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1번 문제
Answer.
(a) Each atom has three translations; the activated complex has three translations,
two rotations, one internal free translation and ;ð3
2Þ 6 vibrations i.e.
zero. The contribution from the internal translation has already been incorpo-
rated in the derivation, so that
Q6¼ 3trans; 2rots; 0vib 2rots
contributions to are ¼
QX QYZ 3trans; 3trans 3trans
TRANSITION STATE THEORY 139
kT Q6¼ 6:2
1012
50
50
value of ¼ dm3 s1
h QX QYZ 5
109
5
109
5
109
¼ 1:2
1013 dm3 s1
(b) An atom has three translations; a linear molecule has three translations, two
rotations and 3N 5 vibrations; the non-linear activated complex has three
translations, three rotations, one internal free translation and ; 3ðN þ 1Þ 7
vibrations i.e. 3N 4 vibrations.
Q6¼ 3trans; 3rots; ð3N 4Þvibs 1rot; 1vib
Contributions to are ¼
QX QYZ 3trans; 3trans; 2rots; ð3N 5Þvib 3trans
kT Q6¼ 6:2
1012
50
5
value of ¼ dm3 s1
h QX QYZ 5
109
5
109
5
109
¼ 1:2
1014 dm3 s1
(c) A non-linear molecule, A, has three translations, three rotations and 3NA 6
vibrations. Likewise non-linear molecule B has three translations, three
rotations and 3NB 6 vibrations. Total for reactants ¼ six translations, six
rotations and 3NA þ 3NB 12 vibrations.
The non-linear activated complex has three translations, three rotations, one
internal free translation and 3NA þ 3NB 7 vibrations.
≠
× × ≠
≠ ⋅