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Manufacturing facilities
MRPL has the unique distinction of having two hydrocrackers and
two CCR units in one complex which produce high quality low
sulphur fuels. The technology and equipment have been selected
from the best available in the world to ensure quality and reliability
of operation. Multiple units also allow for flexibility in operation
enabling MRPL to processes 40 different types of crude at same
time. The main products produced by distillation of crude in the
main plant and other secondary products are :
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6. Fuel oil is a fraction obtained from petroleum distillation,
either as a distillate or a residue. Broadly speaking, fuel oil is
any liquid petroleum product that is burned in a furnace or
boiler for the generation of heat or used in an engine for the
generation of power.
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BLOCK DIAGRAM OF REFINERY
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MANUFACTURING UNITS
Manufacturing unit of MRPL is divided as follows:
• Crude distillation unit (CDU)
• Vacuum distillation unit(VDU)
• Visbreaker unit(VBU)
• HydroCracker unit(HCU)
• Continuous catalytic reforming(CCR)
• Sulphur recovery unit(SRU)
• Oil movement and storage(OMS)
• Captive power plant(CPP)
• Condition monitoring
• Effluent treatment plants(ETP)
• Workshop
• Mechanical devices
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Block diagram of CDU tower
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lighter products condense at the top. A simple diagram is as shown
below.
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connotes fewer stages in a distillation column in order to effect the
same separation between the overhead and bottoms products.
Lower pressures increase relative volatilities in most systems.
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The purpose of naphtha stabilizer is to remove LPG and fuel gas
from naphtha. Thus making it easier to store and making it less
susceptible to release last amounts of hydrocarbon vapours.
The naphtha stabilizer has 36 trays. The feed from the atmospheric
reflux drum enters at 1170C. LPG is collected as the overhead
product and it is sent to amine treatment unit. A part of this is sent
to the column as the top reflux. The column bottom is maintained
at 1620C with the help of a reboiler which uses LGO CR as the
heating medium. Stabilized naphtha is collected as a bottom
product. Thus goes to the naptha splitter.
Naptha splitter
Naphtha splitter column consists of 30 trays. The stabilized
naphtha from the stabilizer column is pre-heated in heavy naphtha
product heat exchanger and is flashed. Overhead product is light
naphtha which is sent to column as overhead reflux. Heavy
naphtha is collected as the bottom as the bottom product.
VISBREAKER UNIT
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place breaking long chains molecule at centre due to which lighter
compounds like Light Gas Oil (LGO) , Heavy Gas Oil (HGO) ,
Sour Off Gas , Naphtha and Fuel Oil are formed.
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Merox is an acronym for mercaptan oxidation. It is a proprietary
catalytic chemical process developed by UOP used in oil refineries
and natural gas processing plants to remove mercaptans from LPG,
propane, butanes, light naphthas, kerosene and jet fuel by
converting them to liquid hydrocarbon disulfides.
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LPG MEROX:
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organic disulfides (RSSR) which are liquids that are water-
insoluble and are then separated and decanted from the aqueous
caustic solution. The reaction that takes place in the regeneration
step is:
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As is the case with the conventional Merox process for treating
LPG, the jet fuel or kerosene sweetening process also requires that
the feedstock be prewashed to remove any H2S that would interfere
with the sweetening. The reaction that takes place in the batch
caustic prewash vessel is:
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HYDROCRACKER UNIT
The HydroCracker Unit is a device that converts light and
heavy gas oils to more valuable lower boiling point products.
It is essentially catalytic cracking in the presence of hydrogen
at elevated pressure (70 - 210 (Bar)) and moderate
temperature (280 - 450 (C)).The figure below shows a
general hydrocracking unit.
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olefinic and aromatic hydrocarbons and then hydrogenates them.
Any sulfur and nitrogen present in the hydrocracking feedstock
are, to a large extent, also hydrogenated and form gaseous
hydrogen sulfide (H2S) and ammonia (NH3) which are
subsequently removed. The result is that the hydrocracking
products are essentially free of sulfur and nitrogen impurities and
consist mostly of paraffinic hydrocarbons.
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It is a two stage Thompson made reciprocating compressor ratio
10:1 divided over 2 stages without inter cooling.
7) Reflux Pump:
8) Kerosene Pumps:
1. Pretreating:
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The naphtha which comes from CDU contains about 750 ppm
of sulphur and traces of other impurities like arsenic and lead.
These impurities poison the catalyst used in the reformer. Hence
the naphtha is initially subjected to hydro treatment
The feed is first heated and then mixed with hydrogen in the
naphtha hydro treater. This causes a number of reactions of
which hydro desulphurisation is prominent. Treated naphtha and
hydrogen sulphide are then separated. The sulphur content in
the naptha is reduced from 750ppm to .5 ppm.
2. Reforming:
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SULPHAR RECOVERY UNIT
This is a unit wherein the Sulphar is tapped out from Hydrogen
Sulphide present as an impurity. The overall main reaction
equation is:
2 H2S + O2 → S2 + 2 H2O
The main purpose why this is carried out is that the sulphar present
in LPG and fuel gas causes pollution.
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OIL MOVEMENT AND STORAGE (OMS)
For any refinery oil movement and storage facility is as important
as other sections of complex. Refinery crude processing capacity,
product pattern and storage capacity requirement govern the size of
storage facility.
Refinery terminal
Crude and Product Pipeline
Coastal terminal at NMPT
Interconnecting pipelines
Jetty facilities
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Fig : FIXED ROOF TANK
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EFFLUENT TREATMENT PLANT (ETP)
In a refinery there are many by products produced which have
contaminating properties. These have to be treated suitably before
being discharged.
1) Solids Wastes:
2) Liquid Wastes:
3) Bio-Degradable Wastes:
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arise if the wastewater is excessively diluted with washing water or
is highly concentrated such as neat blood or milk. The presence of
cleaning agents, disinfectants, pesticides, or antibiotics can have
detrimental impacts on treatment processes.
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floating oil whereas backward movement at the bottom
leads to sludge collection.
Tilted plate interceptor: it consists of inclined
corrugated plates where the oil drops are intercepted and
coalescence into larger droplets. The oil is skimmed off by
rotating oil skimmer pipe and discharged to wet oil sump.
Equalization tank: the purpose of the tank is to equalize
the waste water in other words homogenize it before
sending for chemical and biological treatment. The water
has to be made uniform and has to be sent at constant flow
rate to chemical treatment
Dissolved air floatation (DAF): DAF releases dissolved
air as a cloud of micro effluent stream. Bubbles float on
surface of oil globules and lift them into surface.
WORKSHOP
The MRPL workshop generally consists of:
1. Electrical workshop.
2. Instrumentation workshop.
3. Mechanical Workshop.
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Mechanical Workshop consists of the following:
MACHINE SHOP:
• Lathe: Used for wide range of operations like
turning, milling, drilling, boring, thread cutting
etc. Various lathe Present are NH32 Lathe , high
pressure Lathe , Energy Heavy duty Lathe , etc
• Shaper Machines
• Slotting Machines
• Safety Valve Test Bench
• Hydraulic Press
• Bench Grinders
• Radial Drilling Machine
WELDING SECTION:
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to form a pool of molten material (the weld pool) that cools to
become a strong joint, with pressure sometimes used in
conjunction with heat, or by itself, to produce the weld.
1) Arc Welding
2) Gas Welding
TIG Welding:
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Applications of TIG Welding
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CAPTIVE POWERPLANT (CPP):
DESCRIPTION:
Fuel oil system: The fuel oil stored in oil tanks. These are pumped
through pipes to the boiler as required. The fuel oil is used as main
fuel in the boiler to convert the water into steam.
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The turbine shaft is connected to the generator which produces the
power. The steam after expansion passes through the condenser
wherein it converted back into water.
Cooling towers:
These are heat removal devices used to transfer process waste heat
to the atmosphere. Cooling towers may either use the evaporation
of water to remove process heat and cool the working fluid to near
the wet-bulb air temperature or rely solely on air to cool the
working fluid to near the dry-bulb air temperature. Common
applications include cooling the circulating water used in oil
refineries, chemical plants, power stations and building cooling.
With respect to drawing air through the tower, there are three types
of cooling towers:
• Natural draft
• Induced draft
• Open draft
• Closed draft
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Fig: cross section of cooling tower
CONDITION MONITORING
Maintenance is grouped as follows
• Breakdown maintenance
• Time base maintenance
• Predictive maintenance
• Condition base maintenance
• Reliability
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• Critical -checked four times a month
• Semi critical-checked two times a month
• Non critical-checked once a month
• To improve lubrication
• To improve filtering of lub oil
Oil test
• Viscosity test
• Contaminant analysis
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• Spectrometric oil analysis
• Particle analysis
• Direct reading ferrography
• Analytic ferrography
MECHANICAL DEVICES
The various Mechanical devices can be classified as :
1. Pumps
2. Bearings
3. Valves
4. Compressors
5. Heat exchangers
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PUMPS:
A pump is a device used to move fluids, such as liquids or slurries.
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• Injection pumps :
These are the pumps used to inject small doses of fluid .large
quantities can not be transmitted using this.
2) Centrifugal pumps
Centrifugal pumps differ from ordinary pumps in that they rely on
kinetic energy rather than mechanical means to move the liquid.
Liquid enters the pump at the centre of a rotating impeller and
gains energy as it moves to the outer diameter of impeller liquid is
forced out of the pump by energy it obtains from the rotating
impeller. Centrifugal pumps can transfer large volumes of liquid
but efficiency and flow decrease as pressure and viscosity increase.
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very minimal friction is developed. The seal prevents any leakage
of the liquid.
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BEARINGS
A bearing is a device to allow constrained relative motion between
two or more parts, typically rotation or linear movement. Bearings
may be classified broadly according to the motions they allow and
according to their principle of operation as well as by the
directions of applied loads they can handle .
JOURNAL BEARINGS
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ROLLER BEARINGS
Ball bearings
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bearings, balls offer lower friction than rollers. Ball bearings can
operate when the bearing races are misaligned. Precision balls are
typically cheaper to produce than shapes such as rollers; combined
with high-volume use, ball bearings are often much cheaper than
other bearings of similar dimensions. Ball bearings may have high
point loads, limiting total load capacity compared to other bearings
of similar dimensions.
Roller bearings
Needle bearing
Needle roller bearings use very long and thin cylinders. Often the
ends of the rollers taper to points, and these are used to keep the
rollers captive, or they may be hemispherical and not captive but
held by the shaft itself or a similar arrangement. Since the rollers
are thin, the outside diameter of the bearing is only slightly larger
than the hole in the middle. However, the small-diameter rollers
must bend sharply where they contact the races, and thus the
bearing fatigues relatively quickly.
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VALVES
A valve is a device that regulates the flow of a fluid (gases,
liquids, fluidized solids, or slurries) by opening, closing, or
partially obstructing various passageways. Valves are
technically pipe fittings, but are usually discussed as a separate
category. In an open valve, fluid flows in a direction from
higher pressure to lower pressure.
Gate Valve
A gate valve, also known as a sluice valve, is a valve that opens by
lifting a round or rectangular gate/wedge out of the path of the
fluid. The distinct feature of a gate valve is the sealing surfaces
between the gate and seats are planar, so gate valves are often used
when a straight-line flow of fluid and minimum restriction is
desired.
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Fig : Gate Valve
Globe Valve
A globe valve is a type of valve used for regulating flow in a
pipeline, consisting of a movable disk-type element and a
stationary ring seat in a generally spherical body. Globe valves are
named for their spherical body shape with the two halves of the
body being separated by an internal baffle.
Needle Valve
A needle valve is a type of valve having a small port and a
threaded, needle-shaped plunger. It allows precise regulation of
flow, although it is generally only capable of relatively low flow
rates.
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These valves allow liquid to flow only in one direction thus
maintaining flow and pressure.
COMPRESSORS
A gas compressor is a mechanical device that increases the
pressure of a gas by reducing its volume.
Centrifugal compressors
Many large snowmaking operations (like ski resorts use this type
of compressor. They are also used in internal combustion engines
as superchargers and turbochargers. Centrifugal compressors are
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used in small gas turbine engines or as the final compression stage
of medium sized gas turbines. Sometimes the capacity of the
compressors is written in NM3/hr. Here 'N' stands for normal
temperature pressure (20oC and 1 atm ) for example 5500 NM3/hr.
Reciprocating compressors
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be the most efficient compressors available, and are typically
larger, and more costly than comparable rotary units.Another type
of reciprocating compressor is the swash plate compressor, which
uses pistons which are moved by a swash plate mounted on a shaft.
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Rotary screw compressors use two meshed rotating positive-
displacement helical screws to force the gas into a smaller space.
These are usually used for continuous operation in commercial and
industrial applications and may be either stationary or portable.
Their application can be from 3 HP(2.2 kW) to over
1,200 horsepower (890 kW) and from low pressure to moderately
high pressure.
HEAT EXCHANGERS:
Heat exchangers are used to describe units that transfer sensible
heat from one stream another in order to conserve energy.
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Spiral tube heat exchangers:
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