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Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra Ac Rf Db Sg Bh Hs Mt Uun Uuu Uub
Cr Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md Mo Lr
Topic 1 : The Planet Earth, The Macroscopic World
The atmosphere
- A pure substance is a single substance that has nothing else mixed with it
- A mixture consists of two or more pure substances mixed together
- A compound is made of two or more elements chemically joined together
- A compound can be broken down into simpler substances by chemical methods
- An element cannot be broken down into simpler substances by chemical
methods
- Ionic compounds are made of metals and non-metals chemically joined together
- Covalent compounds are made of two or more non-metals chemically joined
together
- Macroscopic terms : Element, Compound, Mixture
Microscopic terms : Atom, Molecule, Ion
Weathering: solid rock broken down into smaller pieces and changed into other
materials
Erosion: the wearing away of surface materials and the movement of products of
wearing from where they formed to a different location
Isotopes are different atoms of an element which have the same number of protons
but different number of neutrons
The isotopes of an element have
hav
different masses and physical properties different mass number
same chemical properties same atomic number
chemists use a relative scale to compare the masses of atoms
Relative isotopic mass ≈ mass number of the isotope
The relative atomic mass of an element is the weighted average mass of all the
naturally occurring isotopes of that element on the 12C = 12.00 scale
Electronic arrangement ≡ Electronic configuration
≡ Electronic structure
2(n)2
Atomic Number of electrons Electronic
lectronic
Element st nd rd th
number 1 2 3 4 arrangement
01 Hydrogen 1 1
02 Helium 2 2
03 Lithium 2 1 2, 1
04 Beryllium 2 2 2, 2
05 Boron 2 3 2, 3
06 Carbon 2 4 2, 4
07 Nitrogen 2 5 2, 5
08 Oxygen 2 6 2, 6
09 Fluorine 2 7 2, 7
10 Neon 2 8 2, 8
11 Sodium 2 8 1 2, 8, 1
12 Magnesium 2 8 2 2, 8, 2
13 Aluminium 2 8 3 2, 8, 3
14 Silicon 2 8 4 2, 8, 4
15 Phosphorus 2 8 5 2, 8, 5
16 Sulphur 2 8 6 2, 8, 6
17 Chlorine 2 8 7 2, 8, 7
18 Argon 2 8 8 2, 8, 8
19 Potassium 2 8 8 1 2, 8, 8, 1
20 Calcium 2 8 8 2 2, 8, 8, 2
simplest whole
number ratio of ions
present
δ = ∆ = delta
aqueous solvents (e.g.CCl4) usually contain non-polar molecules.
Non-aqueous
Non-polar
polar molecules attract ions less strongly than polar molecules. Thus,
Non-polar
polar molecules are not strong enough to remove ions from the giant ionic
structure.
Therefore sodium chloride is insoluble in non-aqueous
non solvents.
四面體).
tetrahedron(四面體
no free electrons
does not conduct electricity
flat, parallel layers
six-membered
membered carbon rings
Strong covalent bonds(within layers)
very high melting point
weak van der Waals’ forces
(between layers)
easy to cleave, softness,
softness lubricating
One outer electron of each carbon atom is ‘free’.
free to move in the direction parallel to the layers the electrons are delocalized
belong to the whole structure a form of carbon
most non-metals and covalent compounds have simple molecular structures except
diamond, graphite and quartz.
- The atoms within a molecule are strongly bonded together (by covalent bonds -).
- Each molecule is attracted to neighbouring molecules by
weak intermolecular forces only (----).
The structure of iodine (I – I)
Weak van der Waals’ forces hold the molecules together
Attractive forces
between non
non-polar
molecules are similar.
In general, the larger the molecular size, the greater will be the van der Waals’ forces
between molecules
Molecular size : F2 < Cl2 < Br2 < I2 (down group 7)
Strength of van der Waals’ forces : F2 < Cl2 < Br2 < I2
Melting point : F2(g) < Cl2(g) < Br2(l) < I2(s)
Simple molecular substances may be gases, liquids or solids
Some substances with simple molecular structures are soluble in water and
conduct electricity in aqueous solutions because
they react with water to give mobile ions.
NH3 + H2O → NH4+(aq) + OH−(aq)
HCl + H2O → H3O+(aq) + Cl−(aq)
SO2 + H2O → H+(aq) + HSO3−(aq)