Cálculos

Tabla 1 (Efecto de las concentraciones)

Tubo KMnO4 H2O H2C2O4 Vol. [H2C2O4]i [KMnO4]i Tiempo V H2C2O4 k

(ml) (ml) (ml) Total (s) (M/s) experimental
(ml)
1 0.5 0 1.5 2 0.2625 7.5x10-3 440 5.9654x10-4 2.2727x10-3
2 0.5 0.5 3 4 0.2625 3.75x10-3 301 8.7209x10-4 3.3222x10-3
3 1 1.5 1.5 4 0.13125 7.5x10-3 606 2.1658x10-4 1.65018x10-3

𝑉3 𝑘 [0.13125] 𝑋 [7.5𝑥10−3 ]𝑌 [0.13125] 𝑋

= =
𝑉1 𝑘 [0.2625] 𝑋 [7.5𝑥10−3 ]𝑌 [0.2625] 𝑋

2.1658𝑥10−4
= 0.5𝑥 0.36 = 0.5𝑥
5.9654𝑥10−4
log (0.36)
𝑥= 𝑥 = 1.46 ≈ 1.5
log (0.5)

𝑉2 𝑘 [0.2625]𝑋 [3.75𝑥10−3 ]𝑌 [3.75𝑥10−3 ]𝑦

= =
𝑉1 𝑘 [0.2625] 𝑋 [7.5𝑥10−3 ]𝑌 [7.5𝑥10−3 ]𝑦

8.7209𝑥10−4
= 0.5𝑦 1.46 = 0.5𝑦
5.9654𝑥10−4
log (1.46)
𝑦= 𝑦 = −0.54 ≈ 0
log (0.5)
 𝑥 + 𝑦 = 1.5 + (−0.54) = 0.95 ≈ 1⌋

𝑉 = 𝑘 [𝐻2 𝐶2 𝑂4 ]1.5 [𝐾𝑀𝑛𝑂4 ]−0.5 = 𝑘 [𝐻2 𝐶2 𝑂4 ]1

Tabla 2 (Efecto de la temperatura)

Tubo KMnO4 H2O H2C2O4 Vol. [H2C2O4]i [KMnO4]i Tiempo V H2C2O4 k

(ml) (ml) (ml) Total (s) (M/s) experimental
(ml)
1 1 1.5 1.5 4 0.13125 7.5x10-3 94.2 1.3933x10-3 0.010615
2 1 1.5 1.5 4 0.13125 7.5x10-3 73.8 1.7784x10-3 0.01355
3 1 1.5 1.5 4 0.13125 7.5x10-3 60 2.1875x10-3 0.016666

𝑘1 𝐸𝑎 1 1
ln ( ) = [ − ]
𝑘2 𝑅 𝑇2 𝑇1

0.010615 𝐸𝑎 1 1
ln ( )= [ − ]
0.01355 𝐽
8.314 ( ) 323 𝐾 313 𝐾
𝑚𝑜𝑙 ∙ 𝐾
𝐸𝑎
−0.24406 = [−9.891294𝑥10−5 𝐾]
𝐽
8.314 ( )
𝑚𝑜𝑙 ∙ 𝐾
−0.24406 𝐽
𝐸𝑎 = −5
∙ 8.314 ( )
[−9.891294𝑥10 𝐾] 𝑚𝑜𝑙 ∙ 𝐾
𝐽
𝐸𝑎 = 20514.27 ⌋
𝑚𝑜𝑙
𝐸𝑎
𝑘 = 𝐴 𝑒 −𝑅𝑇
𝐽
20514.27
− 𝑚𝑜𝑙
𝐽
8.314( )∙323𝐾
0.01355 = 𝐴 𝑒 𝑚𝑜𝑙∙𝐾

0.01355 = 𝐴 𝑒 −7.6391
𝐴 = 28.1558⌋
 -4.0
Equation y = a + b*x
60
Adj. R-Square 0.99088
Value Standard Error
-4.1 40
B Intercept -3.20968 0.07575
B Slope -53.70933 3.63511
20
-4.2
0

-20
-4.3
In (k)

-40

-4.4 -60

-80
-4.5
-100

-4.6 -120
0.016 0.018 0.020 0.022 0.024 0.026

1/T (K^-1)