Escolar Documentos
Profissional Documentos
Cultura Documentos
assessment of protection
systems for metal
artefacts
• PROMET:
“Innovative conservation approaches for monitoring
and protecting ancient and historic metals collections
from the Mediterranean basin”
– 6º Framework Program E.U. INCO-MED
– November 2004 - April 2008
– 21 partners from 11 mediterranean countries
– Spain: CENIM-CSIC & UAM
Artificially
Study of real Laboratory
corroded
objects tests
coupons
New Naturally
Laboratory
products corroded
tests
selection coupons
Real exposure
Final list of
products
Application in real
heritage objects
Electrochemistry in Historical and Archaeological Conservation
Lorentz Center. Leiden. 11-15 January 2010 14
Experimental
Reference Platinum
electrode mesh
(counter
electrode)
4.15 cm2
working
electrode
Sample
7
10
2
resistance, cm
6
10
5
10
Electrochemistry in Historical and Archaeological Conservation
Lorentz Center. Leiden. 11-15 January 2010 4
10 19
Rp tests
ID Coating
• Pre-corroded and NC
TC1
No coating (Blank)
15% Paraloid B-72 in acetone
100
Thickness, μm
1.0E+08
80
1.0E+07 Reference **
Accelerated aged
60 1.0E+06
40 1.0E+05
2
Rp, Ω cm
1.0E+04
20
1.0E+03
0
NC TC1 TC2 C1 C2 C3 C4 C5 1.0E+02
Coating
1.0E+01
1.0E+00
NC TC1 TC2 C1 C2 C3 C4 C5
Coating
Electrochemistry in Historical and Archaeological Conservation
Lorentz Center. Leiden. 11-15 January 2010 20
EIS results
107
106
105
Sin recubrimiento
104
|Z|
Cdl
103
102 RS
101
R1
100
10-1 100 101 102 103 104
Frequency (Hz) No coating
Coating 1
Coating 2
Coating 2a
Coating 2b
-90
theta
-45
0
10-1 100 101 102 103 104
Frequency (Hz)
21
EIS results
107
106
105
Sin recubrimiento
104
|Z|
103
102 RS CPE1
101
R1
100
10-1 100 101 102 103 104
Frequency (Hz) No coating
Coating 1
Coating 2
1
Coating 2a
Z CPE
Y0 j
Coating 2b
-90
theta
-45 CPE1
Y0 α R1
2 (1-α)
F /cm s Ω cm2
2.8 × 10-3 0.74 2681
0
10-1 100 101 102 103 104
Frequency (Hz)
22
EIS results
107
106
105
Rennaissance wax
104
|Z|
103 CPE1
102 RS
101
100 R1 CPE2
-1 0 1 2 3 4
10 10 10 10 10 10
No coating
R2
Frequency (Hz)
Coating 1
Coating 2
Coating 2a
Coating 2b CPE1 CPE2
-90 Y0 α R1 Y0 α R2
2
2 (1-α)
F /cm s Ω cm 2 (1-α)
F /cm s Ω cm2
0.4 × 10-3 0.8 22.86 0.3 × 10-3 0.79 2960
theta
-45
0
10-1 100 101 102 103 104
Frequency (Hz)
23
EIS results
107
106
105
Poligen ES 91009
104
|Z|
103
CPE1
102
RS
101
100 R1
10-1 100 101 102 103 104
CPE2
Frequency (Hz) No coating
Coating 1
Coating 2 CPE1 CPE2
Coating 2a
Coating 2b Y0 α R1 Y0 α
2 (1-α) 2 2 (1-α)
-90 F /cm s Ω cm F /cm s
-3
0.4 × 10 0.76 2162 59 × 10-3 0.51
-6 -5
1.17 × 10 0.76 82442 2.7 × 10 0.58
theta
-9 -7
-45 8.89 × 10 0.96 280810 8.3 × 10 0.47
0
10-1 100 101 102 103 104
Frequency (Hz)
24
EIS results
107 Paraloid B72
106
CPE1
105
RS
104
|Z|
103 R1 CPE2
102
101 R2
100
10-1 100 101 102 103 104
CPE1 CPE2
Frequency (Hz) No coating Y0 α R1 Y0 α R2
Coating 3 2
Coating 3a
2 (1-α)
F /cm s Ω cm 2 (1-α)
F /cm s Ω cm2
Coating 3b 2.95 × 10-7 0.56 16725 4.6 × 10-6 0.5 34825
Coating 3c -3 -3
-90 0.39 × 10 0.5 407 1.2 × 10 0.82 1395
-7 -6
4.53 × 10 0.65 32228 1.0 × 10 0.63 1.29 × 106
2.14 × 10-7 0.65 8031 7.6 × 10-6 0.54 28949
theta
-45
0
10-1 100 101 102 103 104
Frequency (Hz)
25
Conclusions