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© 2002 AMCX
Surface Energy Modified AMC141-18
A proven upgrade from PTFE and Parylene Coatings
Background: Inertness and Friction Control
Parylene is very soft. It has a low durometer value and has the
approximate hardness of human skin. A very soft coating is easy to
damage during routine handling, and any scratch to the surface of the
substrate defeats the coating system entirely. Parylene is inert and has
very few active sites to form intra-molecular bonds with other chemicals—
this is why parylene is considered a “nonstick” surface of sorts. However,
the fundamental problem with this property is that since nothing sticks to
the surface, it is hard to get parylene to adhere to the substrate; in reality,
parylene does not bond well to the substrate to surface it is applied to. In
an application where any force is applied perpendicular to the weak
surface bond, as in the case of sliding friction, the parylene coating has a
tendency to dislodge from the substrate; this is known as a poor creep
characteristic. Also, parylene has a very low coefficient of thermal
expansion. When applied to a substrate with a moderate degree of
thermal expansion (i.e., stainless steel), thermal cycling can create shear
stress in the already weak bonds between the parylene and the steel
surface causing failure of the coating system. Parylene application
sometimes requires temperatures high enough to introduce metallurgic
stresses in metal substrates and cause weaknesses and physical
distortions or deviation from metric specifications. Finally, parylene has a
fairly low thermal limitation endpoint in that it sublimates and decomposes
to the vapor monomer at low temperature,
AMC141-18 Properties
The critical surface tension is the primary criterion for wettability by a liquid
on the surface of any object. In effect, a liquid will bead up and roll off of a
material with a critical surface tension that is less than the critical surface
tension of the liquid. If the surface tension of the surface is greater than
the surface tension of the liquid, then the liquid will “wet” the surface.
Teflon and parylene have very low surface tensions in relation to liquids
which come in contact with them; however, a small scratch or nick in the
polymer coating will create sites where sample retention or carry over will
occur on the treated surface. AMC141, as applied, has a medium surface
tension value. In applications where the surface tension is an issue,
AMCX modifies the AMC141 surface to lower the critical surface tension
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by bonding a tough, low surface energy oligomer to the surface that we
call AMC18. The low surface energy oligomer molecule is altered to make
it polar, or 2-sided, and the active side of the molecule is bonded to the
AMC141, leaving the inert moieties of the oligomer facing away from the
substrate. (The oligomer is then cross-linked to further condense and
strengthen the bond with the substrate.) These low surface energy
moieties create the low critical surface energy of the coating. AMC141-18
is essentially inert and non-reactive, and is suitable for use in acids,
solvents and most liquids. It is hydrophobic, lipophobic, does not bind to
hemoglobin, and has extremely low non specific protein binding
characteristics. It will withstand most cleaning methods, it can be sterilized
by autoclave, chemical, or other methods. AMC141-18 is applied in an
environmentally benign manufacturing method and can be scaled up
indefinitely. The AMC141-18 surface system adds approximately 1500
Angstroms (0.15 microns) to the surface of the substrate to be treated,
and tolerances are extremely reproducible. The AMC141-18 system can
be applied to the inner diameter of capillary tubing AMC141-18 is a
standard surface system at AMCX, applied to tens of thousands of items
each year.
** As long as there are no nicks or scratches in the coating. A defect to the surface
negates any protection from corrosion, a problem with Teflon and Parylene coatings.
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The AMC141-18 Surface System
The AMC141-18 surface system is durable, ultra low energy, ultra low
nonspecific protein binding, non-adsorbing surface which is routinely
applied to metals and ceramics for chemical isolation, non-binding of
protein and hemoglobin in biologic systems and anaylsis, and for
hydrophobic characteristics.