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Contents
Articles
Municipal solid waste 1
Landfill gas 3
Landfill gas monitoring 6
Landfill gas migration 9
Biomedical waste 9
References
Article Sources and Contributors 12
Image Sources, Licenses and Contributors 13
Article Licenses
License 14
Municipal solid waste 1
• Biodegradable waste: food and kitchen waste, green waste, paper (can also be recycled).
• Recyclable material: paper, glass, bottles, cans, metals, certain plastics, etc.
• Inert waste: construction and demolition waste, dirt, rocks, debris.
• Composite wastes: waste clothing, Tetra Packs, waste plastics such as toys.
• Domestic hazardous waste (also called "household hazardous waste") & toxic waste: medication, e-waste, paints,
chemicals, light bulbs, fluorescent tubes, spray cans, fertilizer and pesticide containers, batteries, shoe polish.
Waste generation
Waste generation encompasses activities in which materials are identified as no longer being of value and are either
thrown out or gathered together for disposal.
Collection
The functional element of collection includes not only the gathering of solid waste and recyclable materials, but also
the transport of these materials, after collection, to the location where the collection vehicle is emptied. This location
may be a materials processing facility, a transfer station or a landfill disposal site.
Municipal solid waste 2
Disposal
Today the disposal of wastes by land filling or land spreading is the ultimate fate of all solid wastes, whether they are
residential wastes collected and transported directly to a landfill site, residual materials from materials recovery
facilities (MRFs), residue from the combustion of solid waste, compost or other substances from various solid waste
processing facilities. A modern sanitary landfill is not a dump; it is an engineered facility used for disposing of solid
wastes on land without creating nuisances or hazards to public health or safety, such as the breeding of insects and
the contamination of ground water.
Energy Generation
Municipal solid waste can be used to generate energy. Several technologies have been developed that make the
processing of MSW for energy generation cleaner and more economical than ever before, including landfill gas
capture, combustion, pyrolysis, gasification, and plasma arc gasification.[5] While older waste incineration plants
emitted high levels of pollutants, recent regulatory changes and new technologies have significantly reduced this
concern. EPA regulations in 1995 and 2000 under the Clean Air Act have succeeded in reducing emissions of
dioxins from waste-to-energy facilities by more than 99 percent below 1990 levels, while mercury emissions have
been by over 90 percent.[6] The EPA noted these improvements in 2003, citing waste-to-energy as a power source
“with less environmental impact than almost any other source of electricity.”[7]
References
[1] Nonhazardous Waste (http:/ / www. epa. gov/ osw/ nonhaz/ municipal/ ) U.S. Environmental Protection Agency, Municipal Solid Waste
[2] Municipal Solid Waste (http:/ / www. eia. doe. gov/ cneaf/ solar. renewables/ page/ mswaste/ msw. html) U.S. Energy Information
Administration
[3] Mechanical Biological Treatment (http:/ / www. countryside. wales. gov. uk/ fe/ master. asp?n1=366& n2=213& n3=896) Welsh Assembly
(2005) Mechanical Biological Treatment, Environment Countryside and Planning Website, Welsh Assembly
[4] Nonhazardous waste (http:/ / www. eia. doe. gov/ cneaf/ solar. renewables/ page/ mswaste/ msw. html) U.S. Energy Information
Administration
[5] Environmental and Energy Study Institute Issue Brief (http:/ / www. eesi. org/ files/ eesi_msw_issuebrief_072109. pdf)
[6] Combustion Emissions from Hazardous Waste Incinerators, Boilers and Industrial Furnaces,and Municipal Solid Waste Incinerators- Results
from Five STAR Grants and Research Needs U.S. EPA (http:/ / www. epa. gov/ ncer/ publications/ research_results_needs/
combustionEmmissionsReport. pdf)
[7] U.S. EPA Letter to Maria Zannes, President, Integrated Waste Services Association (http:/ / www. wte. org/ userfiles/ file/ epaletter. pdf)
Municipal solid waste 3
External Links
• "Environmentally Sound Managment of Solid Wastes and Sewage-Related Issues" (http://www.unep.org/
documents.multilingual/default.asp?DocumentID=52&ArticleID=69&l=en). United Nations Environment
Programme. Retrieved 2011-02-23.
Landfill gas
Landfill gas is created by the action of microorganisms within a landfill.
Production
Landfill gas production results from chemical reactions and microbes acting upon the waste as the putrescible
materials begins to break down[1] in the landfill. The rate of production is affected by waste composition and landfill
geometry, which in turn influence the bacterial populations within it, chemical make-up, thermal characteristics,
entry of moisture and escape of gas. [2]
The spatially heterogeneous nature of most landfills means that there will be a wide range of physical conditions and
biological ecosystems co-existing simultaneously within most sites. This heterogeneity, together with the frequently
unclear nature of the contents, makes landfill gas production more difficult to predict and control than standard
industrial bioreactors for sewage treatment.
Due to the constant production of landfill gas, the increase in pressure within the landfill (together with differential
diffusion) causes the gas's release into the atmosphere. Such emissions lead to important environmental, hygiene and
security problems in the landfill.[3] [4] Several accidents have occurred, for example at Loscoe, England in 1986,[5]
where migrating landfill gas which was allowed to build up destroyed the property. An accident causing two deaths
occurred from an explosion in a house adjacent to Skellingsted landfill in Denmark in 1991.[6] Due to the risk
presented by landfill gas there is a clear need to monitor gas produced by landfills. In addition to the risk of fire and
explosion, gas migration in the subsurface can result in contact of landfill gas with groundwater. This in turn can
result in contamination of groundwater by organic compounds present in nearly all landfill gas.[7]
Landfill gas is approximately forty to sixty percent methane, with the remainder being mostly carbon dioxide.
Landfill gas also contains varying amounts of nitrogen, oxygen, water vapor, sulfur, and other contaminants. Most of
these other contaminants are known as "non-methane organic compounds" or NMOCs. Some inorganic contaminants
(for example mercury) are also known to be present in landfill gas. There are sometimes also contaminants (for
example tritium) found in landfill gas. The non-methane organic compounds usually make up less than one percent
of landfill gas. In 1991, the EPA identified ninety-four non-methane organic compounds including toxic chemicals
like benzene, toluene, chloroform, vinyl chloride, and carbon tetrachloride. At least forty one of the non-methane
organic compounds are halogenated compounds (chemicals containing halogens: typically chlorine, fluorine, or
bromine). General options for managing landfill gas are: flaring, boiler (makes heat), internal combustion engine
(makes electricity), gas turbine (makes electricity), fuel cell (makes electricity), convert the methane to methyl
alcohol, clean it enough to pipe it to other industries or into natural gas lines.[8]
The Environmental Protection Agency estimates that there are approximately six thousand landfills in the United
States. Most of these landfills are composed of municipal waste, and therefore producing methane. These landfills
are the largest source of anthropogenic methane emissions in the United States. These landfills will contribute an
estimated four hundred and fifty to six hundred and fifty billion cubic feet of methane per year (in 2000).[9]
Landfill gas 4
Monitoring
Some of the gases produced by landfills are hazardous and monitoring techniques have been developed. Flame
ionization detectors, like the Photovac MicroFID can be used to measure methane levels as well as total VOC levels.
Surface monitoring and sub-surface monitoring as well as monitoring of the ambient air is carried out. Under the
Clean Air Act of 1996, it is required that many large landfills install gas collection and control systems, which means
that at the very least the facilities must collect and flare the gas. The Environmental Protection Agency estimates that
another 600 landfills could support gas to energy projects. The Environmental Protection Agency has also
established the Landfill Methane Outreach Program. This program was developed to reduce methane emissions from
landfills in a cost-effective manner by encouraging the development of environmentally and economically beneficial
landfill gas-to-energy projects.[10]
Federal regulations under Subtitle D of RCRA formed in October 1979 regulate the siting, design, construction,
operation, monitoring, and closure of MSW landfills. Subtitle D now requires controls on the migration of methane
in landfill gas. Monitoring requirements must be met at landfills during their operation, and also an additional 30
years after. The landfills affected by Subtitle D of RCRA are required to control gas by establishing a way to check
for methane emissions periodically and therefore prevent off-site migration. Landfill owners and operators must
make sure the concentration of methane gas does not exceed 25% of the EL for methane in the facilities' structures
and the LEL for methane at the facility boundary.[11]
Opposition
Large projects often cost millions of dollars. Some environmental groups claim that the projects do not produce
renewable power because trash (their source) is not renewable. The Sierra Club opposes any government subsidies
for them.[14] The Natural Resources Defense Council (NRDC) believes that government incentives should be
directed more towards solar, wind, and energy-efficiency efforts.
Environmental effects
Landfill gases have an influence on climate change. The major components are CO2 and methane, both of which are
greenhouse gas.
Microbial oxidation
When landfill gas permeates through a soil cover, a fraction of the methane in the gas is oxidized microbially to
CO2.[15]
References
[1] Burdekin, O. (2003) An investigation into the continuous monitoring of landfill gas and the commercial viability of the Intelysis landfill gas
monitor, Manchester University, Unpublished thesis
[2] DoE Report CWM039A+B/92 (http:/ / users. ox. ac. uk/ ~ayoung/ landfill. html) Young, A. (1992)
[3] Brosseau, J. (1994) Trace gas compound emissions from municipal landfill sanitary sites; Atmospheric-Environment 28 (2), 285-293
[4] Christensen, T. H., Cossu, R. & Stegmann, R. (1999) Landfilling of waste: Biogas
[5] Williams and Aitkenhead (1991) Lessons from Loscoe: The uncontrolled migration of landfill gas; The Quarterly Journal of Engineering
Geology 24 (2), 191-207
[6] Danish EPA (http:/ / www2. mst. dk/ common/ Udgivramme/ Frame. asp?pg=http:/ / www2. mst. dk/ Udgiv/ publikationer/ 2001/
87-7944-831-3/ html/ kap30. htm)
[7] Kerfoot, H.B., Chapter 3.5 In Christensen, T. H., Cossu, R. & Stegmann, R. (1999)Landfilling of waste: Biogas
[8] "Primer on Landfill Gas as "Green Energy"" (http:/ / www. energyjustice. net/ lfg/ ). Energy Justice Network. . Retrieved 2010-04-25.
[9] "Landfill Gas" (http:/ / www. gassep. com/ lfg. htm). Gas Separation Technology LLC. . Retrieved 2010-04-26.
[10] "Landfill Gas" (http:/ / www. gassep. com/ lfg. htm). Gas Separation Technology LLC. . Retrieved 2010-04-26.
[11] "Landfill Gas Control Measures" (http:/ / www. atsdr. cdc. gov/ hac/ landfill/ html/ ch5. html). Agency for Toxic Substances & Disease
Registry. . Retrieved 2010-04-26.
[12] Koch, Wendy (2010-02-25). "Landfill Projects on the rise" (http:/ / www. usatoday. com/ money/ industries/ energy/
2010-02-24-landfill-energy_N. htm). USA Today. . Retrieved 2010-04-25.
[13] "Landfill Gas to Energy" (http:/ / www. thinkgreen. com/ landfill-gas-to-energy). Waste Management. . Retrieved 2010-04-26-2010.
[14] Koch, Wendy (2010-02-25). "Landfill Projects on the rise" (http:/ / www. usatoday. com/ money/ industries/ energy/
2010-02-24-landfill-energy_N. htm). USA Today. . Retrieved 2010-04-25.
[15] Scheutz, C., Kjeldsen, P., Bogner, J.E., De Visscher, A., Gebert, J., Hilger, H.A. & Spokas, K. (2009) Microbial methane oxidation
processes and technologies for mitigation of landfill gas emissions. Waste Manage. Res. 27:409-455.
External links
• "Primer on Landfill Gas as "Green Energy"" (http://www.energyjustice.net/lfg/). Energy Justice Network.
Retrieved 2010-04-25.
• Koch, Wendy (2010-02-25). "Landfill Projects on the rise" (http://www.usatoday.com/money/industries/
energy/2010-02-24-landfill-energy_N.htm). USA Today. Retrieved 2010-04-25.
• "Landfill Gas to Energy" (http://www.thinkgreen.com/landfill-gas-to-energy). Waste Management. Retrieved
2010-04-26-2010.
• "Landfill Gas" (http://www.gassep.com/lfg.htm). Gas Separation Technology LLC. Retrieved 2010-04-26.
• "Landfill Gas Control Measures" (http://www.atsdr.cdc.gov/hac/landfill/html/ch5.html). Agency for Toxic
Substances & Disease Registry. Retrieved 2010-04-26.
Landfill gas monitoring 6
Techniques for establishing landfill gas (rather than liquid) as the source of
volatile organic compounds in groundwater samples
Several techniques have been developed for evaluating whether landfill gas (rather than leachate) is the source of
volatile organic compounds (VOCs) in groundwater samples.[1] Leachate water frequently has elevated levels of
tritium compared to background groundwater and a leachate (water) release would increase tritium levels in affected
groundwater samples, while landfill gas has been shown not to do so. Although landfill gas components can react
with minerals and alter inorganic constituents present in groundwater samples such as alkalinity, calcium , and
magnesium, a frequent major leachate constituent, chloride, can be used to evaluate whether leachate has affected the
sample.
Highly soluble VOCs, such as MtBE, diethyl ether, and tetrahydrofuran, are evidence of leachate effects, since they
are too water-soluble to migrate in landfill gas. The presence of highly soluble semi-volatile organic compounds,
such as phenols, are also consistent with leachate effects on the sample. Elevated concentrations of dissolved CO2
have been shown to be a symptom of landfill gas effects - This is because not all of the CO2 in landfill gas reacts
immediately with aquifer minerals, while such reactions are complete in leachate due to the presence of soils as daily
cover in the waste. To assess whether VOCs are partitioning into groundwater in a specific location, such as a
monitoring well, the headspace gas and dissolved VOC concentrations can be compared. If the Henry's Law constant
multiplied by the water concentration is significantly less than the measured gas concentration, the data are
consistent with VOCs partitioning from landfill gas into the groundwater.
[2]
Typical landfill gas composition %(dry volume basis)a
Nitrogen, N2 2-5
Oxygen, O2 0.1-1.0
hydrogen, H2 0-0.2
a
Exact percentage distribution will vary with the age of the landfill
Landfill gas monitoring 8
Typical problems
Most landfills are highly heterogeneous environments, both physically and biologically, and the gas composition
sampled can vary radically within a few metres. [3]
Near-surface monitoring is additionally vulnerable over short time periods to weather effects. As the atmospheric
pressure rises, the rate of gas escape from the landfill is reduced and may even become negative, with the possibility
of oxygen incursion into the upper layers (an analogous effect occurs in the composition of water at the mouth of an
estuary as the sea tide rises and falls). Differential diffusion and gas solubility (varying strongly with temperature
and pH) further complicates this behaviour. Tunnelling effects, whereby large items (including monitoring
boreholes) create bypass shortcuts into the interior of the landfill, can extend this variability to greater depths in
localised zones. Such phenomena can give the impression that bioactivity and gas composition is changing much
more radically and rapidly than is actually the case, and any series of isolated time-point measurements is likely to
be unreliable due to this variance.
Landfill gas often contains significant corrosives such as hydrogen sulphide and sulphur dioxide, and these will
shorten the lifespan of most monitoring equipment as they react with moisture (this is also a problem for landfill gas
utilization schemes).
Physical settlement as waste decomposes makes borehole monitoring systems vulnerable to breakage as the weight
of the material shifts and fractures equipment.
References
[1] Kerfoot, H.B., Chapter 3.5 In Christensen, T. H., Cossu, R. & Stegmann, R. (1999)Landfilling of waste: Biogas
[2] George Tchobanoglous, et al(1993). "Integrated Solid Waste Management - Engineering Principles and Management Issues", MCGraw-Hill
International Editions. Pg.382
[3] DoE Report CWM039A+B/92 (http:/ / users. ox. ac. uk/ ~ayoung/ landfill. html) Young, A. (1992)
External links
• California Integrated Waste Management Board policy (http://www.ciwmb.ca.gov/LEACentral/LandfillGas/
Monitoring/Screening/default.htm)
Landfill gas migration 9
References
CIRCA 665 and BS8485
[1] (http:/ / users. ox. ac. uk/ ~ayoung/ landfill. html) Young, A. (1992), DoE Report CWM039A+B/92
Biomedical waste
Biomedical waste consists of solids, liquids, sharps, and laboratory waste that are potentially infectious or
dangerous and are considered biowaste. It must be properly managed to protect the general public, specifically
healthcare and sanitation workers who are regularly exposed to biomedical waste as an occupational hazard.
Biomedical waste differs from other types of hazardous waste, such as industrial waste, in that it comes from
biological sources or is used in the diagnosis, prevention, or treatment of diseases. Common producers of biomedical
waste include hospitals, health clinics, nursing homes, medical research laboratories, offices of physicians, dentists,
and veterinarians, home health care, and funeral homes.
Components
The following is a list of materials that are generally considered biomedical waste:
Solids
• Catheters and tubes[1]
• Disposable gowns, masks,[1] and scrubs
• Disposable tools, such as some scalpels and surgical staplers
• Medical gloves[1] [2]
• Surgical sutures and staples
• Wound dressings[1]
Biomedical waste 10
Liquids
• Blood[1] [2]
• Body fluids and tissues[1] [2]
• Cell, organ,[1] and tissue[1] cultures
Sharps
• Blades, such as razor or scalpel blades[1] [2]
• Lancets[1] [3]
• Materials made of glass, such as cuvettes and slides[1] [2]
• Metal stylets
• Needles[1] [2]
• Plastic pipettes and tips[1] [2]
• Syringes[2]
Laboratory waste
• Animal carcasses[1] [2]
• Hazardous chemicals with biological components[2]
• Media[2]
• Medicinal plants
• Radioactive material with biological components[2]
• Supernatants[2]
• Syringes
Exceptions
Cadavers, urine, faeces, and cytotoxic drugs are not considered biomedical waste.[1]
References
[1] Maine Department of Environmental Protection. "Biomedical Waste Management Rules" (http:/ / maine. gov/ dep/ rwm/ rules/ pdf/
chapter900effectiveaugust_4_2008. pdf). . Retrieved 2008-12-21.
[2] MIT EHS. "Biomedical Waste" (http:/ / web. mit. edu/ environment/ ehs/ biomed. html). . Retrieved 2008-12-21.
[3] Florida Division of Environmental Health. "Biomedical Waste" (http:/ / www. doh. state. fl. us/ environment/ community/ biomedical/ index.
html). . Retrieved 2008-12-21.
[4] http:/ / www. bmtscorp. com
[5] http:/ / bmtscorp. com/ brochures. htm
Article Sources and Contributors 12
Landfill gas Source: http://en.wikipedia.org/w/index.php?oldid=412758644 Contributors: Alan Liefting, Alexdevisscher, Baeksu, Chemicalinterest, EldridgeProductsInc, Engineman, Fabartus,
Flumstead, Fraggle81, Kinnison, Kjkolb, Kwelshlo, Leary87512, Mion, N419BH, NawlinWiki, Photovac, Qsecofr, Quarak, Rdsmith4, Ropable, Simsliz, Tangerineduel, Teratornis, 21
anonymous edits
Landfill gas monitoring Source: http://en.wikipedia.org/w/index.php?oldid=410513937 Contributors: Ahoerstemeier, Alan Liefting, Aphex140, Bachrach44, Baeksu, Barefootmatt, CPAScott,
CanisRufus, Darklilac, Element16, Fcjohn, Francophile124, Gobonobo, Hkerfoot, Kinnison, Materialscientist, Mild Bill Hiccup, Mishagam, Phoenix-wiki, Photovac, Rich257, Sais571984,
Theodore Kloba, Vortexrealm, 19 anonymous edits
Landfill gas migration Source: http://en.wikipedia.org/w/index.php?oldid=342076676 Contributors: Aphex140, COMPFUNK2, Dlwr300, 6 anonymous edits
Biomedical waste Source: http://en.wikipedia.org/w/index.php?oldid=414863586 Contributors: Camille stevenson, DivineAlpha, EmergingBiotechs, J04n, Jason Quinn, Mindmatrix, Misarxist,
PMDrive1061, Pinethicket, Rjwilmsi, Rui Silva, Schmidtja, Traveler100, Twirligig, Vegaswikian, Vortexrealm, Wavelength, Whododola, Wsonnier, 22 anonymous edits
Image Sources, Licenses and Contributors 13
License
Creative Commons Attribution-Share Alike 3.0 Unported
http:/ / creativecommons. org/ licenses/ by-sa/ 3. 0/