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◊INTRODUCTION
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The field of geochemistry involves study of the
4. A study of the role of processes and compounds that are derived from
living or once-living organisms (organic geochemistry)
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◊HISTORY OF GEOCHEMISTRY
• The term “geochemistry” was first used by the Swiss chemist Schönbein
in 1838.
• You might guess, merely from the etymology of the word, that the field of
geochemistry is somehow a marriage of the fields of geology and
chemistry. That would be a good guess.
• But just how are chemistry and geology combined within geochemistry;
what is the relationship between them?
Perhaps the best explanation would be to state that in geochemistry, we
use the tools of chemistry to solve geological problems; that is, we use
chemistry to understand the Earth and how it works.
• The Earth is part of a family of heavenly bodies, our Solar System, that
formed simultaneously and are closely related. Hence, the realm of
geochemistry extends beyond the Earth to encompass the Solar System.
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Geochemistry has both pure and applied components.
Pure Geochemistry: concerned with “How and Why did the Earth and
Solar System reach their current chemical state?” Current research topics
include:
• Chemical cycles:
Fluxes of elements between earth’s reservoirs, especially between crust
and mantle, and of greenhouse gases between atmosphere and
lithosphere
• Paleoclimates:
Application of stable isotope thermometry
• Astrobiology:
Despite the name, the search for life on other planets involves
geochemistry in a very significant way.
Note:
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◊ELEMENTS
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Classification of the Elements
F
1 2
H He
A B C C C C E
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3 4 5 6 7 8 9
Ne
Li Be B C N O F
I
11 12 (Transition Metals/Heavy Metals in Bold) 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
C C C C C C C C C C I I
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc T V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
D D D J I I
37 38 39 40 41 44 45 46 47 48 49 50 51 52 53 54
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Rb Sr Y Zr Nb Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Mo
D D D J
55 56 57 72 73 74 75
76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re
Os Ir Pt Au Hg Tl Pb Bi Po At Rn
87 88 89
Fr Ra Ac
G 58 59 60 62 53 64 65 66 67 68 69 70 71
REE Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
H 90 92
Actinides Th U
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Important Ocean Elements
2. Geochemical Classification
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(based on which part of Earth the element tends to reside in)
Goldschmidt (1922), the father of geochemistry, suggested a
classification based on where elements were usually found. Only
qualitative, but this classification works because of the similarities in
electronic configuration within the groups:
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The Geochemical Classification of the Elements
B E
A C D F
Large Ion Siderophil
Lithophile HFI Chalcophile Atmophile
Lithophil e
e
F F
1 2
H He
C E F A A
3 4 10
5 6 7 8 9
Li Be Ne
B C N O F
A A A A E D
17 18
11 12 13 14 15 16
Cl Ar
Na Mg Al Si P S
B A A A A A A E E E D D D E D D
35 36
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34
Br Kr
K Ca Sc T V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se
B B B C C E E E D D D E D D
53 54
37 38 39 40 41 42 44 45 46 47 48 49 50 51 52
I Xe
Rb Sr Y Zr Nb Mo Ru Rh Pd Ag Cd In Sn Sb Te
B B C C C E E E E E D D D D D
B 85 86
55 57 72 73 74 75 76 77 78 79 80 81 82 83 84
56 At Rn
Cs La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po
Ba
B B B
87 88 89
Fr Ra Ac
B B B B B B B B B B B B B
REE 58 59 60 62 53 64 65 66 67 68 69 70 71
Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
C C
Actinides 90 92
Th U
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Geochemical Affinity
• In the classification scheme of Goldschmidt, elements are divi ded according to
how they partition between coexisting silicate liquid, sulfide l iquid, metallic
liquid, and gas phase…defined by examining ore smelting slags and meteorites
• Melting a chondrite gives 3 immiscible liquids plus vapor:
Gas Phase Atmophile H, He, N, Noble gases
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◊SOLAR SYSTEM COMPOSITE ABUNDANCE CURVE
Main features:
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o progressing to higher atomic numbers leads to an overall decrease
in abundance, making the heaviest nuclei among the least abundant
o note anomalously low abundance of Li, Be, B as compared to other light
elements
o note anomalously high abundance of Fe
o zig-zag pattern:
Elements having even atomic numbers are on average about ten times
more abundant than elements with similar but odd atomic
numbers.
References:
Brownlow, A.H., 1979, Geochemistry, Prentice Hall.
Krauskopf, K.B. & Bird, D.K., 1995, Introduction to Geochemistry, WCB
McGraw Hill
Mason, B. and Moore, C.B., 1989, Prinsip-Prinsip Geokimia, DBP.
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