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38
Substances were classified into four groups with similar chemical properties.
His classification was unsuccessful because , and a few other compounds were also considered as elements.
39
He arranged the known elements in order of increasing atomic mass. Elements with similar chemical properties were repeated at every eighth element. This was known as the Law of.
This system was inaccurate because the Law of Octaves was obeyed by the first 17 elements only and there were some elements with wrong atomic mass/mass number.
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4 Lothar Meyer (1830-1895) He plotted a graph of .. against for all the known elements.
Na Li Be B Mg Al
Atomic mass
He was successful in showing that the properties of the elements formed a periodic
pattern against their..
5 Dimitri Mendeleev (1834-1907) Arranged the elements in order of ... He grouped the elements according to ... [Elements with similar chemical properties were in the same group]. He left gaps in the table to be filled by .. elements. He was able to predict the properties of undiscovered elements. [e.g : Ekasilicon, Es is predicted by Mendeleev in 1869 was discovered as Germanium, Ge in 1886 ].
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6 Hendry J. G. Moseley (1887-1915) Studied the .. of elements. [Introduced the concepts of proton number of each elements] He concluded that should be used as the basis for the periodic changes of chemical properties of elements instead of the atomic mass.
Arrangement of Elements in the Periodic Table Elements in the Periodic Table are arranged in an .. order of .., ranging from 1 to 112. Elements with .. are placed in the same vertical column called ..
Vertical
column
Horizontal row
Lanthanides Actinides
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Activity 1:In the table below, write : (a) (b) Group 1 to 18 Period number 1 to 7 the symbol of each element from Hydrogen to Calcium He
(c)
H
Lanthanides Actinides The number of valence electrons in an atom decides the .. of an element in the Periodic Table. Example : The proton number of sodium, Na is 11. The electron arrangement of sodium atom is 2.8.1 The valence electron of sodium is 1 Sodium is placed in Group 1 in a Periodic Table. For elements with 1 and 2 valence electrons, the group number of the element is the number of valence electrons in its atom. For elements with 3 to 8 valence electrons, the group number of the element is the number of valence electrons in its atom plus ten (+10) [ valence electron + 10 ] Example : The proton number of chlorine is 17 The electron arrangement of chlorine is 2.8.7 The valence electrons of chlorine is 7 Chlorine is placed in Group 17 [ 7 +10 ]
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Elements from Period 3 Complete the following table. Element Na Mg Al Si P S Cl Ar Proton number 11 12 13 14 15 16 17 18 2.8.7 7 17 2.8.3 3 13 Electron arrangement 2.8.1 Valence electron 1 Group 1 The position in the period of an element in the Periodic Table is determined by the number of Group : ..10 Valence electrons + occupied/filled with electrons in the atom of that element.
The period number of an element is the number of shell occupied with electrons in its atom. Example : The proton number of magnesium is 12 The electron arrangement of magnesium is 2.8.2 There are 3 shells occupied with electrons in magnesium atom. The period number of magnesium in the Period Table is 3 Activity 2:Complete the following table : Element Proton number Electron arrangement Number of valence electron Group Number of shells occupied with electrons Li 3 2.1 C 6 O 8 Ne 10 Mg 12 2.8.2 Al 13 2.8.3 3 13 3 P 15 Cl 17 K 19 Ca 20
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Period Specific name of certain groups : Group 1 2 3 to 12 17 18 Specific name Alkali metal # Alkali-earth metal Transition element # Halogen # Noble gas #
# The important groups that will be studied from the aspect of physical and chemical properties. Activity 3:1 Write the electron arrangement for each element in the following Periodic Table. Symbol of element : [ Standard form ]
A
1 PERIOD 2 1 H 1 . 7 Li 3 GROUP 1 2 9 Be 4
.number
X
Z
..number 18 13 11 B 5 27 Al 13 14 12 C 6 28 Si 14 15 14 N 7 31 P 15 16 16 O 8 32 S 16 17 19 F 9 35 Cl 17 4 He 2 20 N e 10 40 Ar 18
... .. 23 24 Na Mg 11 12 .. 39 K 19 .. .. 40 Ca 20 .. 3 4 5 6 7 8 9 1 0 1 1 1 2
TRANSITION ELEMENTS
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Complete the statement and answer the following questions based on the table below. Nucleon number 9 31 35
Element A B C
Number of neutrons 4 16 18
. . The electron arrangement of atom A is.. The valence electron of atom A is .. Atom A is in Group ..and Period .. (ii) Atom B is in Group ..and Period .. (iii) A student states that atom C is in Group 17 and Period 3 in Periodic Table of Element. Is the statement true or false? Explain your answer. ........ . . . Advantages of Grouping Elements in the Periodic Table The systematic arrangement of elements in the Periodic Table helps us to study the elements systematically, especially in their and .. properties. Elements with the .. number of . are placed in the same Group because they have the same chemical properties. Elements are arranged systematically in the Periodic Table in the order of increasing proton number which enable chemists to study, understand and remember : (a) the chemical and physical properties of all the elements and compounds in an orderly manner. (b) the properties of elements and their compounds are predicted based on the position of elements in the Periodic Table. (c) the relationship between the elements from different groups can be known.
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C GROUP 18 ELEMENTS [Refer to Text Book, page 64] 1. Group 18 elements consists of ., .., .., , . and .. 2. These elements are known as gases.
Krypton, Kr
Increases
Increases
Increases
The atomic size as the number of shells in the atom increases from Helium
to Radon. The melting and boiling points is very low. because the atoms of Noble gases are attracted by weak force. Less energy is required to overcome it. However, the melting and boiling points . when going down Group 18. because the atomic size of each element down the group,
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the forces of. between the atoms of each element become stronger thus more is required to the stronger forces of .. . during melting or boiling. The density of an element .. down the group because the atomic mass of each element is The Inert Property of Group 18 Elements All Noble gases are inert which means .. . Noble gases and the electron arrangement of their atoms. Noble gas Helium Neon Argon Krypton Xenon Radon Electron arrangement 2 2.8 2.8.8 2.8.18.8 2.8.18.18.8 2.8.18.32.18.8
Helium has two valence electrons. This is called a . electron arrangement. Other Noble gases have eight valence electron called the .. electron arrangement. These electron arrangements are very stable. That is why Noble gases exist as monoatomic gases and are chemically unreactive; because they achived the stable octet/duplet electron arrangement. Uses of Group 18 Elements Noble gas Helium, He Neon, Ne Argon, Ar Krypton, Kr Xenon, Xe Radon, Rn Uses
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GROUP 1 ELEMENTS
2. Group 1 are also known as which react with water to form alkaline
solutions.
3. Write the symbols in the boxes for all the elements in Group 1 in the Periodic Table of
Elements :
4. Write the proton number and electron arrangement for all elements in Group 1.
Elements Li Na K Rb Cs Fr Proton number 3 Electron arrangement Density / g cm-3 0.534 0.971 0.862 1.530 1.973 Boiling point / 0 C 1360 900 777 505
All Group 1 elements have valence electron in their outermost occupied shells.
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Change in the physical properties going down the group : The atomic size because the number of shells increases. The density because the increasing in atomic mass is faster than the increasing in atomic volume/size. The melting and boiling points because when the atomic size increases, the metal bond between the metal atoms becomes weaker. The hardness of the metal .
6. Chemical Properties of Group 1 elements : (a) React with water to produce alkaline metal hydroxide solutions [colourless
solutions] and released gas.
Metal G1 + H2O metal hydroxide + Hydrogen gas Red litmus paper turns blue
metal*
water
Metal*
Li
The solution formed; turns .. litmus paper to ... Sodium moves . on water surface with sound.
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Reactivity increases
Na The .. solution formed; turns . litmus paper to .. Potassium moves . on water surface with . sound. K The . solution formed; turns . litmus paper to ..
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Chemical equation : # Chemical equation 2Li Lithium + 2H2O Water hydroxide 2LiOH Lithium + H2 Hydrogen gas
(b) React with oxygen gas to produce metal oxides [white solids]. Metal G1 + O2 metal oxide
Gas jar spoon
Gas jar
White fume
Metal*
Li
Na
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A solid is produced. Chemical equation : Example: 4Li Lithium + O2 Oksigen gas + 4K + O2 O2 2Li2O Lithium Oxide 2Na2O
(c) React with chlorine gas to produce metal . [white solids]. Metal G1 + Cl2 metal chloride
Gas jar spoon
Gas jar
White fume
Elements
Observations Lithium burns with a .. flame. A . solid is produced. Sodium burns .. with a flame. A . solid is produced. Potassium burns ... with a ... flame. A solid is produced.
Li
Na
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Group 1 elements also react with bromine gas to form metal bromides. Complete the chemical equation following. 2Li Na K + + + Br2 Br2 Br2 2LiBr .. ..
Alkali metals have one valence electron in their outermost occupied shells. Each of them reacts by donating one electron from its outermost occupied shell to form an ion with a charge of +1, thus achieving the stable electron arrangement of the atom of noble gas. Example : Na 2.8.1 Na+ 2.8 + e K 2.8.8.1 K+ 2.8.8 + e
the number of shells occupied with electrons are the atomic size of atoms are
the single valence electron becomes away from the nucleus. the force of attraction between the nucleus and valence electron (nuclei attraction) becomes
electron to achieve the stable octet/duplet electron arrangement of the atom of Noble gases.
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Activity 4 :1. Table below shows the electron arrangements of element W, X and Y. Arrange the elements in ascending order of reactivity. Element W X Y Proton Number 11 3 19 Electron Arrangement 2.8.1 2.1 2.8.8.1
b
X
a
Answer : .
[ Size of atom increases when the number of shells filled with electrons increases] Safety precautions in handling Group 1 elements Alkali metals are very reactive. Safety precautions must be taken when handling alkali metals. The elements must be stored in paraffin oil in bottles Do not hold alkali metals with your bare hands Use forceps to take them Wear safety goggles Wear safety gloves Use a small piece of alkali metal when conducting experiments
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GROUP 17 ELEMENTS
1.
F
Fluorine
Cl
Chlorine
Br
Bromine
I
Iodine
At
Astatine
2. Group 17 elements are known as .. 3. Halogens exist as diatomic molecules.{ F2, Cl2, Br2, I2 } 4. Halogens have .. valence electrons. 5. All Group 17 elements are non-metals.
6. Write the symbol in the boxes for all the element in Group 17 in the Periodic Table of Elements : 17
7. Elements F Cl Br I At
Going down the : Write the proton number and electron arrangementgroup : Proton number Electron arrangement Proton number : .... Number of protons : Number of electrons : 35 53 85 2.8.18.7 2.8.18.18.7 2.8.18.32.18.7 Number of shells occupied with electrons : ... Atomic size : Molecular size : ..
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8.
(i)
Physical properties of elements in Group 17 : Complete the table below : Symbo l Proton Number 9 17 35 53 2.8.18.7 2.8.18.18.7 Electron Arrangemen t Melting point / o C -220 -101 -7 114 Boilin g point / o C -188 -34 59 184 Physical state at room Temp.
Element
Colour
(ii)
Physical state of halogens at room temperature, 25 oC : Fluorine and chlorine are ............... , bromine is a ..................... and iodine is a ...............
(iii) (iv)
The colour of the elements becomes .. going down the group. Halogen have melting and boiling points because their molecules are attracted to each other by . inter-molecular forces. (Van der Waals force : force of attraction between molecules).
(v)
When going down the group, the melting and boiling points increases / decreases. This is because : the molecular size .. Forces of attraction between molecules becomes Need . energy to overcome the forces of attraction between molecules. the melting and boiling points ..
9.
Chemical Properties
(a)
In general :
Br2
H2O
HBr +
HOBr
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Cl2
H2O
+ Hydrochloric acid
Bromine water
water
Heat
Br2
+ Hypobromus acid
Iodine (solid)
water
Heat
I2
+ Hypoiodus acid
(b)
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Potassium manganate(VII)
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2Fe
3Cl2
Fe
Fe
I2 Iron(III) .....................
Alkali
(c)
Halogen reacts with sodium hydroxide, NaOH solution to produce , .. and water.
Example :
Chlorine gas Sodium hydroxide solution
2KOH
+ Cl2
KCl
KOCl
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57 +
Halogens have seven valence electrons in their outermost occupied shells. Each of them reacts by receiving one electron in its outermost occupied shell to form an ion with a charge of -1, or by sharing a pair of electrons thus achieving the stable electron arrangement of the atom of noble gas. Example :
F
2.7
F2.8
Cl
2.8.7
Cl2.8.8
Complete the electron arrangement for the atoms and molecule of flourine below :
Fluorine
Exists as diatomic molecules [ 2 atoms of elements sharing a pair of its valence electron ] to achive the stable octet electron arrangement.
Chemical properties of all elements are . because the number of valence electrons are the same and attain/achive the Noble gas arrangement in a similar way.
10.
Reactivity of Group 17 elements : When going down Group 17, the proton number are the number of shells occupied with electrons are the atomic size of atoms are the outermost occupied shell of each halogen atoms becomes away from the nucleus.
the nuclei attraction forces to attract one electron into the outermost occupied shell by the nucleus becomes it is for the atom to attract one electron to achieve stable octet/duplet electron arrangement of the atom of Noble gas.
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Activity 5 :1
The strength of halogen atom to attract electron decrease from Fluorine to Astatine [Electronegativity decreases] this causes the reactivity down the group.
Chlorine, bromine and iodine have similar chemical properties. Do you know WHY???
Chlorine, bromine and iodine have . number of valence electrons. When halogens take part in chemical reactions, their atom always gain . electron to achieve . electron arrangement / a stable electron arrangement.
The reactivity of halogens decrease down the group. Do you know WHY??? The explanation
The atomic size . down the group. The distance of the outermost shell becomes from the nucleus. The force of attraction of the nucleus on the electrons of the outermost shell
..
Why fluorine atom forms a negative ion more easily than chlorine? The explanation
The atomic size of flourine is . than chlorine. The between nucleus of fluorine atom and valence
electrons are . Fluorine atom can electron easily.
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Safety precautions in handling Group 17 elements 1. The vapour of flourine, chlorine and bromine are
1.
Elements X, Y and Z are in the same group in the Periodic Table of Elements. Element Proton number X 9 Y 17 Z 35
(a) What is the valence electron of the elements X, Y and Z? (b) Which group in the periodic table can you find the elements X, Y and Z? (c) Element Y can react with water. State two chemical properties of the solution produced? (d) Write an equation for the reaction between element Z and hot iron. 2. (a) List all halogen elements from the top to the bottom of Group 17. . (b) Which are the most reactive and least reactive halogen?
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3.
Write the chemical equations for the following reaction : (a) (b) (c) Chlorine with water bromine with iron : ... : ...
4.
Explain the changes to the reactivity of halogens when going down Group 17. The atomic size of halogen .. down the group. The distance of the outermost shell becomes from the nucleus. Therefore, the force of attraction by the nucleus on the electrons in the outermost shell becomes
5.
Explain the changes to the electronegativity of halogens when going down Group 17. The atomic size of halogen .. down the group. The distance of the outermost shell becomes from the nucleus. Therefore, the force of attraction by the nucleus on the electrons in the outermost shell becomes
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ELEMENTS IN A PERIOD Properties of elements in Period 3 Complete the table below. Element of Period 3 Proton number Electron arrangement Valence electron [ Group ] Atomic size Physical state at room temperature Electronegativity solid Na 11 2.8.1 1 [1] [ ] [ ] [ ] [ ] [ ] [ ] Mg 12 Al 13 Si 14 P 15 S 16 Cl 17 Ar 18 2.8.8 [ ]
Electropositivity
1.
The proton number increases by unit from one element to the next element. 2. All the atoms of the elements have shells occupied/filled with electrons.
3.
The number of valence electrons in each atom increases from to .. 4. The atomic radius/size of atom of the elements ..
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This is also due to the ..of the nuclei attraction force on the in the outermost shell and the in atomic size.
6.
All the elements in Period 3 exist as .. except chlorine and argon which are ACID-BASE properties of oxides of elements in Period 3. P4O10
Na2O
MgO
Al2O3
SiO2
SO2
Cl2O7
(oxides)
.. oxide
(. oxides)
Basic oxides reacts with acids to form . and .. Example : Na2O + 2HNO3 2NaNO3 + H2O
Acidic oxides reacts with alkalis to form . and .. Example : SO2 + 2NaOH Na2SO3 + H2O
Amphoteric oxides can react with both acids and alkalis. Na & Mg are ., Al is ., Si, P, S & Cl are .
The elements change from metals to metalloid and finally to non-metals across the period. Uses of semi-metals (metalloids) in Industry
Semiconductors are used to make diodes and transistors that widely used in the
making of microchips for the manufacture of electrical and microelectronic equipments such as computers, mobile phones, televisions, digital cameras and video recorders.
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SEMI-METALS e.g : silicon and germanium used to make . and . widely used in the making of ..
for the manufacture of : ..and .. Activity 7 :1 Table below shows the symbol of element, proton number and atomic radius of elements in Period 3. Element Proton number Atomic radius Electron arrangement (a) Complete the electron arrangement in the above table. (b) When crossing the period from left to right, the atomic size decreases. Explain why. Na 11 0.156 Mg 12 0.136 Al 13 0.125 Si 14 0.117 P 15 0.111 S 16 0.104 Cl 17 0.099 Ar 18 -
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(c) Write the symbol of elements for metal, metalloid and non-metal. Metal 1. . 2. . 3. . Metalloid 1. Non-metal 1. . 2. 3. 4.
(d)
Table below shows the symbol of oxide compound when the elements in period 3 are reacted with oxygen. Na2O MgO Al2O3 P4O10 SO2
Classify the oxides into basic oxide, acidic oxide and amphoteric oxide. Basic oxide Acidic oxide Amphoteric oxide
TRANSITION ELEMENTS 1. Elements from Group . to Group . in the Periodic Table. [ Between Group . to Group .] 2. All transition elements are ., thus, these elements have the following properties :
. melting and boiling points solids with surfaces. .. densities ductile good .. of heat and malleable electricity high tensile strength
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Different Oxidation Numbers Transition elements can form ions with different oxidation numbers when forming compounds. Transition Element Iron, Fe Copper, Cu Nickel, Ni Oxidation Number +2 +3 +1 +2 +2 +3 Ni3+ Copper(I) ion Cu2+ Ni(NO3)2 Ni(NO3)3 Name of ion Iron(II) ion Ionic symbol Fe2+ Fe3+ Cu2O Copper(II) oxide Example of compound Formula Name FeCl2 Iron(II) chloride Iron(III) chloride
Coloured Ions or Compounds The colours of some aqueous solutions of ions of transition elements : Name of Ion of transition element Chromate ion Dichromate ion Manganate(VII) ion Iron(II) ion Iron(III) ion Copper(II) ion Cobalt(II) ion Manganese(II) ion Chromium(III) ion Nickel(II) ion Examples of some precious stones and the transition elements present which give their distinctive colours : Precious Colour Transition Element Formula of Ion of transition element Colour in aqueous solution
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Act as Catalysts Transition elements or its compounds can act as catalysts in certain reactions. Catalysts are chemicals which can increase the rate of a reaction. Example : Industrial Process Haber Process Contact Process Ostwald Process Product Transition element used as catalyst
Fe
FIGURE 1 Based on Figure 1 above, answer the following questions :
(a)
(b) (c)
In figure above, mark X in the boxes for all the transition element. State one specific characteristic of transition element.
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(d)
(e)
Write the chemical equation for the reaction between aluminium and oxygen gas.
Based on the above informations, which gas is more suitable to be used in meteorological balloons? Give one reason.
Table 2 shows the proton numbers of element P, Q, R, S and T. Element P Q R S T Proton number 3 6 9 11 17 TABLE 2 (a) (b) Complete the electron arrangement for all elements above. In which Group is element S located in the Periodic Table of Elements? ...... (b) State two elements in Table 2 that shows the same chemical properties.Explain the answer. ... Electron arrangement
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(c)
(i)
Between elements P and S, which one is more reactive? Explain your answer. .. .. .. .. ..
(d)
END OF CHAPTER 4
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