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4541/1
Kimia
Kertas 1
Okt
2009
1 ¼ jam
PEPERIKSAAN PERCUBAAN SPM TAHUN 2009
PERINGKAT ZON SAMARAHAN
KIMIA
Kertas 1
A 2.1
B 2.8.7
C 2.8.8
D 2.8.8.2
A Sodium-23
B Iodine-131
C Hydrogen-2
D Carbon-14
A Iron
B Nitrogen
C Water
D Sodium chloride
4. Diagram 1 shows a small crystal of copper (II) sulphate in a test tube containing
jelly.
Jelly
Diagram 1
After two days, the jelly turned blue in colour. What is the aim of the
experiment?
A To measure the size of the jelly particles
B To show that matter is made up of discrete and tiny particles
C To investigate the colour of copper (II) sulphate
D To prove that copper (II) sulphate is a gas at room temperature
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5. Table 1 shows the melting and boiling points of five compounds, P,Q,R,S and
T.
Table 1
Which substance exists as a gas at room temperature?
A P
B P and Q
C Q and R
D S and T
NaNO2
Name the substance above.
A Sodium nitrate
B Sodium nitrite
C Potassium nitrate
D Potassium nitrite
7. How many oxygen atoms have equal mass with two magnesium atoms?
(Relative atomic mass: O=16, Mg=24)
A 2
B 3
C 4
D 5
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8. Diagram 2 shows two balloons filled with hydrogen gas and nitrogen gas
respectively.
500 cm3 of
Hydrogen gas 500 cm3 of
Nitrogen gas
Diagram 2
9. The following equation shows the reaction between copper (II) oxide
powder and dilute nitric acid.
If 1.6g of copper (II) oxide powder reacts completely with excess nitric
acid, what is the mass of copper (II) nitrate formed in the reaction?
(Relative atomic mass: Cu=64, O=16, N=14)
A 1.88g
B 2.24g
C 2.52g
D 3.76g
A Helium
B Nitrogen
C Oxygen
D Neon
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11. Which of the following acts as a catalyst in the Haber process for the
manufacture of ammonia?
A Iron powder
B Platinum
C Nickel
D Vanadium(V) oxide
P Q R
Diagram 3
A Q, R, P
B Q, P, R
C P, R, Q
D P, Q, R
13. Table 2 shows the numbers of protons, electrons and neutrons of atoms X and
Y.
Atom Number
Proton Electron Neutron
X 11 11 12
Y 12 12 12
Table 2
Which of the following is true about atoms X and Y?
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14. The chemical equation below shows the reaction between chlorine and water
X Y
A HCl HOCl
B HCl H2
C HOCl ClO2
D HOCl HCl2
A NaCl
B MgO
C CO2
D CaO
16. Which of the following explains why covalent compounds have low melting
and boiling points?
A Covalent bonds are weak bonds
B Their molecules repel each other strongly
C Their molecules are held together by weak electrostatic forces
D Their molecules are held together by weak intermolecular forces
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17. Diagram 4 shows the electron arrangement of a substance formed between two
atoms of Z
Z Z
Diagram 4
A Consists of ions
B Conduct electricity in molten state
C The compound has a low melting point
D Dissolves in water
Table 3
Which of the following is true about the formula and the type of bond of the
compound formed by the reactions between K and L ?
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20. Lead (II) bromide can only conduct electricity in the molten state but not
in the solid state.
A In the solid state the particles in lead (II) bromide exist as atoms
B When melted the lead and bromide atoms change to ions which then carry
charges
C The lead ions and bromide ions in lead (II) bromide can only move freely in a
molten state
D Electrons can only flow freely when the lead (II) bromide is melted
21.
Diagram 5
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22.
Diagram 6
A simple cell is set up as shown above by immersing metal X and Y into dilute
sodium chloride solution. The electron flows in the direction as shown in
Diagram 6. What metal could be X and Y?
X Y
A Tin Magnesium
B Copper Lead
C Zinc Iron
D Silver Tin
Diagram 7
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24. Which of the following statements are true about an acid?
I contains oxygen
II contains hydrogen ion in aqueous solution
III has a pH more than 7
IV reacts with metal to give off hydrogen gas
A I and IV
B II and III
C II and IV
D II, III and IV
25. Calculate the mass of potassium hydroxide needed to prepare 500 cm3 0.5 mol
dm-3 of standard solution. (Relative atomic mass: H=1, O=16, K=39)
A 7g
B 14 g
C 21 g
D 28 g
26. Which of the ionic equation shows the reaction between hydrochloric acid and
sodium hydroxide solution ?
A H+ + OH- H2O
B 2H+ + O2- H2O
C Na+ + Cl- NaCl
D H+ + Cl- HCl
27. 12.5 cm3 0.5 mol dm-3 of sulphuric acid neutralizes 50 cm3 of sodium hydroxide
solution. Calculate the concentration of the sodium hydroxide solution.
(Relative atomic mass : H=1, O=16, Na=23)
A 2 g dm-3
B 4 g dm-3
C 5 g dm-3
D 10 g dm-3
A Barium sulphate
B Magnesium sulphate
C Lead (II) sulphate
D Calcium sulphate
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29. Name the process used to manufacture of sulfuric acid in industry.
A Contact process
B Haber process
C Ostwald process
D Addition polymerization
A A pure metal
B Compound consisting of two or more metals
C A mixture of two or more elements in which the major component is a metal
D A mixture of two or more elements in which the major components is a non-metal
31. A series of test is carried out on solution Y and the results are shown in the Table 4:
Table 4
Name the substance present in solution Y.
A Zinc sulphate
B Lead (II) nitrate
C Aluminium chloride
D Aluminium sulphate
32. Which of the following sets of conditions is the optimum condition for the
manufacture of ammonia?
Pressure (atmosphere) Temperature (°C) Catalyst
A 200 450 Iron
B 450 200 Iron
C 200 450 Vanadium (V) oxide
D 450 200 Vanadium (V) oxide
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33. Steel is made up of 99% iron and 1% carbon. The presence of carbon atoms in iron
makes it hard and strong. Which statement below best explains the purpose of
adding carbon atoms to iron?
A I and II
B II and IV
C I, II and III
D I, III and IV
34. Which of the following does not affect the rate of reaction?
A Presence of catalyst
B Volume of solution
C Concentration of a solution
D Total surface area of solid reactant
35. Table 5 shows the volume of carbon dioxide gas, CO2 collected in the reaction
between calcium carbonate powder and dilute hydrochloric acid.
Table 5
What is the average rate of reaction in the third minute?
A 0.037 cm3s-1
B 0.043 cm3s-1
C 0.048 cm3s-1
D 0.058 cm3s-1
36. Which of the following pairs of general formula and homologous series is correct?
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37. Which of the following structural formula represents an alcohol?
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38. Diagram 8 shows the molecular formulae of two compounds A and B. Substance X is
formed when both compounds react with each other.
Compound A Compound B
C2H5OH C2H5COOH
Substance X
Diagram 8
Ethyl propanoate
Ethyl propanoate
Propyl propanoate
Propyl propanoate
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39. Diagram 9 shows part of a polymer molecule.
Diagram 9
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40. Diagram 10 shows an experiment to investigate the rate of corrosion in iron nail when it
pairs up with other metals.
Diagram 10
After the test tubes were set aside for two days, which test tube has the highest intensity in
blue colour?
A Test tube W
B Test tube X
C Test tube Y
D Test tube Z
42. Iron (II) ion, Fe2+ in solution can be converted to iron (III) ion, Fe3+ by adding acidified
potassium manganate (VII) solution. Which of the following can replace acidified
potassium manganate (VII) solution in this reaction?
A Zinc powder
B Potassium iodide solution
C Sulphur dioxide gas
D Bromine water
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Carbon Carbon
electrode X electrode Y
Diagram 11
Which of the following is the correct statement for the experiment?
A Electrons flow from X to Y.
B Electrode X is the positive terminal.
C Hydrogen gas is liberated at electrode X.
D Iron is deposited at electrode Y.
Diagram 12
Which of the following are the correct changes in the oxidation state of sulphur?
A 0 +4 +6 +6
B 0 +4 +6 +7
C 1 +3 +6 +8
D 1 +4 +6 +6
45. Which of the following detergent additives is used to convert stains into colourless
substances on cloth?
A Proteases
B Silicone
C Sodium tripolyphosphate
D Sodium perborate
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46. The reaction between nitrogen and oxygen can be represented by the following equation:
Which of the following energy level diagram represent the above reaction?
A
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47. Diagram 13 shows the change in the heat of combustion of a few alcohols.
Diagram 13
Which of the following explain the increase in the heat of combustion of alcohols.
A an increase in the sootiness of the alcohols when burnt.
B an increase in the reactivity of alcohols.
C an increase in the relative molecular mass.
D an increase in the carbon and hydrogen atoms per molecule of alcohol.
48. The following information shows the results of an experiment to determine the heat
change for a displacement reaction between zinc powder and copper (II) sulphate
solution.
Volume of copper (II) sulphate solution = 50 cm3
Mass of zinc powder = 1.0 g
Initial temperature of copper (II) sulphate solution = 28.5 0C
Highest temperature of mixture = 38.5 0C
What is the heat released by the displacement reaction between zinc and copper (II)
sulphate solution?
[Specific heat capacity of water = 4.2 J g-1 0C-1 ; Density of solution = 1.0 g cm-3]
A 2100 J
B 2142 J
C 2184 J
D 3195 J
50. Soaps are prepared by hydrolyzing fats or oils under alkaline condition. Name the reaction
for the production of soap.
A Neutralization.
B Esterification.
C Saponification.
D Oxidation.
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NAMA:.................................................... Tingkatan :..............................
Kimia
Kertas 2
Oktober
2009
2 ½ jam
KIMIA
Kertas 2
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SULIT 1 ZON SAMARAHAN SARAWAK
Section A
[60 marks]
Answer all questions.
1. Diagram 1 shows the arrangement of the apparatus used to determine the melting point
of substance X.
Diagram 1
(a) What is meant by melting point?
[1 mark]
(b) State the error that was made in the arrangement of the apparatus above.
[1 mark]
(c) Graph 1 shows the heating curve of substance X.
Graph 1
(i) State the melting point of substance X.
[1 mark]
(ii) Explain why there is no change in temperature form Q to R.
[2 marks]
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SULIT 2 ZON SAMARAHAN SARAWAK
Table 1 shows the melting point and boiling point of three substances.
Substances Melting point (°C) Boiling point (°C)
P - 106 - 25
Q -4 76
R 801 1056
Table 1
(d) What is the physical state of P and Q at room temperature?
P:___________________ Q:______________________
[2 marks]
(e) Table 2 shows the number of protons, nucleon number and number of electrons for four
elements.
Element Number of protons Nucleon number Number of electrons
W 6 12 6
X 8 16 8
Y 13 27 10
Z 17 35 17
Table 2
(i) What is the number of neutrons for element Z?
[1 mark]
(ii) State an element from Table 2 which is an isotope to the atom 14
6 A.
[1 mark]
(iii) Give a reason for your answer in (e )(ii).
[1 mark]
Halogen:_______________________________________________________________
Noble gas:_____________________________________________________________
[4 marks]
(b)(i) Determine one pair of elements that is placed in the same group.
[1 mark]
(ii) Give reason for your answer in (b)(i).
[1 mark]
(c) State the group where an element Z is located.
[1 mark]
(d) The element X and Y are placed in Group 11 and 17 respectively. Write a chemical
equation for the reaction between the elements X and Y.
[1 mark]
(e)(i) Choose the element that reacts vigorously with cold water.
[1 mark]
(ii) Write the chemical equation to represent the chemical reaction in (e) (i).
[1 mark]
3. Diagram 2 shows the set-up of an electrolytic cell. Beaker I contains the components of
a simple chemical cell whereas electrolysis takes place in the Beaker II.
BBB
Beaker I Beaker II
Beaker I Beaker II
Diagram 2
Beaker I :______________________________________________________________
Beaker II :______________________________________________________________
[2 marks]
(b) Which metal is the negative terminal in Beaker I ?
[1 mark]
(c) (i) State the process that took place in the copper electrode in Beaker I.
[1 mark]
(ii) What would you observed at the silver electrode in Beaker I?
[1 mark]
(d) Write the half - equations for reactions which took place at the anode and the cathode
in Beaker II.
Anode:_________________________________________________________________
Cathode:_______________________________________________________________
[2 marks]
(e)(i) What happens to the voltmeter reading when the copper electrode in Beaker I is
replaced with zinc electrode?
[1 mark]
[2 marks]
4. Observation
Experiment Solution X Solution Y Solution Z
Test with damp Blue litmus paper No change No change
blue litmus paper turns red
Test with damp red No change No change Red litmus paper
litmus paper turns blue
Used as an The bulb lights up The bulb does not The bulb lights up
electrolyte in a light up
circuit with a bulb
Solutions X and Y are the same solution but in different solvents. The table above
shows the observations made when an experiment is carried out on solutions X, Y and
Z.
(a) Why solution X can change the colour of the litmus paper but Y cannot ?
[2 marks]
(b) Name a possible solvent used to produce
solution X : ____________________________________________________________
solution Y : ____________________________________________________________
[2 marks]
Alkaline : ______________________________________________________________
[2 marks]
(d) (i) State two observations when limestone is added into solution X in a test tube.
[2 marks]
(ii) With an example, write a chemical equation for the reaction that occurs in (d) (i).
[1 mark]
(e) If solution X and Z are mixed, state all the products formed.
[1 mark]
5. Five experiments were carried out to determine the rate of reaction of sulphuric acid with
sodium thiosulphate solution at 28 oC, 40 oC, 50 oC, 60 oC, and 70 oC respectively.
Diagram 3 shows the set-up of the experiment.
Diagram 3
The time taken for the ‘X’ mark to be completely invisible is shown in Table 4.
[1 mark]
[1 mark]
(c) Sketch a graph of temperature against 1/time.
[2 marks]
(d) Based on the graph drawn in (d), state an inference based on the relationship between the
rate of reaction and the temperature.
[1 mark]
[2 marks]
(f) Write an equation for this reaction.
[1 mark]
(g) State two factors other than temperature, which can affect the speed of rate of reaction.
[2 marks]
Compound J Compound K
Compound J: ___________________________________________________________
Compound K: __________________________________________________________
[2 marks]
[1 mark]
(ii) Write the molecular formula for a compound that has 7 carbon atoms and in the same
homologous series as K.
[1 mark]
(c) Draw the structural formulae for another two isomers of compound J.
[2 marks]
(d) Compound J combines with each other at high temperature and pressure in the presence
of a catalyst to form a new substance L.
(i) Name the process for the formation of substance L.
[1 mark]
(ii) Draw the structural formula of substance L.
[1 mark]
(e) An isomer of compound K is added into a test tube containing acidified potassium
manganate(VII) solution and heated for a few minutes.
(i) State one observation for this experiment.
[1 mark]
(ii) Write an equation for this reaction.
[1 mark]
Section B
[20 marks]
Answer any question from this section
7 Table 5 shows the heat of combustion for several types of alcohol.
(b) Draw a graph comprising the heat of combustion against the number of carbon atoms per
molecule on a graph paper. [3 marks]
(c) i Based on the graph in (b), state the relationship between the number of carbon atoms
per molecule and the heat of combustion values. [ 1 mark]
ii Explain why the heat of combustion of butanol is higher than the heat of
combustion of ethanol. [3 marks]
(d)
Diagram 4
(e) The thermochemical equation for the combustion of propanol in excess oxygen is as
follows:
2C3H7OH + 9O2 → 6CO2 + 8H2O
ΔH = -2017 kJ molˉ¹
0.4 g of propanol is burned in excess oxygen, in the laboratory.
[Relative atomic mass: H = 1, C = 12, O = 16, Molar gas volume = 24 dm³ molˉ1 at room
condition]
Section C
[20 marks]
Answer any question from this section
(b) Explain how the disposal of synthetic polymers into the environment causes pollution.
[6 marks]
10 (a) The rusting of iron is one of the major problems faced in present times. Suggest three
methods how this problem may be overcomed. [3 marks]
ii State the oxidizing and reducing agents for the redox reaction [2 marks]
(c) You are supplied with iron(II) sulphate, bromine water, dilute sulphuric acid,
carbon electrodes, U-tube and voltmeter.
Answer :
1 B 21 B 41 C
2 D 22 C 42 D
3 A 23 D 43 B
4 B 24 C 44 A
5 A 25 B 45 D
6 B 26 A 46 B
7 A 27 D 47 D
8 B 28 B 48 A
9 D 29 A 49 A
10 A 30 C 50 C
11 A 31 A
12 C 32 A
13 B 33 C
14 A 34 B
15 C 35 A
16 D 36 C
17 C 37 D
18 B 38 B
19 C 39 C
20 C 40 C