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PEPERIKSAANPERCUBAANSETARASTPM
NEGERI SEMBILAN DARUL KHUSUS
TAHUN2011

t1J&
DO NOT OPEN THIS BOOKLET UNTIL YOU ARE TOLD TO DO SO
Instructions to candidates:
There are fifty questions in this paper. For each question, four suggested answers are
given. Choose one correct answer and indicate it on the multi-choice answer sheet
provided
Read the instructions on the multiple-choice answer sheet ve1y carefully.
Answer all questions. Marks will not be deducted for wrong answers.
This question paper consists of 17 printed pages and 1 blank page,
Jabatan Pelajaran Negeri Sembilan 2011
Percnbaan STPM 96211 [ Lihat sebelah
*This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL*
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Section A
Four suggested answers labelled A, B, C, and D are given for each question. Choose one correct
answer.
t Chlorofluorocarbons, CFC, are responsible for the destruction of.ozone in.the stratosphere.
In the stratosphere, theCFCmolecules are fragmented by ultraviolet radiation to produce
chlorine free radicals, Cl . What is.i:he composition of a
35
Cl free radical?
A
B
c
D
Number of proton
35
17
17
17
Number of electron Number of neutron
35 35
17 18
18 18
17 35
2. Which of the following species will be deflected most in a mass spectrometer?
A J6y+
B J6y2+
c J8y>
D J8y2+
3. X andY are two elements in the Periodic Table. The proton number of X is 28, and Y
2
+ ion
is isoelectronic with X. Which of the following electronic configurations is correct?
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A
B
c
D
Element/ ion
X
y
--
y2'
y2+
Electronic configuration
ls
2
2s
2
2p
6
3s
2
3p
6
3d
10
4s
2
ls
2
2s
2
2p
6
3s
2
3p
6
3d
8
4s
2
ls
2
2s
2
2p
6
3s
2
3p
6
3d
8
4s
2
ls
2
2s
2
2p
6
3s
2
3p
6
3d
10
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3
4. The diagram below shows the lines in the visible region of the electromagnetic spectrum of
the hydrogen atom.
II I I
400
J
500
Wave length/nm
600 700
Which of the following electronic transitions between energy levels produces the line J?
A D2 __,_ DJ
B 113--+ 11]
c n3 --+ n2
D 114--+ 112
5. Which ofthe following sets of physical properties is that of a transition element?
A
B
c
D
Melting point/ C
3'27
650
1539
1410
'--- -
Boiling point
1
C
0
1750
1150
2800
2500
Density/ gcm
3
Ability to conduct
electricity
11.3 Good
1.7 Good
7.9 Good
2.3 Weak
6. Which of the following sets of elements has the same type of bonding and 1s
arranged in ascending order of melting points?
A Cl, S, P
B Ge, C,B
C Cs, Rb, K
D Be, Mg, Ca
7. Which ofthe following species has a bond angle of 109.5?
A NH/
B SF4
C XeF4
D ICl4.
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8. The following reaction is ftrst order with respect to [P] and zero order with respect
to [Q].
P + Q -7 products
If the rate constant doubles for each 10 'C rise in temperature, which of the
following sets of conditions will give the greatest rate of reaction? .
A
B
c
D
...... T'
[P]/ moldm
0.1
0.1
0.3
0.3
[Q]/ moldm
3
0.2
0.3
0.1
0.1
Temperature/ 'C
40
30
20
30
9. The reaction of acidified aqueous potassium iodide with hydrogen peroxide is given
by the following equation :-
2r(aq) + H
2
02(aq) + 2H+(aq) -7 b(aq) + 2H
2
0(l)
The reaction mechanism is thought to involve the following steps:
H
2
0
2
+ r -7 H
2
0 +or (slow)
or+ H+ -7 HOI (fast)
HOI+ H+ + r -7 1
2
+ H
2
0 (fast)
Which one of the following conclusions cannot be drawn from this information?
A The acid acts as a catalyst.
B The iodide ion is oxidized by the hydrogen peroxide.
C The rate equation for the reaction is; rate= k[H
2
0
2
] [ I"]
D The reaction is first order with respect to the iodide ion.
10. The equilibrium constant, Kp for the reaction:
PCls(g) ~ PCh(g) + Clz(g)
is 3.81 x 10
2
at 600 K and 2.69 x 10
3
at 700 K. Which of the following statements could be
wrong?
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A K, = Kp(RT).
B The reaction is endothermic.
C The proportion of PCh in the equilibrium mixture increases with decreasing pressure.
D The equilibrium amount of reactants and products are not affected by addition of a
catalyst.
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5
11. The F-F bond in F
2
molecule is relatively weak because the lone pairs of electrons onone F.
atom repel the lone pair on the other F atom; Kp = 7.83 atm at 1500 K for the reaction ..
)fthe equilibri_umpartial pressure of F
2
molecules at 1500 K is 0.200 atm, what percentage .
of the F
2
molecules is dissociated at 1500 K?
A 75.8%
B 79.7%
c 86.2%
D 88.7%
12. The following reaction equations may be Arrhenius, Bronsted-Lowry, and/or Lewis acid-
base reactions. Which of the following reactions is a Bronsted-Lowry and a Lewis acid-
base reaction?
A A!Ch + Cl' -7 AICI4.
B Ag+ + 2NHJ -7 Ag(NH3)2+
C H,S04 + NH3 -7 HS04. + NH/
D Al(OH)J + 3HNOJ -7 Atl+ + 3H,O + 3No3
13. A saturated solution ofMg(OHh in water at room temperature has pH= 10.35. Calculate
the solubility product, K,p for Mg(OH)
2
at room temperature.
[Ionic product of water at 25 C, Kw = 1.0 x 10'
14
mo1
2
dm-
6
]
A 1.12xl0
11
B 4.49 X 10'
11
C 5.61 X 10'
12
D 2.84 X 10 '
13
14. Calculate the concentrations ofNH/ and NH
3
and the pH of a solution prepared by mixing
20.0 g of NaOH and 500 cm
3
of 1.5 mol dm
3
NH
4
CL Assume that the volume remains
constant.
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[Base dissociation constant ofNH
3
, Kb = 1.8 x I o
5
mol dm-
3
; relative atomic masses: Na =
23, 0 = 16, H = 1.)
A
B
c
D
[NH/]
0.50
0.75
1.0
0.50
[NH
3
] pH
1.0 9.56
0.50 ll.5
1.0 9.26
0.50 9.26
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15. In a steam distillation experiment to obtain diphenylamine, C
12
H
11
N, the total vapour
pressure reaches 101.0 kPa at 99.4 C. At this temperature the vapour pressure of water is
99.2 kPa. Calculate the minimum mass of steam required to obtain 100 g of
diphenylamine. [Relative atomic masses: C = 12, H = 1, N = 14.]
A ;587 g
B 666 g
c 678 g
D 866 g
16. Separate samples of three amino acids, X, Y and Z, were spotted on the base line of a thin
layer chromatography sheet. The chromatogram produced using a particular mobile phase
is shown below. The Rr values of known amino acids are given in a separate table as
shown below.
Solvent front
Origin L======:.J
6
0
Amino acid
Alanine
Arganine
Isoleucine
Proline
Taurine
Valine
Which of the following sets below correspond to X, Y and Z?
X
y
z
A Isoleucine Alanine Valine
B Proline Taurine Arganine
c Isoleucine Taurine Alanine
D Proline Taurine Arganine
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Rr value
0.56
0.61
0.82
0.89
0.34
0.75
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17. The table below shows the standard electrode potentials for several half-cell reactions
Half-cell reaction E
8
IV
Half-cell reaction
E
8
/V ...
. ..
Ba-+
+ Ba -2.90
CrJ+ + Cr
. ..
c 0.74
co-++ 2e - 0.28
Pb0
2
+ H' + Pb_+ +2H,O - +1A7
.
CoJ++e

+ 1.82
...
------ - -""--
Which of the following redox reactions will give the highest value of e.m.f?
A Co
2
+ + Ba Co + Ba
2
+
B 2Cr
3
+ + 3Ba 2Cr + 3Ba
2
+
C 2Co
3
+ + Ba Ba
2
+ + 2Co
2
+
D 2Co
3
+ + Pb
2
+ + 2H
2
0 2Co
2
+ + Pb0
2
+ 4H+
18. In the electrolysis of dilute sulphuric acid, calculate the quantity of electricity in Faradays
that will be required to produce 112 cm
3
of gas at the anode measured at s.t.p?
[I mole of gas at s.t.p occupies 22.4 dm
3
]
A F/200
B F/100
C F/50
D F/25
19. Which of the following reaction equations involves the enthalpy change of formation?
A 2H(g) + '/, 02(g) H20(g)
B CO(g) + y, 02(g) C02(g)
C 2N(g) + 3H
2
(g) 2NH
3
(g)
D 2C(s) + 3H2(g) C2H6(g)
20. Which of the following variation in properties is caused by the increase in the atomic or
ionic size of the Group 2 elements when going down the group?
A the decreasing basicity of the oxides
B the increasing solubility of the sulphates
C the decreasing thermal stability of the carbonates
D the increasing reactivity of the elements towards water
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21. Which of the following is not true of aluminium chloride?
A Anhydrous aluminium chloride can act as a Lewis acid.
B In the vapour state, aluminium chloride consists of the Al
3
+ and cr ions ..
C At room conditions, aluminium chloride exists in the dim eric form, AbCl
6
D Aluminium chloride can be prepared by the reaction of aluminium with hydrogen
chloride gas,
22. Which of the following best explains why silicon tetrachloride and not carbon tetrachloride
is hydrolysed by water?
A The C-Cl bond is stronger than the Si-Cl bond.
B The silicon atom is bigger than the carbon atom.
C Carbon can undergo catenation whereas silicon cannot
D Silicon can use available d orbitals to expand its valency, whereas carbon cannot
Lead (IV) chloride decomposes to lead(Il) chloride when warmed. What can be deduced
from this information alone?
A Lead is a metaL
B Lead (IV) chloride is readily hydrolysed by cold water.
C Lead (IV) chloride is covalent whereas lead(Il) chloride is ionic.
D The +2 oxidation state oflead is more stable than the +4 oxidation state.
24. The method used in the industrial preparation of nitrogen gas is
A decomposition of ammonia in air
B Fractional distillation of liquefied air
C thermal decomposition of ammonium nitrate
D thermal decomposition of ammonium chromate
25. Which of the following properties increases when going down Group 17?
A the oxidising ability ofthe halogen
B the electronegativity of the halogen
C the lattice energy of the sodium halide
D the strength of the halide ion as a reducing agent
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26. Which of the following statements about the complex [Co(H
2
NCH
2
CH
2
NH
2
)3]
3
+ is not .
correct?
A the complex has an octahedral shape.
B the ligand in the complex is bidentate.
C the oxidation state of cobalt in the complex is +3.
D the coordination number of cobalt in the complex is 3.
27. Consider the species in the following equation:-
Which of the following statements is not correct?
[Proton Number ofTi = 22]
A water acts as a Lewis base.
B the complex ions are octahedral in shape.
C the [Ti(H
2
0)
6
]
3
+ ion can act as a Bronsted-Lowry acid.
D the electronic configurations of the titanium ion is !s
2
2s
2
2p
6
3s
2
3p
6
4s
1
28. How many stereo isomers does compound X have?
/OH
@-cH=CHCH(OH)CHl
X
A 0 B 2 c 4
29. Acetaminophene is a drug used in headache remedies
H CH
3
I I
HO-@-N--C=O acetaminophene
Which of the foilowing statements about acetaminophene is true?
A it is soluble in water
B it reacts with PCI
5
to give dense white fumes
C if forms a yellow precipitate with alkaline iodine solution
D 6
D it can be synthesised from the reaction of I-bN--OH and CH
3
COCI
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30. Consider the four compounds below labelled I, II, Ill and IV.
Cl COOH CH3 Cl
0 0

I I
CHcOH OH OH OH
l ll lil IV
Which of the following answers give the correct sequence of the above compounds in
decreasing order of acidity?
A II, IV, lll and I
B II, Ill, IV, I
C I, Ill, IV, II
D Ill, I, IV, II
31. P, C
3
H
7
N is a liquid that dissolves readily in dilute hydrochloric acid. Q, C
2
H
5
NO is a
solid that gives an alkaline gas when heated with aqueous sodium hydroxide. Which of the
following pairs of compounds could P and Q be?
A
B
c
D
p
CH2=CHNH(CH3)
CH
3
CH=CHNH
2
CH3NHCH=CH2
H' <;:--......_____
I /(:H(NH2)2

Q
CH3CONH2
H2NCH2CHO
CH
3
CH=NOH

HN/
32. Part of the structure of a polymer is shown below:-
Which of the following statements about the above polymer is correct?
A it is resistant to alkaline hydrolysis.
B it is both a polyester and a poly amide
C it reacts with HCN in the presence of a trace of acid
D it can be made from ClCO(CH
2
)
4
COCl and HOCH2(CH
2
)2CH
2
NH
2
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33. The polymer whose repeat unit is shown below occurs in bacteria as cell storage material:- ..
CH3 H 0
I I II
-0-C-C-C-
1 I
H H
This polymer can be formed by the polymerisation of
0
II
A CH
3
CH-C-OH
I
OH
B CH
3
CH=CH-COOH
I
OH
C CH
3
CH--CH
2
-COCl
I
OH
34. A compound R has all the following properties:-
(i) it is neutral
(ii) it gives an orange precipitate with 2,4 dinitrophenylhydrazine
(iii) it forms a yellow precipitate with aqueous iodine in sodium hydroxide solution
Which ofthe following could be R?
A
g
1
CCH1
B
;Q(H
H
3
C COCH
3
c
ifH:OH
D
~ C H 2 0 H
CH2CHO COCH
3
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35. In the reaction scheme below, one of the steps is incorrectly represented. There could .be an
error in specifying the reactants, the products or the reagents used. Which is the incorrectly
represented step'!
LiAIH4
CH
3
CN ~ CH,CH2NH2
H20/I-t J Step 2
CH,C02H
A step I
Step 1
Step 3
B step 2
Step 4
C step 3 D step 4
36. Which of the following compounds can be used to prepare a stable solution of a diazonium
salt at 5C
..<\ CONl-h B NH2

6
C CH
3
D
~ ~ l b
~ N H ,
37. In which of the following pairs of compounds (which have approximately the same
molecular mass) is the first member more volatile than the second?
and
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38. Compound S, C
4
H
8
0
2
is resistant to oxidation. When treated with sodium,one mole of S
liberates 0.5 mol of hydrogen gas. Sis
A CH1CH2 C02CH1
B CI-1JCH2CH2C02H
C CH1CH2COCH20H
D CHJCH(OH)CI-hCHO
39. It has been estimated that every atom of chlorine generated from a chlorofluorocarbon in
the strastophere, one hundred thousand molecules of ozone may be destroyed. Which of
the following statements about the chlorine atoms given below is correct?
A they initiate the formation of oxygen free radicals
B they are regenerated in a chain propagation reaction.
C they remove oxygen formed by the reaction 20
3
~ 30
2
D they achieve high activation energy by absorbing ultra violet light
40. The compound E below reacts with aqueous sodium hydroxide when heated. What type of
reaction does E undergo?
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CI--@--CH2CH2Cl
E
A electrophilic addition
B electrophilic substitution
C free radical substitution
D nucleophilic substitution
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Section B
For each oft he questions in this section one or more oft he three numbered statements 1 to 3
may be correct. Decide whether each oft he statements is or is nor correct. The responses A to D
should be selected on the basis of the following.
A B c D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2, and 3 are
correct. correct. correct.
41. A group of mountain climbers discovered that water boils at a lower temperature at the top
of a mountain. Which statement(s) is/are t r u e ~
At the mountain top, the pressure is low and water will only boil when the vapour
pressure equals the prevailing pressure.
2 At lower temperature, the kinetic energy of molecules is low, thus water boil at lower
temperature.
3 At lower temperature, fewer molecules vaporise and thus boiling point of water
drops
42 The rate equation for the reaction
F2(g) + 2Cl0
2
(g) ~ 2FCl02(g)
at 500C is given by: Rate of reaction= k [F
2
][CI0
2
]
0
Which statement(s) about the rate equation is/are correct?
The overall order of reaction is 1.
2 The rate constant depends on temperature.
3 The unit of the rate constant is mor
1
s
1
43. Several standard redox potential values are given in the table below:
Redox reactions E
8
/ V
Fe-+ (aq) + 2e ;:==:::': Fe(s) -0.44
Fe'+ (aq) + e ;:==:::': Fe-+ (aq) + 0.77
HN0
2
(aq) + H+ (aq) + e ;:==:::': NO(g) + H
2
0(l) + 0.99
Sn
4
+ (aq) + 2e ~ sn-+ (aq)
+ 0.15
Which of the following will oxidise Sn
2
+ ions to Sn
4
+ ions under standard conditions?
1 HN0
2
(aq)
2 Fe
3
+ (aq)
3 Fe
2
+ (aq)
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~ ~
A B c D
I only is correct. 1 and 2 only are 2 and 3 only are 1, 2, and 3 are
correct. correct. correct.
44. Three standard redox potential values are given in the table below:
Redox reactions E
8
IV
co'+ (aq) + e ~ co+ (aq)
+ 1.81
Cr'+ (aq) + e ~ Cr + (aq)
1-041
--
Ti'+ (aq) + e ~ Ti"+ (aq) -0.37
Which of the following redox reaction(s) can occur under standard conditions0
Co
3
+ (aq) + Cr
2
+ (aq) -7 Co
2
+ (aq) + Crh (aq)
2 Cr
3
+ (aq) + Ti"+ (aq) -7 Cr
2
+ (aq) + Ti
3
+ (aq)
3 Ti
3
+ (aq) + Co
2
+ (aq) -7 Ti
2
+ (aq) + Co
3
+ (aq)
45. The diagram below shows the Born-Haber cycle for the formation of potassium bromide
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K' (g) + e + Br(g)
j K'(g) + e + Y, Br2(g)
t K+ (g) + B( (
- ~ - - - - - - - - - - - - - - - - - - - - - - -
K(g) + y, Br2(g)
g)
622
510
280
90
K(s) + ~ S Br2 (g)
0
KBr(s)
- 392
Which of the followings enthalpy changes can be correct(v deduced from the above
Born-Haber cycle?
l Electron affinity of bromine is -342 kJ mor
1
2 The lattice energy of potassium bromide is- 672 kJ mor
1
3 The enthalpy change for the reaction Br
2
(g) -7 2Br(g) is- 224 kJ
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A B c D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2, and 3are
correct. correct. correct.
46. P
4
0
10
is a solid while P406 is a liquid. Which of the following statement(s) can be used to
explain this observation?
P
4
010 is ionic while P
4
06 is covalent.
2 P
4
0
10
has more electrons than P
4
0
6
3 The size ofP,0
10
is bigger than that of P
4
0
6
47. Which of the following reaction(s) of ammonia involve(s) the lone pair electrons on the
nitrogen atom?
1 Nl-b(g) + HCl(g) -'7 NH4Cl(s)
2 NH
3
(g) + CH
3
l(g) -'7 CH3NH3 +r(s)
3 2NH
3
(l) + 2Na(s) -'7 2NaNH
2
(s) + l-lz(g)
48. Many sunburn ointments contain benzocaine which rlieves the pain caused by sunburn. It
can be made in the laboratory using the following reaction scheme. Which of the following
reagents in these steps is/are correct ?
CH
3
COOH

step I requires hot acidified KMn0
4
solution
2 step 2 requires refluxing with acid catalysed ethanol
3 step 3 requires the reagent lithium tetrahydridoaluminate (LiAlH
4
)
49. Which of the following test(s) below can be used separately to distinguish between the
following hydroxy compounds X andY ?
HO--CHJ (X) HOCH(CHJ)-<Q>-OH (Y)
adding hot aqueous alkaline iodine
2 adding aqueous bromine solution
3 adding hot acidified potassium manganate(Vll) solution
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A B c D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2, and 3 are
correct. correct. correct .
. .
50. Methadone, a narcotic analgesic can be used as a substitute for heroin
From the structure of Methadone above, it can be concluded that Methadone:-
1 gives nitrogen gas with cold nitrous acid
2 turns the red litmus solution to blue
3 gives an orange precipitate when heated with 2,4 dinitrophenylhydrazine
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