SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

SECTION 1. IDENTIFICATION

Product name : KEMELIX D309-LQ-(CQ)

Chemical name : Concentrated solution of an ethoxylated phenolic resin in an

aromatic solvent
Manufacturer or supplier's details
Company name of supplier : Croda Canada Ltd

Address : Suite 1000

1700 Langstaff Road
Vaughan
L4K 3S3
CA

Telephone : (905) 886-1383

Telefax : (905) 886-4753

Emergency telephone num- : USA: 24 Hour Emergency Response Information CHEMTREC

ber toll free: 1-800-424-9300; direct/international: 1-703-527-3887.
CANADA: CANUTEC 1-888-CAN-UTEC (226-8832), 613-996-
6666 or *666. EUROPE: 00 32 3575 5555. ASIA PACIFIC -
excl. China: +65 6542-9595. CHINA: +86 816-635 2206.
AUSTRALIA: +61 2 9616 5890. SOUTH AFRICA: +32 3 575
55 55. BRASIL:Suatrans 0800 707 7022 / 0800 707 1767.
LATAM: Suatrans (+55) 11 98149-0850 / (+55) 19 3833-5300.
INDIA: +91 22 30948601/2. JAPAN: +65 6542 9595 (24 時間
日本語対応無料通話, シンガポール). TÜRKIYE: Sağlik
Bakanliği Ulusal Zehir Merkezi - 114

Recommended use of the chemical and restrictions on use

Recommended use : De-emulsifier

Prepared by : Product Safety and Regulatory Affairs Department

(732) 417-0800

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the Hazardous Products Regulations

Flammable liquids : Category 4

Eye irritation : Category 2A

Carcinogenicity : Category 2

Specific target organ toxicity : Category 3 (Central nervous system)

- single exposure

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SAFETY DATA SHEET
KEMELIX D309-LQ-(CQ)
Version Revision Date:
1.0 07/11/2018
Aspiration hazard
Chronic aquatic toxicity
GHS label elements
Hazard pictograms
Signal word
Hazard statements
Precautionary statements
Product code: Date of last issue: Print Date :
RAK3284 - 12/24/2018
Date of first issue:
07/11/2018
: Category 1
: Category 3
:
: Warning
: H227 Combustible liquid.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H412 Harmful to aquatic life with long lasting effects.
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P331 Do NOT induce vomiting.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 Store in a well-ventilated place.
P403 + P233 Store in a well-ventilated place. Keep container
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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
May irritate skin.
Ingestion may cause irritation to mucous membranes.
May cause irritation of respiratory tract.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components
Chemical name CAS-No. Concentration (% w/w)
Hydrocarbons, C10, aromatics, <1% naph- 64742-94-5 >= 20 - < 30
thalene
Naphthalene 91-20-3 >= 0.1 - < 1

Actual concentrations are withheld as confidential business information.

SECTION 4. FIRST AID MEASURES

If inhaled : If breathed in, move person into fresh air.

If symptoms persist, call a physician.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : Immediately flush eye(s) with plenty of water.

If eye irritation persists, consult a specialist.

If swallowed : If large quantities of this material are swallowed, call a physi-

cian immediately.

Most important symptoms : See section 2 and 11

and effects, both acute and
delayed

SECTION 5. FIREFIGHTING MEASURES

Flammable properties
Flash point : 63 °C

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

cumstances and the surrounding environment.

Use water spray, alcohol-resistant foam, dry chemical or car-
bon dioxide.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire- : Do not use a solid water stream as it may scatter and spread
fighting fire.
Do not allow run-off from fire fighting to enter drains or water
courses.

Specific extinguishing me- : Standard procedure for chemical fires.

thods

Further information : Use water spray to cool unopened containers.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Ensure adequate ventilation.
gency procedures

Methods and materials for : Soak up with inert absorbent material.

containment and cleaning up Sweep up and shovel into suitable containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Handle in accordance with good industrial hygiene and safety
practice.

Conditions for safe storage : Store in original container.

Keep container tightly closed in a dry and well-ventilated
place.

Materials to avoid : No special restrictions on storage with other products.

Further information on sto- : Stable under recommended storage conditions.

rage stability

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

exposure) concentration
Hydrocarbons, C10, aromatics, 64742-94-5 TWA 200 mg/m3 CA AB OEL
<1% naphthalene (As total hydro-
carbon vapour)
TWA 200 mg/m3 CA AB OEL
(total hydrocarbon
vapor)
TWA 200 mg/m3 ACGIH
(total hydrocarbon
vapor)
Naphthalene 91-20-3 TWA 10 ppm CA AB OEL
52 mg/m3
STEL 15 ppm CA AB OEL
79 mg/m3
TWA 10 ppm CA BC OEL
STEL 15 ppm CA BC OEL
TWAEV 10 ppm CA QC OEL
52 mg/m3
STEV 15 ppm CA QC OEL
79 mg/m3
TWA 10 ppm ACGIH
STEL 15 ppm ACGIH

Personal protective equipment

Respiratory protection : In the case of vapour formation use a respirator with an ap-
proved filter.

Hand protection

Remarks : Impervious gloves

Eye protection : Tightly fitting safety goggles

Skin and body protection : Impervious clothing

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : amber

Odour : No data available

Odour Threshold : No data available

pH :

Melting point/freezing point : No data available

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

Decomposition temperature : No data available

Initial boiling point and boiling No data available

range

Flash point : 63 °C

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : No data available

Relative vapour density : No data available

Relative density : No data available

Solubility(ies)
Water solubility : immiscible

Partition coefficient: n- : No data available

octanol/water

Auto-ignition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable at normal ambient temperature and pressure.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Hazardous polymerisation does not occur.

tions

Conditions to avoid : None known.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : In case of fire hazardous decomposition products may be

products produced such as:
Carbon oxides

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Product:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Skin corrosion/irritation

Product:
Species : Rat
Result : Mild skin irritant
Remarks : Information given is based on data obtained from similar sub-
stances.

Serious eye damage/eye irritation

Product:
Species : Rabbit
Result : Eye irritation
Remarks : Information given is based on data obtained from similar sub-
stances.

Further information

Product:
Remarks : No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:
Toxicity to fish : LC50 (turbot): 42.3 mg/l
Exposure time: 96 h
Test Type: static test

LC50 (Pleuronectes platessa (plaice)): 18 mg/l

Exposure time: 96 h
Test Type: semi-static test

Toxicity to daphnia and other : LC50 (Crangon crangon (shrimp)): 9.45 mg/l
aquatic invertebrates Exposure time: 96 h
Test Type: semi-static test

Components:

Naphthalene:

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

M-Factor (Acute aquatic tox- : 1

icity)

M-Factor (Chronic aquatic : 1

toxicity)

Persistence and degradability

Product:
Biodegradability : Test Type: Biological Oxygen Demand (BOD 28 DAY/COD)
Biodegradation: 5 %
Method: OECD 301C: Modified MITI Test (I)
Remarks: Information given is based on data obtained from
similar substances.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: No data available

Mobility in soil

Product:
Distribution among environ- : Remarks: No data available
mental compartments

Other adverse effects

Product:
Results of PBT and vPvB : This substance/mixture contains no components considered
assessment to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Additional ecological informa- : Information given is based on data obtained from similar sub-
tion stances.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents.

Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulations

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

TDG
Not regulated as a dangerous good

Special precautions for user

Remarks : DOT - Regulated in bulk containers (>119 gallons) - only.

SECTION 15. REGULATORY INFORMATION

The components of this product are reported in the following inventories:

TSCA : All chemical substances in this product are listed on the TSCA
Inventory.

REACH : On the inventory, or in compliance with the inventory

DSL : On the inventory, or in compliance with the inventory

AICS : On the inventory, or in compliance with the inventory

NZIoC : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

Additions, Deletions, Revisions

Section 3
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
CA AB OEL : Canada. Alberta, Occupational Health and Safety Code (table
2: OEL)
CA BC OEL : Canada. British Columbia OEL
CA QC OEL : Québec. Regulation respecting occupational health and safe-

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SAFETY DATA SHEET

KEMELIX D309-LQ-(CQ)
Version Revision Date: Product code: Date of last issue: Print Date :
1.0 07/11/2018 RAK3284 - 12/24/2018
Date of first issue:
07/11/2018

ty, Schedule 1, Part 1: Permissible exposure values for air-

borne contaminants
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
CA AB OEL / TWA : 8-hour Occupational exposure limit
CA AB OEL / STEL : 15-minute occupational exposure limit
CA BC OEL / TWA : 8-hour time weighted average
CA BC OEL / STEL : short-term exposure limit
CA QC OEL / TWAEV : Time-weighted average exposure value
CA QC OEL / STEV : Short-term exposure value

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECx - Concentration associated with x% response; ELx - Loading rate associated with x% re-
sponse; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan);
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - Internation-
al Agency for Research on Cancer; IATA - International Air Transport Association; IBC - Interna-
tional Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk;
IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization;
IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dan-
gerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
vention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC -
No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Tox-
icology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Eco-
nomic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Preven-
tion; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Con-
trol Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on
the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS -
Workplace Hazardous Materials Information System
Revision Date : 07/11/2018

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

CA / EN

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