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Methyl Mercury (both forms) is much more toxic than mercury metal;
Hydrogen is always +1
Oxygen is always -2
N 2 , NH 3 , NO 3 -, NO 2 , NO, NO 2 -, H 2 S, S,
The more positive the potential, the greater the tendency for the reaction to proceed as
written.
∆G0 = -nFE 0
Since we do not know about ALL of the species present in any particular sample of
natural water, we can not write the arrive any balanced redox reaction that suppose to
occur.
pE = -log a e-
pE diagrams tell us the most thermodynamic stable form in certain water environments.
Boundry pH pE
O 2 /H 2 O 0 20.75
O 2 /H 2 O 10 10.75
H 2 /H 2 O 0 0
H 2 /H 2 O 10 -10
NO 3 -/NO 2 - 0 14.15
NO 3 -/NO 2 - 10 4.15
NO 3 -/NH 4 + 0 14.90
NO 3 -/NH 4 + 10 2.40
NO 2 -/NH 4 + 0 15.14
NO 2 -/NH 4 + 10 1.81
Figure 2. pE/pH Diagram for Nitrogen (N-O-H System)