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Wave Nature of Electron

As a young student at the University of Paris, Louis DeBroglie had been
impacted by relativity and the photoelectric effect, both of which had been
introduced in his lifetime. The photoelectric effect pointed to the particle
properties of light, which had been considered to be a wave phenomenon. He
wondered if electons and other "particles" might exhibit wave properties. The
application of these two new ideas to light pointed to an interesting possibility:

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Confirmation of the DeBroglie hypothesis came in the Davisson-

Germer experiment.

Examples of electron waves

deBroglie wavelength

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Examples of Electron Waves

Two specific examples supporting the wave nature of electrons as suggested in
the DeBroglie hypothesis are the discrete atomic energy levels and the
diffraction of electrons from crystal planes in solid materials.

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Click on either example for further details.

The wave nature of the electron must be invoked to explain the behavior of
electrons when they are confined to dimensions on the order of the size of an
atom. This wave nature is used for the quantum mechanical "particle in a box"
and the result of this calculation is used to describe the density of energy states
for electrons in solids.
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DeBroglie Hypothesis
Suggested by De Broglie in about 1923, the path to the wavelength expression
for a particle is by analogy to the momentum of a photon. Starting with the
Einstein formula:

Another way of expressing this is

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Therefore, for a particle of zero rest mass

For a photon:

The momentum-wavelength relationship for a photon can

then be derived and this DeBroglie wavelength relationship
applies to other particles as well.

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Electron wavelength Baseball wavelength? Photon momentum

Calculation of DeBroglie wavelength
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DeBroglie Wavelengths

The Davisson-Germer experiment

showed that electrons exhibit the
DeBroglie wavelength given by:

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Calculation
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DeBroglie Wavelengths

The Davisson-Germer experiment

showed that electrons exhibit the

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DeBroglie wavelength given by:

The wavelength associated with a particle can be calculated from:

wavelength = h/(mass x velocity)

For a particle of mass x10^ kg = =

traveling at velocity x10^ m/s

the associated DeBroglie wavelength is x10^ m=
m= nm.
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You may enter values in any of the boxes. When you have finished entering
data, click on the quantity you wish to calculate in the formula above.
Wavelength values will be reconciled, but no further calculation will be done
until you select which item you wish to calculate. Caution! This calculation is
non-relativistic and accurate only for speeds much less than the speed of light.
For speeds over a tenth of the speed of light a relativistic calculation should be
used.

If you explore the wavelength values for ordinary macroscopic

objects like baseballs, you will find that their DeBroglie
wavelengths are ridiculously small. Comparison of the power of
ten for the wavelength will show what the wavelengths of ordinary
objects are much smaller than a nucleus. The implication is that for
ordinary objects, you will never see any evidence of their wave
nature, and they can be considered to be particles for all practical
purposes.

Alternate calculation of DeBroglie wavelength in terms of

particle energy
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