A SEMINAR REPORT ON Organic light emitting diode

SUBMITTED BY MAHTAB ALAM (EC THIRD YR) [0805231031] Seminar Guide Er. Ravi Prakash Seminar In charge Dr. V.K.Singh

INSTITUTE OF ENGINEERING & TECHNOLOGY SITAPUR ROAD, LUCKNOW Department of Electronics Engineering

Acknowl d

nt

me a great sense of pleasure to present t e B ech Seminar report undertaken It gi during B Tech. Third Year. I owe special debt of gratitude to respected Er. Ravi prakash for his constant support and guidance throughout the course of our work. His sincerity, thoroughness and perseverance have been a constant source of inspiration for me. It is only his cognizant efforts that mine endeavor have seen light of the day. I also do not like to miss the opportunity to acknowledge the contribution of all dignitary Staff-members of I.E.T. Lucknow for their kind assistance and cooperation during the development of our Seminar report. Last but not the least, I acknowledge my friends for their contribution in the completion of the seminar report. Apart from the efforts of me, the success of this project depends largely on the encouragement and guidelines of many others. I take this opportunity to express my gratitude to the people who have been instrumental in the successful completion of this report.

Declaration
I hereby declare that this submission is my own work and that, to the best of my knowledge and belief, it contain no material previously published of written by another person nor material which to a substantial extent has been accepted for the award of another degree or diploma of the university or other institute of higher learning, except where due acknowledgment has been made in the text.

Signature:

Name:

Mahtab alam

Roll No: 0805231031 Date:

Table of Content
(1) (2) (3) (4) (5) (6)
Abstract 5 Introduction... 7 OLED Technology 10 Development.. 11 The Electroluminescence......................... 11 Type Of OLED... 12 (6.1)Passive-Matrix OLED Pmoled .. 12 (6.2)Active-Matrix OLED Amoled ... 13 (6.3)Transparent OLED. 13 (6.4)Top-Emitting OLED . 13 (6.5)Foldable OLED . 13 (6.6)White OLED.. 13 Working Principle . 14 Material Technologies.. 16 Device Architectures. 19 Advantages And Disadvantages . 20 (1) Advantages 20 (2) Disadvantages 21 (3) Comparison Between LCD And OLED . 23 Manufacturers And Commercial Use.. 25 Application ... 26 (1) Samsung Application 26 (2) Sony Application 27 (3) Military Application 28 (4) Oled Module In Intelligent Traffic Control System. 30 (5) High Level Light Emission Efficiency Contribute To The Reduction Of Energy Consumption. 30 (6) New Source Of Light That Illuminate The Wide Surface Area 30 (7) Light Weight Flexible OLED 31 (8) Developing New Photovoltaic Panels That Are Lightweight, Flexible And Transparent.. 31 Conclusion 33 34

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(13) (14) References ...

Organic Light E itting Diode

1. Abstract
If ever a technology has begged to be disrupted, it is Liquid Crystal Displays. Invented in 1963 and envisioned as a slimmed-down replacement for bulky cathode ray tubes or as screens for wall mounted televisions a use never realized due to problems scaling up to large surfaces liquid crystal displays have instead become the standard for everything from watches to laptop computers. Despite this, however, remains high production and commercial expenses that have never come down enough to successfully mass market these displays, leaving the technology vulnerable to new innovations.

With the imaging appliance revolution underway, the need for more advanced handheld devices that will combine the attributes of a computer, PDA, and cell phone is increasing and the flat-panel mobile display industry is searching for a display technology that will revolutionize the industry. The need for new lightweight, low-power, wide viewing angled, handheld portable communication devices have pushed the display industry to revisit the current flat-panel digital display technology used for mobile applications. Struggling to meet the needs of demanding applications such as e-books, smart networked household appliances, identity management cards, and display-centric handheld mobile imaging devices, the flat panel industry is now looking at new displays known as Organic Light Emitting Diodes (OLED).

Organic Light Emitting Diode technology, pioneered and patented by Kodak/Sanyo, enables full color, full-motion flat panel displays with a level of brightness and sharpness not possible with other technologies. Unlike traditional LCDs, OLEDs are self-luminous and do not require backlighting, diffusers, polarizers, or any of the other baggage that goes with liquid crystal displays. Essentially, the OLED consists of two charged electrodes sandwiched on top of some organic light emitting material. This eliminates the need for bulky and environmentally undesirable mercury lamps and yields a thinner, more versatile and more compact display. Their low power consumption provides for maximum efficiency and helps minimize heat and electric interference in electronic devices. Armed with this combination of features, OLED displays communicate more information in a more engaging way while adding less weight and taking up less space. There are two forms of OLED displays:
y y

Passive-matrix Active-matrix

2. Introduction
An organic light emitting diode (OLED) is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compounds which emit light in response to an electric current. This layer of organic semiconductor material is situated between two electrodes. Generally, at least one of these electrodes is transparent. An OLED display consists of very thin sandwiched layers of materials. When an electric current is supplied, the negatively charged electrons in the cathode layer move through the organic substances towards the positively charged anode layer. The reverse happens from the anode's side, as positively charged electrons are drawn towards the cathode leaving holes in the conductive material. These positively charged holes jump to the organic material to recombine with electrons, which causes electroluminescent light. The chemical composition of the organic material dictates which colors of light are produced Contents. Organic light emitting diodes (OLEDs) offer great promise in displays of all sizes and shapes, and in both commercial and home lighting solutions. OLEDs, or organic electroluminescent (OEL) devices as some call them, are already in use as mobile device displays and mobile phone displays. Prototype large screen and HD OLED televisions always draw the eye away from any other model regardless of its size. In addition OLED technology lends itself to innovative solid-state lighting, as well as flexible lighting solutions and flexible displays, even displays based on organic TFTs.

OLED-A provides a forum for the interchange of technical and market information. Our membership includes companies involved in small-molecule OLED technology and polymer technology (PLED or light-emitting polymers). OLED-A serves its membership by fostering the more rapid development of OLED technology and OLED products; serving as a resource on OLED markets and products for media and investors; functioning as a catalyst in the development of standards for OLEDs; and providing a forum to promote and market OLED technology products OLEDs are used in television screens, computer monitors, small, portable system screens such as mobile phones and PDAs, watches, advertising, information, and indication. OLEDs are also used in light sources for space illumination and in large-area light-emitting elements. Due to their early stage of development, they typically emit less light per unit area than inorganic solid-state based LED point-light sources. An OLED display functions without a backlight. Thus, it can display deep black levels and can be thinner and lighter than liquid crystal displays. In low ambient light conditions such as dark rooms, an OLED screen can achieve a higher contrast ratio than an LCD using either cold cathode fluorescent lamps or the more recently developed LED backlight.

There are two main families of OLEDs: those based upon small molecules and those employing polymers. Adding mobile ions to an OLED creates a Light-emitting Electrochemical Cell or LEC, which has a slightly different mode of operation. OLED displays can use either passive-matrix (PMOLED) or active-matrix addressing schemes. Active-matrix OLEDs (AMOLED) require a transistor backplane to switch each individual pixel on or off, and can make higher resolution and larger size displays possible.

Passive Displays:

The passive-matrix OLED display has a simple structure and is well suited for low-cost and low-information content applications such as alphanumeric displays. It is formed by providing an array of OLED pixels connected by intersecting anode and cathode conductors. Organic materials and cathode metal are deposited into a rib structure (base and pillar), in which the rib structure automatically produces an OLED display panel with the desired electrical isolation for the cathode lines. A major advantage of this method is that all patterning steps are conventional, so the entire panel fabrication process can easily be adapted to large-area, high-throughput manufacturing. To get a passive-matrix OLED to work, electrical current is passed through selected pixels by applying a voltage to the corresponding rows and columns from drivers attached to each row and column. An external controller circuit provides the necessary input power, video data signal and multiplex switches. Data signal is generally supplied to the column lines and synchronized to the scanning of the row lines. When a particular row is selected, the column and row data lines determine which pixels are lit. A video output is thus displayed on the panel by scanning through all the rows successively in a frame time, which is typically 1/60 of a second. Active Displays: In contrast to the passive-matrix OLED display, active-matrix OLED has an integrated electronic back plane as its substrate and lends itself to high -resolution, highinformation content applications including videos and graphics. This form of display is made possible by the development of polysilicon technology, which, because of its high carrier mobility, provides thin-film-transistors (TFT) with high current carrying capability and high switching speed. In an active-matrix OLED display, each individual pixel can be addressed independently via the associated TFTs and capacitors in the electronic back plane. That is, each pixel element can be selected to stay on during the entire frame time, or duration of the video. Since OLED is an emissive device, the display aperture factor is not critical, unlike LCD displays where light must pass through aperture. Therefore, there are no intrinsic limitations to the pixel count, resolution, or size of an active-matrix OLED display, leaving the possibilities for commercial use open to our imaginations. Also, because of the TFTs in the active-matrix design, a defective pixel produces only a dark effect, which is considered to be much less objectionable than a bright point defect, like found in LCDs.

3. OLED Technology
Discovery of polymeric conductors in the 1970s. Polymeric materials, which have historically been classified exclusively as electrical insulators, are now finding varied applications as both conductors and semiconductors. Expensive ceramic semiconductors that are brittle and difficult to pattern have historically been the driving force of the digital age for the last fifty years. But now combinations of properties exist today in polymers that are making many previously impossible appliances a reality. Within a very short time organic conductors have been developed with the conductivity of metals such as copper, while organic electronics has evolved photoelectric cells, diodes, light emitting diodes, lasers and transistors. The result is that a class of plastic materials referred to as conjugated polymers are fast displacing traditional materials such as natural polymers (e.g. wood), metals, ceramics and glass in many applications owing to the combination of their physical/mechanical properties (light weight combined with physical strength) and ease of processability (the ability to mould the shape of plastic materials or extrude into sheet and rod through a die). What this means is that OLEDs can be deployed in a wide range of electronic devices and can be used extensively throughout any given device. Active components of displays can be polymers, substrates can be polymers, logical electronics can be polymers, and so on. In the years ahead OLEDs will see applications in personal computers, cell phones, televisions, general wide area lighting, signs, billboards, communications and any of a number of information appliances.

4. Developments
The first observations of electroluminescence in organic materials were in the early 1950s by A. Bernanose and co-workers at the Nancy-Universit, France. They applied highvoltage alternating current (AC) fields in air to materials such as acridine orange, either deposited on or dissolved in cellulose or cellophane thin films. The proposed mechanism was either direct excitation of the dye molecules or excitation of electrons Device performance was limited by the poor electrical conductivity of contemporary organic materials. This was overcome by the discovery and development of highly conductive polymers. For more on the history of such materials, see conductive polymers.

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5. The Electroluminescence
Electroluminescence from polymer films was first observed by Roger Partridge at the National Physical Laboratory in the United Kingdom. The device consisted of a film of poly(n-vinylcarbazole) up to 2.2 micrometers thick located between two charge injecting electrodes. The results of the project were patented in 1975 and published in 1983. The first diode device was reported at Eastman Kodak by Ching W. Tang and Steven Van Slyke in 1987. This device used a novel two-layer structure with separate hole transporting and electron transporting layers such that recombination and light emission occurred in the middle of the organic layer. This resulted in a reduction in operating voltage and improvements in efficiency and led to the current era of OLED research and device production. Research into polymer electroluminescence culminated in 1990 with J. H. Burroughes et al. at the Cavendish Laboratory in Cambridge reporting a high efficiency green light-emitting polymer based device using 100 nm thick films of poly(p-phenylene vinylene).

6. Type Of OLED
There are several types of OLEDs (1)Passive-matrix OLED (2)Active-matrix OLED (3)Transparent OLED (4)Top-emitting OLED (5)Bottom-emitting OLED (6)Foldable OLED (7)White OLED

6.1 Passive-matrix OLED - PMOLED

PMOLEDs have strips of cathode, organic layers and strips of anode. The anode strips are arranged perpendicular to the cathode strips. The intersections of the cathode and anode make up the pixels where light is emitted. External circuitry applies current to selected strips of anode and cathode, determining which pixels get turned on and which pixels remain off. Again, the brightness of each pixel is proportional to the amount of applied current. PMOLEDs are easy to make, but they consume more power than other types of OLED, mainly due to the power needed for the external circuitry. PMOLEDs are most efficient for text and icons and are best suited for small screens (2- to 3-inch diagonal) such as those you
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find in cell phones, PDAs and MP3 players. Even with the external circuitry, passive-matrix OLEDs consume less battery power than the LCDs that are currently used in these devices.

6.2 Active-matrix OLED - AMOLED

AMOLEDs have full layers of cathode, organic molecules and anode, but the anode layer overlays a thin film transistor (TFT) array that forms a matrix. The TFT array itself is the circuitry that determines which pixels get turned on to form an image. AMOLEDs consume less power than PMOLEDs because the TFT array requires less power than external circuitry, so they are efficient for large displays. AMOLEDs also have faster refresh rates suitable for video. The best uses for AMOLEDs are computer monitors, large screen TVs and electronic signs or billboards.

6.3 Transparent OLED

Transparent OLEDs have only transparent components (substrate, cathode and anode) and, when turned off, are up to 85 percent as transparent as their substrate. When a transparent OLED display is turned on, it allows light to pass in both directions. A transparent OLED display can be either active- or passive-matrix. This technology can be used for heads-up displays.

6.4 Top-emitting OLED

Top-emitting OLEDs have a substrate that is either opaque or reflective. They are best suited to active-matrix design. Manufacturers may use top-emitting OLED displays in smart cards.

6.5 Foldable OLED

Foldable OLEDs have substrates made of very flexible metallic foils or plastics. Foldable OLEDs are very lightweight and durable. Their use in devices such as cell phones and PDAs can reduce breakage, a major cause for return or repair. Potentially, foldable OLED displays can be sewn into fabrics for "smart" clothing, such as outdoor surv ival clothing with an integrated computer chip, cell phone, GPS receiver and OLED display sewn into it.

6.6 White OLED A white organic LED (OLED) incorporating a blue phosphorescent dye and a downconversion phosphor has achieved a luminous efficacy of 25 lm/W. This high-efficacy device was enabled by lowering the device operating voltage, increasing the outcoupling efficiency, and incorporating highly efficient phosphorescent emitters.

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7. Working principle

Schematic of a bila er OLED: 1. Cathode () 2. Emissive La er 3. Emission of radiation 4. Conductive La er 5. Anode (+) A t pical OLED is composed of a la er of organic materials situated between two electrodes the anode and cathode all deposited on a substrate. The organic molecules are electricall conductive as a result of delocali ation of pi electrons caused b conjugation over all or part of the molecule. These materials have conductivit levels ranging from insulators to conductors and therefore are considered organic semiconductors. The highest occupied and lowest unoccupied molecular orbitals ( HOMO and LUMO) of organic semiconductors are analogous to the valence and conduction bands of inorganic semiconductors. Originall the most basic pol mer OLEDs consisted of a single organic la er. One example was the first light-emitting device s nthesi ed b J. H. Burroughs et l which involved a single la er of pol (p-phen lene vin lene). However multila er OLEDs can be fabricated with two or more la ers in order to improve device efficienc . As well as conductive properties different materials ma be chosen to aid charge injection at electrodes file or block a charge from reaching the opposite b providing a more gradual electronic pro electrode and being wasted. Man modern OLEDs incorporate a simple bila er structure consisting of a conductive la er and an emissive la er. t During operation a voltage is applied across the OLED such tha the anode is positive with respect to the cathode. A current of electrons flows through the device from cathode to anode as electrons are injected into the LUMO of the organic la er at th cathode and e withdrawn from the HOMO at the anode. This latter process ma also be described as the injection of electron holes into the HOMO. Electrostatic forces bring the electrons and the holes towards each other and the recombine forming anexciton a bound state of the electron and hole. This happens closer to the emi sive la er because in organic s semiconductors holes are generall more mobile than electrons. The deca of this excited state results in a relaxation of the energ levels of the electron accompanied b emission of radiation whose fre uenc is in the visible region. The fre uenc of this radiation depends

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on the band gap of the material, in this case the difference in energy between the HOMO and LUMO. As electrons and holes are fermions with half integer spin, an exciton may either be in a singlet state or a triplet state depending on how the spins of the electron and hole have been combined. Statistically three triplet exactions will be formed for each singlet exciton. Decay from triplet states (phosphorescence) is spin forbidden, increasing the timescale of the transition and limiting the internal efficiency of fluorescent devices. Phosphorescent organic light-emitting diodes make use of spinorbit interactions to facilitate intersystem crossing between singlet and triplet states, thus obtaining emission from both singlet and triplet states and improving the internal efficiency. Indium tin oxide (ITO) is commonly used as the anode material. It is transparent to visible light and has a high work function which promotes injection of holes into the HOMO level of the organic layer. A typical conductive layer may consist of PEDOT:PSS as the HOMO level of this material generally lies between the workfunction of ITO and the HOMO of other commonly used polymers, reducing the energy barriers for hole injection. Metals such as barium and calcium are often used for the cathode as they have low work functions which promote injection of electrons into the LUMO of the organic layer. Such metals are reactive, so require a capping layer of aluminium to avoid degradation. Single carrier devices are typically used to study the kinetics and charge transport mechanisms of an organic material and can be useful when trying to study energy transfer processes. As current through the device is composed of only one type of charge carrier, either electrons or holes, recombination does not occur and no light is emitted. For example, electron only devices can be obtained by replacing ITO with a lower work function metal which increases the energy barrier of hole injection. Similarly, hole only devices can be made by using a cathode comprised solely of aluminium, resulting in an energy barrier too large for efficient electron injection.

How works the OLED technology?

To enhance the colour or brightness, manufacturers can add complex chains of molecules (polymers) to the carbon-based layers. Unlike LCDs, which require backlighting, OLED displays are "emissive" devices, meaning they emit light rather than modulate transmitted or reflected light. Thin organic layers serve these displays as a source of light, which offers significant advantages in relation to conventional technologies:
y y y y y

brighter and more brilliant picture unlimited viewing angle low power consumption economic production fast "response time"
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The prerequisites for a breakthrough of this technology in the market, which is estimated in 2010 to be worth over USD 2 billion, are the optimization of certain critical performance data such as lifetime and efficiency. This requires innovations in materials meaning that chemistry will decide about the future and the success of the OLED technology. OLEDs Organic Light-Emitting Diodes are the light of the future Video wallpaper - just a millimeter thick - could transform your living room wall into a flat screen and electronic film as thin as a sheet of paper could serve as your screen for the internet, the news, images or games. In future, all of this will be possible thanks to organic light-emitting diodes, so-called OLEDs. In this episode you will learn more about this revolution in lighting technology:

8. Material Technology
Efficient OLEDs using small molecules were first developed by Dr. Ching W. Tang et al. at Eastman Kodak. The term OLED traditionally refers specifically to this type of device, though the term SM-OLED is also in use. Molecules commonly used in OLEDs include organometallic chalets (for example Alq3, used in the organic light-emitting device reported by Tang et al.), fluorescent and phosphorescent dyes and conjugated dendrimers. A number of materials are used for their charge transport properties, for example triphenylamine and derivatives are commonly used as materials for hole transport layers. Fluorescent dyes can be chosen to obtain light emission at different wavelengths, and compounds such as beryline, rubrene and quinacridone derivatives are often used. Alq3 has been used as a green emitter, electron transport material and as a host for yellow and red emitting dyes. The production of small molecule devices and displays usually involves thermal evaporation in a vacuum. This makes the production process more expensive and of limited use for large-area devices than other processing techniques. However, contrary to polymerbased devices, the vacuum deposition process enables the formation of well controlled, homogeneous films, and the construction of very complex multi-layer structures. This high flexibility in layer design, enabling distinct charge transport and charge blocking layers to be formed, is the main reason for the high efficiencies of the small molecule OLEDs. Coherent emission from a laser dye-doped tandem SM-OLED device, excited in the pulsed regime, has been demonstrated. The emission is nearly diffraction limited with a spectral width similar to that of broadband dye lasers. Polymer light-emitting diodes (PLED), also light-emitting polymers (LEP), involve an electroluminescent conductive polymer that emits light when connected to an external voltage. They are used as a thin film for full-spectrum colour displays. Polymer OLEDs are

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quite efficient and require a relatively small amount of power for the amount of light produced. Vacuum deposition is not a suitable method for forming thin films of polymers. However, polymers can be processed in solution, and spin coating is a common method of depositing thin polymer films. This method is more suited to forming large-area films than thermal evaporation. No vacuum is required, and the emissive materials can also be applied on the substrate by a technique derived from commercial inkjet printing. However, as the application of subsequent layers tends to dissolve those already present, formation of multilayer structures is difficult with these methods. The metal cathode may still need to be deposited by thermal evaporation in vacuum. Typical polymers used in PLED displays include derivatives of poly(p-phenylene vinylene) and polyfluorene. Substitution of side chains onto the polymer backbone may determine the colour of emitted light or the stability and solubility of the polymer for performance and ease of processing. While unsubstituted poly(p-phenylene vinylene) (PPV) is typically insoluble, a number of PPVs and related poly(naphthalene vinylene)s (PNVs) that are soluble in organic solvents or water have been prepared via ring opening metathesis polymerization

Phosphorescent materials
Phosphorescent organic light emitting diodes use the principle of electrophosphorescence to convert electrical energy in an OLED into light in a highly efficient manner, with the internal quantum efficiencies of such devices approaching 100%. Typically, a polymer such as poly(n-vinylcarbazole) is used as a host material to which an organometallic complex is added as a dopant. Iridium complexes [40] such as Ir(mppy)3 are currently the focus of research, although complexes based on other heavy metals such as platinum have also been used. The heavy metal atom at the centre of these complexes exhibits strong spin-orbit coupling, facilitating intersystem crossing between singlet and triplet states. By using these phosphorescent materials, both singlet and triplet exactions will be able to decay radioactively, hence improving the internal quantum efficiency of the device compared to a standard PLED where only the singlet states will contribute to emission of light. Applications of OLEDs in solid state lighting require the achievement of high brightness with good CIE coordinates (for white emission). The use of macromolecular species like polyhedral oligomeric silsesquioxanes (POSS) in conjunction with the use of phosphorescent species such as Ir for printed OLEDs has exhibited brightnesses as high as 10,000 cd/m2.

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9. Device Architectures
Structure


Bottom or top emission: Bottom emission devices use a transparent or semi-transparent bottom electrode to get the light through a transparent substrate. Top emission devices use a transparent or semi-transparent top electrode emitting light directly. Top-emitting OLEDs are better suited for active-matrix applications as they can be more easily integrated with a non-transparent transistor backplane. Transparent OLEDs use transparent or semi-transparent contacts on both sides of the device to create displays that can be made to be both top and bottom emitting (transparent). TOLEDs can greatly improve contrast, making it much easier to view displays in bright sunlight. This technology can be used in Head-up displays, smart windows or augmented reality applications. Novaled's OLED panel presented in Finetech Japan 2010, boasts a transparency of 6070%. Stacked OLEDs use a pixel architecture that stacks the red, green, and blue subpixels on top of one another instead of next to one another, leading to substantial increase in gamut and color depth, and greatly reducing pixel gap. Currently, other display technologies have the RGB (and RGBW) pixels mapped next to each other decreasing potential resolution. Inverted OLED: In contrast to a conventional OLED, in which the anode is placed on the substrate, an Inverted OLED uses a bottom cathode that can be connected to the drain end of an n-channel TFT especially for the low cost amorphous silicon TFT backplane useful in the manufacturing of AMOLED displays.

Patterning technologies
Patternable organic light-emitting devices use a light or heat activated electroactive layer. A latent material (PEDOT-TMA) is included in this layer that, upon activation, becomes highly efficient as a hole injection layer. Using this process, light-emitting devices with arbitrary patterns can be prepared. Colour patterning can be accomplished by means of laser, such as radiation-induced sublimation transfer (RIST). Organic vapour jet printing (OVJP) uses an inert carrier gas, such as argon or nitrogen, to transport evaporated organic molecules (as in Organic Vapor Phase Deposition). The gas is expelled through a micron sized nozzle or nozzle array close to the substrate as it is being translated. This allows printing arbitrary multilayer patterns without the use of solvents. Conventional OLED displays are formed by vapor thermal evaporation (VTE) and are patterned by shadow-mask. A mechanical mask has openings allowing the vapor to pass only on the desired location.
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Backplane technologies
For a high resolution displa like a TV a TFT backplane is necessar to drive the pixels correctl . Currentl Low Temperature Pol cr stalline silicon LTPS-TFT is used for commercial AMOLED displa s. LTPS-TFT has variation of the performance in a displa so various compensation circuits have been reported.Due to the si e limitation of the excimer laser used for LTPS the AMOLED si e was limited. To cope with the hurdle related to the panel si e amorphous-silicon/microcr stalline-silicon backplanes have been reported with large displa protot pe demonstrations.

10. ADVANTAGES AND DISADVANTAGES

Demonstration of a 4.1" protot pe flexible displa from Son

10.1A vantages
The different manufacturing process of OLEDs lends itself to several advantages over flat-panel displa s made with LCD technolog .


Lower cost in the f t re: OLEDs can be printed onto an suitable substrate b an inkjet printer or even b screen printing theoreticall making them cheaper to produce than LCD or plasma displa s. However fabrication of the OLED substrate is more costl than that of a TFT LCD until mass production methods lower cost through scalabilit . Roll roll vapour-deposition methods for organic devices do allow mass production of thousands of devices per minute for minimal cost although this techni ue also induces problems in that multi-la er devices can be challenging to make. Light weight & fle ible plastic s bstrates: OLED displa s can be fabricated on flexible plastic substrates leading to the possibilit offlexible organic light-emitting diodes being fabricated or other new applications suc as roll-up displa s embedded in fabrics or h clothing. As the substrate used can be flexible such as PET. the displa s ma be produced inexpensivel . Wi er viewing angles & improve brightness: OLEDs can enable a greater artificial contrast ratio (both d namic range and static measured in purel dark conditions) and viewing angle compared to LCDs because OLED pixels directl emit light. OLED pixel colours appear correct and unshifted even as the viewing angle approaches 90 from normal.
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Better power efficiency: LCDs filter the light emitted from a backlight, allowing a small fraction of light through so they cannot show true black, while an inactive OLED element does not produce light or consume power. Response time: OLEDs can also have a faster response time than standard LCD screens. Whereas LCD displays are capable of between 2 and 8 ms response time offering a frame rate of +/-200 Hz, an OLED can theoretically have less than 0.01 ms response time enabling 100,000 Hz refresh rates.


10.2 Disadvantages


Current costs: OLED manufacture currently requires process steps that make it extremely expensive. Specifically, it requires the use of Low-Temperature Polysilicon backplanes; LTPS backplanes in turn require laser annealing from an amorphous silicon start, so this part of the manufacturing process for AMOLEDs starts with the process costs of standard LCD, and then adds an expensive, time-consuming process that cannot currently be used on large-area glass substrates. Lifespan: The biggest technical problem for OLEDs was the limited lifetime of the organic materials. In particular, blue OLEDs historically have had a lifetime of around 14,000 hours to half original brightness (five years at 8 hours a day) when used for flatpanel displays. This is lower than the typical lifetime of LCD, LED or PDP technology each currently rated for about 25,000 40,000 hours to half brightness, depending on manufacturer and model. However, some manufacturers' displays aim to increase the lifespan of OLED displays, pushing their expected life past that of LCD displays by improving light outcoupling, thus achieving the same brightness at a lower drive current. In 2007, experimental OLEDs were created which can sustain 400 cd/m2 of luminance for over 198,000 hours for green OLEDs and 62,000 hours for blue OLEDs. Color balance issues: Additionally, as the OLED material used to produce blue light degrades significantly more rapidly than the materials that produce other colors, blue light output will decrease relative to the other colors of light. This differential color output change will change the color balance of the display and is much more noticeable than a decrease in overall luminance. This can be partially avoided by adjusting colour balance but this may require advanced control circuits and interaction with the user, which is unacceptable for some users. In order to delay the problem, manufacturers bias the colour balance towards blue so that the display initially has an artificially blue tint, leading to complaints of artificial-looking, over-saturated colors. More commonly, though, manufacturers optimize the size of the R, G and B subpixels to reduce the current density through the subpixel in order to equalize lifetime at full luminance. For example, a blue subpixel may be 100% larger than the green subpixel. The red subpixel may be 10% smaller than the green.

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Efficiency of blue OLEDs: Improvements to the efficiency and lifetime of blue OLEDs is vital to the success of OLEDs as replacements for LCD technology. Considerable research has been invested in developing blue OLEDs with high external quantum efficiency as well as a deeper blue color. External quantum efficiency values of 20% and 19% have been reported for red (625 nm) and green (530 nm) diodes, respectively. However, blue diodes (430 nm) have only been able to achieve maximum external quantum efficiencies in the range between 4% to 6%.

Water damage: Water can damage the organic materials of the displays. Therefore, improved sealing processes are important for practical manufacturing. Water damage may especially limit the longevity of more flexible displays. Outdoor performance: As an emissive display technology, OLEDs rely completely upon converting electricity to light, unlike most LCDs which are to some extent reflective; e-ink leads the way in efficiency with ~ 33% ambient light reflectivity, enabling the display to be used without any internal light source. The metallic cathode in an OLED acts as a mirror, with reflectance approaching 80%, leading to poor readability in bright ambient light such as outdoors. However, with the proper application of a circular polarizer and anti-reflective coatings, the diffuse reflectance can be reduced to less than 0.1%. With 10,000 fc incident illumination (typical test condition for simulating outdoor illumination), that yields an approximate photopic contrast of 5:1. Power consumption: While an OLED will consume around 40% of the power of an LCD displaying an image which is primarily black, for the majority of images it will consume 6080% of the power of an LCD however it can use over three times as much power to display an image with a white background such as a document or website. This can lead to reduced real-world battery life in mobile devices.

Screen burn-in: Unlike displays with a common light source, the brightness of each OLED pixel fades depending on the content displayed. The varied lifespan of the organic dyes can cause a discrepancy between red, green, and blue intensity. This leads to image persistence, also known as burn-in. UV sensitivity: OLED displays can be damaged by prolonged exposure to UV light. The most pronounced example of this can be seen with a near UV laser (such as a Bluray pointer) and can damage the display almost instantly with more than 20 mW leading to dim or dead spots where the beam is focused. This is usually avoided by installing a UV blocking filter over the panel and this can easily be seen as a clear plastic layer on the glass. Removal of this filter can lead to severe damage and an unusable display after only a few months of room light exposure.


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10.3 Comparison Between LCD And OLED



 

Low power consumption is the reasen why OLED is a better choice for portable devices. It also makes OLEDs, and a candidate to be the white-light "bulb" of the future Greater brightness. Light sources based on organic electroluminiscent materials offer the potential to make a high light intensity possible at a low energy consumption on mechanically flexible substrates." said project head Prof. Dr. Karl Leo (IAPP) about the high expectations. - The Flat screen are brighter, and have a fuller viewing angle. Better durability OLED-Displays can operate in a temperature range Lighter weight - the screen can be made very thin, and can be 'printed' on flexible surfaces. OLED-Structure: Organic light emitting diodes consist of stacks of organic layers (thickness about 100 nm), which are inserted between a cathode and an anode. Usually, the substrate is glass coated with a transparent conductive oxide being the anode, followed by the organic stack, consisting of hole transport and electron transport materials, followed by the inorganic cathode. Key advantages of the organic luminescence are the chemical variability of the organic light-emitting diodes, allowing virtually any color including white, and the thin film system, allowing large-area and low-cost deposition, and the possibility to use thin and even flexible substrates to realize a novel class of lighting and display solutions not possible for other technologies. In the OLED technology, two different material groups have to be distinguished: OLED materials with low molecular weight called small-molecule (SM) OLED. SMOLED were first introduced by the research group led by Dr. Ching Tang at the Kodak Laboratories in 1987. The deposition of SM-OLEDs is based on vacuum thermal evaporation. Polymer based OLED (PLEDs) are based on long polymer organic chains and are deposited by spin-cast or ink-jet principles. OLED displays have other advantages over LCDs as well:
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Increased brightness Faster response time for full motion video Lighter weight Greater durability

Broader operating OLEDs emit light in a similar manner to LEDs, through a process called electrophosphorescence.

The process is as follows: The battery or power supply of the device containing the OLED applies a voltage across the OLED. An electrical current flows from the cathode to the anode through the organic layers (an electrical current is a flow of electrons).
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The cathode gives electrons to the emissive layer of organic molecules. The anode removes electrons from the conductive layer of organic molecules. (This is the equivalent to giving electron holes to the conductive layer.)At the boundary between the emissive and the conductive layers, electrons find electron holes.When an electron finds an electron hole, the electron fills the hole (it falls into an energy level of the atom that's missing an electron).When this happens, the electron gives up energy in the form of a photon of light (see How Light Works). The OLED emits light. The color of the light depends on the type of organic molecule in the emissive layer. Manufacturers place several types of organic films on the same OLED to make color displays. The intensity or brightness of the light depends on the amount of electrical current applied: the more current, the brighter the light.

11. Manufacturers and commercial uses

A 3.8 cm (1.5 in) OLED display from a Creative ZEN V media player OLED technology is used in commercial applications such as displays for mobile phones and portable digital media players, car radios and digital camerasamong others. Such portable applications favor the high light output of OLEDs for readability in sunlight and their low power drain. Portable displays are also used intermittently, so the lower lifespan of organic displays is less of an issue. Prototypes have been made of flexible and rollable displays which use OLEDs' unique characteristics. Applications in flexible signs and lighting are also being developed. Philips Lighting have made OLED lighting samples under the brand name 'Lumiblade' available online. OLEDs have been used in most Motorola and Samsung colour cell phones, as well as some HTC, LG and Sony Ericsson models. Nokia has also recently introduced some OLED products including the N85 and the N86 8MP, both of which feature an AMOLED display.
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OLED technology can also be found in digital media players such as the Creative ZEN V, the iriver clix, the Zune HD and the Sony Walkman X Series. The Google and HTC Nexus One Smartphone includes an AMOLED screen, as does HTC's own Desire and Legend phones. However due to supply shortages of the Samsungproduced displays, certain HTC models will use Sony's SLCD displays in the future, while the Google and Samsung Nexus S Smartphone will use "Super Clear LCD" instead in some countries. Other manufacturers of OLED panels include Anwell Technologies Limited, Chi Mei Corporation, LG, and others. DuPont stated in a press release in May 2010 that they can produce a 50-inch OLED TV in two minutes with a new printing technology. If this can be scaled up in terms of manufacturing, then the total cost of OLED TVs would be greatly reduced. Dupont also states that OLED TVs made with this less expensive technology can last up to 15 years if left on for a normal eight hour day.

The use of OLEDs may be subject to patents held by Eastman Kodak, DuPont, General Electric, Royal Philips Electronics, numerous universities and others. There are by now literally thousands of patents associated with OLEDs, both from larger corporations and smaller technology companies.

12. Application of Organic Light Emitting Diode

(1) Samsung applications
By 2004 Samsung, South Korea's largest conglomerate, was the world's largest OLED manufacturer, producing 40% of the OLED displays made in the world, and as of 2010 has a 98% share of the global AMOLED market. The company is leading the world OLED industry, generating $100.2 million out of the total $475 million revenues in the global OLED market in 2006. As of 2006, it held more than 600 American patents and more than 2800 international patents, making it the largest owner of AMOLED technology patents. Samsung SDI announced in 2005 the world's largest OLED TV at the time, at 21 inches (53 cm). This OLED featured the highest resolution at the time, of 6.22 million pixels. In addition, the company adopted active matrix based technology for its low power consumption and high-resolution qualities. This was exceeded in January 2008, when Samsung showcased the world's largest and thinnest OLED TV at the time, at 31 inches and 4.3 mm. In May 2008, Samsung unveiled an ultra-thin 12.1 inch laptop OLED display concept, with a 1,280768 resolution with infinite contrast ratio. According to Woo Jong Lee, Vice President of the Mobile Display Marketing Team at Samsung SDI, the company expected OLED displays to be used in notebook PCs as soon as 2010.

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In October 2008, Samsung showcased the world's thinnest OLED display, also the first to be 'flappable' and bendable. It measures just 0.05 mm (thinner than paper), yet a Samsung staff member said that it is "technically possible to make the panel thinner. To achieve this thickness, Samsung etched an OLED panel that uses a normal glass substrate. The drive circuit was formed by low-temperature polysilicon TFTs. Also, low-molecular organic EL materials were employed. The pixel count of the display is 480 272. The contrast ratio is 100,000:1, and the luminance is 200 cd/m. The colour reproduction range is 100% of the NTSC standard. In the same month, Samsung unveiled what was then the world's largest OLED Television at 40-inch with a Full HD resolution of 19201080 pixel. In the FPD International, Samsung stated that its 40-inch OLED Panel is the largest size currently possible. The panel has a contrast ratio of 1,000,000:1, a colour gamut of 107% NTSC, and a luminance of 200 cd/m (peak luminance of 600 cd/m). At the Consumer Electronics Show (CES) in January 2010, Samsung demonstrated a laptop computer with a large, transparent OLED display featuring up to 40% transparency and an animated OLED display in a photo ID card. Samsung's latest AMOLED Smartphone use their Super AMOLED trademark, with the Samsung Wave S8500 and Samsung i9000 Galaxy S being launched in June 2010. In January 2011 Samsung announced their Super AMOLED Plus displays- which offer several advances over the older Super AMOLED displays - real stripe matrix (50% more sub pixels), thinner form factor, brighter image and a 18% reduction in energy consumption.

(2) Sony applications

Sony XEL-1, the world's first OLED TV. (front)

Sony XEL-1 (side)

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The Sony CLI PEG-VZ90 was released in 2004, being the first PDA to feature an OLED screen. Other Sony products to feature OLED screens include the MZ-RH1 portable minidisc recorder, released in 2006 and the Walkman X Series. At the Las Vegas CES 2007, Sony showcased 11-inch (28 cm, resolution 960540) and 27-inch (68.5 cm, full HD resolution at 19201080) OLED TV models. Both claimed 1,000,000:1 contrast ratios and total thicknesses (including bezels) of 5 mm. In April 2007, Sony announced it would manufacture 1000 11-inch OLED TVs per month for market testing purposes. On October 1, 2007, Sony announced that the 11-inch model, now called the XEL1, would be released commercially; the XEL-1 was first released in Japan in December 2007. In May 2007, Sony publicly unveiled a video of a 2.5-inch flexible OLED screen which is only 0.3 millimeters thick. At the Display 2008 exhibition, Sony demonstrated a 0.2 mm thick 3.5 inch display with a resolution of 320200 pixels and a 0.3 mm thick 11 inch display with 960540 pixels resolution, one-tenth the thickness of the XEL-1. In July 2008, a Japanese government body said it would fund a joint project of leading firms, which is to develop a key technology to produce large, energy-saving organic displays. The project involves one laboratory and 10 companies including Sony Corp. NEDO said the project was aimed at developing a core technology to mass-produce 40 inch or larger OLED displays in the late 2010s. In October 2008, Sony published results of research it carried out with the Max Planck Institute over the possibility of mass-market bending displays, which could replace rigid LCDs and plasma screens. Eventually, bendable, transparent OLED screens could be stacked to produce 3D images with much greater contrast ratios and viewing angles than existing products. Sony exhibited a 24.5" prototype OLED 3D television during the Consumer Electronics Show in January 2010. In January 2011, Sony announced the Next Generation Portable handheld game console (the successor to the PSP) will feature a 5-inch OLED screen. On February 17, 2011, Sony announced its 25" OLED Professional Reference Monitor aimed at the Cinema and high end Drama Post Production market.

(3) Military Application

Low-power Organic Light Emitting Diode (OLED) displays are used in a growing numbers of applications supporting dismounted soldiers and commanders in situational awareness, thermal imaging, simulation and training. Two types of OLED applications are currently under various phases of maturation the near-eye microdisplays, developed by eMagin and Flexible OLED developed by Universal Display Corp. (UDC).

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OLED technolog promises to revolutioni e ever thing known about information displa from video walls to d namic pricing in supermarkets. For the militar Top-emitting OLED (TOLED) applications could include wrist-mounted featherweight rugged PDAs and wearable electronic displa s such as "displa sleeves" Other applications could be conformed high-contrast automotive instrument panels windshield displa s and visor mounted displa s to be used b for pilots drivers and divers etc. More futuristic applications could be utili ed in camouflage s stems "smart" light emitting windows/shades etc. Until 2005 OLEDs were used primaril for testing. Yet in 2004 and mostl b 2005 this technolog is being integrated in more militar s stems and on the long run is expected to replace most small form-factor LCD displa s. Among the applications where OLED technolog is alread maturing are near-e e displa s of virtual images When projected on a -through) displa such image appears like an head mounted helmet mounted or visor (see image in a movie theater or on a computer monitor but is created using magnif ing optics from a ver small displa near to the e e. Such an image displa ed with ver high resolution can appear solid and real or made see-through depending on the t pe optics used. Militar and industrial customers are moving from the testing and evaluation phase into deplo ment. According to Kenneth Ge er vice president of development at Lite e S stems Inc the compan has ordered OLEDs in production uantities to suppl orders received from militar users in the USA Europe and Australia. Several s stems have also been deplo ed to war fighters in Ira . "We anticipate additional programs moving into deplo ment phases in 2006 - 2007" said Ge er. Other users of OLED displa s include SaabTech integrating eMagin's OLED into the protot pe Soldier.

(4) Application of OLED Mo

le in Intelligent Traffic Control System

OLED displa module was used as a man-machine interface in the traffic signal s stem. In this design the OLED displa reali es the 12864 pixels of picture and character monochrome displa with 16 gra -scales. The intelligent traffic signal s stem with OLED -machine interface and adapt to the harsh outdoor displa not onl can provide good man environment but also can achieve multi-phase and multi-time control of traffic flow. The intelligent traffic signal s stem with OLED displa uses the ARM9 as processor so a scientific algorithm can be embedded in it to carr out effective control of traffic flow.

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(5)High-level Light Emission Efficiency Contributes to the Reduction of Energy Consumption

The environmental impact of OLED lighting is small because, unlike fluorescent lamps which contain mercury, it does not contain substances that can harm the environment after disposal. Furthermore, thanks to its high light emission efficiency (the efficiency of converting electricity to light), OLED lighting holds the future promise of reducing energy consumption compared to current mainstream fluorescent light sources. Society has high expectations for the practical application of OLED lighting as a technology of low environmental impact.

(6)New Source of Lighting That Evenly Illuminates Wide Surface Areas

Until now, spaces have been illuminated by point or linear light sources, such as incandescent light bulbs and fluorescent lamps. OLED lighting, in contrast, has characteristics not found in conventional lighting, emitting a uniform light from the whole surface, over a large area. Moreover, OLED lighting closely resembles natural light. Not only that, it does not include ultraviolet rays, which reduces negative impact on the eye.

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(7)Lightweight, Thin, Flexible OLED Lighting Has Multiple Potential Applications

Examples of applications

With OLED lighting, the light source itself illuminates a wide area evenly. This makes it possible to have an entire ceiling or wall serve as an illumination device. Moreover, if plastic film is used for the substrate base, then flexibly curved lighting becomes a real possibility in the future. OLED lighting offers greater potential for applications, including revolutionary design of indoor lighting and new applications in interior spaces, illumination inside vehicles and aircraft, novel monuments and artworks, and other exciting lighting options.
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R&D : Introduction of OLED Technology

(8) Developing New Photovoltaic Panels That Are Lightweight, Flexible and Transparent
Konica Minolta began developing organic thin-film photovoltaic panels in April 2010, in collaboration with the U.S. company Konarka Technologies, Inc., a technologically sophisticated manufacturer that was the first in the world to commercialize this type of photovoltaic panel. By combining the company's expertise with the Group's wealth of technologies, Konica Minolta aims to dramatically improve photovoltaic conversion efficiency, achieve longer life, and reduce manufacturing costs.

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The organic thin-film photovoltaic panels currently under development are expected to exhibit properties unlike traditional photovoltaic panels, such as being lightweight, flexible, and transparent, as well as being capable of generating electricity via incoming light at shallow angles or with limited brightness. Such properties will make an array of new applications possible, including attaching photovoltaic panels to windows on buildings and large canopy covers.

Organic light emitting diode panel with blue monochrome emission and resolution of 160160 has been fabricated by using vacuum evaporation. It has the device structure of anode/hole injection layer/hole transport layer/emitting layer/electron transport layer/hole blocking layer/cathode respectively, and total thickness of organic layers besides anode and cathode electrode is 131 nm. Conventional photolithographic process was applied for patterning ITO, insulator and cathode separator and open aperture ratio of each pixel is 64.4%. Driving module selected the PWM method to embody the color depth of 16 gradations with the electric current control and it introduced a dual scan method that considered the panel brightness increase and device stability.

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13. CONCLUSION
From above discussion we conclude that it is a field of rapid development in near future. With the development in various technology this not only reduce the price but also improve the quality of the display screen As it use organic chemical which found in abundance , it reduce the problem of pollution . Organic molecule and polymer have short life span, also they are bio degradable. Organic light emitting diode will also improve the efficiency of the electronic screen. It has more efficient than the LCD, LED and CRT. It has more brightness and contrast ratio as compare with other type of screen. In future we not only use this in screen technology but also use as illumination, it will replace LED, bulb, CFL completely because of the inexpensive device and greater efficiency. It will also open the exciting field of flexible screen which find even more use in the near future. The screen which can foldable will find great use in TV, wallpaper display, advertizing board etc. Also military use of this technology will find it attractive. But from the current technology OLED find several hurdle in its path such as high cost of production, short life span of the organic compound , fading effect , low brightness ratio and differential power consumption for different colures etc . With the development of the technology the problems in field of the organic light emitting diode will be resolve and. OLED will find greater use in near future .

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14. Reference
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http://impnerd.com/the-history-and-future-of-oled http://www.oled-research.com/oleds/oleds-history.html http://www.voidspace.org.uk/technology/top_ten_phone_techs.shtml#keep-your-eyeon-flexible-displays-coming-soon http://www.pocket-lint.com/news/news.phtml/23150/24174/samsung-say-oled-notready.phtml http://www.cepro.com/article/study_future_bright_for_oled_lighting_market/ http://www.technologyreview.com/energy/21116/page1/ http://optics.org/cws/article/industry/37032 http://jalopnik.com/5154953/samsung-transparent-oled-display-pitched-asautomotive-hud

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