4 πR2 T (B) 7πR2 T
(C) 16πR T2
(D) 36πR2 T
e
in
Ans. D
Sol. ∆U = T(∆A)
nl
R
2
∆U = T 1000 × 4π − 4πR2 = T × 4π(9R2)
-O
10
∆U = 36πR2T
25. A train of mass M is moving on a circular track of radius R with constant speed v. The
st
length of train is half the perimeter of track. The linear momentum of the train will be
(A) 0 (B) 2Mν/π
Te
Ans. B
n
+90
Sol. Total momentum = ∫ (dm)v cos θ
pe
θ =−90
M
dm = × Rdθ
O
πR
M 2Mv
Total momentum = ∫ πR vRdθ cos θ = π
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AIITS-OT-PCM-JEE(Main)/19 8
26. The force exerted by a liquid density ρ, on the wall of the dam b
of width b, as shown in the figure, Atmospheric pressure is P0.
ρgh
(A) P0 + bh (B) (P0 + ρgh ) bh h
2
ρgh P + ρgh
(C) P0 + bh (D) 0 bh
3 2
n
io
Ans. A
ρgh
ut
Sol. Pressure due to liquid =
2
Force = (Total Pressure) (Area of wall)
ol
27. A uniform disc of radius R lies in the x – y plane, with its centre at origin moment of
-S
inertia about z – axis is equal to its moment of inertia about line y = x + c. The value of c
will be –
R R
(A) − (B) ±
PC
2 2
+R
(C) (D) – R
4
-M
Ans. B
L
MR2 Y
Sol. For disc z-axis I = X′
2
e
IX′ = X
4
nl
mR 2
IL = + m(C cos 45o )2
4
-O
(C) υ0 + g / 2 + f / 3 (D) υ0 + g + f
Te
Ans. C
dx
Sol. = v = v 0 + gt + ft 2
n
dt
pe
∫ dx = ∫ vdt
0
O
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9 AIITS-OT-PCM-JEE(Main)/19
29. A car accelerates from rest with a constant acceleration α on a straight road. After
gaining a velocity ν the car moves with the same velocity for some-time. Then the car
decelerated to rest with a retardation β . If the total distance covered by the car is equal
to S, the total time taken for its motion is
S ν 1 1 S ν α
(A) + + (B) + +
ν 2α β ν α β
n
ν ν S νν ν
(C) + − +
io
(D)
α β ν 2α β
ut
Ans. A
V
ol
1 v v
Sol. t + t − + v = s
α β
v1
2
-S
θ
t
Area under v – t curve = S
PC
30. In order to do work :
(A) force must act at any angle to the displacement
(B) Force may not act along the same direction as is the displacement
-M
(C) must act along the direction of displacement
(D) must act normal to the direction of displacement
Ans. B
Sol. Component of force or force must be act in direction of displacement to do positive work.
e
in
nl
-O
st
Te
n
pe
O
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AIITS-OT-PCM-JEE(Main)/19 10
Chemistry PART – II
SECTION – A
(One Options Correct Type)
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and
n
(D), out of which ONLY ONE option is correct.
io
31. XeF4 is planar whereas CCl4 is tetrahedral because
(A) in XeF4, Xe is sp2 hybridised and C is sp3 hybridised in CCl4.
ut
(B) Xe is sp3d2 hybridised in XeF4 but due to the presence of two lone pairs of electrons,
the shape is planar whereas in CCl4, C is sp3 hybridised.
ol
(C) in both XeF4 and CCl4, the central atom is sp3 hybridised.
(D) Xe is a noble gas whereas C is a non-metal.
-S
Ans. B
Sol. XeF4 is planar because Xe is sp3d2 hybridised. Due to the presence of two lone pairs of
electrons, the shape is reduced to a square planar. CCl4 is tetrahedral because C is sp3
PC
hybridised. The correct answer is (B)
(A) 0 (B) 1
in
(C) 2 (D) 4
nl
Ans. C
Sol. SO32− get oxidized and its `n’ factor is 2.
-O
33. The compound most likely to decolourise a cold solution of alkaline potassium
Te
permanganate is
CH3
pe
CH3
Ans. A
Sol. It is a test for unsaturation. As benzene and naphthalene is also unsaturated, but they
are stabilized due to resonance, and thus does not give Bayer’s test.
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11 AIITS-OT-PCM-JEE(Main)/19
34. Which one of the following compounds will give in the presence of peroxide a product
different from that obtained in the absence of peroxide?
(A) 1-butene HCl (B) 1-butene, HBr
(C) 2-butene, HCl (D) 2-butene, HBr.
Ans. B
Sol. Peroxide effect is observed when unsymmetrical alkene is treated with HBr only (and not
n
with HCl and Hl).
io
35. Of the following transitions in hydrogen atom, the one which gives an absorption line of
ut
lowest frequency is
(A) n = 1 to n = 2 (B) n = 3 to n = 8
ol
(C) n = 2 to n = 1 (D) n = 8 to n = 3
-S
Ans. B
Sol. Absorption line in the spectra arise when energy is absorbed i.e., electron shifts from
lower to higher orbit, out of a and b, b will have the lowest frequency as this falls in the
Paschen series.
PC
36. Each of the following pair contains species with the same geometry EXCEPT
(A) P O34− , S O24− (B) NH+4 , BF4−
-M
(C) CO2, C2H2 (D) N2O, NO2
Ans. D
Sol. In (A) P O−43 and S O−42 both are isoelectronic and tetrahedral in shape. Same is in (B)
e
also. In (C) each C atom in C2H2 is sp hybridized same as C in CO2 hence, both are
linear. Only in (D) N2O is linear whereas NO2 is bent and therefore, the answer is (D)
in
nl
37. A reaction mixture containing H2, N2 and NH3 has partial pressures 2 atm, 1 atm and 3
atm respectively at 725 K. If the value of Kp for the reaction, N2(g) + 3H2(g) 2NH3(g)
-O
is 4.28 × 10–5 atm–2 at 725 K, in which direction the net reaction will go ?
(A) Forward
(B) Backward
(C) No net reaction
st
Ans. B
(P )
2
NH3 (3)2 9
Sol. Qp = = = atm−2 = 1.125 atm–2.
P × (P )
3
(1)(2)3 8
n
N2 H2
Since value of Qp is larger than Kp (4.28 × 10–5 atm–2), it indicates net reaction will
pe
38. 10 L of aqueous solution contains 0.1 mole of each of NaCl, CH3COONa and
CH3COOH. What is the pH of the solution?
[Ka of CH3COOH = 10–5]
(A) 3 (B) 6
(C) 4 (D) 5
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AIITS-OT-PCM-JEE(Main)/19 12
Ans. D
Sol. pH = pK a + log
[CH3COONa] = 5 + log 0.110 = 5
[CH3COOH] 0.1
10
39. A solution of HCl is diluted so that its pH changes by 0.3. How does concentration of H+
ion change?
n
(A) 0.5 times of initial value (B) 0.3 times of initial value
io
(C) 10–3 times increases (D) None
ut
Ans. A
Sol. Let H+ ion concentration changes by x factor.
ol
Q pH = – log [H3O+]
∴ pH + ∆pH = – log {x(H3O+]} = –log x – log [H3O+]
-S
or ∆pH = – log x = 0.3
∴ x = 0.5
40. If for two gases of molecular weights MA and MB at temperature TA and TB, TAMB = TBMA,
PC
then which property has the same magnitude for both the gases.
(A) density (B) pressure
(C) KE per mole (D) Urms -M
Ans. D
PM MB MA ∴
Sol. i) Density of a gas ( ρ ) = . Since = . at the same pressure ρA = ρB.
RT TB TA
e
3
iii) KE per mole = RT
nl
2
∴ It will be different for the two gases
-O
3RT T T
iv) Urms = , Since A = B ; Urms of A = Urms of B
M MA NB
41. Assuming that air is 79% by mole of N2, 20% O2 and 1% Ar, the density of air at 25°C
st
and 1 atm is
(A) 1.18 g/lit (B) 1.08 g/lit
Te
Ans. A
n
Sol. PV = nRT
w RT ρRT
pe
P= =
M V M
PM eff
ρ=
O
RT
M eff = (0.79 × 28) + (0.20 × 32) + (0.01× 39.9) = 28.9
28.9 × 1
∴ρ = = 1.18 g / lit
0.0821× 298
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13 AIITS-OT-PCM-JEE(Main)/19
42. SiO2 + HF → X + Y
HF
→Z
Compound (Z) in the above reaction is:
(A) SiF4 (B) H2SiF4
n
(C) H2SiF6 (D) H2SiF3
io
Ans. C
ut
Sol. SiO 2 → SiF4 → H2 [SiF6 ]
ol
43. Pyrosilicate ion is:
(A) SiO22− B) SiO42−
-S
(C) Si2O76− D) Si2O77−
Ans. C
Si ( OH)4
→ 2H4 SiO4 → H6 Si2O7
PC
Sol. −H O 2
Cl Cl Cl Cl Cl Cl
in
Cl Cl Cl
(X ) (Y) (Z)
nl
Ans. B
Sol. Anti elimination.
st
45. OH
Te
H+
→ P, P is
∆
HO
n
pe
OH
[info there is interconversion between the given compounds
O
CH2 ]
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AIITS-OT-PCM-JEE(Main)/19 14
(A) (B)
n
(C) (D)
io
ut
Ans. D
ol
Sol. Ring expansion.
-S
46. For the reaction equilibrium
2NOBr ( g) 2NO ( g) + Br2 ( g )
P K
If PBr2 =at equilibrium and P is total pressure. The ratio P is equal to
PC
9 P
1 1
(A) (B)
9 81 -M
1 1
(C) (D)
27 3
Ans. B
e
2
PNOPBr2
Sol. KP =
in
2
PNOBr
nl
Ans. B
Sol. ∆G = -ive for spontaneous
Te
48. The first ionisation enthalpies of Na, Mg, Al and Si are in the order:
(A) Na < Mg > Al < Si (B) Na > Mg > Al > Si
n
Ans. A
Sol. Mg has full filled s-orbital.
O
49. The types of hybrid orbitals of nitrogen in NO+2 ,NO3− and NH+4 respectively are expected to
be
(A) sp, sp3 and sp2 (B) sp, sp2 and sp3
2 3
(C) sp , sp and sp (D) sp2, sp3 and sp
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15 AIITS-OT-PCM-JEE(Main)/19
Ans. B
Sol. O H
O=N=O, N , N
O O H H
H
n
50. Which molecule/ion out of the following does not contain unpaired electrons?
(A) N2+
io
(B) O2
(C) O22− (D) B2
ut
Ans. C
ol
π 2p2 πα 2p2y
Sol. σ1s2 , σ α 1s2 , σ2s2 , σα 2s2 , σ2p2 , π 2p2y πα 2p2z
z
-S
51. In each of the following total pressure set-up at equilibrium is assumed to be equal and
is 1 atm. With equilibrium constants Kp given as K1, K2 & K3 for I, II & III equilibria
respectively, which of the following is correct ?
PC
I. CaCO3(s) CaO(s) + CO2(g), K1
II. NH4HS(s) NH3(g) + H2S(g), K2
III. NH2CO2NH4(s) 2NH3(g) + CO2(g), K3
(A) K1 = K2 = K3 (B) K1 < K2 < K3
-M
(C) K3 < K2 < K1 (D) None of these
Ans. C
e
( ) 2 1
2
K 3 = pNH3 × pCO2 = ×
-O
3 3
4 1 4
= × = = 0.148 atm3
9 3 27
∴ The order is K1 > K2 > K3
st
52. Under the same reaction conditions, initial concentration of 1.386 mol. dm–3 of a
Te
substance becomes half in 40 seconds and 20 seconds through first order and zero
[K1 ]
order kinetics, respectively. Ratio of the rate constants for first order (K1) and zero
[K 0 ]
n
Ans. A
0.693 0.693 A 1.386
Sol. K1 = = K0 = 0 =
t1/2 40 2t1/2 2 × 20
K1 0.693 40
= ×
K0 40 1.386
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AIITS-OT-PCM-JEE(Main)/19 16
0.693
= = 0.5mol– litre
1.386
53. Solubility of AgCl in water, 0.01M CaCl2, 0.01M NaCl and 0.05M AgNO3 are S1, S2, S3
and S4 respectively then.
(A) S1 < S2 < S3 < S4 (B) S1 > S3 > S2 > S4
n
(C) S1 > S2 = S3 > S4 (D) S1 > S3 > S4 < S2
io
Ans. B
Sol. AgCl Ag+ + Cl–
ut
In CaCl2
CaCl2 Ca+2 + 2Cl–
ol
0.01 0.01 2×0.01
In NaCl
-S
NaCl Na+ + Cl–
0.01 0.01 0.01
In AgNO3
AgNO3 Ag+ + Cl–
PC
0.05 0.05 0.05
common ion effect is maximum in AgNO3
So, S1 > S3 > S2 > S4
-M
+ Na2 CO3
54. SiCl4 H2 O
→ (A)
Heat
→ (B) Heat
→(C). The compound (C) is;
(A) SiO2 (B) Si
(C) SiC (D) Na2SiO3
e
in
Ans. D
+ Na2 CO3
Sol. SiCl4 + H2O
→ Si(OH)4
Heat
→ SiO2 → Na2SiO3
nl
Heat
(A) (B ) (C)
-O
55. Aluminium chloride exists as a dimmer, Al2Cl6, in solid state as well as in solution of non-
polar solvents such as benzene. When dissolved in water, it gives :
3+
(A) Al3 + + 3Cl− (B) Al (H2O )6 + 3Cl−
st
3−
(C) Al ( OH)6 + 3HCl (D) Al2O3 + 6HCl
Te
Ans. B
Sol. The dimeric formula, Al2Cl6, is retained in non-polar solvent but is broken into
Al (H2O )6 Cl3 on dissolution in water on account of high heat of hydration.
n
pe
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17 AIITS-OT-PCM-JEE(Main)/19
Ans. A
n
57. A mixture of two gases is formed when an organic acid heated with conc.H2SO4. When
the gaseous mixture is passed through KOH solution, one gas is absorbed. The
io
unabsorbed gas combines with chlorine and forms a poisonous gas. The organic acid
and the two gases evolved with conc. H2SO4 are respectively:
ut
(A) CH3COOH, CO2, CO
(B) oxalic acid, CO2, CO
ol
(C) HCOOH, CO, H2O
(D) none of these
-S
Ans. B
PC
KOH
→
2 4
CO + CO2 → CO ←
Sol. –H2O CO2 is Poisonous gas
absorbed ↓
COOH COCl2 -M
58. An inorganic compound (A) made of two most occurring elements in the earth’s crust
and used in building construction when made to react with carbon, forms a poisonous
gas (B) which is most stable hetero diatomic molecule. Compounds (A) and (B) are
(A) SiO2, CO2 (B) SiO2, CO
e
Ans. B
nl
Sol. SiO2 is a compound of oxygen and silicon, the two most abundant elements of earth’s
crust and is used in building construction.
-O
59. A reaction, 2A → 3B takes place according to first order kinetics. The time in which the
concentration of reactant and product become equal is (k = 4.6 × 10–2 min–1), (log 5 =
0.7; log 3 = 0.48; log 2 = 0.3)
st
Ans. A
Sol. 2A 3B
n
t=0 a 0
t = t a – 2x 3x
pe
3x
given =1
a – 2x
O
a 2.3 a
i.e. x = ⇒ t = log = 11.0 min
5 4.6 × 10 –2
a – 2x
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AIITS-OT-PCM-JEE(Main)/19 18
60. A vessel contains H2 and H2S gases at a partial pressures of 1 and 2 atm respectively at
certain temperature then the reaction, 8 H2S (g) 8H2(g) + S8(s) occurs. It is found
nH nH S
that 2 = 2 (n represents no of moles). Then identify the correct
nH2S at equilibrium nH2 at time,t =0
value of the given property :
n
(A) KP = 1/256
(B) KP = 256
io
(C) At equilibrium the volume of the gaseous mixture is doubled when provided with
frictionless piston
ut
(D) KP = KC = 320
ol
Ans. B
nH2 1
-S
Sol. Initially =
nH2S 2
8H2S 8H2 + S8
Initial moles : 2 1 –
PC
moles at equil : 2–x 1+x –
nH2 1+ x
At equilibrium : = =2
nH2S 2 − x
-M
Hence x = 1
KP = 28/18 = 256
e
in
nl
-O
st
Te
n
pe
O
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19 AIITS-OT-PCM-JEE(Main)/19
SECTION – A
(One Options Correct Type)
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and
n
(D), out of which ONLY ONE option is correct.
io
61. (
Find number of integral values of a for which equation loge x 2 + 5x = loge ( x + a + 3 ) )
ut
has exactly one solution
(A) 4 (B) 5
ol
(C) 6 (D) 1
-S
Ans. B
Sol. Here x ∈ ( −∞, − 5 ) ∪ ( 0, ∞ )
(1, 5)
We have x 2 + 5x = x + a + 3
PC
x 2 + 4x = a + 3
From the graph 0 < a + 3 ≤ 5
−3 < a ≤ 2
–5 –4
∴ Number of integral values of a O
-M
⇒ {−2, − 1,0,1,2}
⇒5
e
If a and b are real number such that 3a + 4b = 25 then the minimum value of a2 + b2 is
in
62.
equal to
nl
(A) 1 (B) 5
(C) 25 (D) not defined
-O
Ans. C
Sol. We can consider a like x and b like y
∴P ( x, y ) is a point which lies on 3x + 4y = 25
st
∴ minimum x2 + y 2 = 25
pe
x
63. Equation of a circle is x 2 + y 2 = r 2 which has two chords y = 0 and y =
. In smaller
O
3
sector between chords a circle of radius unity touches the chords and the circle
internally, then r is
(A) 1 + 2 − 6 (B) 2 + 3
(C) −1 + 2 + 6 (D) 1 + 2 + 6
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AIITS-OT-PCM-JEE(Main)/19 20
Ans. D
C1C2
Sol. = cos ec15o
1
1
=
sin15o
o
1 15
n
= 1
(
sin 45o − 30o ) M
io
C1 C2
1
=
ut
sin 45 cos 30 − cos 45o sin30o
o o
1 2 2
ol
= =
1 3 1 1 3 −1
× − .
-S
2 2 2 2
2 2 ( 3 +1 )=
=
3 −1
2 3 +1 = 6 + 2 ( )
PC
∴ C1M = C1C2 + C2M = 6 + 2 + 1
64.
-M
In parabola y 2 = 4x, two shortest normal chords are diagonals of a quadrilateral, then
area of quadrilateral is
(A) 24 2 (B) 18 2
(C) 72 2 (D) 36 2
e
in
Ans. D
Sol. For shortest normal chord t = 2, − 2 B
nl
( )
A
∴ A 2,2 2
-O
D ( 2, − 2 2 )
C ( 8, − 4 2 )
B ( 8,4 2 )
st
D
∴ area of ABCD
Te
C
1
( )
= × ( 8 − 2 ) 4 2 + 8 2 = 3 × 12 2 = 36 2
2
n
x2 y2
+ = 1, then equation of ellipse E2 whose foci are ends of
pe
x2 y2 x2 y2
(A) + =1 (B) + =1
7 16 16 7
x2 y2 x2 y2
(C) + =1 (D) + =1
9 16 7 9
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21 AIITS-OT-PCM-JEE(Main)/19
Ans. A
Sol. Here SB = OB ' = 7 + 9 = 4 B’
∴ B ' = ( 0, 4 ) (0, 3)
x2 y2
∴ equation is + =1 B E1
7 16
n
O S ( 7, 0 ) (4, 0)
io
ut
ol
-S
66. A circle passes through (3, 4) and (10, 11) then length of tangent to this circle from (2, 3)
is
(A) Variable (B) 8
PC
(C) 4 2 (D) 4
Ans. D
PA.PB = PT 2
Sol.
-M
T
2 × 8 2 = PT 2
PT = 4
e
in
B (10, 11)
nl
P (2, 3) A (3, 4)
-O
( x − 1) + ( y − 2) − ( x − 5) + ( y − 5) = 4
2 2 2 2
67. Let P(x, y) be a variable point such that
5 4
(A) (B)
Te
4 3
5 3
(C) (D)
3 2
n
Ans. C
S = (1,2 )
pe
Sol.
S ' = ( 5,5 )
O
( 5 − 1) + (5 − 2) = 5
2 2
SS ' = 2ae =
5
ae =
2
2a = 4 a = 2
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AIITS-OT-PCM-JEE(Main)/19 22
5 5
2e =∴e =
2 4
1 1
Now 2 + =1
( e ')
2
e
1 1
+ 2 =1
n
25 / 16 e '
1 16 9
io
2
= 1− =
e' 25 25
ut
25 5
e'2 = ⇒ e' =
9 3
ol
t 6 − 8t 4
If α, β are roots of x 2 − 5x − 8 = 0 and t n = αn − βn then
-S
68. is
5t 5
(A) 5 (B) 4
(C) 8 (D) 1
PC
Ans. D
Sol. We know that t n − 5t n −1 − 8t n −2 = 0
∴t 6 − 5t 5 − 8t 4 = 0
-M
t 6 − 8t 4
∴ =1
5t 5
e
1 1
(A) (B)
9 3
nl
(C) 9 (D) 18
-O
Ans. C
x2 y2 x2 y2
Sol. Here + = 1and − = 1 are orthogonal then they will be confocal also.
a 2 b2 A 2 B2
∴ ae = Ae '
st
∴a2 e2 = A 2 e'2
Te
a2 − b 2 = A 2 + B 2
45 45 5 25
− =5+ =
4 α 4 4
α − 4 25 1
n
= ×
4α
pe
4 45
α−4 5
=
α 9
O
9α − 36 = 5α
4α = 36
α=9
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23 AIITS-OT-PCM-JEE(Main)/19
70. The value of sin3 10o + sin3 50o − sin3 70o is equal to
−3 3
(A) (B)
2 4
−3 −3
(C) (D)
4 8
n
Ans. D
io
Sol.
1
4
(
4 sin3 10 + 4 sin3 50 − 4 sin3 70 )
ut
1
= ( 3 sin10 − sin30 + 3 sin50 − sin150 − 3 sin 70 + sin 210 )
4
ol
1 3
= 3 ( sin10 + sin50 − sin 70 ) −
-S
4 2
1 3 1 3 −3
= 3 ( 2 sin 30 cos 20 − sin 70 ) − = 3 ( cos 20 − sin70 ) − =
4 2 4 2 8
PC
71. (
The number of solution of the equation 16 sin5 x + cos5 x = 11( sin x + cos x ) in the )
interval [0, 2π] is
-M
(A) 6 (B) 7
(C) 8 (D) 9
Ans. A
e
( (
16 1 − 2 sin2 x cos2 x − sin x cos x sin2 x + cos2 x − sin x cos x ) ) = 11
nl
(
16 1 − 2 sin2 x cos2 x − sin x cos x + sin2 x cos2 x = 11 )
-O
16 (1 − sin 2
)
x cos2 x − sin x cos x = 11
16 sin2 x cos2 x + 16 sin x cos x − 5 = 0
( 4 sin x cos x + 5 )( 4 sin x cos x − 1) = 0
st
4 sin x cos x + 5 ≠ 0
Te
12 12 12 12 12 12
There are 6 solutions in [0, 2π]
O
H1 + 2 H20 + 3
72. If H1,H2 ,....H20 are 20 harmonic means between 2 and 3 then + =
H1 − 2 H20 − 3
(A) 20 (B) 21
(C) 40 (D) 38
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AIITS-OT-PCM-JEE(Main)/19 24
Ans. C
Sol. 2,H1,H2 ,.....H20 ,3 are in H.P.
1 1 1 1 1
, , ,........, , are in A.P.
2 H1 H2 H20 3
Suppose common difference is d
1 1 1 1
n
+ +
2 H1 3 H20
+
io
Now
1 1 1 1
− −
ut
2 H1 3 H20
1 1 1 1 1 1 1 1
+ + − + −
ol
2 H1 3 H20 3 2 H20 H1 21d + 19d
= + = = = 40
−d d d d
-S
73. The coefficient of xr [ 0 ≤ r ≤ n − 1] in the expansion of
( x + 3) + ( x + 3) ( x + 2) + ( x + 3) ( x + 2) + ...... + ( x + 2 )
n −1 n−2 n−3 2 n −1
is
PC
(
(A) n Cr 3n − 2n ) (
(B) n Cr 3n−r − 2n−r )
(C) n
C (3
r
r n −r
+2 ) (D) None of these
-M
Ans. B
Given expression is equidistant be ( x + 3 ) − ( x + 2 )
n n
Sol.
∴ Coefficient of xr = nCr xr .3n−r − nCr xr .2n−r = nCr 3n−r − 2n−r x r ( )
e
in
z −2
If z lies on the circle z − 2i = 2 2 then the value of arg
nl
74. is equal to
z + 2
π π
-O
(A) (B)
3 4
π π
(C) (D)
6 2
st
Ans. B
Te
z + 2
pe
1
= ∠ACB C
2 C
1 π π
O
= × = B A
2 2 4 (2, 0)
X
(–2, 0)
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25 AIITS-OT-PCM-JEE(Main)/19
π
75. If z − 2 − i = z sin − arg z then locus of z is
4
(A) a pair of straight lines (B) circle
(C) parabola (D) ellipse
Ans. C
n
Sol. Say arg z = θ
io
z = x + iy and z = r
( z − 2 − i) =
1
( z cos θ − z sin θ )
ut
2
x−y
ol
( x − 2) + ( y − 1) =
2 2
-S
Distance of (x, y) from (2, 1) = Distance of (x, y) from line x – y = 0
∴ locus of z is a parabola
76. In a decagon find number of points of intersection of diagonals which will lie inside the
PC
decagon if no three diagonals are concurrent
(A) 35 C2 (B) 10 C2 × 8 C2
(C) 9 C6 (D) 10
C4
-M
Ans. D
Sol. Select any 4 points we will get a quadrilateral and for each quadrilateral we will get one
point of intersection of diagonals.
e
in
77. Let y be an element of the set A = {1,2,3,5,6,10,15,30} and x1, x 2 , x 3 be positive integer
such that x1x 2 x 3 = y then the number of positive integral solutions of x1. x 2 . x 3 = y is
nl
(A) 64 (B) 27
-O
Ans. A
Sol. Number of solutions of the given equation is same as the number of solutions of the
equation x1x 2 x3 x 4 = 30 = 2 × 3 × 5 (there x 4 is dummy variable) hence number of
st
solutions is 43 = 64
Te
78. 7 people leave their bag outside the temple and returning after working the deity picked
one bag each at random. In how many ways at least one and at most three of them get
their correct bags?
n
Ans. B
Sol. Number of ways getting one correct
1 1 1 1 1 1
= 7 C1. 6 1 − + − + − + = 7C1 × 265
1 2 3 4 5 6
Number of ways of getting two correct
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AIITS-OT-PCM-JEE(Main)/19 26
1 1 1 1 1
= 7 C2 5 1 − + − + − = 7 C2 × 44
1 2 3 4 5
Number of ways of getting three correct
1 1 1 1
= 7 C3 4 1 − + − + = 7C3 × 9
1 2 3 4
n
Required number of ways = 7 C1 × 265 + 7C2 × 44 + 7 C3 × 9
io
1
If 2a + 3c + 2b =
ut
79. and a, b, c, > 0 then maximum value of term independent of x in the
5
25
1
−
1
ol
expansion of abx 2 + cx 3 is
-S
C15 ( 35 )
25 25 25
(A) C10 (B)
35 35
25 1 25 1
(C) C15 (D) C10
35 25
PC
Ans. C
25 −r r
( 25 −r ) −3
Tr +1 = 25 Cr ( ab )
2
Sol. x
.c r . x
-M
25 − r −r
n = 25, + = 0 ⇒ r = 15
2 3
∴ T16 = 25 C15 a10b10 c15
e
≥ a ×b ×c
35
-O
35
1
∴ ≥ a10b10 c15
35
1 1
(A) −1, − or ( −2, − 1) (B) ( −1, − 1) or −2, −
2 2
1 1
(C) ( −2, 2 ) or , − 1 (D) (1, 2) or , − 1
n
2 2
pe
Ans. A
( 2a + b ) − 3c ( 2a + b ) + 2c 2 = 0
2
Sol.
O
( 2a + b − c )( 2a + b − 2c ) = 0
2a + b − c = 0 ⇒ ( −2, − 1)
1
2a + b − 2c = 0 ⇒ −1, −
2
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27 AIITS-OT-PCM-JEE(Main)/19
1 1 1 1 1
81. The sum of the infinite series 1 + 1 + + 1 + + 2 2 + .....∞ is
2
3 2 2 3
12 9
(A) (B)
5 5
8 5
(C) (D)
5 3
n
io
Ans. B
1 1 1 1 1
S = 1 + 1 + + 1 + + 2 2 + .....
ut
Sol.
2 3 2 2 3
ol
S 1 1 1
= + 1 + 2 + ....
3 3 2 3
-S
2S 1 1
= 1+ + 2 2 + .....
3 2 × 3 2 .3
2S 1 6 9
= = S=
PC
3 1 5 5
1−
6
Ans. A
Sol. Inverse of p ∨ ( q → r ) → ( q ∧ p ) is ~ p ∨ ( q → r ) →~ ( q ∧ p )
nl
≡ ~ p∧ ~ ( q → r ) → ( ~ q∨ ~ p )
-O
≡ ~ p ∧ ( q∧ ~ r ) → ( ~ q∨ ~ p )
83. A lamp post standing at a point A on a circular path of radius ‘r’ subtends an angle α at
some point B on the path and AB subtends an angle of 45o at any other point on the
st
r
(A) tan α (B) 2r tan α
2
r
(C) 2 r cot α (D) cot α
n
2
pe
Ans. B
O
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AIITS-OT-PCM-JEE(Main)/19 28
n
BCA = 90o
io
Also CA = CB = r B
C
⇒ AB = 2r
ut
Also hcot α = 2r
ol
⇒ h = 2 r tan α
-S
84. By mathematical induction 11n+ 2 + 122n+1 is divisible by
(A) 132 (B) 133
(C) 233 (D) 11
PC
Ans. B
Sol. Let us denote by P (n) the statement:
11n +2 + 122n+1 is divisible by 133.
-M
For n = 1, we find P (1) is true i.e. 113 + 123
( )
= (11 + 12 ) 112 − 11× 12 + 122 = ( 23 )(133 ) is divisible by 133.
∴ P (n) is true for n = 1.
e
( )
= 11 11k +2 + 122k +1 + 133.122k +1
= (11) 133q + 133.122k +1 [using (1)]
( )
st
∴P ( k + 1) is true.
∴ By the principle of mathematical induction, the result is true for all n ∈ N .
n
(A) –7 (B) –5
(C) –3 (D) 0
O
Ans. A
Sol. Since α, β, γ are roots of x 3 − 2x 2 + 3x − 4 = 0
α + β + γ = 2, ∑ αβ = 3, αβγ = 4
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29 AIITS-OT-PCM-JEE(Main)/19
α2β2 + β2 α 2 + γ 2 α 2 = ( αβ + βγ + γα ) − 2αβγ ( α + β + γ )
2
= 32 − 2 ( 4 )( 2 ) = 9 − 16 = −7
86. If a,a1,a2 ,.....a2n ,b are in A.P and g,g1,g2 ,........g2n ,b are in G.P. and h is the H.M. of a
a + a2n a2 + a2n−1 a + an+1
and b, then 1 + + ..... + n is equal to
n
g1g2n g2 g2n−1 gn gn+1
io
n
(A) nh (B)
h
ut
2n
(C) 2nh (D)
h
ol
Ans. D
-S
Sol. Given, a,a1,a 2 ,.....a 2n ,b are in A.P.
∴ a + b = a1 + a 2n = a 2 + a2n −1 = ....... = an + an +1
Also given a,g1,g2 ,.......g2n ,b are in G.P.
PC
∴ab = g1g2n = g2 g2n −1 = gn gn +1
2ab
Further h =
a+b
-M
∴ The given expression
n (a + b) a + b 2n
= = 2n =
ab 2ab h
e
87. Normals are drawn from a point P to y 2 = 4x . The slopes of the normals are m1,m2 ,m3 .
in
(A) 2 (B) 1
(C) 4 (D) none of these
-O
Ans. A
Sol. Let P be (h, k). If m be the slope of a normal, then m3 + m ( 2 − h ) + k = 0 .
k
Now m1m2m3 = −k ⇒ m3 = −
st
α
Te
k3 k
So, − + − ( 2 − h) + k = 0
α3 α
k2 1
This ⇒ − 3 − ( 2 − h ) + 1 = 0
n
α α
⇒ α3 − α 2 ( 2 − h) − k 2 = 0
pe
⇒ locus is α3 − 2α2 + α 2 x − y 2 = 0
⇒ α = 2 as the locus is y 2 = 4x
O
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AIITS-OT-PCM-JEE(Main)/19 30
Ans. B
n
Sol. Both are rectangular hyperbolas.
io
( )
n
89. If 5 + 2 6 = I + f, n,I ∈ N and 0 ≤ f < 1, then I is
ut
1 1
(A) −f (B) −f
ol
f 1+ f
1 1
(C) −f (D) +f
-S
1− f 1+ f
Ans. C
( )
n
PC
Sol. Given 5 + 2 6 =I+ f …..(1)
0 ≤ f <1
( )
n
Let 5 − 2 6 =F
-M
0 ≤F <1
I + f + F in an integer, ⇒ f + F is integer
0 ≤ f +F < 2 ⇒ f +F =1
e
∴ 1− f = F
( )
in
n
From (1), we get I = 5 + 2 6 −f
nl
1 1
= −f = −f
F 1− f
-O
π 1 2π 1 3π 1 4π
90. If S = sin + sin + sin + sin + ..........∞ then S =
3 2 3 3 3 4 3
π
st
(A) 0 (B)
3
π π
Te
(C) (D)
2 6
Ans. B
n
x2 x3
− log (1 − x ) = x + + + .....
2 3
iπ
O
Put x = e 3
π π
iπ iπ i2 i3
e 3 e 3
⇒ − log 1 − e 3 = e 3 + + + .....
2 3
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31 AIITS-OT-PCM-JEE(Main)/19
π π
iπ i2 i3
π sin π e 3 e 3
⇒ − log 1 − cos − i = e 3
+ + + .....
3 3 2 3
π π
iπ i2 i3
π π π e 3 e 3
⇒ − log 2 sin2 − 2i sin cos = e 3 + + + .....
6 6 6 2 3
π π
n
iπ i2 i3
π π π e 3 e 3
⇒ − log −2i sin cos + i sin = e 3 + + + .....
io
6 6 6 2 3
π π
ut
π π iπ i2 i3
−i −i e 3 e 3
⇒ − loge 2
+ loge 6
=e + +3
+ .....
2 3
ol
π π
iπ i2 i3
π π e 3 e 3
-S
⇒ − −i + i = e 3 + + + .....
2 6 2 3
π π
iπ i2 i3
π e 3 e 3
⇒ − −i = e 3 + + + .....
PC
3 2 3
π π
iπ i2 i3
π e 3 e 3
⇒ i = e3 + + + .....
3 2 3
-M
Compose imaginary part both sides.
2π 3π
sin sin
π π 3 + 3 + ....
= sin +
3 3 2 3
e
in
nl
-O
st
Te
n
pe
O
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