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Describe geothermal energy and the ways it is harnessed, and evaluate its advantages and disadvantages Describe ocean energy sources and the ways they can be harnessed, and evaluate their advantages and disadvantages Explain hydrogen fuel cells and assess future options for energy storage and transportation
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Europe Iceland
Atlantic Ocean
Africa
Mid-Atlantic Ridge. Most of Icelands 290,000 people live in the capital city of Reykjavik, leaving much of the island an unpeopled and starkly beautiful landscape of volcanoes, hot springs, and glaciers. The magma that gave birth to the island heats its groundwater in many places, giving Iceland some of the worlds best sources of geothermal energy. Iceland has also dammed some of its many rivers for hydropower. Together these two renewable energy sources provide 73% of the countrys energy supply and virtually all its electricity generation. Yet the nation, like most others,
Iceland are blazing a bold new path, one they believe the rest of the world may follow. Iceland aims to become the first nation to leave fossil fuels behind and convert to an economy based completely on renewable energy. Iceland is essentially a hunk of lava the size of Kentucky that has risen out of the North Atlantic from the rift between tectonic plates known as the
he Viking explorers who first set foot centuries ago on the remote island of Iceland were trailblazers. Today the citizens of the nation of
also depends on fossil fuels. Oil powers its automobiles, some of its factories, and its economically vital fishing fleetand together these have given Iceland one of the highest per capita rates of greenhouse gas emission in the world. Because it possesses no fossil fuel reserves, all fossil fuels must be importeda weak link in an otherwise robust economy that has given its citizens one of the highest per capita incomes in the world. Enter Bragi rnason, a University of Iceland professor popularly known as Dr. Hydrogen. rnason began
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arguing in the 1970s that Iceland could achieve independence from fossil fuel imports, boost its economy, and serve as a model to the world by converting from fossil fuels to a renewable energy economy based on hydrogen. He suggested zapping water with Icelands cheap and renewable electricity in a chemical reaction called electrolysis, splitting the hydrogen from the oxygen and then using the hydrogen to power fuel cells that would produce and store electricity. The process is clean; nothing is combusted, and the only waste product is water. In the late 1990s rnasons countrymen began to listen. The nations leaders decided to embark on a grand experiment to test the efficacy of switching to a hydrogen economy. By setting an example for the rest of the world to follow, and by getting a head start at producing and exporting hydrogen fuel, these leaders hoped Iceland could become a Kuwait of the North and get rich by exporting hydrogen to an energy-hungry world, as Kuwait has done by exporting oil. The leaders planning the shift to a hydrogen economy sketched a stepped transition in which fossil fuels would be phased out over 3050 years. Conversion of the Reykjavik bus fleet to run on hydrogen fuel is the first step. After that, Icelands 180,000 private cars would be powered by fuel cells, and then the fishing fleet would be converted to hydrogen. The final stage would be the export of hydrogen fuel to mainland Europe. To make this happen, Icelanders in 1999 teamed up with corporate partners looking to develop technology for the future. Auto company Daimler-Chrysler is producing hydrogen buses, oil company Royal Dutch Shell is running hydrogen filling stations to fuel the buses, and Norsk Hydro is providing electrolysis technology. In 2003, the worlds first commercial hydrogen filling station opened in Reykjavik, and three hydrogen-fueled buses began operation. The public-private consortium, Icelandic New Energy (INE), is monitoring the technologys effectiveness and the costs of developing infrastructure. Icelands citizens are behind the effort; a recent poll showed 93% support among Icelanders. Meanwhile, Daimler-Chrysler has introduced trios of hydrogen-fueled buses to nine other European cities. Hydrogen buses are also being developed by other companies and run in cities in Europe and throughout the world, from Tokyo to Chicago to Perth to Winnipeg. Hydrogen refueling stations are being demonstrated in Japan, Singapore, and the United States, and fuel-cell passenger automobiles are being tested in Japan and California. A global hydrogen economy could be closer than we suspect.
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Hydropower 44.6%
Biomass 46.5%
Solar (1.0%)
Solar
Wind
Geothermal
Ocean
Energy source
FIGURE 21.2 The new renewable energy sources are growing substantially faster than the total primary energy supply. Solar power has grown by 32% each year since 1971, and wind power has grown by 52% each year. Because these sources began from such low starting levels, however, their overall contribution to our energy supply is still small. Go to at www.aw-bc.com/ withgott or on the student CD-ROM. Data from International Energy
Hydropower 73.6%
for nearly 75%, and biomass 14%. As of 2004, geothermal power accounted for 8.3%, wind for 3.9%, and solar for just 0.2% (Figure 21.1b).
renewable sources, the leader in growth is wind power, which has expanded by about 50% each year over the past three decades. Because these sources started from such low levels of use, however, it will take them some time to catch up to conventional sources. For instance, the absolute amount of energy added by a 50% increase in wind power is still less than the amount added by just a 1% increase in oil, coal, or natural gas. The rapid growth of the new renewables has been motivated by concerns over diminishing fossil fuel supplies and the environmental impacts of fossil fuel combustion (Chapter 19). As these concerns build, advances in technology are making it easier and less expensive to harness renewable energy sources. The new renewables promise several benefits over fossil fuels. As they replace fossil fuels, they help alleviate air pollution and the greenhouse gas emissions that drive global climate change (Chapter 18). Unlike fossil fuels, renewable sources are inexhaustible on time scales relevant to human societies. Developing renewables can also help diversify an economys mix of energy, lowering price volatility and protecting against supply restrictions such as those caused by the 1973 oil embargo or by Hurricane Katrina in 2005 ( p. 579). New energy sources also can create new employment opportunities and sources of income and property tax for local communities, especially in rural areas passed over by other economic
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development. In many rural areas and developing countries, locally based renewable sources may prove cheaper to use for electricity than would extending the electricity grid infrastructure out from cities. Rapid growth in renewable energy sectors seems likely to continue as population and consumption grow, global energy demand expands, fossil fuel supplies decline, and citizens demand cleaner environments. More governments, utilities, corporations, and consumers are now promoting and using renewable energy sources, and, as a result, the costs of renewables are falling.
diminishing fossil fuel supplies could outpace our ability to develop new sources, and we could find our economies greatly disrupted, and our environment greatly degraded. Thus, encouraging the speedy development of renewable energy alternatives holds promise for bringing us a vigorous and sustainable energy economy without the environmental impacts of fossil fuels.
Solar Energy
The sun provides energy for almost all biological activity on Earth ( pp. 105106) by converting hydrogen to helium in nuclear fusion ( pp. 595596). Each square meter of Earths surface receives about 1 kilowatt of solar energy 17 times the energy of a lightbulb. As a result, an averagesized house whose roof is covered in panels that harness solar energy has enough roof area to generate all its power needs. The suns raw energy is so strong that if only 0.1% of Earths surfaceroughly the combined area of New Mexico and South Dakotawere covered with solar panels, we would have enough solar energy to power all the worlds electrical plants. The amount of energy Earth receives from the sun each day, if it could be collected in full for our use, would be enough to power human consumption for 27 years. Clearly, the potential for using sunlight to meet our energy needs is tremendous. However, all this free energy from the sun cannot be harnessed just yet. We are still in the process of developing solar technologies and learning the most effective and cost-efficient ways to put the suns energy to use. The most commonly used way to harness solar energy is through passive solar energy collection. In this approach, buildings are designed and building materials are chosen to maximize direct absorption of sunlight in winter, even as they keep the interior cool in the heat of summer. This approach contrasts with active solar energy collection, which makes use of technological devices to focus, move, or store solar energy. We tend to think of using solar power as a novel phenomenon, but people have chosen and designed their living sites with passive solar collection in mind for millennia. Moreover, solar energy was first harnessed with active solar technology in 1767, when Swiss scientist Horace de Saussure built a thermal solar collector to heat water and cook food. In 1891, U.S. inventor Clarence Kemp claimed the first commercial patent for a solar-powered water heater. Two California entrepreneurs bought the patent rights and outfitted one-third of the homes in Pasadena, California, with solar water heaters by 1897.
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antifreeze solutions are run through tubes that pass through the collectors, transferring heat throughout a building. Heated water can be pumped to tanks to store the heat for later use and through pipes designed to release the heat into the building. Such systems have proven especially effective for heating water for residences. Active solar energy is being used for heating, cooling, and water purification in Gaviotas, a remote town in the high plains of Colombia far from any electrical grid. Engineers have developed inexpensive solar panels that harvest enough solar energy, even under cloudy skies, to boil drinking water for a family of four. They also have designed, built, and installed a unique solar refrigerator in a rural hospital, along with a large-scale solar collector to boil and sterilize water. Their innovations show that solar power does not need to be expensive or confined to regions that are always sunny.
Active solar energy collection can heat air and water in buildings
One active method for harnessing solar energy involves using solar panels or flat-plate solar collectors, most often installed on rooftops. These panels generally consist of dark-colored, heat-absorbing metal plates mounted in flat boxes covered with glass panes. Water, air, or
FIGURE 21.3 At the Solar Two facility operated by Southern California Edison in the desert of southern California, mirrors are spread across wide expanses of land to concentrate sunlight onto a receiver atop a power-tower. Heat is then transported through fluid-filled pipes to a steamdriven generator that produces electricity.
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Light
Panel
Module Array
FIGURE 21.4 A photovoltaic (PV) cell converts sunlight to electrical energy. When sunlight hits a layer of silicon infused with phosphorus, electrons are released and travel toward the layer of silicon laced with boron. This movement of electrons induces an electric current, producing electricity. PV cells are grouped in modules, which can comprise panels, which can be erected in arrays.
transported by fluids (often molten salts) piped to a steamdriven generator to create electricity. These solar power plants can harness light from large mirrors spread across many hectares of land. The worlds largest such plant so fara collaboration among government, industry, and utility companies in the California desertproduces power for 10,000 households. Another approach is the use of solar-trough collection systems, which consist of mirrors that gather sunlight and focus it on oil in troughs. The superheated oil creates steam that drives turbines, as in conventional power plants.
posing plate. The flow of electrons from one plate to the other creates an electrical current, which can be converted into alternating current (AC) and used for residential and commercial electrical power (Figure 21.4). The plates of a PV cell are made primarily of silicon, enriched on one side with phosphorus and on the other with boron. Silicon is a semiconductor, so it conducts and controls the flow of electricity. Because of the chemical properties of boron and phosphorus, the phosphorusenriched side has excess electrons, and the boron-enriched side has fewer electrons. When sunlight strikes the cell surface, it transfers energy and causes electrons to move. When wires connect the two sides, electricity is created as electrons flow from the phosphorus-enriched side to the boron-enriched side. Photovoltaic cells can be connected to batteries that store the accumulated charge until it is needed. You may be familiar with small PV cells that power your watch or your calculator. Atop the roofs of homes and other buildings, multiple PV cells are arranged in modules. These modules can comprise panels, which can be gathered together in flat arrays. Increasingly, PV roofing tiles are being used instead of these arrays. PV roofing
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tiles look like normal roofing shingles but generate electricity by the photovoltaic effect. In some remote areas, such as Xcalak, Mexico, PV systems are being used in combination with wind turbines ( pp. 627628) and a diesel generator to power entire villages.
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FIGURE 21.5 Because some locations receive more sunlight than others, harnessing solar energy is more profitable in some areas than in others. In the United States, many areas of Alaska and the Pacific Northwest receive only 34 kilowatt-hours per square meter per day, whereas most areas of the Southwest receive 67 kilowatt-hours per square meter per day. Data from National
Solar radiation (kWh/m2/day) 6.57.0 6.06.5 5.56.0 5.05.5 4.55.0 4.04.5 3.54.0 3.03.5
However, decreases in price and improvements in energy efficiency of solar technologies so far are encouraging, even in the absence of significant financial commitment from government and industry. At their advent in the 1950s, solar technologies had efficiencies of around 6%, while costing $600 per watt. Recent single-crystal silicon PV cells are showing 15% efficiency commercially and 24% efficiency in lab research, suggesting that future solar technologies may be more efficient than any energy technologies we have today. Solar systems have become much cheaper over the years and now can often pay for themselves in 1015 years. After that time, they provide energy virtually for free as long as the equipment lasts. With future technological advances, some experts believe that the time to recoup investment could fall to 13 years.
Wind Energy
Wind energy can be thought of as an indirect form of solar energy, because it is the suns differential heating of air masses on Earth that causes wind to blow. We can harness power from wind by using devices called wind turbines, mechanical assemblies that convert winds kinetic energy, or energy of motion, into electrical energy.
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FIGURE 21.6 A wind turbine converts winds energy of motion into electrical energy. Wind causes the blades of a wind turbine to spin, turning a shaft that extends into the nacelle that is perched atop the tower. Inside the nacelle, a gearbox converts the rotational speed of the blades, which can be up to 20 revolutions per minute (rpm) or more, into much higher rotational speeds (over 1,500 rpm). These high speeds provide adequate motion for a generator inside the nacelle to produce electricity.
Tower
Nacelle
equipment to monitor and control the turbines activity. Most of todays towers range from 40 to 100 m (131328 ft) tall. Higher is generally better, to minimize turbulence (and potential damage) and to maximize wind speed. Most rotors consist of three blades and measure 4280 m (138262 ft) across. Turbines are designed to yaw, or rotate back and forth in response to changes in wind direction, ensuring that the motor faces into the wind at all times. Turbines can be erected singly, but they are most often erected in groups called wind parks, or wind farms. The worlds largest wind farms contain several hundred or thousand turbines spread across the landscape. Engineers have designed turbines to begin turning at specific wind speeds to harness wind energy as efficiently as possible. Some turbines create low levels of electricity by turning in light breezes. Others are programmed to rotate only in strong winds, operating less frequently but generating large amounts of electricity in short time periods. Slight differences in wind speed can yield substantial differences in power output, for two reasons. First, the energy content of a given amount of wind increases as the square of its velocity; thus if wind velocity doubles, energy quadruples. Second, an increase in wind speed causes more air molecules to pass through the wind turbine per unit time, making power output equal to wind velocity cubed. Thus a doubled wind velocity actually results in an eightfold increase in power output.
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perts agree that wind powers rapid growth will continue, because only a very small portion of this resource is currently being tapped. Meteorological evidence suggests that wind power could be expanded in the United States to meet the electrical needs of the entire country (see The Science behind the Story, p. 632).
U.S. (16%)
India (5%)
FIGURE 21.7 Most of the worlds fast-growing wind power generating capacity is concentrated in a handful of countries. Tiny Denmark obtains the highest percentage of its energy needs from wind, but the larger nations of Germany, the United States, and Spain have so far developed more total wind capacity. Data from
Global Wind Energy Council; and American Wind Energy Association. 2005. Global wind energy market report. AWEA.
generation in 2004a small amount but nearly 20 times more than solar power. So far, wind energy production is geographically concentrated; only five nations account for 82% of the worlds wind energy output (Figure 21.7). California and Texas account for two-thirds of the wind power generated within the United States. Denmark is a leader in wind power; there, a series of wind farms supplies over 20% of the nations electricity needs. Ex-
FIGURE 21.8 More and more wind farms are being developed offshore, because offshore winds tend to be stronger yet less turbulent. Denmark is a world leader in wind power, and much of it comes from offshore turbines. This Danish wind farm is one of several that provide over 20% of the nations electricity.
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growth in the near future. Wind advocates in Iceland are considering developing 240 offshore wind turbines in the nations waters to meet future electricity demand for its hydrogen economy.
Currently, startup costs of wind farms generally are higher than those of fossil-fuel-driven plants, but wind farms incur fewer expenses once they are up and running. Advancing technology is driving down the costs of wind farm construction; as large wind farms become more efficient, the cost of each unit of electricity produced is dropping.
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Wind power density at 10 m height (watts/m2) 4001,000 300400 250300 200250 150200 100150 0100 (a) Annual average wind power
WA (240) OR (263)
MT (2) WY (285)
VT (6) MN (615) WI (53) IA (632) IL (51) MI (2) OH (7) NY (48) PA (129) MA (1)
CA (2096)
CO (229) NM (267)
WV (66) TN (29)
OK (176) TX (1293)
HI (9)
AK (1)
D. L., et al. 1987. Wind energy resource atlas of the United States. Golden, CO: Solar Energy Research Institute; (b) National Renewable Energy Laboratory, U.S. Department of Energy, 2005.
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Wind Prospectors
array of three or four hollow cups set to catch the wind and rotate around a vertical rod. The force of wind on the cups causes them to rotate at a speed proportional to the wind speed; the greater the wind, the faster the cups rotate. Wind direction is measured by a vane that turns on a vertical axis pointing directly into the wind. The cup wheel and wind vane are connected electrically to speed and direction dials, which relay wind data. More than 80 landowners borrowed anemometers from the state in the Idaho programs first year, and sent data to the state every 60 days for review by energy planners and for subsequent posting online. The studies have generated new funding and wind farm plans in the state. In the fall of 2003, one farm near Idaho Falls won a $500,000 federal grant to help build a 1.5-megawatt wind farm that could supply power for approximately 500 homes. In eastern Idaho, five anemometers set up on Shoshone-Bannock tribal lands have revealed good prospects for a commercial wind farm on two Native American reservations. The research effort has shown that the lands are worldclass sites for wind power, according to a state energy official. With average wind speeds in the 29 km/hr (18 mi/hr) range, further study of the tribal lands revealed possible sites for large-scale commercial wind farms, which could mean jobs and revenue for the reservations. Similar wind prospecting programs are now under way on other reservations, as well as in other states, including Utah, Oregon, Virginia, and Missouri.
translate into energy? In Idaho, where resource planners decided that the states power future lies in generating electricity from wind. Now scores of Idahoans, from small farmers to Native American tribes, have joined in the search for gusts with energy potential. By handing out wind-measuring devices to interested landowners, Idaho has turned its citizens into wind prospectors who pinpoint potential areas for wind farms. Idaho first launched the public wind prospecting program in 2001, after joining several other northwestern states in a regional research effort. People who join the program must collect data on wind speed and direction, share that data with the state, and agree to make it public. A promising wind farm site requires some infrastructure, such as roads for erecting wind turbines and transmission lines for sending out power the turbines generate. But the single most important factor is the speed and frequency of the wind. Effective commercial wind farms have a steady flow of wind just above ground level, with regular gusts of at least 21 km/hr (13 mi/hr) at a height of about 50 m (164 ft). Determining whether a site merits further study starts with analyzing existing data. In many parts of the developed world, decades worth of weather information have been compiled into computerized wind maps that indicate general wind conditions. In Idaho, energy planners provide prospectors with starter maps that divide the state into seven wind classes and reveal
To determine where to build wind farms, Idahos wind prospectors use anemometers, which collect and relay wind data. Cup wheels rotate to indicate wind speed, and a vane turns on a vertical axis to reveal wind direction.
which general areas might have enough wind to make a wind farm worthwhile. Areas listed as Class 3 or higher, with wind speeds of about 23 km (14.3 mi) per hour at 50 m (164 ft) above ground, offer the best possibilities. Such maps, however, may not provide enough detail about a specific location. A piece of property, for example, may sit in a Class 3 area but be sheltered by a small hill that blocks the wind. Knowing that kind of detail requires site-specific on-the-ground research. To make such research possible, Idaho loans landowners in areas listed as Class 3 or higher devices called anemometers (see the figure), which measure wind speed and direction. The Idaho program uses a common cup anemometer, with an
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area residents, even though many of these residents like to think of themselves as environmentalists. Wind turbines are also known to pose a threat to birds and bats, which can be killed when they fly into the rotating blades. At Californias Altamont Pass wind farm, which is located in a region with one of the densest populations of golden eagles in the country, turbines killed many eagles and other raptors during the 1990s. Studies since then at other sites have suggested that bird deaths may be a less severe problem than was initially feared. It has been estimated that roughly one to two birds are killed per turbine per yearfar fewer than the millions already being killed annually by television, radio, and cell phone towers, tall buildings, automobiles, domestic cats, pesticides, and other human causes. Bat mortality may be higher, but more research is needed. The key for protecting birds and bats seems to be selecting sites that are not on flyways or in the midst of prime habitat for species that are likely to fly into the blades.
of volcanic activity along the spreading boundary of two tectonic plates. Because of the geothermal heat in this region, volcanoes and geysers are numerous in Iceland. In fact, the word geyser originated from the Icelandic Geysir, the name for the islands largest geyser, which recently resumed its periodic eruptions after many years in dormancy. Geothermal power plants use the energy of naturally heated water to generate power. Rising underground water and steam are harnessed to turn turbines and create electricity. Geothermal energy is renewable in principle (its use does not affect the amount of heat produced in Earths interior), but the power plants we build to use this energy may not all be capable of operating indefinitely. If a geothermal plant uses heated water at a rate faster than the rate at which groundwater is recharged, the plant will eventually run out of water. This is occurring at The Geysers, in Napa Valley, California, where the first generator was built in 1960. In response, operators have begun injecting municipal wastewater into the ground to replenish the supply. More and more geothermal power plants throughout the world are now injecting water, after it is used, back into aquifers to help maintain pressure and thereby sustain the resource. A second reason geothermal energy may not always be renewable is that patterns of geothermal activity in Earths crust shift naturally over time, so an area that produces hot groundwater now may not always do so.
Geothermal Energy
Geothermal energy is one form of renewable energy that does not originate from the sun. Instead, it is generated from deep within Earth. The radioactive decay of elements amid the extremely high pressures deep in the interior of our planet generates heat that rises to the surface through magma (molten rock, p. 206) and through fissures and cracks. Where this energy heats groundwater, natural spurts of heated water and steam are sent up from below. Terrestrial geysers and submarine hydrothermal vents ( pp. 106107) are the surface manifestations of these processes. Iceland is built from magma that extruded above the oceans surface and cooledmagma from the Mid-Atlantic Ridge ( pp. 209, 471472), the area
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2 Where natural
fissures or cracks appear, heated water or steam surfaces in geysers or hot springs Geyser Fault
Cooling tower
Recharge area
Steam
1 Magma heats
groundwater
Injection well
FIGURE 21.10 With geothermal energy (a) magma heats groundwater deep in the earth (1), some of which is let off naturally through surface vents such as geysers (2). Geothermal facilities tap into heated water below ground and channel steam through turbines in buildings to generate electricity (3). After being used, the steam is often condensed and pumped back into the aquifer to maintain pressure (4). At Nesjavellir geothermal power station in Iceland (b), steam is piped from four wells to a condenser at the plant where cold water pumped from lakeshore wells 6 km (3.7 mi) away is heated. The water, heated to 83 C (181 F), is sent through an insulated 270-km (170-mi) pipeline to Reykjavik and environs, where residents use it for washing and space heating.
natural gas. Such direct use of naturally heated water is cheap and efficient, but it is feasible only in areas such as Iceland or parts of Oregon, where geothermal energy sources are available and near where the heat must be transported. Thermal energy from water or solid earth can also be used to drive a heat pump to provide energy. Geothermal ground source heat pumps (GSHPs) use thermal energy from near-surface sources of earth and water rather than the deep geothermal heat for which utilities drill. Roughly half a million GSHPs are already used to heat U.S. residences. Compared to conventional electric heating and cooling systems, GSHPs heat spaces 5070%
more efficiently, cool them 2040% more efficiently, can reduce electricity use by 25%60%, and can reduce emissions by up to 72%. These pumps work because soil does not vary in temperature from season to season as much as air does. The pumps heat buildings in the winter by transferring heat from the ground into buildings; they cool buildings in the summer by transferring heat from buildings into the ground. Both types of heat transfer are accomplished by a single network of underground plastic pipes that circulate water. Because heat is simply moved from place to place rather than being produced using outside energy inputs, heat pumps can be highly energy-efficient.
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Basin Barrage
Ocean
Turbine
Basin Barrage
Basin Barrage
Ocean
Turbine
Basin Barrage
3 Tide recedes;
water level in basin remains high
FIGURE 21.11 Energy can be extracted from the movement of the tides at coastal sites where tidal flux is great enough. One way of doing so is involves using bulb turbines in concert with the outgoing tide. At high tide, ocean water is let through the sluice gates, filling an interior basin. At low tide, the basin water is let out into the ocean, spinning turbines to generate electricity.
waves to push air into and out of chambers, turning turbines to generate electricity (Figure 21.12). No commercial wave energy facilities are operating yet, but some have been deployed as demonstration projects in several western European nations.
has been most fully developed. Each day the tropical oceans absorb an amount of solar radiation equivalent to the heat content of 250 billion barrels of oilenough to provide 20,000 times the electricity used daily in the United States. The oceans sun-warmed surface is higher in temperature than its deep water, and OTEC approaches are based on this gradient in temperature. In the closed cycle approach, warm surface water is piped into a facility to evaporate chemicals, such as ammonia, that boil at low temperatures. These evaporated gases spin turbines to generate electricity. Cold water piped in from ocean depths then condenses the gases so they can be reused. In the open cycle approach, the warm
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Column of air
Incoming waves
FIGURE 21.12 Coastal facilities can make use of energy from the motion of ocean waves. As waves are let into and out of a tightly sealed chamber, the air inside is compressed and decompressed, creating air flow that rotates turbines to generate electricity.
water level within the chamber compresses and decompresses the column of air above it
surface water is evaporated in a vacuum, and its steam turns the turbines and then is condensed by the cold water. Because the ocean water loses its salts as it evaporates, water can be recovered, condensed, and sold as desalinized freshwater for drinking or agriculture. Research on OTEC systems has been conducted in Hawaii and other locations, but costs remain high, and as of yet no facility is commercially operational.
Hydrogen
All the renewable energy sources we have discussed can be used to generate electricity more cleanly than can fossil fuels. As useful as electricity is to us, however, it cannot be stored easily in large quantities for use when and where it is needed. This is why vehicles rely on fossil fuels for power. The development of fuel cells and hydrogen fuel show promise to store energy conveniently and in considerable quantities and to produce electricity at least as cleanly and efficiently as renewable energy sources. In the hydrogen economy that Icelands leaders and many energy experts worldwide envision, hydrogen fuel, together with electricity, will serve as the basis for a clean, safe, and efficient energy system. This system will use as a fuel the universes simplest and most abundant element. In this system, electricity generated from renewable sources that are intermittent, such as wind or solar energy, can be used to produce hydrogen. Fuel cells can then employ hydrogen to produce electrical energy as needed to power vehicles, computers, cell phones, home heating, and countless other applications. Fuel cell technology has been used since the 1960s in NASAs space flight programs. Basing an energy system on hydrogen could alleviate dependence on foreign fuels and help fight climate change. For these reasons, governments are funding research into hydrogen and fuel cell technology, and automobile companies are investing in research and development to produce vehicles that run on hydrogen.
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for new ways to generate energy, some are looking past wind farms and solar panels to an unlikely power sourcepond scum. Algae are being studied as an innovative way to generate large amounts of hydrogen to move society toward a more sustainable energy future. Hydrogens benefits hinge on how hydrogen fuel is produced. Some methods release substantial amounts of carbon dioxide, and other, nonpolluting, processes can be costly. These drawbacks have kept scientists searching for new hydrogen sources. At the University of California at Berkeley, plant biologist Anastasios Melis thought one possible hydrogen source might be a single-celled aquatic plant known to be a capable, if sporadic, hydrogen producer. The alga Chlamydomonas reinhardtii was
Could green algae such as this provide hydrogen for our energy needs?
known to emit small amounts of hydrogen for brief periods of time when deprived of light. Melis hypothesized that the alga might be encouraged to produce hydrogen in large amounts. He set
Electrolysis produces pure hydrogen, and it does so without emitting the carbon- or nitrogen-based pollutants of
fossil fuel combustion. However, whether this strategy for producing hydrogen will cause pollution over its entire life cycle depends on the source of the electricity used for the electrolysis. If coal is burned to create the electricity, then the entire process will not reduce emissions compared with reliance on fossil fuels. If, however, the electricity is produced by some less-polluting renewable source, then hydrogen production by electrolysis would create much less pollution and greenhouse warming than reliance on fossil fuels. The cleanliness of a future hydrogen economy in Iceland or anywhere else would, therefore, depend largely on the source of electricity used in electrolysis. The environmental impact of hydrogen production will also depend on the source material for the hydrogen. Besides water, hydrogen can be obtained from biomass and fossil fuels. Obtaining hydrogen from these sources generally requires less energy input, but results in emissions
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Hydrogenase is normally active only after Chlamydomonas reinhardtii has been deprived of light. When the alga is deprived of light, the light-dependent reactions of photosynthesis ebb, little oxygen is produced, and hydrogenase is activated. When light returns and the alga begins producing oxygen again, hydrogenase is promptly deactivated, and its associated hydrogen release stops. Meliss team wanted to activate hydrogenase so that more hydrogen would be produced. But simply keeping the algae in the dark would not escalate hydrogen production because the algas metabolic functions slowed without light, resulting in small amounts of released hydrogen. The researchers decided to try limiting the algas oxygen output another way, by putting it on a sulfur-free, bright-light regimen. The lack of sulfur would hinder
photosynthesis, limiting oxygen output enough to activate hydrogenase and trigger hydrogen production. The presence of light would keep the algae metabolically active and releasing large amounts of byproducts. The researchers cultured large quantities of the algae in bottles in labs. Then they deprived the cultures of sulfur but kept the algae exposed to light for long periods of timein some cases up to 150 hours. After the sustained light exposure, gas and liquids were extracted from the bottles and analyzed. The analysis supported the teams hypothesis. Without sulfur or photosynthesis, the algae were not producing oxygen. This low-oxygen, or anaerobic, environment had induced hydrogenase, which spurred the algae to begin splitting water molecules and releasing gas. The plants had released amounts of
hydrogen that were substantial relative to the size of the algal cultures. Hydrogen also dominated the algas emissionsin gas collection analysis, approximately 87% of the gas was hydrogen, 1% was carbon dioxide, and the remaining 12% was nitrogen with traces of oxygen. The research teams published their findings in the journal Plant Physiology in 2000. Many questions remain about algae-derived hydrogen, particularly how much fuel can be harvested continuously using this photobiological process. Nevertheless, the research results so far are helping to fuel the momentum of a future hydrogen economy. Within 30 years, some federal energy experts predict that photobiological methods for generating hydrogen could be commonplace meaning cars on future freeways might just be powered by pond scum.
of carbon-based pollutants. For instance, extracting hydrogen from the methane (CH4) in natural gas entails producing one molecule of the greenhouse gas carbon dioxide for every four molecules of hydrogen gas:
CH4 + 2H2O 4H2 + CO2
Weighing
the Issues:
Thus, whether a hydrogen-based energy system is environmentally cleaner than a fossil fuel system depends on how the hydrogen is extracted. In addition, some new research suggests that leakage of hydrogen from the production, transport, and use of the gas at Earths surface could potentially deplete stratospheric ozone and lengthen the atmospheric lifetime of the greenhouse gas methane. Research into these questions is ongoing, because scientists do not want society to switch from fossil fuels to hydrogen without first knowing the possible risks from hydrogen.
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Hydrogen (fuel)
H2
H 2O
1 In the negative
electrode, hydrogen is stripped of its electrons, leaving hydrogen ions (protons, H+) Negative electrode
H+ H+
3 Meanwhile,
the protons traverse the membrane
4 In the positive electrode, water is formed when Oxygen oxygen combines with the protons and electrons that flow from the negative electrode
Positive electrode
FIGURE 21.13 Hydrogen fuel drives electricity generation in a fuel cell, creating water as a waste product. Atoms of hydrogen are first stripped of their electrons (1). The electrons move from a negative electrode to a positive one, creating a current and generating electricity (2). Meanwhile, the hydrogen ions pass through a proton exchange membrane (3) and combine with oxygen to form water molecules (4).
2 The electrons
move from the negative electrode to the positive electrode, creating a current and generating electricity
gens electrons from one electrode to the other creates the output of electricity.
The way this occurs within one common type of fuel cell is shown in Figure 21.13. Hydrogen gas (usually compressed and stored in an attached fuel tank) is allowed into one side of the cell, whose middle consists of two electrodes that sandwich a membrane that only protons (hydrogen ions) can move across. One electrode, helped by a chemical catalyst, strips the hydrogen gas of its electrons, creating two hydrogen ions that begin moving across the membrane. Meanwhile, on the other side of the cell, oxygen molecules from the open air are split into their component atoms along the other electrode. These oxygen ions soon bind to pairs of hydrogen ions traveling across the membrane, forming molecules of water that are expelled as waste, along with heat. While this is occurring, the electrons from the hydrogen atoms have traveled to a device that completes an electric current between the two electrodes. The movement of the hydro-
C H A P T E R T W E N T Y- O N E
VIEWPOINTS
Is establishing a hydrogen economy, as Iceland is trying to do, the best way to reduce the use of fossil fuels?
Abundant, reliable, and affordable energy is an essential component of a healthy economy. Because hydrogen can be produced from a wide variety of domestically available resources and can be used in heat, power, and fuel applications, it is uniquely positioned to contribute to our growing energy demands, particularly for resourceconstrained communities. However, if we are to realize the true benefits of a hydrogen economy, other renewables must play a substantial role in the efficient and affordable production of the hydrogen. Several renewable options could make a substantial impact in the production of hydrogen: electrolysis powered by wind, photovoltaic, solar-thermal electric, hydropower, and geothermal energy; use of microorganisms and semiconductors to split water; and the thermal and biological conversion of biomass and wastes. Researchers around the globe are working on improving these renewable technologies. As a result, costs continue to drop. Technologies for renewable hydrogen production, coupled with advances in hydrogen production equipment (e.g., electrolyzers) can supply cost-competitive hydrogen and will ultimately play a substantial role in our energy supply. In addition to the potential supply of affordable hydrogen, these technologies also offer a wide variety of opportunities for developing new centers of economic growth. Most investments in renewable energy are spent on materials and workmanship to build and maintain the facilities, rather than on costly energy imports. Therefore, funds are usually spent regionally and even locally, leading to new jobs and investments in local economies. Because of this synergistic relationship, the shift toward a hydrogen economy will naturally facilitate the advancement of renewable energy. By diversifying our energy supply, we will not only reduce our dependence on imported fuels, but also will benefit from cleaner technologies and investment in our communities.
Susan Hock directs the Electric and Hydrogen Technologies and Systems Center of the National Renewable Energy Daryl Prigmore has studied energy and the environment since Laboratory. The center conducts research activities in four the late 1960s. After receiving bachelor and master of science areas: distributed power systems integration, hydrogen degrees in mechanical engineering from Colorado State technologies and systems, geographic University, he spent 10 years in industry with a information system analysis, and solar company developing solar, geothermal, and lowExplore this issue measurements and instrumentation. pollution automotive power systems. He has
further by accessing Viewpoints at www.aw-bc.com/withgott.
Well never use the last drop of oil, the last chunk of coal, the last cubic foot of natural gas, or the last pound of uranium. Eventually though, these fossil and nuclear fuels will become too expensive to extract, or politics will make one or more of them unavailable, leaving us to ask how well satisfy our voracious appetite in the future. We should immediately apply all practical energy conservation strategies. Mother Nature is out there making more fossil fuels as we speak, but we dont have time to wait the few million years that will take. The short list of renewables: solar, wind, hydro, biomass, geothermal, waves, tides, and ocean thermal energy conversion. These are all relatively benign and abundant. An alternative: hydrogen. It can either be burned or electrochemically used in fuel cells to provide useful energy. The by-product or exhaust is water. You start with water, get some energy, and end up with water, making it renewable. Another form of hydrogen energy is fusion, hydrogen atoms fusing to form helium plus a lot of energy, the way the sun does it. The catch? It takes about as much energy to extract hydrogen gas from water (by electrolysis) as you get back from your energy conversion device. Until it becomes cheaper (economically and in physical terms), fossil fuels will continue to rule the energy world. The breakthrough may involve using our renewable energy resources to separate hydrogen from other molecules. Arguably, to reduce our dependence on fossil fuels, the priority list for this country should be: 1. Energy conservation 2. Wind 3. Passive solar 4. Biomass 5. Active solar 6. Hydrogen (chemical) 7. Hydroelectricity 8. Hydrogen (fusion) 9. Others (geothermal, tides, waves, ocean thermal)
taught energy science classes for the past 23 years, 20 at the University of Colorado (Colorado Springs).
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Environmental Issues and the Search for Solutions 5 Air conditioning 4 Cooling 3 Fuel cell
stacks units unit
7 Water
vapor exhaust
supply unit
6 Electric motor
The hydrogen-fueled Citaro buses operating in Reykjavik and other European capitals are designed by Mercedes-Benz and Daimler-Chrysler. Hydrogen is stored in nine fuel tanks (1) The fuel cell supply unit (2) controls the flow of hydrogen, air, and cooling water into the fuel cell stacks (3). Cooling units (4) and the air conditioning unit (5) dissipate waste heat produced by the fuel cells. Electricity generated by the fuel cells is changed from direct current (DC) to alternating current (AC) by an inverter, and it is transmitted to the electric motor (6), which powers the operation of the bus. The vehicles exhaust (7) consists simply of water vapor.
FIGURE 21.14
hydrogen fuel is supplied, without ever needing recharging. For all these reasons, hydrogen fuel cells are being used to power vehicles, including the buses now operating on the streets of Reykjavik and many other European, American, and Asian cities (Figure 21.14).
Conclusion
The coming decline of fossil fuel supplies and the increasing concern over air pollution and global climate change have convinced many people that we will need to shift to renewable energy sources that will not run out and will not pollute. Renewable sources with promise for sustaining our civilization far into the future without greatly degrading our environment include solar energy, wind energy, geothermal energy, and ocean energy sources.
Moreover, by using electricity from renewable sources to produce hydrogen fuel, we may be able to use fuel cells to produce electricity when and where it is needed, helping convert our transportation sector to a nonpolluting, renewable basis. Most renewable energy sources have been held back for a variety of reasons, including little funding for research and development, and artificially cheap market prices for nonrenewable resources that do not include external costs. Despite this, renewable technologies have progressed far enough to offer hope that we can shift from fossil fuels to renewable energy with a minimum of economic and social disruption. Whether we can also limit environmental impact will depend on how soon and how quickly we make the transition and to what extent we put efficiency and conservation measures into place.
C H A P T E R T W E N T Y- O N E
REVIEWING OBJECTIVES
You should now be able to:
Outline the major sources of renewable energy and assess their potential for growth
The new renewable energy sources include solar, wind, geothermal, and ocean energy sources. They are not truly new, but rather are in a stage of rapid development. (pp. 621622) The new renewables currently provide far less energy and electricity than the conventional renewables, hydropower and biomass energyand only a small fraction of the energy and electricity we obtain from fossil fuels. (pp. 621622) Use of new renewables is growing quickly, and this growth is expected to continue as people seek to move away from fossil fuels. (pp. 622623)
Describe geothermal energy and the ways it is harnessed, and evaluate its advantages and disadvantages
Energy from radioactive decay in Earths core rises toward the surface and heats groundwater. Energy from this heated water and steam is harnessed at the surface or by drilling at geothermal power plants. (pp. 633634) Use of geothermal energy for direct heating of water, as well as for electricity generation, can be efficient, clean, and renewable. (pp. 633635) Geothermal sources occur only in certain areas and may become exhausted if too much water is pumped out without being replenished. (p. 635)
Describe solar energy and the ways it is harnessed, and evaluate its advantages and disadvantages
Energy from the suns radiation can be harnessed using passive methods or by active methods involving powered technology. (pp. 623624) Major solar technologies include solar panels, mirrors to concentrate solar rays, and photovoltaic cells. (pp. 624626) Solar energy is perpetually renewable, and solar technology creates no emissions and allows for decentralized power. (p. 626) Solar radiation varies in intensity from place to place and time to time, and harnessing solar energy remains expensive. (p. 627)
Describe ocean energy sources and the ways they can be harnessed, and evaluate their advantages and disadvantages
Major ocean energy sources include the motion of tides and waves and the thermal heat of ocean water. (pp. 635637) Tidal and wave energy is perpetually renewable and holds much promise, but so far technologies have seen only limited development. (pp. 635637)
Explain hydrogen fuel cells and assess future options for energy storage and transportation
Hydrogen can serve as a fuel to store and transport energy, so that electricity generated by renewable sources can be made portable and used to power vehicles. (p. 637) Hydrogen can be produced through electrolysis, but it may also be produced by using fossil fuelsin which case its environmental benefits are greatly reduced. (pp. 638639) There is some concern that releasing excess hydrogen could have negative impacts on the atmosphere. (p. 639) Fuel cells create electricity by controlling an interaction between hydrogen and oxygen, and they produce only water as a waste product. (pp. 640, 642) Hydrogen can be clean, safe, and efficient. Fuel cells are silent, are nonpolluting, and do not need recharging. (pp. 640, 642)
Describe wind energy and the ways it is harnessed, and evaluate its advantages and disadvantages
Energy from wind is harnessed using wind turbines mounted on towers. (pp. 627628) Turbines are often erected in arrays at wind farms located on land or offshore. Wind farms are developed in locations with optimal wind conditions. (pp. 628632) Wind energy is renewable, turbine operation creates no emissions, wind farms can generate economic benefits, and the cost of wind power is nearly competitive with that of electricity generated from fossil fuels. (p. 630) Wind is an intermittent resource and occurs at adequate strengths only in some locations. Turbines kill some birds and bats, and wind farms can face opposition from local residents. (pp. 630633)
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SEEKING SOLUTIONS
1. Why might a hydrogen economy be closer than we think? Why might it instead not come to pass? Do you think water could be the coal of the future? Why or why not? 2. For each source of renewable energy discussed in this chapter, what factors are standing in the way of an expedient transition from fossil fuel use? 3. Explain how the use of new renewable energy sources can reduce fossil fuel emissions. 4. Do you think development and implementation of renewable energy resources to replace fossil fuels can be moved forward without great social, economic, and environmental disruption? What steps would need to be taken? Will market forces alone suffice to bring about this transition? Do you think such a shift will be good for the economy? 5. Iceland is giving itself many years to phase in its planned hydrogen economy. Do you think the United States could transition to a hydrogen economy more quickly, less quickly, or not at all? Why? What steps could the United States take to accelerate such a transition? 6. Imagine you are the CEO of a company that develops wind farms. Your staff is presenting you with three options, listed below, for sites for your next development. Describe at least one likely advantage and at least one likely disadvantage you would expect to encounter with each option. What further information would you like to know before deciding on which to pursue? Option A. A remote rural site in North Dakota Option B. A ridge-top site among the suburbs of Philadelphia Option C. An offshore site off the Florida coast
C H A P T E R T W E N T Y- O N E
0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month
Average per capita residential use of electricity in the United States in 2004 (red line) and average influx of solar radiation per square meter for Topeka, Kansas (blue line). The dashed lines represent the yearly average values for each. Data from Renewable
Resource Data Center, National Renewable Energy Laboratory, U.S. Department of Energy (DOE); and Energy Information Administration. 2005. Annual energy review 2004. DOE.
1. Given a 10% efficiency for photovoltaic conversion of solar energy, approximately how many square meters of photovoltaic cells would be needed to supply one persons residential electrical needs for a year, based on the yearly average values? How many square meters would be needed if efficiency were improved to 40%? 2. Given the same 10% conversion efficiency, approximately how many square meters of photovoltaic cells would be required to supply one persons residential electrical needs during the month of April? During July? How many square meters would be required to supply the average U.S. household of four people for each of those months? 3. Commercially available photovoltaic systems of this capacity cost approximately $20,000. The average cost of electricity in the United States is approximately 9 per kilowatt-hour. At these prices, how long would it take for the PV system to generate $20,000 worth of electricity? Calculate a combination of PV system cost and electricity cost at which the system would pay for itself in 10 years.
1. What additional information do you need in order to increase the accuracy of your estimates for the areas in the table above? 2. Considering the distribution of solar radiation in the United States, where do you think it will be most feasible to greatly increase the percentage of electricity generated from photovoltaic solar cells? 3. The purchase price of a photovoltaic system is considerable. What other costs and benefits should you consider, in addition to the purchase price, when contemplating going solar?
Take It Further
Go to www.aw-bc.com/withgott or the student CD-ROM where youll find: Suggested answers to end-of-chapter questions Quizzes, animations, and flashcards to help you study Research Navigator database of credible and reliable sources to assist you with your research projects graphs
tutorials to help you master how to interpret current news articles that link the topics that you study to case studies from your region to around the world