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EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
1. Why is a burn from steam typically much more severe than a burn from boiling water?
2. Identify the most important type of interparticle forces present in the solids of each of the
following substances.
a. NaCl
b. Cdiamond
c. H2O
d. H2CO
e. Ne
3. Consider the compounds Cl2, HCl, F2, NaF, and HF. Which compound has a boiling point
closest to that of argon? Briefly explain.
4. In each of the following groups of substances, pick (circle) the one that has the given
property. (2 points each)
a. highest boiling point:
CCl4
CF4
CBr4
LiF
F2
HCl
CH3OCH3
CH3CH2OH
CH3CH2CH3
Page 1 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
6. Consider a 75.0-g sample of H2O(g) at 125C. What phase or phases* are present when
215 kJ of energy is removed from this sample? *for water: steam and/or liquid water
and/or ice
Page 2 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
7. An aqueous antifreeze solution is 40.0% ethylene glycol (C2H6O2) by mass. The density of
the solution is 1.05 g/cm3. Calculate the (3 points each)
a. molality
b. molarity
8. Which solvent, water or hexane (C6H14), would you choose to dissolve each of the
following? (1 point each)
a. NaCl ...............................................................................................H2O........... C6H14
b. HF .................................................................................................H2O........... C6H14
c. Octane (C8H18) ...............................................................................H2O........... C6H14
d. (NH4)2SO4 .....................................................................................H2O........... C6H14
Page 3 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
9. The vapor pressure of a solution containing 53.6 g glycerin (C3H8O3) in 133.7 g ethanol
(C2H5OH) is 113 torr at 40C. Calculate the vapor pressure of pure ethanol at 40C
assuming that glycerin is a nonvolatile, nonelectrolyte solute in ethanol.
10. A 2.00-g sample of a large biomolecule was dissolved in 15.0 g of carbon tetrachloride.
The boiling point of this solution was found to be 77.85C. Calculate the molar mass of the
biomolecule. For carbon tetrachloride, the boiling-point constant is 5.03Ckg/mol, and the
normal boiling point of pure carbon tetrachloride is 76.50C.
Page 4 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
Winter 2009
week 5
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
revised 2/03/2009
11. How would you prepare 1.0 L of an aqueous solution of sodium chloride having an osmotic
pressure of 15 atm at 22C? Assume that sodium chloride exists as Na+ and Cl- ions in
solution.
II
III
IV
II
III
IV
II
III
IV
II
III
IV
II
III
IV
(2 points each)
Page 5 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
13. The central idea of the collision model is that molecules must collide in order to react. Give
two reasons why not all collisions of reactant molecules result in product formation.
Page 6 of 12
CHM 102
100 points, 2 hrs 15 mins.
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Wallace
Winter 2009
week 5
revised 2/03/2009
[S2O82-]0
0.040
0.040
0.020
0.040
0.030
Page 7 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
c. How much time is required for the concentration of A to decrease to 7.00 x 10-4 M?
Page 8 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
17. The mechanism for the reaction of nitrogen dioxide with carbon monoxide to form nitric
oxide and carbon dioxide is thought to consist of two steps:
NO2 + NO2 NO3 + NO (slow)
NO3 + CO NO2+ CO2 (fast)
a. Write the rate law expected for this mechanism. (3 points)
18. Draw a rough sketch of the energy profile (for a chemical reaction) for each of the
following cases. Show where these values are measured on each profile.
a. E = +10 kJ/mol; Ea = 25 kJ/mol
b. E = -10 kJ/mol; Ea = 50 kJ/mol
Page 9 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
Winter 2009
week 5
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
revised 2/03/2009
153-170 points
136-152
119-135
102-118
<102
Page 10 of 12
CHM 102
100 points, 2 hrs 15 mins.
Winter 2009
week 5
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Wallace
revised 2/03/2009
2
2A
4
Be
9.01
12
Mg
24.31
20
Ca
40.08
38
Sr
87.62
56
Ba
137.3
88
Ra
226
13
3A
5
B
10.81
13
Al
26.98
31
Ga
69.72
49
In
114.8
81
Tl
204.4
113
14
4A
6
C
12.01
14
Si
28.09
32
Ge
72.59
50
Sn
118.7
82
Pb
207.2
114
15
5A
7
N
14.01
15
P
30.97
33
As
74.92
51
Sb
121.8
83
Bi
209.0
115
16
6A
8
O
16.00
16
S
32.07
34
Se
78.96
52
Te
127.6
84
Po
(209)
3
3B
21
Sc
44.96
39
Y
88.91
71
Lu
175.0
103
Lr
(262)
4
4B
22
Ti
47.88
40
Zr
91.22
72
Hf
178.5
104
Rf
5
5B
23
V
50.94
41
Nb
92.91
73
Ta
180.9
105
Db
6
6B
24
Cr
52.00
42
Mo
95.94
74
W
183.9
106
Sg
7
7B
25
Mn
54.94
43
Tc
(98)
75
Re
186.2
107
Bh
8
8B
26
Fe
55.85
44
Ru
101.1
76
Os
190.2
108
Hs
9
8B
27
Co
58.93
45
Rh
102.9
77
Ir
192.2
109
Mt
10
8B
28
Ni
58.69
46
Pd
106.4
78
Pt
195.1
110
Uun
11
1B
29
Cu
63.55
47
Ag
107.9
79
Au
197.0
111
Uuu
12
2B
30
Zn
65.38
48
Cd
112.4
80
Hg
200.6
112
Uub
57
La
138.9
89
Ac
(227)
58
Ce
140.1
90
Th
232.0
59
Pr
140.9
91
Pa
231.0
60
Nd
144.2
92
U
238.0
61
62
63
64
65
66
67
68
69
70
93
Np
(237)
94
Pu
(244)
95
Am
(243)
96
Cm
(247)
97
98
99
100
101
102
17
7A
9
F
19.00
17
Cl
35.45
35
Br
79.90
53
I
126.9
85
At
(210)
18
8A
2
He
4.00
10
Ne
20.18
18
Ar
39.95
36
Kr
83.80
54
Xe
131.3
86
Rn
(222)
He
Li
1.0
Be
1.5
B
2.0
C
2.5
N
3.0
O
3.5
F
4.0
Ne
Na
0.9
Mg
1.2
Al
1.5
Si
1.8
P
2.1
S
2.5
Cl
3.0
Ar
K
0.8
Ca
1.0
Sc
1.3
Ti
1.5
V
1.6
Cr
1.6
Mn
1.5
Fe
1.8
Co
1.9
Ni
1.9
Cu
1.9
Zn
1.6
Ga
1.6
Ge
1.8
As
2.0
Se
2.4
Br
2.8
Kr
3.0
Rb
0.8
Sr
1.0
Y
1.2
Zr
1.4
Nb
1.6
Mo
1.8
Tc
1.9
Ru
2.2
Rh
2.2
Pd
2.2
Ag
1.9
Cd
1.7
In
1.7
Sn
1.8
Sb
1.9
Te
2.1
I
2.5
Xe
2.6
Cs
0.7
Ba
0.9
La
1.1
Hf
1.3
Ta
1.5
W
1.7
Re
1.9
Os
2.2
Ir
2.2
Pt
2.2
Au
2.4
Hg
1.9
Tl
1.8
Pb
1.9
Bi
1.9
Po
2.0
At
2.2
Rn
2.4
Fr
0.7
Ra
0.9
Ac
1.1
Rf
Ha
Sg
Ns
Hs
Mt
Page 11 of 12
CHM 102
100 points, 2 hrs 15 mins.
Wallace
EXAM #1
Chemistry, 7th ed., Zumdahl & Zumdahl, ch. 10-12
Winter 2009
week 5
revised 2/03/2009
Page 12 of 12