Escolar Documentos
Profissional Documentos
Cultura Documentos
Project Team
Group: No2
Clarence McKelry
Dynicia Braxton
Rodney Pujada
Robert Thomas
1
Contents
1. pH Analysis 3
2. Total Dissolved Solid Dried at 180 ⁰C 4
3. Total Suspended Solids Dried at 103-105 ⁰C 6
4. Chlorine Analysis 8
5. Determination of Sulfate 11
6. Oil & Grease Analysis 17
7. Hardness Analysis 19
8. Sewage Water Analysis 20
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1. Title : pH Analysis
1.1. Method#: 4500-H+ A. pH Value
1.2. Analytes:
Sample ID#: A-7543-b
Sample ID#: B - 1500
Sample ID#: B – 1214-0
Sample ID#: F – 882-3
Sample ID#: C – 222-4
1.3. Date Due: Wednesday, April 14th, 2010
1.4. Prepared by: Dynicia and Clarence
1.5. Objective: To determine pH liquid unknown sample.
1.6. Data Analysis:
1.7. Conclusion
All of samples are acid and colorless
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2. Title: Total Dissolved Solid Dried at 180 ⁰C
2.1 Method#: 2540 C. Total Dissolved Solid Dried at 180 ⁰C
2.2 Analytes:
Sample ID#: A-7543-b
Sample ID#: B - 1500
Sample ID#: B – 1214-0
Sample ID#: F – 882-3
Sample ID#: C – 222-4
Sample ID#: A – 3614
2.3 Date Due: Wednesday, April 21th, 2010
2.4 Prepared by: Rodney and Clarence
2.5 Objective: Determine the concentration of total suspended solid in each samples.
2.6 The Sample Handling and Preservation
a) Preserve by refrigeration at 4 ⁰C
b) The maximum holding for samples is 28 days
2.7 Data Analysis
Table No 1: Experimental Data
4/19/2010 4/19/2010 4/19/2010 4/20/2010 4/21/2010
Dish with
Sample ID# Dish empty 7:30 AM 9:45 AM 9:00 AM 9:00 AM sample
4
mg Average(W1,W2,W3) mg (B-A)/0.025
A-7543-b 58960.7 58963.8 3.1333 125.3
B-1500 58437.8 58439.9 2.1000 84.0
B-1214-0 73392.0 73390.7 -1.2667 -50.7
F-882-3 72586.3 72562.7 -23.6333 -945.3
C-222-4 66456.2 66468.7 12.5333 501.3
A-3614 68181.8 66183.2 -1998.6333 -79945.3
A-7543-b
Duplicate 68121.5 67453.0 -668.4667 -26738.7
2.8 Calculations
a) Calculating total dissolved solids concentration:
2.9 Conclusion
We made a mistakes in samples:
Sample ID#: B – 1214-0
Sample ID#: F – 882-3
Sample ID#: A – 3614
Duplicate Sample ID#: A-7543-b
a) Preserve by refrigeration at 4 C
Gooch with
4/15/2010 4/15/2010 4/15/2010 4/15/2010 sample
Gooch empty
Sample ID +filter 9:30 AM 10:00 AM 10:30 AM Average (g)
mg Average(W1,W2,W3) mg (B-A)/0.025
A-7543-b 19056.3 19047.7 -8.6 -344.0
F-882-3 18516.4 18514.8 -1.6 -64.0
B-1500 17650.3 17638.4 -11.9 -477.3
C-222-4 17232.9 17233.0 0.1 2.7
A-7543-b
Duplicate 17022.4 17398.8 376.4 15054.7
A-3614 18849.0 18848.4 -0.6 -24.0
B-1214-0 18520.0 18520.5 0.5 21.3
3.8 Calculation
a) Calculating total suspended solids concentration:
3.9 Conclusion
We made a mistake in sample
Sample ID#: A-7543-b and duplicate
Sample ID#: B - 1500
Sample ID#: F – 882-3
Sample ID#: A – 3614
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4. Title: Chlorine Analysis
-
4.1 Method#: 4500-Cl C. Mercuric Nitrate Method
4.2 Analytes:
Sample ID#: A-7543-b
Sample ID#: B - 1500
Sample ID#: B – 1214-0
Sample ID#: C – 222-4
Sample ID#: A – 3614
Titrant
Sample ID Volume
(mL)
A-7543-b 0.70
B - 1500 3.30
B – 1214-0 4.30
C – 222-4 2.00
A – 3614 0.70
C – 222-4
Duplicate 2.00
8
B - 1500 3.30 0.0141 50 32.99
B – 1214-0 4.30 0.0141 50 42.99
C – 222-4 2.00 0.0141 50 19.99
A – 3614 0.70 0.0141 50 7.00
C – 222-4
2.00 0.0141 50 19.99
Duplicate
4.8 Calculation
Prepared Hg(NO3)2 Concentration = 0.0141 N
mg/L Cl = (A – B) x N x 35.450
mL sample
Where:
A = mL of titrant (mercuric nitrate) for sample
B = mL of titrant (mercuric nitrate) for blank
N = normality of mercuric nitrate titrated concentration = 0.0141 N
For sample A- 7543-b
mg/L Cl = (0.70 – 0.01) x 0.0141 x 35.450
50 mL sample
mg/L Cl = 7.00 mg/Cl
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5. Title: Determination of Sulfate
5.1 Method# : 4500-SO42- E. Turbidimetric Method
5.2 Analytes:
Sample ID#: F – 882-3
Sample ID#: A – 3614
Sample ID#: B – 1214-0
5.3 Prepared by: Rodney
5.4 Date Due: Tuesday, April 27th, 2010
5.5 Objective: To determine the sulfate concentration by comparison by reading with a
standard curve.
5.6 Summary of Method:
a) Sulfate ion is converted to a barium sulfate suspension under controlled
conditions.
b) The resulting turbidity is determined by spectrophotometer and compared to a
calibration curve prepared from standard sulfate conditions.
5.7 The Sample Handling and Preservation
a) Preserve by refrigeration at 4 ⁰C
b) The maximum holding for samples is 28 days
5.8 Data Analysis
Table No 1 Sulfate Calibration Curve
Concentration Absorbance
mg/L
0 0
10 0.06
20 0.12
30 0.18
40 0.25
Sample ID Absorbance
10
F-882-3 0.01
F-882-3
Duplicate 0.01
A-3614 0.56
B-1214-0 0.75
5.9 Graphic
a) Standard Calibration Curve
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5.10 Calculation
a) Calculating volumes (mL) for standard concentration:
Prepared Na2SO4 149.7 mg/1L
Prepared dilution of 10, 20, 30, 40 mg/L
C1*V1 = C2*V2
Where:
C1 = sulfate concentration = 149.7 mg/L
V1 = unknown volume in mL
C2 = sulfate dilution concentration = 10 mg/1L
V2 = volume of dilution concentration (10 mg/L) = 100 mL
V1 = (C2*V2) / C1
V1 = 6.68 mL
volume for
Concentration dilution
mg/L mL
10 6.68
20 13.36
30 20.04
40 26.7
5.11 Conclusion
We need to prepared new concentration of standard near to the concentrations of
samples. 100mg/L and 90mg/L
13
14
6. Title : Oil & Grease Analysis
6.1 Method#: 5520 B. Partition Gravimetric Method
6.2 Analytes:
Sample ID#: A – 41202
Sample ID#: A – 41201
6.3 Prepared by: Robert and Rodney
6.4 Date Due: Thursday, May 6th, 2010
6.5 Objective: To determine the dissolved or emulsified oil and grease in unknown
samples by using partition gravimetric method.
6.6 The Sample Handling and Preservation
a) Preserve by refrigeration at 4 ⁰C
b) If analysis is delayed for more than a few days, the sample is acidified with 5
mL of 1:1 HCl
c) Do not exceed the recommended holding time of 28 days
6.7 Data Analysis
Table No 1Gravimetric difference of Standard
(Wt of flask
Sample Wt of wt of flask Concentration
w/sample- Wt.
ID Sample Date Amount empty w/sample Oil & Grease % Recovery
of empty flask)
Used (L) flask (g) (g) (mg) (mg/L)
Standard 4/24/2010 1.00 80.4534 81.2052 751.80 751.80 75 %
Standard 4/26/2010 1.00 102.5927 103.5560 963.30 963.30 96 %
6.8 Calculation
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7. Title: Hardness Analysis
7.1 Method#: 2340 C. EDTA Titrimetric Method
7.2 Analytes:
Sample ID#: A-7543-b
Sample ID#: B - 1500
Sample ID#: B – 1214-0
Sample ID#: F – 882-3
Sample ID#: C – 222-4
Sample ID#: A – 3614
7.3 Prepared by: Dynicia
7.4 Date Due: Thursday, April 22th, 2010
7.5 Objective: To determine hardness by EDTA titrimetric method.
7.6 The Sample Handling and Preservation
a) Preserve by refrigeration at 4 ⁰C
b) The maximum holding for samples is 28 days
7.7 Data Analysis
Table No 1
Run N1 RunN2
A-7543-b 1.80 1.80 0.01 0.025 0.7200 0.7200
B - 1500 3.61 13.40 0.01 0.025 1.4440 5.3600
B – 1214-0 5.00 4.90 0.01 0.025 2.0000 1.9600
F-882-3 0.01 0.61 0.01 0.025 0.0040 0.2440
C – 222-4 3.20 4.51 0.01 0.025 1.2800 1.8040
A – 3614 7.81 28.50 0.01 0.025 3.1240 11.4000
A-7543-b
2.41 4.60 0.01 0.025 0.9640 1.8400
Duplicate
Blank 0.01 0.01 0.01 0.025 0.0040 0.0040
Table No 2
CaCO3
Sample ID Concentration
(mg/L)
17
A-7543-b 0.7200
B - 1500 5.3600
B – 1214-0 1.9600
F-882-3 0.2440
C – 222-4 1.8040
A – 3614 11.4000
A-7543-b Duplicate 1.8400
Blank 0.0040
7.8 Calculation
Hardness (EDTA),as mg CaCO3/L = A x B x 1000
mL sample
Where
A = mL titration for sample and
B = mg CaCO3, equivalent to 1.00 mL EDTA titrant
For sample A-7543-b
Hardness (EDTA),as mg CaCO3/L = 1.80 mL x 0.01 x 1000
25 mL sample
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